| Common Name: | KNOCK'ER LOOSE PENETRATING SOLVENT NO. 03024 (ITEM 1003276) |
| Manufacturer: | CRC |
| SDS Revision Date: | 8/18/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 12P769, 12P770, 3APN8, 3EED8, 3EED9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: KNOCK'ER LOOSE(R*) PENETRATING SOLVENT
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: NO. 03024 (ITEM# 1003276)
RECOMMENDED USE: PENETRANT
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC):
800-424-9300 (US)
703-527-3887 (INTERNATIONAL)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE LIQUIDS: CATEGORY 4
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1A
ASPIRATION HAZARD: CATEGORY 1
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 2
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
COMBUSTIBLE LIQUID. MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. CAUSES
SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE
IRRITATION. TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM FLAMES AND HOT SURFACES-NO SMOKING. USE WITH ADEQUATE
VENTILATION. OPEN DOORS AND WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH
AIR SUPPLY DURING USE AND WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY
SYMPTOMS LISTED ON THIS LABEL, INCREASE VENTILATION OR LEAVE THE AREA.
AVOID BREATHING MIST OR VAPOR. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED
WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES/EYE PROTECTION/FACE PROTECTION. AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER/DOCTOR. DO NOT INDUCE VOMITING.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
COLLECT SPILLAGE.
STORAGE: STORE IN A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
DISTILLATES (PETROLEUM), HYDROTREATED 64742-46-7 50 - 60
MIDDLE
DIPROPYLENE GLYCOL MONOMETHYL 88917-22-0 10 - 20
ETHER ACETATE
DIPROPYLENE GLYCOL MONOPROPYL 29911-27-1 10 - 20
ETHER (DPMP)
TURPENTINE, OIL 8006-64-2 10 - 20
2,6-DIMETHYL-4-HEPTANONE 108-83-8 3 - 5
DISTILLATES (PETROLEUM), HYDROTREATED 64742-47-8 1 - 3
LIGHT
NAPHTHA (PETROLEUM), HYDROTREATED 64742-48-9 1 - 3
HEAVY
PINE OIL 8002-09-3 1 - 3
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
IF BREATHING IS DIFFICULT, REMOVE TO FRESH AIR AND KEEP AT REST IN A
POSITION COMFORTABLE FOR BREATHING. CALL A PHYSICIAN IF SYMPTOMS
DEVELOP OR PERSIST.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND
WATER.
IN CASE OF ECZEMA OR OTHER SKIN DISORDERS:
SEEK MEDICAL ATTENTION AND TAKE ALONG THESE INSTRUCTIONS. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. RINSE MOUTH. DO NOT
INDUCE VOMITING. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT
DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING,
AND BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY
CAUSE AN ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
THE PRODUCT IS COMBUSTIBLE, AND HEATING MAY GENERATE VAPORS WHICH MAY FORM
EXPLOSIVE VAPOR/AIR MIXTURES. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE
FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES. MOVE CONTAINERS FROM
FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
GENERAL FIRE HAZARDS: COMBUSTIBLE LIQUID.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS,
OR FLAMES IN IMMEDIATE AREA). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
CLOTHING DURING CLEAN-UP. AVOID BREATHING MIST OR VAPOR. DO NOT TOUCH
DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE
PROTECTIVE CLOTHING. ENSURE ADEQUATE VENTILATION. LOCAL AUTHORITIES
SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR
PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES
IN IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. THIS PRODUCT IS MISCIBLE IN WATER. PREVENT PRODUCT
FROM ENTERING DRAINS.
SMALL SPILLS:
ABSORB WITH EARTH, SAND OR OTHER NON-COMBUSTIBLE MATERIAL AND TRANSFER
TO CONTAINERS FOR LATER DISPOSAL. WIPE UP WITH ABSORBENT MATERIAL (E.G.
CLOTH, FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. INFORM APPROPRIATE MANAGERIAL OR
SUPERVISORY PERSONNEL OF ALL ENVIRONMENTAL RELEASES. PREVENT FURTHER
LEAKAGE OR SPILLAGE IF SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS,
WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. WHEN
USING DO NOT SMOKE. AVOID BREATHING MIST OR VAPOR. AVOID CONTACT WITH EYES,
SKIN, AND CLOTHING. AVOID PROLONGED EXPOSURE. PROVIDE ADEQUATE VENTILATION.
WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH HANDS THOROUGHLY AFTER
HANDLING. AVOID RELEASE TO THE ENVIRONMENT. OBSERVE GOOD INDUSTRIAL HYGIENE
PRACTICES. USE CARE IN HANDLING/STORAGE. FOR PRODUCT USAGE INSTRUCTIONS,
SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME. STORE IN A COOL, DRY PLACE
OUT OF DIRECT SUNLIGHT. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A
WELL-VENTILATED PLACE. KEEP IN AN AREA EQUIPPED WITH SPRINKLERS. STORE
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
2,6-DIMETHYL-4-HEPTANONE PEL 290 MG/M3
(CAS 108-83-8)
50 PPM
DISTILLATES (PETROLEUM), PEL 400 MG/M3
HYDROTREATED LIGHT (CAS
64742-47-8)
100 PPM
DISTILLATES (PETROLEUM), PEL 5 MG/M3 MIST.
HYDROTREATED MIDDLE (CAS
64742-46-7)
400 MG/M3
100 PPM
NAPHTHA (PETROLEUM), PEL 400 MG/M3
HYDROTREATED HEAVY (CAS
64742-48-9)
100 PPM
TURPENTINE, OIL (CAS 8006-64-2) PEL 560 MG/M3
100 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE FORM
2,6-DIMETHYL-4-HEPTANONE TWA 25 PPM
(CAS 108-83-8)
DISTILLATES (PETROLEUM), TWA 5 MG/M3 INHALABLE
HYDROTREATED MIDDLE (CAS FRACTION.
64742-46-7)
TURPENTINE, OIL (CAS 8006-64-2) TWA 20 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
2,6-DIMETHYL-4-HEPTANONE TWA 150 MG/M3
(CAS 108-83-8)
25 PPM
DISTILLATES (PETROLEUM), TWA 100 MG/M3
HYDROTREATED LIGHT (CAS
64742-47-8)
DISTILLATES (PETROLEUM), STEL 10 MG/M3 MIST.
HYDROTREATED MIDDLE (CAS
64742-46-7)
TWA 5 MG/M3 MIST.
NAPHTHA (PETROLEUM), TWA 400 MG/M3
HYDROTREATED HEAVY (CAS
64742-48-9)
100 PPM
TURPENTINE, OIL (CAS 8006-64-2) TWA 560 MG/M3
100 PPM
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS
TO AN ACCEPTABLE LEVEL. PROVIDE EYEWASH STATION.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: NITRILE. RUBBER.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR
WITH AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING
APPARATUS IN CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS
NEEDED TO DETERMINE ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES,
SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING,
AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO
REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: RED.
ODOR: PLEASANT PINE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -121 DEG. F (-85 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE: 311 DEG. F (155 DEG. C) ESTIMATED
FLASH POINT: 147 DEG. F (63.9 DEG. C) TAG CLOSED CUP
EVAPORATION RATE: MODERATE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 0.7 % ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 8.3 % ESTIMATED
VAPOR PRESSURE: 4.7 HPA ESTIMATED
VAPOR DENSITY: >1 (AIR = 1)
RELATIVE DENSITY: 0.86
SOLUBILITY (WATER): NEGLIGIBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 401 DEG. F (205 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY (KINEMATIC): NOT AVAILABLE.
PERCENT VOLATILE: 100 % ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
AVOID HEAT, SPARKS, OPEN FLAMES AND OTHER IGNITION SOURCES. AVOID
TEMPERATURES EXCEEDING THE FLASH POINT. CONTACT WITH INCOMPATIBLE
MATERIALS.
INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG BASES. STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
ALDEHYDES. KETONES. ORGANIC ACIDS. CARBON OXIDES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: PROLONGED INHALATION MAY BE HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
DROPLETS OF THE PRODUCT ASPIRATED INTO THE LUNGS THROUGH INGESTION OR
VOMITING MAY CAUSE A SERIOUS CHEMICAL PNEUMONIA.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
ASPIRATION MAY CAUSE PULMONARY EDEMA AND PNEUMONITIS. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING,
AND BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY
CAUSE AN ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
PRODUCT SPECIES TEST RESULTS
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8):
ACUTE:
DERMAL:
LD50 RABBIT 16200 MG/KG
INHALATION:
LC50 RAT >5 MG/L, 4 HOURS
ORAL:
LD50 RAT 5285 MG/KG
DIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE (CAS 88917-22-0):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
INHALATION:
LC50 RAT >20 MG/L, 4 HOURS
ORAL:
LD50 RAT >5000 MG/KG
DIPROPYLENE GLYCOL MONOPROPYL ETHER (DPMP) (CAS 29911-27-1):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
5340 MG/KG
ORAL:
LD50 RAT >2000 MG/KG
1475 MG/KG
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8):
ACUTE:
DERMAL:
LD50 RAT >2000 MG/KG
DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE (CAS 64742-46-7):
ACUTE:
DERMAL:
LD50 RAT >2000 MG/KG
ORAL:
LD50 RAT >5000 MG/KG
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (CAS 64742-48-9):
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG
TURPENTINE, OIL (CAS 8006-64-2):
ACUTE:
INHALATION:
LC50 RAT 3590 MG/L, 1 HOURS
ORAL:
LD50 RAT 5760 MG/KG
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
ACGIH SENSITIZATION:
TURPENTINE AND SELECTED MONOTERPENES (CAS 8006-64-2): DERMAL SENSITIZATION
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY: NOT LISTED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS:
NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS. IF ASPIRATED INTO LUNGS
DURING SWALLOWING OR VOMITING, MAY CAUSE CHEMICAL PNEUMONIA, PULMONARY
INJURY OR DEATH.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS SPECIES TEST RESULTS
DIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE (CAS 88917-22-0):
AQUATIC:
ACUTE:
CRUSTACEA LC50 WATER FLEA (DAPHNIA 2701 MG/L, 48 HOURS
MAGNA)
FISH LC50 FATHEAD MINNOW 151 MG/L, 96 HOURS
(PIMEPHALES
PROMELAS)
RAINBOW TROUT, 111 MG/L, 96 HOURS
DONALDSON TROUT
(ONCORHYNCHUS
MYKISS)
DIPROPYLENE GLYCOL MONOPROPYL ETHER (DPMP) (CAS 29911-27-1):
AQUATIC:
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA >100 MG/L, 48 HOURS
MAGNA)
FISH LC50 RAINBOW TROUT, >100 MG/L, 96 HOURS
DONALDSON TROUT
(ONCORHYNCHUS
MYKISS)
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8):
AQUATIC:
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 1.1 MG/L, 48 HOURS
MAGNA)
FISH LC50 FATHEAD MINNOW 3 MG/L, 96 HOURS
(PIMEPHALES
PROMELAS)
DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE (CAS 64742-46-7):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 2.7 - 5.1 MG/L, 48 HOURS
PULEX)
FISH LC50 RAINBOW TROUT, 8.8 MG/L, 96 HOURS
DONALDSON TROUT
(ONCORHYNCHUS
MYKISS)
8.8 MG/L, 96 HOURS
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (CAS 64742-48-9):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA 2.7 - 5.1 MG/L, 48 HOURS
PULEX)
FISH LC50 RAINBOW TROUT, 8.8 MG/L, 96 HOURS
DONALDSON TROUT
(ONCORHYNCHUS
MYKISS)
8.8 MG/L, 96 HOURS
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT
DATA NOT SHOWN.
