| Common Name: | POWDER SILVERWARE PRESOAK (4OZ, PK35) |
| Manufacturer: | W.W. GRAINGER |
| SDS Revision Date: | 8/12/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 11U471 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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W.W. GRAINGER, INC.
SAFETY DATA SHEET
ISSUE DATE: 12-AUG-2015
REVISION DATE: 12-AUG-2015
VERSION: 1
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NAME: POWDER SILVERWARE PRESOAK (4OZ, PK35)
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 11U471
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: PRESOAK AND DETARNISHER.
USES ADVISED AGAINST: USE ONLY AS STATED ON LABEL.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER:
W.W. GRAINGER, INC.
100 GRAINGER PKWY
LAKE FOREST, IL 60045
PHONE: (847)-535-1000
EMERGENCY TELEPHONE NUMBER:
EMERGENCY TELEPHONE:
CHEMTREC: 1-800-424-9300
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
OSHA REGULATORY STATUS:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200)
ACUTE TOXICITY - ORAL: NOT CLASSIFIED
ACUTE TOXICITY - DERMAL: NOT CLASSIFIED
ACUTE TOXICITY - INHALATION (DUSTS/MISTS): CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 3
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
LABEL ELEMENTS:
EMERGENCY OVERVIEW:
WARNING
HAZARD STATEMENTS:
MAY BE HARMFUL IF SWALLOWED
HARMFUL IF INHALED
CAUSES MILD SKIN IRRITATION
CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
APPEARANCE: BLUE
PHYSICAL STATE: GRANULES
ODOR: MILD
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH FACE, HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING
WEAR EYE/FACE PROTECTION
USE IN A WELL-VENTILATED AREA
AVOID BREATHING DUST
PRECAUTIONARY STATEMENTS - RESPONSE:
SPECIFIC TREATMENT (SEE SECTION 4 ON THE SDS)
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ ATTENTION
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC):
OTHER INFORMATION:
UNKNOWN ACUTE TOXICITY:
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS NO. WEIGHT-% TRADE SECRET
SODIUM CARBONATE 497-19-8 30-60 *
SODIUM SULFATE 7757-82-6 15-40 *
TRISODIUM PHOSPHATE 10101-89-0 7-13 *
SODIUM TRIPOLYPHOSHPATE 7758-29-4 3-7 *
ALCOHOL ETHOXYLATE 68439-46-3 1-5 *
*THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET.
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE: IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF SKIN
IRRITATION PERSISTS, CALL A PHYSICIAN. IMMEDIATE MEDICAL ATTENTION IS NOT
REQUIRED. WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER WHILE REMOVING
ALL CONTAMINATED CLOTHES AND SHOES.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES IF SYMPTOMS PERSIST, CALL A PHYSICIAN RINSE THOROUGHLY
WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER AND UPPER
EYELIDS. CONSULT A PHYSICIAN IMMEDIATELY FLUSH WITH PLENTY OF WATER. AFTER
INITIAL FLUSHING, REMOVE ANY CONTACT LENSES AND CONTINUE FLUSHING FOR AT
LEAST 15 MINUTES KEEP EYE WIDE OPEN WHILE RINSING
INHALATION:
REMOVE TO FRESH AIR. IF SYMPTOMS PERSIST, CALL A PHYSICIAN. IMMEDIATE
MEDICAL ATTENTION IS NOT REQUIRED. MOVE TO FRESH AIR IN CASE OF ACCIDENTAL
INHALATION OF VAPORS.
INGESTION:
RINSE MOUTH. DRINK PLENTY OF WATER. DO NOT INDUCE VOMITING. IMMEDIATE
MEDICAL ATTENTION IS NOT REQUIRED. CLEAN MOUTH WITH WATER AND DRINK
AFTERWARDS PLENTY OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. CALL A PHYSICIAN.
SELF-PROTECTION OF THE FIRST AIDER:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS: NO INFORMATION AVAILABLE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTE TO PHYSICIANS: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA CAUTION:
USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NO INFORMATION AVAILABLE.
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE.
SENSITIVITY TO STATIC DISCHARGE: NONE.
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED. AVOID CONTACT WITH EYES AND
SKIN. EVACUATE PERSONNEL TO SAFE AREAS. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY INTO WATERWAYS, SEWERS, BASEMENTS OR CONFINED AREAS. DO NOT
FLUSH INTO SURFACE WATER OR SANITARY SEWER SYSTEM. PREVENT FURTHER LEAKAGE
OR SPILLAGE IF SAFE TO DO SO. PREVENT PRODUCT FROM ENTERING DRAINS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL. PICK UP AND TRANSFER TO PROPERLY
LABELED CONTAINERS. AFTER CLEANING, FLUSH AWAY TRACES WITH WATER. PREVENT
PRODUCT FROM ENTERING DRAINS. DAM UP.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS. USE PERSONAL
PROTECTIVE EQUIPMENT AS REQUIRED. USE WITH LOCAL EXHAUST VENTILATION. DO
NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE CONDITIONS:
KEEP CONTAINER TIGHTLY CLOSED. KEEP OUT OF THE REACH OF CHILDREN. KEEP
CONTAINERS TIGHTLY CLOSED IN A COOL, WELL-VENTILATED PLACE. KEEP IN
PROPERLY LABELED CONTAINERS.
INCOMPATIBLE MATERIALS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
THIS PRODUCT, AS SUPPLIED, DOES NOT CONTAIN ANY HAZARDOUS MATERIALS WITH
OCCUPATIONAL EXPOSURE LIMITS ESTABLISHED BY THE REGION SPECIFIC REGULATORY
BODIES.
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING CONTROLS: SHOWERS, EYEWASH STATIONS & VENTILATION SYSTEMS.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: TIGHT SEALING SAFETY GOGGLES. FACE PROTECTION SHIELD.
SKIN AND BODY PROTECTION: WEAR CHEMICAL RESISTANT GLOVES.
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, NIOSH/MSHA
APPROVED RESPIRATORY PROTECTION SHOULD BE WORN. POSITIVE-PRESSURE SUPPLIED
AIR RESPIRATORS MAY BE REQUIRED FOR HIGH AIRBORNE CONTAMINANT
CONCENTRATIONS. RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE WITH
CURRENT LOCAL REGULATIONS.
GENERAL HYGIENE:
WHEN USING DO NOT EAT, DRINK OR SMOKE. WASH CONTAMINATED CLOTHING BEFORE
REUSE. REGULAR CLEANING OF EQUIPMENT, WORK AREA AND CLOTHING IS
RECOMMENDED.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: GRANULES
APPEARANCE: BLUE
ODOR: MILD
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS - METHOD
PH 11.0 - 12.0 1% SOLUTION
MELTING POINT/FREEZING POINT NO INFORMATION AVAILABLE
BOILING POINT / BOILING RANGE NO INFORMATION AVAILABLE
FLASH POINT NONE
EVAPORATION RATE NO INFORMATION AVAILABLE
FLAMMABILITY (SOLID, GAS) NO INFORMATION AVAILABLE
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
LOWER FLAMMABILITY LIMIT NO INFORMATION AVAILABLE
VAPOR PRESSURE NO INFORMATION AVAILABLE
VAPOR DENSITY NO INFORMATION AVAILABLE
SPECIFIC GRAVITY NO INFORMATION AVAILABLE
WATER SOLUBILITY COMPLETELY SOLUBLE
SOLUBILITY IN OTHER SOLVENTS NO INFORMATION AVAILABLE
PARTITION COEFFICIENT NO INFORMATION AVAILABLE
AUTOIGNITION TEMPERATURE NO INFORMATION AVAILABLE
DECOMPOSITION TEMPERATURE NO INFORMATION AVAILABLE
KINEMATIC VISCOSITY NO INFORMATION AVAILABLE
VISCOSITY NO INFORMATION AVAILABLE
EXPLOSIVE PROPERTIES NO INFORMATION AVAILABLE
OXIDIZING PROPERTIES NO INFORMATION AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DATA AVAILABLE
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: EXTREMES OF TEMPERATURE AND DIRECT SUNLIGHT.
INCOMPATIBLE MATERIALS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE: NO DATA AVAILABLE
PRODUCT INFORMATION: NO DATA AVAILABLE.
INHALATION: NO DATA AVAILABLE.
EYE CONTACT: SEVERELY IRRITATING TO EYES.
SKIN CONTACT: MAY CAUSE IRRITATION.
INGESTION: NO DATA AVAILABLE.
