| Common Name: | STA-BIL ETHANOL FUEL TREATMENT & STABILIZER - PROTECTION |
| Manufacturer: | GOLD EAGLE |
| SDS Revision Date: | 9/9/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 10N792 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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STA-BIL(R*) ETHANOL FUEL TREATMENT & STABILIZER - PROTECTION
SAFETY DATA SHEET
GOLD EAGLE(R*)
| SECTION 1 - IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: STA-BIL(R*) ETHANOL FUEL TREATMENT & STABILIZER - PROTECTION
SYNONYMS: 584094
PRODUCT CODE:
22232; 22264; 22265; 22268; 22269; 22274; 22275; 22281; 22282; 22284;
22288; 22291; 22296; 22804; 22805; 22811
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
RECOMMENDED USE: GASOLINE FUEL STABILIZER
RESTRICTIONS ON USE: DO NOT USE IN DIESEL FUEL
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER:
GOLD EAGLE CO.
4400 S. KILDARE AVENUE
CHICAGO, IL 606324372
UNITED STATES
HTTP://WWW.GOLDEAGLE.COM/
TELEPHONE (GENERAL): 7733764400
EMERGENCY TELEPHONE NUMBER:
MANUFACTURER: 1-800-535-5053 - (INFOTRAC #22283)
| SECTION 2 - HAZARD IDENTIFICATION | |
UNITED STATES (US):
ACCORDING TO: OSHA 29 CFR 1910.1200 HCS
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
OSHA HCS 2012:
FLAMMABLE LIQUIDS 4
ASPIRATION 1
SPECIFIC TARGET ORGAN TOXICITY SINGLE EXPOSURE 3: NARCOTIC EFFECTS
CARCINOGENICITY 2
REPRODUCTIVE TOXICITY 2
LABEL ELEMENTS:
OSHA HCS 2012:
DANGER:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
COMBUSTIBLE LIQUID
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
MAY CAUSE DROWSINESS OR DIZZINESS
SUSPECTED OF CAUSING CANCER.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES AND/OR HOT SURFACES. NO SMOKING.
AVOID BREATHING MIST/VAPOURS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IN CASE OF FIRE: USE APPROPRIATE MEDIA FOR EXTINCTION.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
DO NOT INDUCE VOMITING.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE/DISPOSAL:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
KEEP COOL.
STORE LOCKED UP.
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
OSHA HCS 2012:
UNDER UNITED STATES REGULATIONS (29 CFR 1910.1200 - HAZARD COMMUNICATION
STANDARD), THIS PRODUCT IS CONSIDERED HAZARDOUS.
| SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCES: MATERIAL DOES NOT MEET THE CRITERIA OF A SUBSTANCE.
MIXTURES:
COMPOSITION:
CHEMICAL NAME IDENTIFIERS %
DISTILLATES (PETROLEUM), CAS: 64742-47-8 76.15%
HYDROTREATED LIGHT
SWEETENED MIDDLE DISTILLATE CAS: 64741-86-2 3.32% TO 4.9634%
SOLVENT NAPHTHA CAS: 64742-94-5 2.110108% TO 4.203589%
ETHYLENE GLYCOL MONOBUTYL ETHER CAS: 111-76-2 2.25% TO 2.5%
CONFIDENTIAL INGREDIENT NDA 0.166% TO 0.8134%
NAPHTHALENE CAS:91-20-3 0.01500027% TO 0.3572027%
CHEMICAL NAME LD50/LC50 CLASSIFICATIONS ACCORDING TO
REGULATION/DIRECTIVE
DISTILLATES (PETROLEUM), NDA OSHA HCS 2012:
HYDROTREATED LIGHT FLAM. LIQ. 4; ASP. TOX. 1;
STOT SE 3:
NARC.
