| Common Name: | TOUGH GUY GRAFFITI & SPRAY PAINT REMOVER |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 8/30/2007 |
| SDS Format: | No Format Specified |
| Item Number(s): | 2DBX9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MATERIAL SAFETY DATA SHEET
HMIS(R*):
HEALTH 2
FLAMMABILITY 4
REACTIVITY 0
PERSONAL PROTECTION B
IDENTITY: TOUGH GUY GRAFFITI & SPRAY PAINT REMOVER
PART NUMBER: 2DBX9
NOTE:
BLANK SPACES ARE NOT PERMITTED. IF ANY ITEM IS NOT APPLICABLE, OR NO
INFORMATION IS AVAILABLE, THE SPACE MUST BE MARKED TO INDICATE THAT.
| SECTION 1: COMPANY IDENTIFICATION |  |
MANUFACTURED FOR: W.W. GRAINGER, INC.
ADDRESS (NUMBER, STREET, CITY, STATE, AND ZIP CODE):
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045
EMERGENCY TELEPHONE NUMBER: 1-800-228-5635
TELEPHONE NUMBER FOR INFORMATION: 1-847-535-5400
SIGNATURE OF PREPARER (OPTIONAL):
| SECTION 2: INGREDIENTS/IDENTITY INFORMATION | |
COMPONENTS CAS NO. OSHA ACGIH- OTHER LIMITS %
(CHEMICAL IDENTITY, PEL TLV RECOMMENDED (OPT.)
COMMON NAME(S))
ACETONE 67-64-1 1000 500 15 - 40%
PPM PPM
TOLUENE 108-88-3 200 50 STEL: 150 PPM 10 - 30%
PPM PPM
METHOXY 107-98-2 NONE 100 STEL: 150 PPM 7 - 13%
ISOPROPANOL PPM
ISOBUTANE 75-28-5 800 800 7 - 13%
PPM PPM
DIMETHYL ADIPATE 627-93-0 NONE NONE 7 - 13%
DIMETHYL GLUTARATE 1119-40-0 NONE NONE 7 - 13%
PPG-2 METHYL ETHER 34590-94-8 100 100 STEL: 150 PPM 3 - 7%
(SKIN DESIGNATION) PPM PPM
D-LIMONENE 5989-27-5 NONE NONE 30 PPM (MANU.) 3 - 7%
(R-p-MENTHA-1,
8-DIENE)
PROPANE 74-98-6 1000 ASPHYXIANT 3 - 7%
PPM
ANY SUBSTANCE LISTED AS HAZARDOUS BY THE STATES OF CALIFORNIA, FLORIDA,
ILLINOIS, MICHIGAN, NEW JERSEY, OHIO, PENNSYLVANIA OR TEXAS IS DESCRIBED
ABOVE IF KNOWN PRESENT IN REGULATED CONCENTRATIONS.
| SECTION 3: HAZARDS IDENTIFICATION | |
ROUTE(S) OF ENTRY:
EYES?: YES
INHALATION?: YES
SKIN?: YES
INGESTION?: YES
ACUTE HEALTH HAZARDS:
DANGER. EXTREMELY FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL OR FATAL IF
SWALLOWED. ASPIRATION HAZARD. CAUSES EYE IRRITATION. MAY BE HARMFUL IF
INHALED. MAY CAUSE SKIN IRRITATION. MAY BE HARMFUL IF ABSORBED THROUGH
SKIN. CONTENTS UNDER PRESSURE.
CHRONIC HEALTH HAZARDS:
REPEATED OR PROLONGED OCCUPATIONAL OVEREXPOSURE CAN CAUSE DERMATITIS AND
PAINTER'S SYNDROME.
CARCINOGENICITY:
CHEMICAL: NONE
OSHA: NO
NTP: NO
IARC: NO
SIGNS AND SYMPTOMS OF EXPOSURE:
REDNESS, TEARING, STINGING OR BURNING IN EYES. REDNESS, DRYNESS OR
IRRITATION OF SKIN. DROWSINESS, DIZZINESS, LOSS OF COORDINATION, NAUSEA,
VOMITING OR FATIGUE. IRRITATION OF NOSE, THROAT OR DIGESTIVE TRACT.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
PRE-EXISTING SKIN, HEART, LIVER AND KIDNEY DISORDERS MAY BE ADVERSELY
AFFECTED IF EXPOSURES OCCUR. FOLLOW GOOD CHEMICAL HYGIENE PRACTICES TO
AVOID THIS HAZARD.
| SECTION 4: EMERGENCY AND FIRST AID PROCEDURES | |
EYES:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES LIFTING
EYELIDS TO INSURE COMPLETE REMOVAL. SEE A PHYSICIAN IMMEDIATELY.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED BY A PHYSICIAN. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON. CALL A PHYSICIAN OR POISON CONTROL
CENTER IMMEDIATELY.
INHALATION:
GET TO FRESH AIR. IF BREATHING HAS STOPPED, QUALIFIED PERSONNEL SHOULD
ADMINISTER ARTIFICIAL RESPIRATION.
SKIN:
IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE
REMOVING CONTAMINATED CLOTHING. IF IRRITATION ARISES AND PERSISTS, CALL A
PHYSICIAN. LAUNDER CONTAMINATED CLOTHING AND SHOES BEFORE REUSE.
| SECTION 5: FIRE FIGHTING MEASURES | |
USA FLAME PROJECTION TEST (ASTM D-3065):
>18", FLASHBACK: EXTREMELY FLAMMABLE
FLAMMABLE LIMITS: NO DATA
LEL: NO DATA
UEL: NO DATA
EXTINGUISHING MEDIA:
USE CARBON DIOXIDE, DRY CHEMICAL, OR FOAM. TREAT AS AN OIL FIRE. BURNING
LIQUID MAY FLOAT ON WATER.
SPECIAL FIRE FIGHTING PROCEDURES:
KEEP CONTAINERS COOL AND VAPORS DOWN WITH WATER SPRAY. PREVENT RUNOFF FROM
ENTERING SEWERS AND PUBLIC WATERWAYS. WEAR SELF-CONTAINED BREATHING
APPARATUS (SCBA) IN CHEMICAL FIRES.
HAZARDOUS PRODUCTS OF COMBUSTION:
OXIDES OF CARBON AND VARIOUS HYDROCARBONS.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
AEROSOL CONTAINER (PRESSURIZED) MAY BURST IF HEATED OVER 120 DEG. F.
FLAMMABLE CONTENTS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
SMALL SPILL:
WIPE UP SMALL RELEASES WITH A DRY ABSORBENT CLOTH OR OTHER ABSORBENT
MATERIAL.
LARGE SPILL:
ABSORB LIQUID WITH VERMICULITE, ABSORBENT CLOTH, OR OTHER ABSORBENT
MATERIAL. PREVENT MATERIAL FROM ENTERING SEWERS OR DRAINS. VENTILATE AREA
AND BLOCK TRAFFIC. TRANSFER CONTAMINATED MATERIAL INTO SUITABLE CONTAINER
FOR PROPER DISPOSAL.
| SECTION 7: HANDLING AND STORAGE | |
HANDLING:
DO NOT USE AROUND IGNITION SOURCES SUCH AS HEAT, SPARKS, OPEN FLAME,
WELDING ARCS, ETC. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE. DO NOT SWALLOW. WASH THOROUGHLY AFTER
HANDLING. AVOID INHALING MIST OR VAPORS. DO NOT DELIBERATELY CONCENTRATE
AND INHALE VAPORS. USE WITH ADEQUATE VENTILATION. DIRECT SPRAY AWAY FROM
FACE.
STORAGE:
FOLLOW LABEL DIRECTIONS CAREFULLY. KEEP OUT OF REACH OF CHILDREN. STORE IN
A COOL (UNDER 120 DEG. F) DRY LOCATION AWAY FROM HEAT, SPARKS, OPEN FLAME,
AND DIRECT SUNLIGHT. REPLACE CAP WHEN NOT IN USE. DO NOT PUNCTURE OR
INCINERATE CONTAINER.
| SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EYE PROTECTION: YES, USE GOGGLES OR APPROVED SAFETY GLASSES (ANSI Z87).
SKIN PROTECTION: YES, IMPERVIOUS.
RESPIRATORY PROTECTIONS:
NOT USUALLY NECESSARY. USE WITH ADEQUATE VENTILATION. USE NIOSH/MSHA
APPROVED RESPIRATOR IF PELS OR TLVS ARE EXCEEDED.
ENGINEERING CONTROLS:
VENTILATION NOT USUALLY NECESSARY BUT SHOULD BE PROVIDED IN THE EVENT OF
OVEREXPOSURE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE AND ODOR:
CLEAR COLORLESS LIQUID/GEL WITH AN AROMATIC SOLVENT AND CITRUS ODOR IN AN
AEROSOL CAN.
pH: N/A
SPECIFIC GRAVITY (70 DEG. F): 0.888
BOILING POINT: 205 DEG. F
MELTING POINT: NO DATA
EVAPORATION RATE (BUTYL ACETATE = 1) NO DATA
PRESSURE (PSIG. @ 70 DEG. F): 50 +/- 10
VAPOR DENSITY (AIR = 1): >1
SOLUBILITY IN WATER: INSOLUBLE
VOLATILE ORGANIC COMPOUNDS (VOCS):
405.76 GRAMS PER LITER OR 49.98% BY WEIGHT VOC'S
| SECTION 10: STABILITY AND REACTIVITY | |
HAZARDOUS POLYMERIZATION:
THIS PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS:
OXIDES OF CARBON AND VARIOUS HYDROCARBONS.
CHEMICAL STABILITY: STABLE
INCOMPATIBILITY (MATERIALS TO AVOID): STRONG OXIDIZING AND REDUCING AGENTS.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
NO DATA
| SECTION 12: ECOLOGICAL INFORMATION | |
NO DATA
| SECTION 13: DISPOSAL CONSIDERATION | |
DISPOSAL METHOD:
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE, AND FEDERAL
REGULATIONS.
RCRA WASTE INFORMATION:
IF THIS PRODUCT BECOMES A WASTE, IT WOULD BE A HAZARDOUS WASTE (D001) AS
DEFINED BY RCRA (40 CFR 261). HOWEVER THE WASTE SHOULD BE PROPERLY
CHARACTERIZED TO EVALUATE WHETHER ITS COMPOSITION HAS BEEN MODIFIED PRIOR
TO DISPOSAL.
| SECTION 14: TRANSPORT INFORMATION | |
DOT INFORMATION - 49 CFR 172.101:
PROPER SHIPPING DESCRIPTION: CONSUMER COMMODITY
HAZARD CLASS: ORM-D
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION:
PROPER SHIPPING DESCRIPTION: AEROSOLS
HAZARD CLASS: 2
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
AIR TRANSPORTATION:
PROPER SHIPPING DESCRIPTION: AEROSOLS, FLAMMABLE
HAZARD CLASS: 2.1
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
MARINE POLLUTANTS: NONE
| SECTION 15: REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
TSCA (TOXIC SUBSTANCES CONTROL ACT) STATUS:
ALL INGREDIENTS ARE ON THE TSCA INVENTORY OR ARE NOT REQUIRED TO BE LISTED
ON THE TSCA INVENTORY.
CERCLA RQ - 40 CFR 302.4 (A):
TOLUENE (CAS: 108-88-3) 1000 LBS
ACETONE (CAS: 67-64-1) 5000 LBS
SARA 313 COMPONENTS - 40 CFR 372.65:
TOLUENE (CAS: 108-88-3) 17%
STATE AND LOCAL REGULATIONS:
CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL (TOLUENE) KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
| SECTION 16: ADDITIONAL INFORMATION | |
DATE PREPARED: 08/30/07
WARNING!
THE USE OF THIS PRODUCT IS BEYOND THE CONTROL OF THE MANUFACTURER;
THEREFORE, NO GUARANTEE, EXPRESSED OR IMPLIED, IS MADE AS TO THE EFFECTS OF
SUCH OR THE RESULTS TO BE OBTAINED IF NOT USED IN ACCORDANCE WITH
DIRECTIONS OR ESTABLISHED SAFE PRACTICE. THE USER MUST ASSUME ALL
RESPONSIBILITY, INCLUDING INJURY OR DAMAGE, RESULTING FROM ITS MISUSE AS
SUCH, OR IN COMBINATION WITH OTHER MATERIALS. THE MANUFACTURER WARRANTS
ONLY THAT THIS PRODUCT MEETS THE MANUFACTURER'S SPECIFICATIONS FOR SUCH
PRODUCT. THIS WARRANTY IS IN LIEU OF ALL OTHER WARRANTIES, EXPRESS OR
IMPLIED, AS TO DESCRIPTION , QUALITY, MERCHANTABILITY. FITNESS FOR ANY
PARTICULAR PURPOSE, PRODUCTIVENESS, OR ANY OTHER MATTER, OF THIS PRODUCT.
THE MANUFACTURER SHALL BE IN NO WAY RESPONSIBLE FOR THE IMPROPER USE OF
THIS PRODUCT. THE SOLE AND EXCLUSIVE REMEDY AGAINST THE MANUFACTURER FOR
BREACH OF WARRANTY SHALL BE REIMBURSEMENT OF THE PURCHASE PRICE OF THE
PRODUCT IN THE EVENT THAT A DEFECTIVE CONDITION OF THE PRODUCT SHALL BE
FOUND TO EXIST. NO OTHER REMEDY (INCLUDING BUT NOT LIMITED TO INCIDENTAL OR
CONSEQUENTIAL DAMAGES FOR INJURY TO PERSON OR PROPERTY OR ANY OTHER
INCIDENTAL OR CONSEQUENTIAL LOSS) SHALL BE AVAILABLE.