| Common Name: | ROUND BLUE SPICE TOUGH GUY (10A684) |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 2/2/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 10A684 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ISSUING DATE: NO DATA AVAILABLE
REVISION DATE: 02-FEB-2015
REVISION NUMBER: 1
UL
THE SUPPLIER IDENTIFIED BELOW GENERATED THIS SDS USING THE UL SDS TEMPLATE.
UL DID NOT TEST, CERTIFY, OR APPROVE THE SUBSTANCE DESCRIBED IN THIS SDS,
AND ALL INFORMATION IN THIS SDS WAS PROVIDED BY THE SUPPLIER OR WAS
REPRODUCED FROM PUBLICALLY AVAILABLE REGULATORY DATA SOURCES. UL MAKES NO
REPRESENTATIONS OR WARRANTIES REGARDING THE COMPLETENESS OR ACCURACY OF
THE INFORMATION IN THIS SDS AND DISCLAIMS ALL LIABILITY IN CONNECTION WITH
THE USE OF THIS INFORMATION OR THE SUBSTANCE DESCRIBED IN THIS SDS. THE
LAYOUT, APPEARANCE AND FORMAT OF THIS SDS IS (C) 2014 UL LLC. ALL RIGHTS
RESERVED.
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT IDENTIFIER:
PRODUCT NAME: ROUND BLUE SPICE TOUGH GUY (10A684)
OTHER MEANS OF IDENTIFICATION:
SYNONYMS: NONE
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: TOILET/URINAL CARE PRODUCT - NON-AEROSOL
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER NAME: W.W GRAINGER
SUPPLIER ADDRESS:
100 GRAINGER PARKWAY
LAKE FOREST, IL 60045
SUPPLIER PHONE NUMBER: 800-472-4643
EMERGENCY TELEPHONE NUMBER: 800-228-5635
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
SKIN IRRITATION: CATEGORY 1
EYE IRRITATION: CATEGORY 1
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
EMERGENCY OVERVIEW:
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
MAY CAUSE SKIN IRRITATION
MAY CAUSE EYE IRRITATION
EXCLAMATION MARK
APPEARANCE: BLUE
PHYSICAL STATE: SOLID
ODOR: SPICE
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
REMOVE THE CONTAMINATED CLOTHING AND WASH.
PRECAUTIONARY STATEMENTS - RESPONSE:
SPECIFIC TREATMENT (SEE SUPPLEMENTAL FIRST AID INSTRUCTIONS ON THIS LABEL)
EYES:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING IF IRRITATION PERSISTS CONSULT A
DOCTOR/PHYSICIAN.
SKIN:
IF ON SKIN:
NO ADVERSE REACTION EXPECTED. WASH WITH SOAP AND WATER
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION
INGESTION:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING
PRECAUTIONARY STATEMENTS - STORAGE:
STORE LOCKED UP
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
PRECAUTIONARY STATEMENTS - DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
UNKNOWN TOXICITY:
25.8391% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
OTHER INFORMATION:
TOXIC TO AQUATIC LIFE
REPEATED OR PROLONGED SKIN CONTACT MAY CAUSE ALLERGIC REACTIONS WITH
SUSCEPTIBLE PERSONS
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO WEIGHT-% TRADE SECRET
ETHYLENE OXIDE-NONYLPHENOL POLYMER 9016-45-9 40 - 70 *
MAIZE STARCH 9005-25-8 10 - 30 *
PHOSPHORIC ACID 7664-38-2 3 - 7 *
SUBTILISINS (PROTEOLYTIC ENZYMES) 9014-01-1 1 - 5 *
DIDECYLDIMETHYLAMMONIUM CHLORIDE 7173-51-5 1 - 5 *
ETHANOL 64-17-5 0.1 - 1 *
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE:
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE. IMMEDIATE MEDICAL
ATTENTION IS REQUIRED.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. KEEP EYE WIDE OPEN WHILE RINSING. REMOVE CONTACT LENSES,
IF PRESENT AND IF IRRITATION PERSISTS CONSULT A DOCTOR/PHYSICIAN.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER FOR AT LEAST 15 MINUTES.
