| Common Name: | R&O 68 HYDRAULIC OIL |
| Manufacturer: | VALVOLINE |
| SDS Revision Date: | 7/31/2016 |
| SDS Format: | No Format Specified |
| Item Number(s): | 12W334 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
V(TM)
VALVOLINE(TM)
SAFETY DATA SHEET
VALVOLINE(TM) R&O 68 HYDRAULIC OIL
VV70240
REVISION DATE: 07/31/2016
PRINT DATE: 08/30/2022
MSDS NUMBER: R0137402
VERSION: 1.1
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: VALVOLINE(TM) R&O 68 HYDRAULIC OIL
PRODUCT CODE: VV70240
COMPANY:
VALVOLINE LLC
3499 BLAZER PARKWAY
LEXINGTON, KY 40509
UNITED STATES OF AMERICA
E-MAIL ADDRESS: SDS@VALVOLINE.COM
TELEPHONE: 1-800-TEAMVAL
TELEFAX:
EMERGENCY TELEPHONE NUMBER: 1-800-VALVOLINE
| 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
SKIN SENSITISATION: CATEGORY 1
ACUTE AQUATIC TOXICITY: CATEGORY 3
CHRONIC AQUATIC TOXICITY: CATEGORY 3
GHS-LABELLING:
HAZARD PICTOGRAMS: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P261: AVOID BREATHING DUST/ FUME/ GAS/ MIST/ VAPOURS/ SPRAY.
P272:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280: WEAR PROTECTIVE GLOVES.
RESPONSE:
P302 + P352:
IF ON SKIN: WASH WITH PLENTY OF WATER.
P333 + P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ ATTENTION.
P362 + P364: TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
DISPOSAL:
P501:
DISPOSE OF CONTENTS/ CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CONCENTRATION
ALKYL PHENOL >=0.1 - <1 %
HEXAHYDRO-1,3,5-TRIS-(-2-HYDROXYETHYL)-S-TRIAZINE 4719-04-4 >=0.1 - <1 %
| 4. FIRST AID MEASURES | |
GENERAL ADVICE:
CONSULT A PHYSICIAN.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
FIRST AID MEASURES FOR DIFFERENT EXPOSURE ROUTES:
IN CASE OF EYE CONTACT:
FLUSH EYES WITH WATER AT LEAST 15 MINUTES. GET MEDICAL ATTENTION IF EYE
IRRITATION DEVELOPS OR PERSISTS.
REMOVE CONTACT LENSES.
IN CASE OF SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING AND SHOES IMMEDIATELY.
WASH OFF IMMEDIATELY WITH PLENTY OF WATER.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
IF SKIN IRRITATION PERSISTS, CALL A PHYSICIAN.
IF INHALED:
MOVE TO FRESH AIR.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
IN CASE OF SHORTNESS OF BREATH, GIVE OXYGEN.
IF SWALLOWED:
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
CONSULT A PHYSICIAN IF NECESSARY.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED (NEW):
SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING,
SWALLOWING, AND/OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE:
STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA)
IRRITATION (NOSE, THROAT, AIRWAYS)
NOTES TO PHYSICIAN (NEW):
NO HAZARDS WHICH REQUIRE SPECIAL FIRST AID MEASURES.
| 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
ABC POWDER
CARBON DIOXIDE (CO2)
DRY CHEMICAL
WATER MIST
UNSUITABLE EXTINGUISHING MEDIA: HALONS
HAZARDOUS COMBUSTION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE
HYDROCARBONS
SPECIFIC EXTINGUISHING METHODS:
KEEP CONTAINERS AND SURROUNDINGS COOL WITH WATER SPRAY.
PREVENT FIRE EXTINGUISHING WATER FROM CONTAMINATING SURFACE WATER OR THE
GROUND WATER SYSTEM.
FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED
OF IN ACCORDANCE WITH LOCAL REGULATIONS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
USE PERSONAL PROTECTIVE EQUIPMENT.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF
SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
ENVIRONMENTAL PRECAUTIONS:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST).
LARGE SPILLS SHOULD BE COLLECTED MECHANICALLY (REMOVE BY PUMPING) FOR
DISPOSAL.
KEEP IN SUITABLE, CLOSED CONTAINERS FOR DISPOSAL.
ADDITIONAL ADVICE:
COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
TECHNICAL MEASURES:
NORMAL MEASURES FOR PREVENTIVE FIRE PROTECTION.
ADVICE ON SAFE HANDLING:
DO NOT BREATHE VAPOURS OR SPRAY MIST.
FOR PERSONAL PROTECTION SEE SECTION 8.
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS.
AVOID EXCEEDING OF THE GIVEN OCCUPATIONAL EXPOSURE LIMITS (SEE SECTION 8).
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
AVOIDANCE OF CONTACT: STRONG OXIDIZING AGENTS
STORAGE:
CONDITIONS FOR SAFE STORAGE:
STORE IN ORIGINAL CONTAINER.
