| Common Name: | MINIMAL EXPANSION FOAM NO. 14077 (ITEM 1004808) |
| Manufacturer: | CRC INDUSTRIES |
| SDS Revision Date: | 1/25/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 12W320 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: MINIMAL EXPANSION FOAM
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: NO. 14077 (ITEM# 1004808)
RECOMMENDED USE: FOAM INSULATOR AND SEALANT
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES. INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC): 800-424-9300 (US)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS:
ACUTE TOXICITY, INHALATION: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
SENSITIZATION, RESPIRATORY: CATEGORY 1
SENSITIZATION, SKIN: CATEGORY 1
CARCINOGENICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 RESPIRATORY TRACT IRRITATION
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 1
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES
SERIOUS EYE IRRITATION. HARMFUL IF INHALED. MAY CAUSE ALLERGY OR ASTHMA
SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. MAY CAUSE RESPIRATORY
IRRITATION. SUSPECTED OF CAUSING CANCER. CAUSES DAMAGE TO ORGANS THROUGH
PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER
IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT BREATHE MIST/VAPORS. DO NOT
APPLY WHILE EQUIPMENT IS ENERGIZED. EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS. VAPORS WILL ACCUMULATE READILY AND MAY IGNITE. USE ONLY WITH
ADEQUATE VENTILATION; MAINTAIN VENTILATION DURING USE AND UNTIL ALL VAPORS
ARE GONE. OPEN DOORS AND WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR
SUPPLY DURING USE AND WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY
SYMPTOMS LISTED ON THIS LABEL, INCREASE VENTILATION OR LEAVE THE AREA. WASH
THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE
WORKPLACE. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE
PROTECTION. IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT
BEFORE REUSE.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER/DOCTOR.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. STORE LOCKED UP. PROTECT FROM SUNLIGHT.
DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. EXPOSURE TO
HIGH TEMPERATURE MAY CAUSE CAN TO BURST.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION:
WHEN EXPOSED TO EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE TO
HARMFUL OR FATAL CORROSIVE GASES SUCH AS HYDROGEN CHLORIDE AND POSSIBLY
PHOSGENE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
CHLORINATED PARAFFINS 63449-39-8 10 - 30
POLYMERIC DIPHENYLMETHANE 9016-87-9 10 - 30
DIISOCYANATE
4,4-DIPHENYLMETHANE DIISOCYANATE 101-68-8 7 - 13
(M.D.I.)
ISOBUTANE 75-28-5 5 - 10
TRIS(2-CHLOROISOPROPYL) PHOSPHATE 13674-84-5 5 - 10
DIMETHYL ETHER 115-10-6 1 - 5
PROPANE 74-98-6 1 - 5
SOYBEAN OIL 8001-22-7 1 - 5
2,2-DIMORPHOLINYLDIETHYL ETHER 6425-39-4 0.5 - 1.5
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. OXYGEN OR ARTIFICIAL RESPIRATION IF NEEDED. DO NOT USE
MOUTH-TO-MOUTH METHOD IF VICTIM INHALED THE SUBSTANCE. INDUCE ARTIFICIAL
RESPIRATION WITH THE AID OF A POCKET MASK EQUIPPED WITH A ONE-WAY VALVE OR
OTHER PROPER RESPIRATORY MEDICAL DEVICE.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND WATER.