MAY CAUSE AN ALLERGIC SKIN REACTION. IN THE CASE OF SKIN IRRITATION OR
ALLERGIC REACTIONS SEE A PHYSICIAN.
INHALATION:
REMOVE TO FRESH AIR. GET MEDICAL ATTENTION IMMEDIATELY IF SYMPTOMS OCCUR.
INGESTION:
RINSE MOUTH IMMEDIATELY AND DRINK PLENTY OF WATER. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. CALL A PHYSICIAN.
SELF-PROTECTION OF THE FIRST AIDER:
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. WEAR PERSONAL PROTECTIVE CLOTHING (SEE SECTION 8).
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MOST IMPORTANT SYMPTOMS AND EFFECTS:
BURNING SENSATION. ITCHING. RASHES. HIVES.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. MAY CAUSE SENSITIZATION OF SUSCEPTIBLE PERSONS.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA:
CAUTION: USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
THE PRODUCT CAUSES BURNS OF EYES, SKIN AND MUCOUS MEMBRANES. THERMAL
DECOMPOSITION CAN LEAD TO RELEASE OF IRRITATING GASES AND VAPORS. PRODUCT
IS OR CONTAINS A SENSITIZER. MAY CAUSE SENSITIZATION BY INHALATION AND SKIN
CONTACT. IN THE EVENT OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
UNIFORM FIRE CODE:
SENSITIZER: SOLID
IRRITANT: SOLID
HAZARDOUS COMBUSTION PRODUCTS: CARBON OXIDES.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NO.
SENSITIVITY TO STATIC DISCHARGE: NO.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR. WEAR SELF
CONTAINED BREATHING APPARATUS FOR FIRE FIGHTING IF NECESSARY.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. ENSURE ADEQUATE VENTILATION.
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
OTHER INFORMATION: REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8. PREVENT FURTHER
LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
PICK UP AND TRANSFER TO PROPERLY LABELED CONTAINERS. USE PERSONAL
PROTECTIVE EQUIPMENT AS REQUIRED. COVER POWDER SPILL WITH PLASTIC SHEET OR
TARP TO MINIMIZE SPREADING AND KEEP POWDER DRY. AVOID GENERATION OF DUST.
CLEAN CONTAMINATED SURFACE THOROUGHLY. SOAK UP WITH INERT ABSORBENT
MATERIAL. DAM UP. SWEEP UP AND SHOVEL INTO SUITABLE CONTAINERS FOR
DISPOSAL. AFTER CLEANING, FLUSH AWAY TRACES WITH WATER.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. DO NOT EAT, DRINK OR SMOKE
WHEN USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
STORE LOCKED UP.
KEEP OUT OF THE REACH OF CHILDREN.
INCOMPATIBLE PRODUCTS: NONE KNOWN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
MAIZE STARCH TWA: 10 MG/M3 TWA: TWA:
9005-25-8 15 MG/M3 10 MG/M3
TOTAL DUST TOTAL DUST
TWA: TWA:
5 MG/M3 5 MG/M3
RESPIRABLE FRACTION RESPIRABLE DUST
(VACATED) TWA:
15 MG/M3 TOTAL DUST
(VACATED) TWA:
5 MG/M3
RESPIRABLE FRACTION
PHOSPHORIC ACID STEL: 3 MG/M3 TWA: 1 MG/M3 IDLH: 1000 MG/M3
7664-38-2
TWA: 1 MG/M3 (VACATED) TWA: TWA: 1 MG/M3
1 MG/M3
(VACATED) STEL: STEL: 3 MG/M3
3 MG/M3
SUBTILISINS CEILING: (VACATED) STEL: STEL:
(PROTEOLYTIC 0.00006 MG/M3 0.00006 MG/M3 0.00006 MG/M3
ENZYMES) AS CRYSTALLINE 60 MIN 60 MIN SUBTILISINS
9014-01-1 ACTIVE ENZYME
ETHANOL STEL: 1000 PPM TWA: 1000 PPM IDLH:
64-17-5 3300 PPM 10% LEL
TWA: 1900 MG/M3 TWA: 1000 PPM
(VACATED) TWA: TWA: 1900 MG/M3
1000 PPM
(VACATED) TWA:
1900 MG/M3
ACGIH TLV:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS - THRESHOLD LIMIT
VALUE
OSHA PEL:
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION - PERMISSIBLE EXPOSURE LIMITS
IMMEDIATELY DANGEROUS TO LIFE OR HEALTH NIOSH IDLH
OTHER EXPOSURE GUIDELINES:
VACATED LIMITS REVOKED BY THE COURT OF APPEALS DECISION IN AFL-CIO V. OSHA,
965 F.2D 962 (11TH CIR., 1992) SEE SECTION 15 FOR NATIONAL EXPOSURE CONTROL
PARAMETERS
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
TIGHT SEALING SAFETY GOGGLES. WEAR SAFETY GLASSES WITH SIDE SHIELDS
(OR GOGGLES).
