| Common Name: | LIQUID ROC 300 POUCH |
| Manufacturer: | MKT FASTENING |
| SDS Revision Date: | 9/8/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 12A184, 21P655 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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MKT(R*)
...A SOLID CONNECTION
MKT FASTENING LIQUID ROC 300 POUCH
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
REVISION DATE: 09/08/2015
DATE OF ISSUE: 07/16/2015
VERSION: 1.0
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME: MKT FASTENING LIQUID ROC 300 POUCH
1.2. INTENDED USE OF THE PRODUCT:
USE OF THE SUBSTANCE/MIXTURE:
BONDING METAL RODS TO CONCRETE OR MASONRY BASE MATERIALS.
1.3. NAME, ADDRESS, AND TELEPHONE OF THE RESPONSIBLE PARTY:
COMPANY:
MKT FASTENING, LLC
#1 GUNNEBO DRIVE
LONOKE, AR 72086
T: 501-676-2222
INSIDE CONTINENTAL US: 800-424-9300
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
800-424-9300
CHEMTREC - TOLL FREE 24 HOUR EMERGENCY TELEPHONE NUMBER
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
FLAM. LIQ. 3 H226
SKIN IRRIT. 2 H315
EYE DAM. 1 H318
SKIN SENS. 1 H317
CARC. 1A H350
REPR. 2 H361
STOT SE 3 H335
STOT RE 1 H372
ASP. TOX. 1 H304
AQUATIC ACUTE 2 H401
FULL TEXT OF H-PHRASES: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS05: CORROSION
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H226: FLAMMABLE LIQUID AND VAPOR.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H318: CAUSES SERIOUS EYE DAMAGE.
H335: MAY CAUSE RESPIRATORY IRRITATION.
H350: MAY CAUSE CANCER.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H401: TOXIC TO AQUATIC LIFE.
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210:
KEEP AWAY FROM EXTREMELY HIGH OR LOW TEMPERATURES, IGNITION SOURCES, AND
INCOMPATIBLE MATERIALS. - NO SMOKING.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, AND LIGHTING EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE VAPORS, MIST, OR SPRAY.
P264:
WASH HANDS, FOREARMS, AND OTHER EXPOSED AREAS THOROUGHLY AFTER HANDLING.
P270: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272: CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280: WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, AND EYE PROTECTION.
P301+P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR DOCTOR.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER/
SHOWER.
P304+P340:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P314: GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
P321: SPECIFIC TREATMENT (SEE SECTION 4 ON THIS SDS).
P331: DO NOT INDUCE VOMITING.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P362+P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
P370+P378:
IN CASE OF FIRE: USE APPROPRIATE MEDIA (SEE SECTION 5) TO EXTINGUISH.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL,
AND INTERNATIONAL REGULATIONS.
P403+P233+P235:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
KEEP COOL.
P308+310+313:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR.
2.3. OTHER HAZARDS:
EXPOSURE MAY AGGRAVATE THOSE WITH PRE-EXISTING EYE, SKIN, OR RESPIRATORY
CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT % CLASSIFICATION (GHS-US)
IDENTIFIER
RESIN:
1,3-BENZENEDI- (CAS NO): 33.5 NOT CLASSIFIED
CARBOXYLIC ACID, 36346-15-3
POLYMER WITH
2,5-FURANDIONE,
2,2'-OXYBIS
[ETHANOL] AND
1,2-PROPANEDIOL
STYRENE (CAS NO): 18.1 FLAM. LIQ. 3, H226
100-42-5 ACUTE TOX. 4 (ORAL), H302
ACUTE TOX. 4
(INHALATION: VAPOUR), H332
SKIN IRRIT. 2, H315
EYE IRRIT. 2A, H319
CARC. 1B, H350
REPR. 2, H361
STOT SE 3, H335
STOT RE 1, H372
ASP. TOX. 1, H304
AQUATIC ACUTE 2, H401
AQUATIC CHRONIC 3, H412
HARDENER:
CALCIUM OXIDE (CAS NO): 43.38 - 46.21 SKIN IRRIT. 2, H315
1305-78-8 EYE DAM. 1, H318
STOT SE 3, H335
AQUATIC ACUTE 3, H402
DIBENZOYL (CAS NO): 1.4 ORG. PEROX. B, H241
PEROXIDE 94-36-0 EYE IRRIT. 2A, H319
SKIN SENS. 1, H317
AQUATIC ACUTE 1, H400
1,2-BENZENEDI- (CAS NO): 1.4 SKIN SENS. 1, H317
CARBOXYLIC ACID, 84-61-7 REPR. 2, H361
DICYCLOHEXYL AQUATIC CHRONIC 3, H412
ESTER
QUARTZ (CAS NO): 0.235 - 0.945 CARC. 1A, H350
14808-60-7 STOT SE 3, H335
STOT RE 1, H372
FULL TEXT OF H-PHRASES: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
WHEN SYMPTOMS OCCUR:
GO INTO OPEN AIR AND VENTILATE SUSPECTED AREA. OBTAIN MEDICAL ATTENTION IF
BREATHING DIFFICULTY PERSISTS.