IN CASE OF ECZEMA OR OTHER SKIN DISORDERS:
SEEK MEDICAL ATTENTION AND TAKE ALONG THESE INSTRUCTIONS. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
IN THE UNLIKELY EVENT OF SWALLOWING CONTACT A PHYSICIAN OR POISON CONTROL
CENTER. RINSE MOUTH.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING, AND BLURRED VISION. MAY CAUSE RESPIRATORY IRRITATION. DIFFICULTY
IN BREATHING. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH. PROLONGED EXPOSURE MAY CAUSE
CHRONIC EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
WARM. KEEP VICTIM UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF
THE MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
WATER. DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE
TIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY RUPTURE WHEN EXPOSED TO
HEAT OR FLAME. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED. WHEN
EXPOSED TO EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE TO HARMFUL OR
FATAL CORROSIVE GASES SUCH AS HYDROGEN CHLORIDE AND POSSIBLY PHOSGENE.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO
WITHOUT RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR
PRESSURE BUILD UP. USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE
HAZARDS OF OTHER INVOLVED MATERIALS. IN THE EVENT OF FIRE AND/OR EXPLOSION
DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS:
EXTREMELY FLAMMABLE AEROSOL. CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER
MAY RUPTURE WHEN EXPOSED TO HEAT OR FLAME.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. MANY GASES ARE HEAVIER THAN AIR AND
WILL SPREAD ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
BASEMENTS, TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING
DURING CLEAN-UP. DO NOT BREATHE MIST/VAPORS. EMERGENCY PERSONNEL NEED
SELF-CONTAINED BREATHING EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE
CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE
SECTION 3 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. THE PRODUCT IS IMMISCIBLE WITH WATER AND WILL SEDIMENT IN
WATER SYSTEMS. THIS MATERIAL IS CLASSIFIED AS A WATER POLLUTANT UNDER THE
CLEAN WATER ACT AND SHOULD BE PREVENTED FROM CONTAMINATING SOIL OR FROM
ENTERING SEWAGE AND DRAINAGE SYSTEMS WHICH LEAD TO WATERWAYS. STOP THE FLOW
OF MATERIAL, IF THIS IS WITHOUT RISK. WIPE UP WITH ABSORBENT MATERIAL (E.G.
CLOTH, FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
PUT MATERIAL IN SUITABLE, COVERED, LABELED CONTAINERS. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. PRESSURIZED CONTAINER: DO NOT
PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS MISSING OR
DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER INCANDESCENT MATERIAL
DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE IS THOROUGHLY DRY. DO NOT
CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE CONTAINERS TO HEAT, FLAME,
SPARKS, OR OTHER SOURCES OF IGNITION. USE CAUTION AROUND ENERGIZED
EQUIPMENT. THE METAL CONTAINER WILL CONDUCT ELECTRICITY IF IT CONTACTS A
LIVE SOURCE. THIS MAY RESULT IN INJURY TO THE USER FROM ELECTRICAL SHOCK
AND/OR FLASH FIRE. DO NOT BREATHE MIST/VAPORS. AVOID CONTACT WITH EYES,
SKIN, AND CLOTHING. AVOID PROLONGED EXPOSURE. WHEN USING, DO NOT EAT, DRINK
OR SMOKE. SHOULD BE HANDLED IN CLOSED SYSTEMS, IF POSSIBLE. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. WEAR APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. WASH HANDS THOROUGHLY AFTER HANDLING. OBSERVE GOOD INDUSTRIAL
HYGIENE PRACTICES. FOR PRODUCT USAGE INSTRUCTIONS, SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 1 AEROSOL.
PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES OF
IGNITION. THIS MATERIAL CAN ACCUMULATE STATIC CHARGE WHICH MAY CAUSE SPARK
AND BECOME AN IGNITION SOURCE. STORE IN TIGHTLY CLOSED CONTAINER. STORE IN
A WELL-VENTILATED PLACE. STORED CONTAINERS SHOULD BE PERIODICALLY CHECKED
FOR GENERAL CONDITION AND LEAKAGE. STORE AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT. AT THIS TIME, THE
OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
US. OSHA TABLE 2-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE FORM
4,4-DIPHENYLMETHANE CEILING 0.2 MG/M3
DIISOCYANATE (M.D.I.) (CAS 0.02 PPM
101-68-8)
PROPANE (CAS 74-98-6) PEL 1800 MG/M3
1000 PPM
SOYBEAN OIL (CAS PEL 5 MG/M3 RESPIRABLE FRACTION.
8001-22-7) 15 MG/M3 TOTAL DUST.
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
4,4-DIPHENYLMETHANE TWA 0.005 PPM
DIISOCYANATE (M.D.I.) (CAS
101-68-8)
ISOBUTANE (CAS 75-28-5) STEL 1000 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE FORM
4,4-DIPHENYLMETHANE CEILING 0.2 MG/M3
DIISOCYANATE (M.D.I.) (CAS 0.02 PPM
101-68-8)
TWA 0.05 MG/M3
0.005 PPM
ISOBUTANE (CAS 75-28-5) TWA 1900 MG/M3
800 PPM
PROPANE (CAS 74-98-6) TWA 1800 MG/M3
1000 PPM
SOYBEAN OIL (CAS TWA 5 MG/M3 RESPIRABLE MIST.