PERSISTENCE AND DEGRADABILITY:
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
DIPROPYLENE GLYCOL MONOMETHYL ETHER ACETATE: 0.61 OECD 107
DIPROPYLENE GLYCOL MONOPROPYL ETHER (DPMP):
0.87 OECD 107
0.88 OECD 107
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
THE PRODUCT CONTAINS VOLATILE ORGANIC COMPOUNDS WHICH HAVE A PHOTOCHEMICAL
OZONE CREATION POTENTIAL.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL OF WASTE FROM RESIDUES / UNUSED PRODUCTS:
THIS PRODUCT IS NOT A RCRA HAZARDOUS WASTE (SEE 40 CFR PART
261.20 - 261.33). EMPTY CONTAINERS MAY BE RECYCLED. DO NOT ALLOW THIS
MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES. DO NOT CONTAMINATE PONDS,
WATERWAYS OR DITCHES WITH CHEMICAL OR USED CONTAINER. DISPOSE IN
ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE: NOT REGULATED.
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED AS DANGEROUS GOODS.
IATA: NOT REGULATED AS DANGEROUS GOODS.
IMDG: NOT REGULATED AS DANGEROUS GOODS.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL: LISTED SUBSTANCE
NOT LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
CERCLA HAZARDOUS SUBSTANCES:
REPORTABLE QUANTITY: NOT LISTED.
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE
ITS RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130):
NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FEMA PRIORITY SUBSTANCES RESPIRATORY HEALTH AND SAFETY IN THE FLAVOR
MANUFACTURING WORKPLACE:
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8):
OTHER FLAVORING SUBSTANCES WITH OSHA PEL'S
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SECTION 311/312:
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: YES
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
US STATE REGULATIONS:
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE (CAS 64742-46-7)
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (CAS 64742-48-9)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8)
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (CAS 64742-48-9)
PINE OIL (CAS 8002-09-3)
TURPENTINE, OIL (CAS 8006-64-2)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8)
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (CAS 64742-48-9)
TURPENTINE, OIL (CAS 8006-64-2)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8)
DISTILLATES (PETROLEUM), HYDROTREATED LIGHT (CAS 64742-47-8)
US. RHODE ISLAND RTK:
2,6-DIMETHYL-4-HEPTANONE (CAS 108-83-8)
NAPHTHA (PETROLEUM), HYDROTREATED HEAVY (CAS 64742-48-9)
TURPENTINE, OIL (CAS 8006-64-2)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
BENZENE (CAS 71-43-2):
LISTED: FEBRUARY 27, 1987
ETHYLBENZENE (CAS 100-41-4):
LISTED: JUNE 11, 2004
NAPHTHALENE (CAS 91-20-3):
LISTED: APRIL 19, 2002
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/DEVELOPMENTAL TOXIN
BENZENE (CAS 71-43-2):
LISTED: DECEMBER 26, 1997
TOLUENE (CAS 108-88-3):
LISTED: JANUARY 1, 1991
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/MALE REPRODUCTIVE TOXIN
BENZENE (CAS 71-43-2):
LISTED: DECEMBER 26, 1997
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 100 %
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS REGULATED AS A PENETRANT. THIS PRODUCT IS COMPLIANT
FOR USE IN ALL 50 STATES.
VOC CONTENT (CA): 24 %
VOC CONTENT (OTC): 24 %
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL NO
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL NO
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL NO
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) NO
NEW ZEALAND NEW ZEALAND INVENTORY NO
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND NO
CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH
THE INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT
LISTED OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE
GOVERNING COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 11-19-2013
REVISION DATE: 08-18-2017
PREPARED BY: ALLISON YOON
VERSION #: 04
FURTHER INFORMATION:
CRC # 548A/1002565
HMIS(R*) RATINGS:
HEALTH 1
FLAMMABILITY 2
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA RATINGS:
HEALTH 1
FLAMMABILITY 2
INSTABILITY 0
NFPA RATINGS:
1
2
0
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC'S KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY CRC TO BE
ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND DIRECTIONS ON THE
LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION CONTAINED ON THIS
(M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY PROFESSIONAL, OR CRC
INDUSTRIES, INC..
REVISION INFORMATION:
THIS DOCUMENT HAS UNDERGONE SIGNIFICANT CHANGES AND SHOULD BE REVIEWED
IN ITS ENTIRETY.
MATERIAL NAME: KNOCK'ER LOOSE(R*) PENETRATING SOLVENT
SDS US