SKIN AND BODY PROTECTION:
NO SPECIAL PROTECTIVE EQUIPMENT REQUIRED. PROTECTIVE GLOVES.
RESPIRATORY PROTECTION:
NO PROTECTIVE EQUIPMENT IS NEEDED UNDER NORMAL USE CONDITIONS. IF EXPOSURE
LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, VENTILATION AND
EVACUATION MAY BE REQUIRED.
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE. TAKE
OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE. AVOID CONTACT WITH SKIN,
EYES OR CLOTHING. WEAR SUITABLE GLOVES AND EYE/FACE PROTECTION. DO NOT EAT,
DRINK OR SMOKE WHEN USING THIS PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: SOLID
APPEARANCE: BLUE
ODOR: SPICE
COLOR: NO INFORMATION AVAILABLE
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS METHOD
PH NO DATA AVAILABLE NONE KNOWN
MELTING / FREEZING POINT NO DATA AVAILABLE NONE KNOWN
BOILING POINT / BOILING RANGE NO DATA AVAILABLE NONE KNOWN
FLASH POINT NO DATA AVAILABLE NONE KNOWN
EVAPORATION RATE NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY (SOLID, GAS) NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY LIMIT IN AIR:
UPPER FLAMMABILITY LIMIT NO DATA AVAILABLE
LOWER FLAMMABILITY LIMIT NO DATA AVAILABLE
VAPOR PRESSURE NO DATA AVAILABLE NONE KNOWN
VAPOR DENSITY NO DATA AVAILABLE NONE KNOWN
SPECIFIC GRAVITY NO DATA AVAILABLE NONE KNOWN
WATER SOLUBILITY SOLUBLE IN WATER NONE KNOWN
SOLUBILITY IN OTHER SOLVENTS NO DATA AVAILABLE NONE KNOWN
PARTITION COEFFICIENT NO DATA AVAILABLE NONE KNOWN
N-OCTANOL/WATER
AUTOIGNITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
DECOMPOSITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
KINEMATIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
DYNAMIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
EXPLOSIVE PROPERTIES NO DATA AVAILABLE
OXIDIZING PROPERTIES NO DATA AVAILABLE
OTHER INFORMATION:
SOFTENING POINT NO DATA AVAILABLE
VOC CONTENT (%) NO DATA AVAILABLE
PARTICLE SIZE NO DATA AVAILABLE
PARTICLE SIZE DISTRIBUTION
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS POLYMERIZATION: HAZARDOUS POLYMERIZATION DOES NOT OCCUR.
CONDITIONS TO AVOID: NONE KNOWN.
INCOMPATIBLE MATERIALS: NONE KNOWN.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
PRODUCT DOES NOT PRESENT AN ACUTE TOXICITY HAZARD BASED ON KNOWN OR
SUPPLIED INFORMATION.
INHALATION:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE.
NO IRRITATION EXPECTED.
EYE CONTACT:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE.
NOT EXPECTED TO BE AN IRRITANT BASED ON COMPONENTS. MAY CAUSE EYE
IRRITATION. MAY CAUSE BURNS.
SKIN CONTACT:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE.
NOT EXPECTED TO BE A SKIN IRRITANT BASED ON COMPONENTS. PROLONGED
CONTACT MAY CAUSE REDNESS AND IRRITATION.
INGESTION:
SPECIFIC TEST DATA FOR THE SUBSTANCE OR MIXTURE IS NOT AVAILABLE.
INGESTION MAY CAUSE IRRITATION TO MUCOUS MEMBRANES. INGESTION MAY
CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA
COMPONENT INFORMATION:
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS:
ERYTHEMA (SKIN REDNESS). BURNING. MAY CAUSE BLINDNESS. COUGHING AND/ OR
WHEEZING. SYMPTOMS OF ALLERGIC REACTION MAY INCLUDE RASH, ITCHING,
SWELLING, TROUBLE BREATHING, TINGLING OF THE HANDS AND FEET, DIZZINESS,
LIGHTHEADEDNESS, CHEST PAIN, MUSCLE PAIN, OR FLUSHING.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE.
CARCINOGENICITY:
THE TABLE BELOW INDICATES WHETHER EACH AGENCY HAS LISTED ANY INGREDIENT AS
A CARCINOGEN.
CHEMICAL NAME ACGIH IARC NTP OSHA
ETHANOL A3 GROUP 1 KNOWN X
64-17-5
ACGIH (AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS):
A3 - ANIMAL CARCINOGEN
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
GROUP 1 - CARCINOGENIC TO HUMANS
NTP (NATIONAL TOXICOLOGY PROGRAM):
KNOWN - KNOWN CARCINOGEN
OSHA (OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION OF THE US DEPARTMENT
OF LABOR):
X - PRESENT
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
CHRONIC TOXICITY:
NO KNOWN EFFECT BASED ON INFORMATION SUPPLIED. REPEATED CONTACT MAY CAUSE
ALLERGIC REACTIONS IN VERY SUSCEPTIBLE PERSONS. AVOID REPEATED EXPOSURE.
ETHANOL HAS BEEN SHOWN TO BE A REPRODUCTIVE TOXIN ONLY WHEN CONSUMED AS AN
ALCOHOLIC BEVERAGE. ETHANOL HAS BEEN SHOWN TO BE CARCINOGENIC IN LONG-TERM
STUDIES ONLY WHEN CONSUMED AS ALCOHOLIC BEVERAGE.
TARGET ORGAN EFFECTS: EYES. SKIN.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY PRODUCT INFORMATION:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT:
ATEMIX (ORAL): 5,072.00 MG/KG
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC ORGANISMS.
CHEMICAL NAME TOXICITY TO TOXICITY TO TOXICITY TO DAPHNIA MAGNA
ALGAE FISH MICROORGANISMS (WATER FLEA)
PHOSPHORIC ACID 96H LC50: 12H EC50:
7664-38-2 3 - 3.5 MG/L =4.6 MG/L
(GAMBUSIA
AFFINIS)
ETHANOL 96H LC50: EC50: 48H LC50:
64-17-5 >100 MG/L 34634 MG/L 9268 - 14221
(PIMEPHALES 30 MIN MG/L
PROMELAS)
96H LC50: EC50: 48H EC50:
13400 - 15100 35470 MG/L =2 MG/L
MG/L 5 MIN
(PIMEPHALES 24H EC50:
PROMELAS) =10800 MG/L
96H LC50:
12.0 - 16.0
ML/L
(ONCORHYNCHUS
MYKISS)
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION:
CHEMICAL NAME LOG POW
ETHANOL -0.32
64-17-5
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL METHODS:
THIS MATERIAL, AS SUPPLIED, IS NOT A HAZARDOUS WASTE ACCORDING TO FEDERAL
REGULATIONS (40 CFR 261). THIS MATERIAL COULD BECOME A HAZARDOUS WASTE IF
IT IS MIXED WITH OR OTHERWISE COMES IN CONTACT WITH A HAZARDOUS WASTE, IF
CHEMICAL ADDITIONS ARE MADE TO THIS MATERIAL, OR IF THE MATERIAL IS
PROCESSED OR OTHERWISE ALTERED. CONSULT 40 CFR 261 TO DETERMINE WHETHER
THE ALTERED MATERIAL IS A HAZARDOUS WASTE. CONSULT THE APPROPRIATE STATE,
REGIONAL, OR LOCAL REGULATIONS FOR ADDITIONAL REQUIREMENTS.