SWEETENED MIDDLE NDA OSHA HCS 2012:
DISTILLATE NOT CLASSIFIED
SOLVENT NAPHTHA INHALATION-RAT OSHA HCS 2012:
LC50: NOT CLASSIFIED
>590 MG/M3
4 HOUR(S)
SKIN-RABBIT LD50:
>2 ML/KG
ETHYLENE GLYCOL INHALATION-RAT OSHA HCS 2012:
MONOBUTYL ETHER LC50: EYE IRRIT. 2; STOT SE 3:
450 PPM 4 HOUR(S) NARC.; ACUTE TOX. 4 (ORAL);
SKIN-RABBIT LD50: ACUTE TOX. 3 (SKN); REPR. 2
220 MG/KG
INGESTION/
ORAL-RAT LD50:
250 MG/KG
CONFIDENTIAL INGREDIENT NDA OSHA HCS 2012:
NOT CLASSIFIED
NAPHTHALENE SKIN-RABBIT LD50: OSHA HCS 2012:
>20 G/KG FLAM. SOL. 2; ACUTE TOX. 4
INGESTION/ (ORAL); SKIN IRRIT. 2;
ORAL-RAT LD50: MUTA. 2; CARC. 2; REPR. 2;
490 MG/KG STOT SE 3:
NARC.; STOT RE 1 (BLOOD,
EYES, ORAL, INHL)
| SECTION 4 - FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
MOVE VICTIM TO FRESH AIR. ADMINISTER OXYGEN IF BREATHING IS DIFFICULT.
GIVE ARTIFICIAL RESPIRATION IF VICTIM IS NOT BREATHING. IF SIGNS/SYMPTOMS
CONTINUE, GET MEDICAL ATTENTION.
SKIN:
IN CASE OF BURNS, IMMEDIATELY COOL AFFECTED SKIN FOR AS LONG AS POSSIBLE
WITH COLD WATER. DO NOT REMOVE CLOTHING IF ADHERING TO SKIN. REMOVE AND
ISOLATE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND WATER.
EYE:
HOLD EYE OPEN AND RINSE SLOWLY AND GENTLY WITH WATER FOR 15-20 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT, AFTER THE FIRST FIVE MINUTES, THEN
CONTINUE RINSING EYE. GET MEDICAL ATTENTION IMMEDIATELY.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
REFER TO SECTION 11 - TOXICOLOGICAL INFORMATION.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NOTES TO PHYSICIAN:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT. CONSIDERATION SHOULD BE GIVEN TO THE POSSIBILITY THAT
OVEREXPOSURE TO MATERIALS OTHER THAN THIS PRODUCT MAY HAVE OCCURRED.
| SECTION 5 - FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE CARBON DIOXIDE, DRY CHEMICAL, FOAM AND/OR WATER FOG.
UNSUITABLE EXTINGUISHING MEDIA: NO DATA AVAILABLE
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
UNUSUAL FIRE AND EXPLOSION HAZARDS:
CONTAINERS MAY EXPLODE WHEN HEATED.
VAPOR EXPLOSION HAZARD INDOORS, OUTDOORS OR IN SEWERS.
COMBUSTIBLE MATERIAL: MAY BURN BUT DOES NOT IGNITE READILY.
MANY LIQUIDS ARE LIGHTER THAN WATER.
MOST VAPORS ARE HEAVIER THAN AIR. THEY WILL SPREAD ALONG GROUND AND
COLLECT IN LOW OR CONFINED AREAS (SEWERS, BASEMENTS, TANKS).
RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
VAPORS MAY TRAVEL TO SOURCE OF IGNITION AND FLASH BACK.
WATER MAY CAUSE FROTHING.
HAZARDOUS COMBUSTION PRODUCTS: NO DATA AVAILABLE
ADVICE FOR FIREFIGHTERS:
STRUCTURAL FIREFIGHTERS' PROTECTIVE CLOTHING WILL ONLY PROVIDE LIMITED
PROTECTION.
WEAR POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS (SCBA).
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK.
LARGE FIRES:
COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS
OUT.
| SECTION 6 - ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
DO NOT WALK THROUGH SPILLED MATERIAL. USE APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT (PPE) DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS
WEARING APPROPRIATE PROTECTIVE CLOTHING.
EMERGENCY PROCEDURES:
AS AN IMMEDIATE PRECAUTIONARY MEASURE, ISOLATE SPILL OR LEAK AREA FOR AT
LEAST 50 METERS (150 FEET) IN ALL DIRECTIONS. IF TANK, RAIL CAR OR TANK
TRUCK IS INVOLVED IN A FIRE, ISOLATE FOR 800 METERS (1/2 MILE) IN ALL
DIRECTIONS; ALSO, CONSIDER INITIAL EVACUATION FOR 800 METERS (1/2 MILE)
IN ALL DIRECTIONS.
LARGE SPILL:
CONSIDER INITIAL DOWNWIND EVACUATION FOR AT LEAST 300 METERS (1000 FEET)
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS OR FLAMES IN
IMMEDIATE AREA). KEEP UNAUTHORIZED PERSONNEL AWAY. STAY UPWIND. KEEP OUT
OF LOW AREAS. VENTILATE CLOSED SPACES BEFORE ENTERING.
ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAINMENT/CLEAN-UP MEASURES:
STOP LEAK IF YOU CAN DO IT WITHOUT RISK.
ABSORB OR COVER WITH DRY EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL
AND TRANSFER TO CONTAINERS.
USE CLEAN NON-SPARKING TOOLS TO COLLECT ABSORBED MATERIAL.
A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS.
ALL EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED.
LARGE SPILLS: DIKE FAR AHEAD OF LIQUID SPILL FOR LATER DISPOSAL.
LARGE SPILLS:
WATER SPRAY MAY REDUCE VAPOR; BUT MAY NOT PREVENT IGNITION IN CLOSED
SPACES.
| SECTION 7 - HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
USE ONLY IN WELL VENTILATED AREAS. AVOID CONTACT WITH HEAT AND IGNITION
SOURCES. TAKE PRECAUTIONARY MEASURES AGAINST STATIC CHARGES. DO NOT USE
SPARKING TOOLS. ALL EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE
GROUNDED. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT, AVOID DIRECT
CONTACT. AVOID BREATHING . AVOID CONTACT WITH SKIN, EYES, AND CLOTHING.
WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING AND BEFORE EATING,
DRINKING, OR USING TOBACCO.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
STORE IN A TIGHTLY CLOSED CONTAINER. KEEP AWAY FROM INCOMPATIBLE
MATERIALS. STORE IN A WELL-VENTILATED PLACE. STORE IN AN AREA EQUIPPED
WITH AUTOMATIC SPRINKLERS OR FIRE EXTINGUISHING SYSTEM. STORE BELOW 150
DEG. F. EMPTY CONTAINERS CONTAIN PRODUCT RESIDUES, ASSUME EMPTIED
CONTAINERS TO HAVE SAME HAZARDS AS FULL CONTAINERS.
| SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE LIMITS/GUIDELINES:
RESULT ACGIH NIOSH OSHA
NAPHTHALENE TWAS 10 PPM TWA 10 PPM TWA; 10 PPM TWA;
(91-20-3) 50 MG/M3 TWA 50 MG/M3 TWA
STELS 15 PPM STEL 15 PPM STEL; NOT
75 MG/M3 STEL ESTABLISHED
ETHYLENE GLYCOL TWAS 20 PPM TWA 5 PPM TWA; 50 PPM TWA;
MONOBUTYL ETHER 24 MG/M3 TWA 240 MG/M3 TWA
(111-76-2)
EXPOSURE CONTROLS:
ENGINEERING MEASURES/CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL
EXHAUST VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE
LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT BEEN
ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL. USE ONLY
APPROPRIATELY CLASSIFIED ELECTRICAL EQUIPMENT.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY:
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134. USE A
NIOSH/MSHA APPROVED RESPIRATOR IF EXPOSURE LIMITS ARE EXCEEDED OR SYMPTOMS
ARE EXPERIENCED.
EYE/FACE: WEAR CHEMICAL SPLASH SAFETY GOGGLES.
SKIN/BODY: WEAR APPROPRIATE GLOVES.
ENVIRONMENTAL EXPOSURE CONTROLS:
CONTROLS SHOULD BE ENGINEERED TO PREVENT RELEASE TO THE ENVIRONMENT,
INCLUDING PROCEDURES TO PREVENT SPILLS, ATMOSPHERIC RELEASE AND RELEASE TO
WATERWAYS. FOLLOW BEST PRACTICE FOR SITE MANAGEMENT AND DISPOSAL OF WASTE.
KEY TO ABBREVIATIONS:
ACGIH = AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENE
STEL = SHORT TERM EXPOSURE LIMITS ARE BASED ON 15-MINUTE EXPOSURES
NIOSH = NATIONAL INSTITUTE OF OCCUPATIONAL SAFETY AND HEALTH
TWA = TIME-WEIGHTED AVERAGES ARE BASED ON 8H/DAY, 40H/WEEK EXPOSURES
OSHA = OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
| SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON PHYSICAL AND CHEMICAL PROPERTIES:
MATERIAL DESCRIPTION:
PHYSICAL FORM: LIQUID
APPEARANCE/DESCRIPTION: AMBER TO BROWN LIQUID WITH A DISTILLATE ODOR.
COLOR: AMBER TO BROWN.
ODOR: DISTILLATE ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
GENERAL PROPERTIES:
BOILING POINT: 180 F(82.2222 C)
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
SPECIFIC GRAVITY/RELATIVE DENSITY: = 0.83 WATER=1
WATER SOLUBILITY: NEGLIGIBLE < 0.1 %
VISCOSITY: 3 CENTISTOKE (CST, CS) OR MM2/SEC @ 40 C(104 F)
VOLATILITY:
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
EVAPORATION RATE: NO DATA AVAILABLE
VOC (VOL.): 100 %
VOLATILES (VOL.): 100 %
FLAMMABILITY:
FLASH POINT: > 141.5 F(> 60.8333 C)
UEL: 7 %
LEL: 0.8 %
AUTOIGNITION: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
ENVIRONMENTAL:
OCTANOL/WATER PARTITION COEFFICIENT: NO DATA AVAILABLE
| SECTION 10 - STABILITY AND REACTIVITY | |
REACTIVITY: NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: STABLE UNDER NORMAL TEMPERATURES AND PRESSURES.
POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
CONDITIONS TO AVOID: EXCESS HEAT. INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG OXIDANTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
EXCESSIVE HEATING AND/OR INCOMPLETE COMBUSTION WILL PRODUCE CARBON
MONOXIDE.
| SECTION 11 - TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
CAS:
STA-BIL(R*) ETHANOL FUEL TREATMENT & STABILIZER - PROTECTION: NDA
ACUTE TOXICITY:
INGESTION/ORAL-RAT LD50: >2 G/KG
SKIN-RABBIT: >2 G/KG
COMMENTS: NO DEATHS
IRRITATION:
SKIN-RABBIT: ESSENTIALLY NON-IRRITATING
UNREPORTED ROUTE-RABBIT: ESSENTIALLY NON-IRRITATING
COMPONENTS:
SOLVENT NAPHTHA (2.110108% TO 4.203589%): 64742-94-5
ACUTE TOXICITY:
INHALATION-RAT LC50: >590 MG/M3 4 HOUR(S)
SKIN-RABBIT LD50: >2 ML/KG
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)
BEHAVIORAL: IRRITABILITY
IRRITATION:
SKIN-RABBIT:
500 (MICRO)L 24 HOUR(S): MILD IRRITATION
NAPHTHALENE (0.01500027% TO 0.3572027%): 91-20-3
ACUTE TOXICITY:
INGESTION/ORAL-RAT LD50: 490 MG/KG
INGESTION/ORAL-MOUSE TDLO: 158 MG/KG
BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES
LIVER: OTHER CHANGES
BIOCHEMICAL:
METABOLISM (INTERMEDIARY): LIPIDS, INCLUDING TRANSPORT
INHALATION-HUMAN TCLO: 250 MG/M3
SENSE ORGANS AND SPECIAL SENSES:
EYE: LACRIMATION
BEHAVIORAL: HEADACHE
SKIN-RABBIT LD50: >20 G/KG
UNREPORTED-GUINEA PIG LD50: 1200 MG/KG
BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)
IRRITATION:
SKIN-RABBIT: 0.05 ML 24 HOUR(S)
SEVERE IRRITATION
MULTI-DOSE TOXICITY:
INGESTION/ORAL-RAT TDLO: 500 MG/KG 10 DAY(S)-INTERMITTENT
BEHAVIORAL: SLEEP
LUNGS, THORAX, OR RESPIRATION: DYSPNEA
INGESTION/ORAL-RAT TDLO: 4500 MG/KG 10 DAY(S)-INTERMITTENT
BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES
MUTAGEN:
MICRONUCLEUS TEST:
UNREPORTED ROUTE-HUMAN:
LYMPHOCYTE (SOMATIC CELL): 30 MG/L
REPRODUCTIVE:
INGESTION/ORAL-MOUSE TDLO: 2400 MG/KG (7-14D PREG)
REPRODUCTIVE EFFECTS:
EFFECTS ON NEWBORN: LIVE BIRTH INDEX
REPRODUCTIVE EFFECTS:
EFFECTS ON NEWBORN:
VIABILITY INDEX (E.G., # ALIVE AT DAY 4 PER # BORN ALIVE)
INGESTION/ORAL-RAT TDLO: 4500 MG/KG (615D PREG)
REPRODUCTIVE EFFECTS:
EFFECTS ON EMBRYO OR FETUS:
FETOTOXICITY (EXCEPT DEATH, E.G., STUNTED FETUS)
REPRODUCTIVE EFFECTS:
SPECIFIC DEVELOPMENTAL ABNORMALITIES: OTHER DEVELOPMENTAL ABNORMALITIES
TUMORIGEN / CARCINOGEN:
INHALATION-MOUSE TCLO: 30 PPM 6 HOUR(S) 2 YEAR(S)-INTERMITTENT
TUMORIGENIC: NEOPLASTIC BY RTECS CRITERIA
LUNGS, THORAX, OR RESPIRATION: TUMORS
INHALATION-RAT TCLO: 1575 MG/KG 105 WEEK(S)-INTERMITTENT
TUMORIGENIC: CARCINOGENIC BY RTECS CRITERIA
SENSE ORGANS AND SPECIAL SENSES:
OLFACTION: TUMORS
INHALATION-RAT TCLO: 60 PPM 6 HOUR(S) 105 WEEK(S)-INTERMITTENT
TUMORIGENIC: CARCINOGENIC BY RTECS CRITERIA
SENSE ORGANS AND SPECIAL SENSES:
OLFACTION: TUMORS
ETHYLENE GLYCOL MONOBUTYL ETHER (2.25% TO 2.5%): 111-76-2
ACUTE TOXICITY:
INGESTION/ORAL-RAT LD50: 917 MG/KG
LIVER: OTHER CHANGES
KIDNEY, URETER, AND BLADDER: OTHER CHANGES
BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA
INHALATION-RAT LC50: 2900 MG/M3 7 HOUR(S)
LIVER: OTHER CHANGES
KIDNEY, URETER, AND BLADDER: OTHER CHANGES
BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA
SKIN-RABBIT LD50: 220 MG/KG
IRRITATION:
EYE-RABBIT:
100 MG: SEVERE IRRITATION
SKIN-RABBIT:
500 MG-OPEN: MILD IRRITATION
MULTI-DOSE TOXICITY:
INGESTION/ORAL-RAT TDLO: 300 MG/KG 3 DAY(S)-INTERMITTENT
BLOOD: NORMOCYTIC ANEMIA
BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA
INHALATION-RAT TCLO: 432 PPM 7 HOUR(S) 30 DAY(S)-INTERMITTENT
KIDNEY, URETER, AND BLADDER: HEMATURIA
BLOOD: OTHER CHANGES
RELATED TO CHRONIC DATA: DEATH IN THE OTHER MULTIPLE DOSE DATA TYPE FIELD
MUTAGEN:
DNA DAMAGE:
UNREPORTED-MOUSE: 3150 MG/KG 7 DAY(S)
REPRODUCTIVE:
INGESTION/ORAL-RAT TDLO: 600 MG/KG (9-11D PREG)
REPRODUCTIVE EFFECTS:
EFFECTS ON EMBRYO OR FETUS: FETAL DEATH
TUMORIGEN / CARCINOGEN:
INHALATION-MOUSE TCLO: 250 PPM 6 HOUR(S) 2 YEAR(S)-INTERMITTENT
TUMORIGENIC: CARCINOGENIC BY RTECS CRITERIA
LIVER: TUMORS
GHS PROPERTIES CLASSIFICATION
RESPIRATORY SENSITIZATION OSHA HCS 2012: DATA LACKING
SERIOUS EYE DAMAGE/IRRITATION OSHA HCS 2012: DATA LACKING
ACUTE TOXICITY OSHA HCS 2012: DATA LACKING
ASPIRATION HAZARD OSHA HCS 2012: ASPIRATION 1
CARCINOGENICITY OSHA HCS 2012: CARCINOGENICITY 2
SKIN CORROSION/IRRITATION OSHA HCS 2012: DATA LACKING
SKIN SENSITIZATION OSHA HCS 2012: DATA LACKING
STOT-RE OSHA HCS 2012: DATA LACKING
STOT-SE OSHA HCS 2012:
SPECIFIC TARGET ORGAN TOXICITY SINGLE
EXPOSURE 3:
NARCOTIC EFFECTS
TOXICITY FOR REPRODUCTION OSHA HCS 2012: TOXIC TO REPRODUCTION 2
GERM CELL MUTAGENICITY OSHA HCS 2012: NONMUTAGENIC
POTENTIAL HEALTH EFFECTS:
INHALATION:
ACUTE (IMMEDIATE):
MAY AFFECT THE CENTRAL NERVOUS SYSTEM. SYMPTOMS MAY INCLUDE DIZZINESS,
DROWSINESS, LETHARGY, COMA AND DEATH.
CHRONIC (DELAYED): NO DATA AVAILABLE.
SKIN:
ACUTE (IMMEDIATE):
MATERIAL IS CLASSIFIED AS NON-IRRITANT AND NON-CORROSIVE USING GHS
CRITERIA.
CHRONIC (DELAYED): NO DATA AVAILABLE.
EYE:
ACUTE (IMMEDIATE):
MATERIAL IS CLASSIFIED AS NON-IRRITANT USING GHS CRITERIA.
CHRONIC (DELAYED): NO DATA AVAILABLE.
INGESTION:
ACUTE (IMMEDIATE):
MATERIAL MAY BE ASPIRATED INTO LUNGS DURING INGESTION AND/OR SUBSEQUENT
VOMITING. ASPIRATION OF THIS MATERIAL WILL CAUSE SEVERE LUNG INJURY,
CHEMICAL PNEUMONITIS, PULMONARY EDEMA OR DEATH.
CHRONIC (DELAYED): NO DATA AVAILABLE.
CARCINOGENIC EFFECTS:
SUSPECTED OF CAUSING CANCER. THIS PRODUCT CONTAINS COMPONENTS THAT ARE
CONSIDERED CARCINOGENIC BY OSHA, IARC, NTP.
CARCINOGENIC EFFECTS:
CAS IARC NTP
NAPHTHALENE 91-20-3 GROUP 2B-POSSIBLE REASONABLY ANTICIPATED TO BE
CARCINOGEN HUMAN CARCINOGEN
REPRODUCTIVE EFFECTS:
ANIMAL TESTS FOR COMPONENTS HAVE SHOWN ADVERSE REPRODUCTIVE EFFECTS.
KEY TO ABBREVIATIONS:
LD = LETHAL DOSE
TC = TOXIC CONCENTRATION
TD = TOXIC DOSE
| SECTION 12 - ECOLOGICAL INFORMATION | |
TOXICITY:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
PERSISTENCE AND DEGRADABILITY:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
BIOACCUMULATIVE POTENTIAL:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
MOBILITY IN SOIL:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
OTHER ADVERSE EFFECTS:
NON-MANDATORY SECTION - INFORMATION ABOUT THIS SUBSTANCE NOT COMPLIED FOR
THIS REASON.
| SECTION 13 - DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
PRODUCT WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
PACKAGING WASTE:
DISPOSE OF CONTENT AND/OR CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL,
NATIONAL, AND/OR INTERNATIONAL REGULATIONS.
| SECTION 14 - TRANSPORT INFORMATION | |
UN UN PROPER TRANSPORT HAZARD PACKING GROUP ENVIRONMENTAL
NUMBER SHIPPING CLASS(ES) HAZARDS
NAME
DOT NDA NOT NDA NDA NDA
REGULATED
SPECIAL PRECAUTIONS FOR USER: NONE SPECIFIED.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NO DATA AVAILABLE
| SECTION 15 - REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA HAZARD CLASSIFICATIONS: ACUTE, CHRONIC, FIRE
INVENTORY:
COMPONENT CAS TSCA
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 YES
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 YES
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 YES
NAPHTHALENE 91-20-3 YES
SOLVENT NAPHTHA 64742-94-5 YES
SWEETENED MIDDLE DISTILLATE 64741-86-2 YES
UNITED STATES:
LABOR:
U.S. - OSHA - PROCESS SAFETY MANAGEMENT - HIGHLY HAZARDOUS CHEMICALS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - OSHA - SPECIFICALLY REGULATED CHEMICALS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
ENVIRONMENT:
U.S. - CAA (CLEAN AIR ACT) - 1990 HAZARDOUS AIR POLLUTANTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CAA (CLEAN AIR ACT) - ACCIDENTAL RELEASE PREVENTION - FLAMMABLE
SUBSTANCES:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CAA (CLEAN AIR ACT) - ACCIDENTAL RELEASE PREVENTION - TOXIC
SUBSTANCES:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CERCLA/SARA - HAZARDOUS SUBSTANCES AND THEIR REPORTABLE QUANTITIES:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 100 LB
FINAL RQ
45.4 KG
FINAL RQ
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES EPCRA RQS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CERCLA/SARA - SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES TPQS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - EMISSION REPORTING:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 0.1 %
DE MINIMIS
CONCENTRA-
TION
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CERCLA/SARA - SECTION 313 - PBT CHEMICAL LISTING:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CWA (CLEAN WATER ACT) - HAZARDOUS SUBSTANCES:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CWA (CLEAN WATER ACT) - TOXIC POLLUTANTS:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
UNITED STATES - CALIFORNIA:
ENVIRONMENT:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 CARCINO-
GEN,
INITIAL
DATE
4/19/02
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL):
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - NO SIGNIFICANT RISK LEVELS (NSRL):
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 5.8
(MICRO)G/
DAY NSRL
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE:
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 NOT LISTED
NAPHTHALENE 91-20-3 NOT LISTED
ETHYLENE GLYCOL MONOBUTYL ETHER 111-76-2 NOT LISTED
SOLVENT NAPHTHA 64742-94-5 NOT LISTED
SWEETENED MIDDLE DISTILLATE 64741-86-2 NOT LISTED
ANTHRAQUINONE, 1,4-BIS(METHYLAMINO)- 2475-44-7 NOT LISTED
OTHER INFORMATION:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS, OR OTHER REPRODUCTIVE HARM.
| SECTION 16 - OTHER INFORMATION | |
REVISION DATE: 09/SEPTEMBER/2015
PREPARATION DATE: 15/OCTOBER/2014
OTHER INFORMATION:
SCHEDULE B NUMBER: 3811.90.0000.
DISCLAIMER/STATEMENT OF LIABILITY:
INFORMATION PRESENTED HEREIN IS BELIEVED TO BE FACTUAL, AS IT HAS BEEN
DERIVED FROM THE WORKS AND OPINIONS OF PERSONS BELIEVED TO BE QUALIFIED
EXPERTS. HOWEVER, NOTHING CONTAINED IN THIS INFORMATION IS TO BE TAKEN AS
WARRANTY OR REPRESENTATION FOR WHICH THE GOLD EAGLE CO. BEARS LEGAL
RESPONSIBILITY. THE USER SHOULD REVIEW ANY RECOMMENDATIONS IN THE SPECIFIC
CONTEXT OF THE INTENDED USE TO DETERMINE WHETHER THEY ARE APPROPRIATE.
KEY TO ABBREVIATIONS:
NDA = NO DATA AVAILABLE
FORMAT: GHS
LANGUAGE: ENGLISH (US)
OSHA HCS 2012