FIRST-AID MEASURES AFTER SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. DRENCH AFFECTED AREA WITH WATER FOR AT LEAST
15 MINUTES. OBTAIN MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR AT LEAST 60 MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET IMMEDIATE MEDICAL
ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
DO NOT INDUCE VOMITING. RINSE MOUTH. IMMEDIATELY CALL A POISON CENTER OR
DOCTOR/PHYSICIAN.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES:
CAUSES SKIN IRRITATION. MAY CAUSE RESPIRATORY IRRITATION. CAUSES SERIOUS EYE
DAMAGE. SKIN SENSITIZATION. MAY CAUSE CANCER. SUSPECTED OF DAMAGING
FERTILITY OR THE UNBORN CHILD. CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR
REPEATED EXPOSURE. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS/INJURIES AFTER INHALATION:
IRRITATION OF THE RESPIRATORY TRACT AND THE OTHER MUCOUS MEMBRANES.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
REDNESS, PAIN, SWELLING, ITCHING, BURNING, DRYNESS, AND DERMATITIS. MAY
CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
CAUSES PERMANENT DAMAGE TO THE CORNEA, IRIS, OR CONJUNCTIVA.
SYMPTOMS/INJURIES AFTER INGESTION:
ASPIRATION INTO THE LUNGS CAN OCCUR DURING INGESTION OR VOMITING AND MAY
CAUSE LUNG INJURY.
CHRONIC SYMPTOMS:
MAY CAUSE CANCER. SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
IF EXPOSED OR CONCERNED, GET MEDICAL ADVICE AND ATTENTION. IF MEDICAL
ADVICE IS NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
DRY CHEMICAL POWDER, ALCOHOL-RESISTANT FOAM, CARBON DIOXIDE (CO2). WATER MAY
BE INEFFECTIVE BUT WATER SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINER COOL.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A HEAVY WATER STREAM. A HEAVY WATER STREAM MAY SPREAD BURNING
LIQUID.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE OR EXPLOSIVE VAPOR-AIR MIXTURE.
REACTIVITY:
REACTS VIOLENTLY WITH STRONG OXIDIZERS. INCREASED RISK OF FIRE OR EXPLOSION.
5.3. ADVICE FOR FIREFIGHTERS:
PRECAUTIONARY MEASURES FIRE:
EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL FIRE.
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS.
IN CASE OF MAJOR FIRE AND LARGE QUANTITIES:
EVACUATE AREA. FIGHT FIRE REMOTELY DUE TO THE RISK OF EXPLOSION.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
OTHER INFORMATION:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. KEEP AWAY FROM HEAT, HOT
SURFACES, SPARKS, OPEN FLAMES, AND OTHER IGNITION SOURCES. NO SMOKING. USE
SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES. DO NOT BREATHE VAPOR, MIST OR
SPRAY. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: USE APPROPRIATE PERSONAL PROTECTION EQUIPMENT (PPE).
EMERGENCY PROCEDURES:
EVACUATE UNNECESSARY PERSONNEL. STOP LEAK IF SAFE TO DO SO.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES:
VENTILATE AREA. UPON ARRIVAL AT THE SCENE, A FIRST RESPONDER IS EXPECTED TO
RECOGNIZE THE PRESENCE OF DANGEROUS GOODS, PROTECT ONESELF AND THE PUBLIC,
SECURE THE AREA, AND CALL FOR THE ASSISTANCE OF TRAINED PERSONNEL AS SOON AS
CONDITIONS PERMIT. ELIMINATE IGNITION SOURCES.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN ANY SPILLS WITH DIKES OR ABSORBENTS TO PREVENT MIGRATION AND ENTRY
INTO SEWERS OR STREAMS. AS AN IMMEDIATE PRECAUTIONARY MEASURE, ISOLATE SPILL
OR LEAK AREA IN ALL DIRECTIONS.
METHODS FOR CLEANING UP:
CLEAN UP SPILLS IMMEDIATELY AND DISPOSE OF WASTE SAFELY. TRANSFER SPILLED
MATERIAL TO A SUITABLE CONTAINER FOR DISPOSAL. CONTACT COMPETENT AUTHORITIES
AFTER A SPILL. ABSORB AND/OR CONTAIN SPILL WITH INERT MATERIAL. DO NOT TAKE
UP IN COMBUSTIBLE MATERIAL SUCH AS: SAW DUST OR CELLULOSIC MATERIAL. USE
ONLY NON-SPARKING TOOLS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION. SEE SECTION 13,
DISPOSAL CONSIDERATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. TAKE PRECAUTIONARY MEASURES
AGAINST STATIC DISCHARGE. USE ONLY NON-SPARKING TOOLS. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. OBTAIN
SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE (DUST, VAPOR, MIST, GAS).
HYGIENE MEASURES:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PROCEDURES.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
COMPLY WITH APPLICABLE REGULATIONS. TAKE ACTION TO PREVENT STATIC
DISCHARGES. GROUND AND BOND CONTAINER AND RECEIVING EQUIPMENT. USE
EXPLOSION-PROOF ELECTRICAL, VENTILATING, AND LIGHTING EQUIPMENT.
STORAGE CONDITIONS:
STORE IN A DRY, COOL PLACE. KEEP/STORE AWAY FROM DIRECT SUNLIGHT, EXTREMELY
HIGH OR LOW TEMPERATURES AND INCOMPATIBLE MATERIALS. STORE IN A
WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. KEEP IN FIREPROOF
PLACE.
INCOMPATIBLE PRODUCTS: STRONG ACIDS, STRONG BASES, STRONG OXIDIZERS.
7.3. SPECIFIC END USE(S):
BONDING METAL RODS TO CONCRETE OR MASONRY BASE MATERIALS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
FOR SUBSTANCES LISTED IN SECTION 3 THAT ARE NOT LISTED HERE, THERE ARE NO
ESTABLISHED EXPOSURE LIMITS FROM THE MANUFACTURER, SUPPLIER, IMPORTER, OR
THE APPROPRIATE ADVISORY AGENCY INCLUDING:
ACGIH (TLV), NIOSH (REL), OR OSHA (PEL).
STYRENE (100-42-5):
USA ACGIH:
ACGIH TWA (PPM): 20 PPM
USA ACGIH:
ACGIH STEL (PPM): 40 PPM
USA ACGIH:
ACGIH CHEMICAL CATEGORY: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 215 MG/M3
USA NIOSH:
NIOSH REL (TWA) (PPM): 50 PPM
USA NIOSH:
NIOSH REL (STEL) (MG/M3): 425 MG/M3
USA NIOSH:
NIOSH REL (STEL) (PPM): 100 PPM
USA IDLH:
US IDLH (PPM): 700 PPM
USA OSHA:
OSHA PEL (TWA) (PPM): 100 PPM
USA OSHA:
OSHA PEL (CEILING) (PPM): 200 PPM
DIBENZOYL PEROXIDE (94-36-0):
USA ACGIH:
ACGIH TWA (MG/M3): 5 MG/M3
USA ACGIH:
ACGIH CHEMICAL CATEGORY: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 5 MG/M3
USA IDLH:
US IDLH (MG/M3): 1500 MG/M3
USA OSHA:
OSHA PEL (TWA) (MG/M3): 5 MG/M3
CALCIUM OXIDE (1305-78-8):
USA ACGIH:
ACGIH TWA (MG/M3): 2 MG/M3
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 2 MG/M3
USA IDLH:
US IDLH (MG/M3): 25 MG/M3
USA OSHA:
OSHA PEL (TWA) (MG/M3): 5 MG/M3
QUARTZ (14808-60-7):
USA ACGIH:
ACGIH TWA (MG/M3): 0.025 MG/M3 (RESPIRABLE FRACTION)
USA ACGIH:
ACGIH CHEMICAL CATEGORY: A2 - SUSPECTED HUMAN CARCINOGEN
USA NIOSH:
NIOSH REL (TWA) (MG/M3): 0.05 MG/M3 (RESPIRABLE DUST)
USA IDLH:
US IDLH (MG/M3): 50 MG/M3 (RESPIRABLE DUST)
USA OSHA:
OSHA PEL (STEL) (MG/M3): 250 MPPCF/%SiO2+5, 10 MG/M3/%SiO2+2
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE
IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. ENSURE ADEQUATE VENTILATION,
ESPECIALLY IN CONFINED AREAS. ENSURE ALL NATIONAL/LOCAL REGULATIONS ARE
OBSERVED. GAS DETECTORS SHOULD BE USED WHEN FLAMMABLE GASES OR VAPORS MAY BE
RELEASED. PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE
FOLLOWED. USE EXPLOSION-PROOF EQUIPMENT.
PERSONAL PROTECTIVE EQUIPMENT:
GLOVES. PROTECTIVE CLOTHING. PROTECTIVE GOGGLES. INSUFFICIENT VENTILATION:
WEAR RESPIRATORY PROTECTION. FACE SHIELD.
MATERIALS FOR PROTECTIVE CLOTHING:
CHEMICALLY RESISTANT MATERIALS AND FABRICS. WEAR FIRE/FLAME
RESISTANT/RETARDANT CLOTHING.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR FACE SHIELD.
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, APPROVED
RESPIRATORY PROTECTION SHOULD BE WORN. IN CASE OF INADEQUATE VENTILATION,
OXYGEN DEFICIENT ATMOSPHERE, OR WHERE EXPOSURE LEVELS ARE NOT KNOWN WEAR
APPROVED RESPIRATORY PROTECTION.
OTHER INFORMATION: WHEN USING, DO NOT EAT, DRINK OR SMOKE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE:
PART A: LIGHT YELLOW VISCOUS LIQUID
PART B: WHITE POWDER
ODOR: STYRENE ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
EVAPORATION RATE: NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
SOLUBILITY: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
REACTS VIOLENTLY WITH STRONG OXIDIZERS. INCREASED RISK OF FIRE OR EXPLOSION.
10.2. CHEMICAL STABILITY:
FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE OR EXPLOSIVE VAPOR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT, EXTREMELY HIGH OR LOW TEMPERATURES, HEAT, HOT SURFACES,
SPARKS, OPEN FLAMES, INCOMPATIBLE MATERIALS, AND OTHER IGNITION SOURCES.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS, STRONG BASES, STRONG OXIDIZERS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES (CO, CO2). OXIDES OF CALCIUM.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
STYRENE (100-42-5):
LD50 ORAL RAT: 1000 MG/KG
LC50 INHALATION RAT: 11.7 MG/L/4H
DIBENZOYL PEROXIDE (94-36-0):
LD50 ORAL RAT: 7710 MG/KG
1,2-BENZENEDICARBOXYLIC ACID, DICYCLOHEXYL ESTER (84-61-7):
LD50 ORAL RAT: 30 ML/KG
CALCIUM OXIDE (1305-78-8):
LD50 ORAL RAT: >2000 MG/KG
LD50 DERMAL RABBIT: >2500 MG/KG
QUARTZ (14808-60-7):
LD50 ORAL RAT: >5000 MG/KG
LD50 DERMAL RAT: >5000 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY OR SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: MAY CAUSE CANCER.
STYRENE (100-42-5):
IARC GROUP: 2B
NATIONAL TOXICOLOGY PROGRAM (NTP) STATUS:
REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
OSHA HAZARD COMMUNICATION CARCINOGEN LIST:
IN OSHA HAZARD COMMUNICATION CARCINOGEN LIST.
DIBENZOYL PEROXIDE (94-36-0):
IARC GROUP: 3
QUARTZ (14808-60-7):
IARC GROUP: 1
NATIONAL TOXICOLOGY PROGRAM (NTP) STATUS: KNOWN HUMAN CARCINOGENS.
OSHA HAZARD COMMUNICATION CARCINOGEN LIST:
IN OSHA HAZARD COMMUNICATION CARCINOGEN LIST.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS/INJURIES AFTER INHALATION:
IRRITATION OF THE RESPIRATORY TRACT AND THE OTHER MUCOUS MEMBRANES.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
REDNESS, PAIN, SWELLING, ITCHING, BURNING, DRYNESS, AND DERMATITIS. MAY
CAUSE AN ALLERGIC SKIN REACTION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
CAUSES PERMANENT DAMAGE TO THE CORNEA, IRIS, OR CONJUNCTIVA.
SYMPTOMS/INJURIES AFTER INGESTION:
ASPIRATION INTO THE LUNGS CAN OCCUR DURING INGESTION OR VOMITING AND MAY
CAUSE LUNG INJURY.
CHRONIC SYMPTOMS:
MAY CAUSE CANCER. SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: TOXIC TO AQUATIC LIFE.
STYRENE (100-42-5):
LC50 FISH 1:
3.24 - 4.99 MG/L (EXPOSURE TIME: 96 H - SPECIES: PIMEPHALES PROMELAS
[FLOW-THROUGH])
EC50 DAPHNIA 1:
3.3 - 7.4 MG/L (EXPOSURE TIME: 48 H - SPECIES: DAPHNIA MAGNA)
LC50 FISH 2:
19.03 - 33.53 MG/L (EXPOSURE TIME: 96 H - SPECIES: LEPOMIS MACROCHIRUS
[STATIC])
NOEC (ACUTE):
44 MG/KG (EXPOSURE TIME: 14 DAYS - SPECIES: EISENIA FOETIDA [SOIL DRY
WEIGHT])
DIBENZOYL PEROXIDE (94-36-0):
EC50 DAPHNIA 1: 0.07 MG/L
CALCIUM OXIDE (1305-78-8):
LC50 FISH 1:
1070 MG/L (EXPOSURE TIME: 96 H - SPECIES: CYPRINUS CARPIO [STATIC])
12.2. PERSISTENCE AND DEGRADABILITY:
MKT FASTENING LIQUID ROC 300 POUCH:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
MKT FASTENING LIQUID ROC 300 POUCH:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
STYRENE (100-42-5):
BCF FISH 1: 13.5
LOG POW: 2.95
CALCIUM OXIDE (1305-78-8):
BCF FISH 1: (NO BIOACCUMULATION)
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL,
AND INTERNATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS:
AVOID RELEASE TO THE ENVIRONMENT. THIS MATERIAL IS HAZARDOUS TO THE AQUATIC
ENVIRONMENT. KEEP OUT OF SEWERS AND WATERWAYS.
| SECTION 14: TRANSPORT INFORMATION | |
14.1. IN ACCORDANCE WITH DOT:
PROPER SHIPPING NAME: RESIN SOLUTION FLAMMABLE (STYRENE)
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN1866
LABEL CODES: 3
PACKING GROUP: III
ERG NUMBER: 128
CLASS 3, FLAMMABLE LIQUIDS
14.2. IN ACCORDANCE WITH IMDG:
PROPER SHIPPING NAME: RESIN SOLUTION (STYRENE)
HAZARD CLASS: 3
IDENTIFICATION NUMBER: UN1866
PACKING GROUP: III
LABEL CODES: 3
EMS-NO. (FIRE): F-E
EMS-NO. (SPILLAGE): S-E
CLASS 3 - FLAMMABLE LIQUIDS
14.3. IN ACCORDANCE WITH IATA:
PROPER SHIPPING NAME: RESIN SOLUTION (STYRENE)
PACKING GROUP: III
IDENTIFICATION NUMBER: UN1866
HAZARD CLASS: 3
LABEL CODES: 3
ERG CODE (IATA): 3L
CLASS 3, FLAMMABLE LIQUIDS
| SECTION 15: REGULATORY INFORMATION | |
15.1 US FEDERAL REGULATIONS:
MKT FASTENING LIQUID ROC 300 POUCH:
SARA SECTION 311/312 HAZARD CLASSES:
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
1,3-BENZENEDICARBOXYLIC ACID, POLYMER WITH 2,5-FURANDIONE,
2,2'-OXYBIS[ETHANOL] AND 1,2-PROPANEDIOL (36346-15-3):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
STYRENE (100-42-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON UNITED STATES SARA SECTION 313
SARA SECTION 313 - EMISSION REPORTING: 0.1%
DIBENZOYL PEROXIDE (94-36-0):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON UNITED STATES SARA SECTION 313
SARA SECTION 313 - EMISSION REPORTING: 10%
1,2-BENZENEDICARBOXYLIC ACID, DICYCLOHEXYL ESTER (84-61-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
CALCIUM OXIDE (1305-78-8):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SARA SECTION 311/312 HAZARD CLASSES: IMMEDIATE (ACUTE) HEALTH HAZARD
QUARTZ (14808-60-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
15.2 US STATE REGULATIONS:
QUARTZ (14808-60-7):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST:
WARNING:
THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
STYRENE (100-42-5):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
DIBENZOYL PEROXIDE (94-36-0):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) - ENVIRONMENTAL HAZARD LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
CALCIUM OXIDE (1305-78-8):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
QUARTZ (14808-60-7):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
REVISION DATE: 09/08/2015
OTHER INFORMATION:
THIS DOCUMENT HAS BEEN PREPARED IN ACCORDANCE WITH THE SDS REQUIREMENTS OF
THE OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200.
GHS FULL TEXT PHRASES:
ACUTE TOX. 4 (INHALATION: VAPOUR):
ACUTE TOXICITY (INHALATION: VAPOUR) CATEGORY 4
ACUTE TOX. 4 (ORAL): ACUTE TOXICITY (ORAL) CATEGORY 4
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 1
AQUATIC ACUTE 2:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 2
AQUATIC ACUTE 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE HAZARD CATEGORY 3
AQUATIC CHRONIC 3:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD CATEGORY 3
ASP. TOX. 1: ASPIRATION HAZARD CATEGORY 1
CARC. 1A: CARCINOGENICITY CATEGORY 1A
CARC. 1B: CARCINOGENICITY CATEGORY 1B
EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 1
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A
FLAM. LIQ. 3: FLAMMABLE LIQUIDS CATEGORY 3
ORG. PEROX. B: ORGANIC PEROXIDE CATEGORY B
REPR. 2: REPRODUCTIVE TOXICITY CATEGORY 2
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION CATEGORY 2
SKIN SENS. 1: SKIN SENSITIZATION CATEGORY 1
STOT RE 1: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) CATEGORY 1
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
H226: FLAMMABLE LIQUID AND VAPOR
H241: HEATING MAY CAUSE A FIRE OR EXPLOSION
H302: HARMFUL IF SWALLOWED
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS
H315: CAUSES SKIN IRRITATION
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H318: CAUSES SERIOUS EYE DAMAGE
H319: CAUSES SERIOUS EYE IRRITATION
H332: HARMFUL IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H350: MAY CAUSE CANCER
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD
H372: CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
H400: VERY TOXIC TO AQUATIC LIFE
H401: TOXIC TO AQUATIC LIFE
H402: HARMFUL TO AQUATIC LIFE
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING ANY
SPECIFIC PROPERTY OF THE PRODUCT.
SDS US (GHS HAZCOM)
EN (ENGLISH US)