8001-22-7) 10 MG/M3 TOTAL MIST
US. WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE
DIMETHYL ETHER (CAS 115-10-6) TWA 1880 MG/M3
1000 PPM
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION SHOULD BE USED. VENTILATION RATES SHOULD BE
MATCHED TO CONDITIONS. IF APPLICABLE, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION, OR OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS
BELOW RECOMMENDED EXPOSURE LIMITS. IF EXPOSURE LIMITS HAVE NOT BEEN
ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN ACCEPTABLE LEVEL. GENERAL
VENTILATION NORMALLY ADEQUATE. PROVIDE EYEWASH STATION AND SAFETY SHOWER.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: NITRILE. NEOPRENE. RUBBER GLOVES.
OTHER: WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN
CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO DETERMINE
ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
OBSERVE ANY MEDICAL SURVEILLANCE REQUIREMENTS. WHEN USING DO NOT SMOKE.
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: AEROSOL.
COLOR: AMBER.
ODOR: SOLVENT.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: 98.6 DEG. F (37 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
FLASH POINT: 396 DEG. F (202.2 DEG. C) ESTIMATED
EVAPORATION RATE: MODERATE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 1298.4 HPA ESTIMATED
VAPOR DENSITY: >1 (AIR = 1)
RELATIVE DENSITY: 1.05
SOLUBILITY(IES):
SOLUBILITY (WATER): NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
PERCENT VOLATILE: 6% ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. WHEN EXPOSED TO EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE
TO HARMFUL OR FATAL CORROSIVE GASES SUCH AS HYDROGEN CHLORIDE AND POSSIBLY
PHOSGENE. CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS: STRONG BASES. OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES. NITROGEN OXIDES (NOX). HYDROGEN CHLORIDE. PHOSGENE.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
HARMFUL IF INHALED. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
SEVERE EYE IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS,
SWELLING, AND BLURRED VISION. MAY CAUSE RESPIRATORY IRRITATION. DIFFICULTY
IN BREATHING. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: HARMFUL IF INHALED.
COMPONENTS SPECIES TEST RESULTS
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8):
ACUTE:
DERMAL:
LD50 RABBIT >5000 MG/KG
INHALATION:
LC50 RAT 0.38 MG/L, 4 HOURS
ORAL:
LD50 RAT >= 5000 MG/KG
DIMETHYL ETHER (CAS 115-10-6):
ACUTE:
INHALATION:
LC50 RAT 164000 PPM, 4 HOURS
308.5 MG/L, 4 HOURS
ISOBUTANE (CAS 75-28-5):
ACUTE:
INHALATION:
LC50 RAT 142500 PPM, 4 HOURS
POLYMERIC DIPHENYLMETHANE DIISOCYANATE (CAS 9016-87-9):
ACUTE:
DERMAL:
LD50 RABBIT >= 10000 MG/KG
INHALATION:
LC50 RAT 490 MG/M3, 4 HOURS
ORAL:
LD50 RAT >= 2000 MG/KG
TRIS(2-CHLOROISOPROPYL) PHOSPHATE (CAS 13674-84-5):
ACUTE:
DERMAL:
LD50 RAT >5000 MG/KG
INHALATION:
LC50 RAT >4.6 MG/L
ORAL:
LD50 RAT 2800 MG/KG
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8):
3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
CHLORINATED PARAFFINS (CAS 63449-39-8): 2B POSSIBLY CARCINOGENIC TO HUMANS.
POLYMERIC DIPHENYLMETHANE DIISOCYANATE (CAS 9016-87-9):
3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. CAUSES DAMAGE TO ORGANS THROUGH
PROLONGED OR REPEATED EXPOSURE. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
THE PRODUCT IS NOT CLASSIFIED AS ENVIRONMENTALLY HAZARDOUS. HOWEVER, THIS
DOES NOT EXCLUDE THE POSSIBILITY THAT LARGE OR FREQUENT SPILLS CAN HAVE A
HARMFUL OR DAMAGING EFFECT ON THE ENVIRONMENT.
COMPONENTS SPECIES TEST RESULTS
CHLORINATED PARAFFINS (CAS 63449-39-8):
AQUATIC:
FISH LC50 BLUEGILL (LEPOMIS MACROCHIRUS) >0.1 MG/L, 96 HOURS
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF ANY INGREDIENTS IN THE
MIXTURE.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
DIMETHYL ETHER: 0.1
ISOBUTANE: 2.76
PROPANE: 2.36
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
THIS PRODUCT IS NOT A RCRA HAZARDOUS WASTE (SEE 40 CFR PART 261.20 -
261.33). EMPTY CONTAINERS MAY BE RECYCLED. COLLECT AND RECLAIM OR DISPOSE
IN SEALED CONTAINERS AT LICENSED WASTE DISPOSAL SITE. CONTENTS UNDER
PRESSURE. DO NOT PUNCTURE, INCINERATE OR CRUSH. DISPOSE IN ACCORDANCE WITH
ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE: NOT REGULATED.
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ERG CODE: 10L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO.
EMS: F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
DOT; IMDG: LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL: LISTED SUBSTANCE
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8)
POLYMERIC DIPHENYLMETHANE DIISOCYANATE (CAS 9016-87-9)
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8)
ISOBUTANE (CAS 75-28-5) PROPANE (CAS 74-98-6)
CERCLA HAZARDOUS SUBSTANCES: REPORTABLE QUANTITY
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8): 5000 LBS
ISOBUTANE (CAS 75-28-5): 100 LBS
PROPANE (CAS 74-98-6): 100 LBS
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130):
DIMETHYL ETHER (CAS 115-10-6)
ISOBUTANE (CAS 75-28-5)
PROPANE (CAS 74-98-6)
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
CLASSIFIED HAZARD CATEGORIES:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
GAS UNDER PRESSURE
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
SKIN CORROSION OR IRRITATION
SERIOUS EYE DAMAGE OR EYE IRRITATION
RESPIRATORY OR SKIN SENSITIZATION
CARCINOGENICITY
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 311/312 HAZARDOUS CHEMICAL: YES
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) 101-68-8 7 - 13
POLYMERIC DIPHENYLMETHANE DIISOCYANATE 9016-87-9 10 - 30
US STATE REGULATIONS:
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8)
DIMETHYL ETHER (CAS 115-10-6)
ISOBUTANE (CAS 75-28-5)
POLYMERIC DIPHENYLMETHANE DIISOCYANATE (CAS 9016-87-9)
PROPANE (CAS 74-98-6)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8)
DIMETHYL ETHER (CAS 115-10-6)
ISOBUTANE (CAS 75-28-5)
PROPANE (CAS 74-98-6)
SOYBEAN OIL (CAS 8001-22-7)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8)
DIMETHYL ETHER (CAS 115-10-6)
ISOBUTANE (CAS 75-28-5)
PROPANE (CAS 74-98-6)
SOYBEAN OIL (CAS 8001-22-7)
US. RHODE ISLAND RTK:
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8)
DIMETHYL ETHER (CAS 115-10-6)
PROPANE (CAS 74-98-6)
SOYBEAN OIL (CAS 8001-22-7)
CALIFORNIA PROPOSITION 65:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 2016
(PROPOSITION 65):
THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS CURRENTLY LISTED AS
CARCINOGENS OR REPRODUCTIVE TOXINS. FOR MORE INFORMATION GO TO
WWW.P65WARNINGS.CA.GOV.
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22. 69502.3, SUBD. (A)):
4,4-DIPHENYLMETHANE DIISOCYANATE (M.D.I.) (CAS 101-68-8)
CHLORINATED PARAFFINS (CAS 63449-39-8)
ISOBUTANE (CAS 75-28-5)
POLYMERIC DIPHENYLMETHANE DIISOCYANATE (CAS 9016-87-9)
TRIS(2-CHLOROISOPROPYL) PHOSPHATE (CAS 13674-84-5)
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 13.1%
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS: NOT REGULATED
VOC CONTENT (CA): 13.1%
VOC CONTENT (OTC): 13.1%
INTERNATIONAL INVENTORIES:
COUNTRY(S) OR REGION INVENTORY NAME ON INVENTORY
(YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL YES
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING NO
COMMERCIAL CHEMICAL SUBSTANCES
(EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW NO
CHEMICAL SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS YES
AND CHEMICAL SUBSTANCES (PICCS)
TAIWAN TAIWAN CHEMICAL SUBSTANCE INVENTORY YES
(TCSI)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 02-13-2015
REVISION DATE: 01-25-2019
PREPARED BY: ALLISON YOON
VERSION #: 03
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC'S KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY CRC TO BE
ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND DIRECTIONS ON THE
LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION CONTAINED ON THIS
(M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY PROFESSIONAL, OR CRC
INDUSTRIES, INC.
REVISION INFORMATION:
THIS DOCUMENT HAS UNDERGONE SIGNIFICANT CHANGES AND SHOULD BE REVIEWED IN
ITS ENTIRETY.
MATERIAL NAME: MINIMAL EXPANSION FOAM
SDS US