CHEMICAL NAME ORAL LD50 DERMAL LD50 INHALATION LC50
SODIUM CARBONATE = 4090 MG/KG = 2300 MG/M3
497-19-8 (RAT) (RAT) 2 H
SODIUM SULFATE >10000 MG/KG
7757-82-6 (RAT)
TRISODIUM PHOSPHATE = 7400 MG/KG
10101-89-0 (RAT)
SODIUM TRIPOLYPHOSHPATE = 3120 MG/KG >7940 MG/KG
7758-29-4 (RAT) (RABBIT)
ALCOHOL ETHOXYLATE = 1400 MG/KG >2 G/KG
68439-46-3 (RAT) (RABBIT)
= 1378 MG/KG
(RAT)
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS: NO INFORMATION AVAILABLE.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
IRRITATION: MAY CAUSE SKIN IRRITATION.
SENSITIZATION: NO INFORMATION AVAILABLE.
GERM CELL MUTAGENICITY: NO INFORMATION AVAILABLE.
CARCINOGENICITY: NO INFORMATION AVAILABLE.
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE.
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
CHRONIC TOXICITY: AVOID REPEATED EXPOSURE.
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY - PRODUCT INFORMATION:
UNKNOWN ACUTE TOXICITY:
0% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
17% OF THE MIXTURE CONSISTS OF COMPONENTS(S) OF UNKNOWN HAZARDS TO THE
AQUATIC ENVIRONMENT
CHEMICAL NAME ALGAE/AQUATIC FISH CRUSTACEA
PLANTS
SODIUM CARBONATE 242: 120 H 300: 96 H 265: 48 H DAPHNIA
497-19-8 NITZSCHIA MG/L LEPOMIS MAGNA MG/L EC50
EC50 MACROCHIRUS
MG/L LC50
STATIC 310 -
1220: 96 H
PIMEPHALES
PROMELAS MG/L
LC50 STATIC
SODIUM SULFATE 13500: 96 H 630: 96 H DAPHNIA
7757-82-6 LEPOMIS MACRO- MAGNA MG/L EC50
CHIRUS MG/L 2564: 48 H DAPHNIA
LC50 13500 - MAGNA MG/L EC50
14500: 96 H
PIMEPHALES
PROMELAS MG/L
LC50 3040 -
4380: 96 H
LEPOMIS MACRO-
CHIRUS MG/L
LC50 STATIC
6800: 96 H
PIMEPHALES
PROMELAS MG/L
LC50 STATIC
SODIUM TRIPOLYPHOSHPATE 1650: 48 H
7758-29-4 LEUCISCUS IDUS
MG/L LC50
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
DISPOSAL OF WASTES:
DISPOSAL SHOULD BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND
LOCAL LAWS AND REGULATIONS.
CONTAMINATED PACKAGING: DO NOT REUSE CONTAINER.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
| 15. REGULATORY INFORMATION | |
INTERNATIONAL INVENTORIES:
TSCA: COMPLIES
DSL/NDSL: COMPLIES
EINECS/ELINCS: DOES NOT COMPLY
AICS: COMPLIES
LEGEND:
TSCA: UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL: CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
EINECS/ELINCS:
EUROPEAN INVENTORY OF EXISTING CHEMICAL SUBSTANCES/EUROPEAN LIST OF
NOTIFIED CHEMICAL SUBSTANCES
AICS: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES
US FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS WHICH ARE
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
REACTIVE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
CWA (CLEAN WATER ACT):
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42)
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL
CHEMICAL NAME HAZARDOUS SUBSTANCES CERCLA/SARA REPORTABLE QUANTITY
RQS RQ (RQ)
TRISODIUM 5000 LB RQ 5000 LB FINAL RQ
PHOSPHATE RQ 2270 KG FINAL RQ
10101-89-0
US STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW JERSEY MASSACHUSETTS PENNSYLVANIA
SODIUM SULFATE X X
7757-82-6
TRISODIUM X X
PHOSPHATE
10101-89-0
SODIUM X X
TRIPOLYPHOSHPATE
7758-29-4
U.S. EPA LABEL INFORMATION:
EPA PESTICIDE REGISTRATION NUMBER: NOT APPLICABLE
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARDS 1
FLAMMABILITY 0
INSTABILITY 0
PHYSICAL AND CHEMICAL PROPERTIES: YES
HMIS:
HEALTH HAZARDS 1
FLAMMABILITY 0
PHYSICAL HAZARDS 0
PERSONAL PROTECTION N/A
ISSUE DATE: 12-AUG-2015
REVISION DATE: 12-AUG-2015
REVISION NOTE: NO INFORMATION AVAILABLE
DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.