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
MATERIALS TO AVOID: STRONG OXIDIZING AGENTS
OTHER DATA: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
CONTAINS NO SUBSTANCES WITH OCCUPATIONAL EXPOSURE LIMIT VALUES.
ENGINEERING MEASURES:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION
TO MAINTAIN EXPOSURE BELOW LEVEL OF OVEREXPOSURE (FROM KNOWN, SUSPECTED
OR APPARENT ADVERSE EFFECTS).
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
WHEN WORKERS ARE FACING CONCENTRATIONS ABOVE THE EXPOSURE LIMIT THEY MUST
USE APPROPRIATE CERTIFIED RESPIRATORS.
EYE PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS
HAND PROTECTION:
WEAR RESISTANT GLOVES SUCH AS:
MATERIAL: POLYVINYL ALCOHOL
SKIN AND BODY PROTECTION:
WEAR AS APPROPRIATE: SAFETY SHOES
HYGIENE MEASURES:
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.
WHEN USING DO NOT EAT, DRINK OR SMOKE.
ENSURE THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE
WORKSTATION LOCATION.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
ODOUR: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: >199 DEG. C
METHOD: CLEVELAND OPEN CUP
UPPER EXPLOSION LIMIT:
6 %(V)
CALCULATED EXPLOSIVE LIMIT
LOWER EXPLOSION LIMIT:
1 %(V)
CALCULATED EXPLOSIVE LIMIT
VAPOUR PRESSURE:
1.3333333 HPA (20 DEG. C)
CALCULATED VAPOR PRESSURE
DENSITY: 0.8704 G/CM3 (15.56 DEG. C)
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
SOLUBILITY IN OTHER SOLVENTS: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
THERMAL DECOMPOSITION: NO DATA AVAILABLE
| 10. STABILITY AND REACTIVITY | |
POSSIBILITY OF HAZARDOUS REACTIONS:
NO HAZARDS TO BE SPECIALLY MENTIONED.
HAZARDOUS POLYMERISATION DOES NOT OCCUR.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE
HYDROCARBONS
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT:
ACUTE ORAL TOXICITY: NO DATA AVAILABLE
ACUTE INHALATION TOXICITY: NO DATA AVAILABLE
ACUTE DERMAL TOXICITY: NO DATA AVAILABLE
SKIN CORROSION/IRRITATION: NO DATA AVAILABLE
SERIOUS EYE DAMAGE/EYE IRRITATION: NO DATA AVAILABLE
RESPIRATORY OR SKIN SENSITISATION: NO DATA AVAILABLE
COMPONENTS:
HEXAHYDRO-1,3,5-TRIS-(-2-HYDROXYETHYL)-S-TRIAZINE:
ACUTE ORAL TOXICITY:
LD 50 RAT, MALE: 1,620 MG/KG
LD 50 RAT, FEMALE: 1,956 MG/KG
ACUTE INHALATION TOXICITY:
LC 50 RAT: 0.371 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: DUST/MIST
ACUTE DERMAL TOXICITY:
LD 50 RAT: >2 G/KG
RESPIRATORY OR SKIN SENSITISATION:
SPECIES: GUINEA PIG
CLASSIFICATION: MAY CAUSE SENSITIZATION BY SKIN CONTACT.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
PRODUCT: NO DATA AVAILABLE
COMPONENTS:
ALKYL PHENOL:
ECOTOXICOLOGY ASSESSMENT:
ACUTE AQUATIC TOXICITY: VERY TOXIC TO AQUATIC LIFE.
CHRONIC AQUATIC TOXICITY:
VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
HEXAHYDRO-1,3,5-TRIS-(-2-HYDROXYETHYL)-S-TRIAZINE:
TOXICITY TO FISH:
LC 50 (ONCORHYNCHUS MYKISS (RAINBOW TROUT)): >100 MG/L
EXPOSURE TIME: 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC 50 (WATER FLEA (DAPHNIA MAGNA)): 27.9 MG/L
EXPOSURE TIME: 48 H
TOXICITY TO ALGAE:
ERC50 (GREEN ALGAE): >10 - 100 MG/L
EXPOSURE TIME: 72 H
PERSISTENCE AND DEGRADABILITY:
PRODUCT: NO DATA AVAILABLE
COMPONENTS:
HEXAHYDRO-1,3,5-TRIS-(-2-HYDROXYETHYL)-S-TRIAZINE:
BIODEGRADABILITY: READILY BIODEGRADABLE
BIOACCUMULATIVE POTENTIAL:
PRODUCT: NO DATA AVAILABLE
COMPONENTS:
HEXAHYDRO-1,3,5-TRIS-(-2-HYDROXYETHYL)-S-TRIAZINE:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 0.071
MOBILITY IN SOIL:
PRODUCT: NO DATA AVAILABLE
COMPONENTS: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS:
PRODUCT:
OZONE-DEPLETION POTENTIAL: NO DATA AVAILABLE
COMPONENTS: NO DATA AVAILABLE
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
WASTE FROM RESIDUES:
DISPOSE OF IN ACCORDANCE WITH THE EUROPEAN DIRECTIVES ON WASTE AND
HAZARDOUS WASTE.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER.