CONTAMINATED PACKAGING:
DISPOSE OF CONTENTS/CONTAINERS IN ACCORDANCE WITH LOCAL REGULATIONS.
CALIFORNIA HAZARDOUS WASTE CODES: 331
THIS PRODUCT CONTAINS ONE OR MORE SUBSTANCES THAT ARE LISTED WITH THE
STATE OF CALIFORNIA AS A HAZARDOUS WASTE.
CHEMICAL NAME CALIFORNIA HAZARDOUS WASTE
PHOSPHORIC ACID CORROSIVE
7664-38-2
ETHANOL TOXIC
64-17-5 IGNITABLE
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
PROPER SHIPPING NAME: NON REGULATED
HAZARD CLASS: N/A
TDG: NOT REGULATED
MEX: NOT REGULATED
ICAO: NOT REGULATED
IATA: NOT REGULATED
PROPER SHIPPING NAME: NON REGULATED
HAZARD CLASS: N/A
IMDG/IMO: NOT REGULATED
HAZARD CLASS: N/A
RID: NOT REGULATED
ADR: NOT REGULATED
ADN: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
DSL: ALL COMPONENTS ARE LISTED EITHER ON THE DSL OR NDSL.
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
US FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372:
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: YES
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CWA (CLEAN WATER ACT):
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES WHICH ARE REGULATED
POLLUTANTS PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND
40 CFR 122.42):
CHEMICAL CWA - REPORTABLE CWA - TOXIC CWA - PRIORITY CWA - HAZARDOUS
NAME QUANTITIES POLLUTANTS POLLUTANTS SUBSTANCES
PHOSPHORIC 5000 LB X
ACID
7664-38-2
CERCLA:
THIS MATERIAL, AS SUPPLIED, CONTAINS ONE OR MORE SUBSTANCES REGULATED AS
A HAZARDOUS SUBSTANCE UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302):
CHEMICAL HAZARDOUS SUBSTANCES EXTREMELY HAZARDOUS RQ
NAME RQS SUBSTANCES RQS
PHOSPHORIC ACID 5000 LB RQ:
7664-38-2 5000 LB
FINAL RQ
RQ:
2270 KG
FINAL RQ
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS THE FOLLOWING PROPOSITION 65 CHEMICALS. ETHYL
ALCOHOL IS ONLY A CONSIDERED A PROPOSITION 65 DEVELOPMENTAL HAZARD WHEN
IT IS INGESTED AS AN ALCOHOLIC BEVERAGE.
CHEMICAL NAME CALIFORNIA PROPOSITION 65
ETHANOL - 64-17-5 CARCINOGEN
DEVELOPMENTAL
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA RHODE ILLINOIS
ISLAND
MAIZE STARCH X X
9005-25-8
PHOSPHORIC ACID X X X X
7664-38-2
ETHANOL X
64-17-5
INTERNATIONAL REGULATIONS:
MEXICO:
NATIONAL OCCUPATIONAL EXPOSURE LIMITS:
COMPONENT CARCINOGEN STATUS EXPOSURE LIMITS
PHOSPHORIC ACID MEXICO:
7664-38-2 (3 - 7) TWA: 1 MG/M3
MEXICO:
STEL: 3 MG/M3
ETHANOL MEXICO:
64-17-5 (0.1 - 1) TWA: 1000 PPM
MEXICO:
TWA: 1900 MG/M3
MEXICO - OCCUPATIONAL EXPOSURE LIMITS - CARCINOGENS:
CANADA:
WHMIS HAZARD CLASS:
D2A - VERY TOXIC MATERIALS
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS 1
FLAMMABILITY 0
INSTABILITY 0
PHYSICAL AND CHEMICAL HAZARDS
HMIS:
HEALTH HAZARDS 1
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
REVISION DATE: 02-FEB-2015
REVISION NOTE: NO INFORMATION AVAILABLE
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT
1176974 - ROUND BLUE SPICE TOUGH GUY (10A684)