CONTAINER HAZARDOUS WHEN EMPTY.
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
DISPOSE OF AS UNUSED PRODUCT.
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
DO NOT RE-USE EMPTY CONTAINERS.
DO NOT BURN, OR USE A CUTTING TORCH ON, THE EMPTY DRUM.
DISPOSAL CONSIDERATIONS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
| 14. TRANSPORT INFORMATION | |
INTERNATIONAL TRANSPORT REGULATIONS:
REGULATION:
ID NUMBER:
PROPER SHIPPING NAME:
*HAZARD CLASS:
SUBSIDIARY HAZARDS:
PACKING GROUP:
MARINE POLLUTANT / LTD. QTY.:
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO: NOT DANGEROUS GOODS
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER: NOT DANGEROUS GOODS
INTERNATIONAL MARITIME DANGEROUS GOODS: NOT DANGEROUS GOODS
UN_DG: NOT DANGEROUS GOODS
*ORM = ORM-D, CBL = COMBUSTIBLE LIQUID:
MARINE POLLUTANT: NO
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT
QUANTITY, END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED.
CONSULT SHIPPING DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE
SHIPMENT.
| 15. REGULATORY INFORMATION | |
OTHER INTERNATIONAL REGULATIONS:
NOTIFICATION STATUS:
US. TOXIC SUBSTANCES CONTROL ACT: Y (POSITIVE LISTING)
CANADA. CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA). DOMESTIC SUBSTANCES
LIST (DSL). (CAN. GAZ. PART II, VOL. 133):
Y (POSITIVE LISTING)
AUSTRALIA. INDUSTRIAL CHEMICAL (NOTIFICATION AND ASSESSMENT) ACT:
Y (POSITIVE LISTING)
NEW ZEALAND. INVENTORY OF CHEMICALS (NZIOC), AS PUBLISHED BY ERMA NEW
ZEALAND:
N (NEGATIVE LISTING)
JAPAN. KASHIN-HOU LAW LIST: N (NEGATIVE LISTING)
KOREA. TOXIC CHEMICAL CONTROL LAW (TCCL) LIST: Y (POSITIVE LISTING)
PHILIPPINES. THE TOXIC SUBSTANCES AND HAZARDOUS AND NUCLEAR WASTE CONTROL
ACT:
Y (POSITIVE LISTING)
CHINA. INVENTORY OF EXISTING CHEMICAL SUBSTANCES: N (NEGATIVE LISTING)
| 16. OTHER INFORMATION | |
FURTHER INFORMATION:
OTHER INFORMATION:
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS
ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS MSDS HAS BEEN
PREPARED BY VALVOLINE'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT.
LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE, BUT NOT NECESSARILY ARE,
USED IN THIS SAFETY DATA SHEET:
ACGIH: AMERICAN CONFERENCE OF INDUSTRIAL HYGIENISTS
BEI: BIOLOGICAL EXPOSURE INDEX
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY).
CMR: CARCINOGENIC, MUTAGENIC OR TOXIC FOR REPRODUCTION
FG: FOOD GRADE
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS.
H-STATEMENT: HAZARD STATEMENT
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION.
IATA-DGR:
DANGEROUS GOODS REGULATION BY THE "INTERNATIONAL AIR TRANSPORT
ASSOCIATION" (IATA).
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
ICAO-TI (ICAO):
TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION"
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
LOGPOW: OCTANOL-WATER PARTITION COEFFICIENT
LCXX: LETHAL CONCENTRATION, FOR XX PERCENT OF TEST POPULATION
LDXX: LETHAL DOSE, FOR XX PERCENT OF TEST POPULATION.
ICXX: INHIBITORY CONCENTRATION FOR XX OF A SUBSTANCE
ECXX: EFFECTIVE CONCENTRATION OF XX
N.O.S.: NOT OTHERWISE SPECIFIED
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OEL: OCCUPATIONAL EXPOSURE LIMIT
P-STATEMENT: PRECAUTIONARY STATEMENT
PBT: PERSISTENT , BIOACCUMULATIVE AND TOXIC
PPE: PERSONAL PROTECTIVE EQUIPMENT
STEL: SHORT-TERM EXPOSURE LIMIT
STOT: SPECIFIC TARGET ORGAN TOXICITY
TLV: THRESHOLD LIMIT VALUE
TWA: TIME-WEIGHTED AVERAGE
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
WEL: WORKPLACE EXPOSURE LEVEL
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
DOT: DEPARTMENT OF TRANSPORTATION
FIFRA: FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT
HMIRC: HAZARDOUS MATERIALS INFORMATION REVIEW COMMISSION
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PMRA: HEALTH CANADA PEST MANAGEMENT REGULATORY AGENCY
RTK: RIGHT TO KNOW
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM