| Common Name: | LOCTITE SI 5900 INSTANT GASKET MAKER KNOWN AS 5900 FLANGE SEALANT, 20166 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 4/1/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 12Z235 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 006.1
ISSUE DATE: 04/01/2015
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE SI 5900 INSTANT GASKET MAKER KNOWN AS 5900 FLANGE SEALANT
IDH NUMBER: 212184
PRODUCT TYPE: SILICONE
ITEM NUMBER: 20166
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING DUST OR FUMES. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED
WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR EYE AND FACE
PROTECTION. WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: NOT PRESCRIBED
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
CALCIUM CARBONATE 471-34-1 30 - 60
SILICONE RESIN PROPRIETARY 10 - 30
OXIMINO SILANE PROPRIETARY 1 - 5
OCTADECANOIC ACID 57-11-4 1 - 5
CARBON BLACK 1333-86-4 1 - 5
ALUMINUM 7429-90-5 0.1 - 1
BUTAN-2-ONE O,O',O",O"'- 34206-40-1 0.1 - 1
SILANETETRAYLTETRAOXIME
3-(TRIMETHOXYSILYL)PROPYLAMINE 13822-56-5 0.1 - 1
WHITE MINERAL OIL (PETROLEUM), HIGHLY 8042-47-5 0.1 - 1
REFINED
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
METHYL ETHYL KETOXIME IS FORMED DURING CURE.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR IN CASE OF ACCIDENTAL INHALATION OF VAPOURS OR
DECOMPOSITION PRODUCTS. IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL
ATTENTION.
SKIN CONTACT:
WIPE OFF PASTE WITH PAPER TOWEL OR CLOTH. WASH WITH SOAP AND WATER. IF SKIN
IRRITATION PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF CONTAINED BREATHING APPARATUS. PREVENT INHALATION OF FUMES AND
GASES.
UNUSUAL FIRE OR EXPLOSION HAZARDS: NONE
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. FORMALDEHYDE. IRRITATING ORGANIC
VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. MAINTAIN GOOD VENTILATION FOR LARGE
SPILLS. PLACE SCRAP MATERIAL IN A WELL VENTILATED AREA AND ALLOW TO CURE TO
RUBBER.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. DO NOT HANDLE CONTACT LENSES UNTIL
ALL SEALANT HAS BEEN REMOVED FROM HANDS. RESIDUAL SEALANT MAY TRANSFER TO
LENSES AND CAUSE EYE IRRITATION. DO NOT WEAR CONTACT LENSES.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 0 DEG. C (32 DEG. F) AND 32 DEG. C
(89.6 DEG. F)
STORE IN A DRY AREA BELOW 90 DEG. F. KEEP CONTAINER CLOSED.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
CALCIUM CARBONATE 10 MG/M3 TWA 5 MG/M3 PEL NONE NONE
TOTAL DUST. RESPIRABLE
FRACTION.
15 MG/M3 PEL
TOTAL DUST.
SILICONE RESIN NONE NONE NONE NONE
OXIMINO SILANE NONE NONE NONE NONE
OCTADECANOIC ACID 10 MG/M3 TWA NONE NONE NONE
CARBON BLACK 3 MG/M3 TWA 3.5 MG/M3 PEL NONE NONE
INHALABLE
FRACTION.
ALUMINUM 1 MG/M3 TWA 5 MG/M3 PEL NONE NONE
RESPIRABLE (AS Al)
FRACTION. RESPIRABLE
DUST.
15 MG/M3 PEL
(AS Al)
TOTAL DUST.
BUTAN-2-ONE O,O',O", NONE NONE NONE NONE
O"'-SILANETETRAYL-
TETRAOXIME
3-(TRIMETHOXYSILYL) NONE NONE NONE NONE
PROPYLAMINE
WHITE MINERAL OIL 5 MG/M3 TWA 5 MG/M3 TWA NONE NONE
(PETROLEUM), HIGHLY INHALABLE MIST
REFINED FRACTION.
5 MG/M3 PEL
MIST.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE A DUST MASK FOR PARTICULATE CONCENTRATIONS EXCEEDING THE OCCUPATIONAL
EXPOSURE LIMIT. USE AN ORGANIC VAPOR RESPIRATOR FOR CONCENTRATIONS
EXCEEDING THE OCCUPATIONAL EXPOSURE LIMIT.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. SAFETY SHOWERS AND EYE
WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
PERMEATION RESISTANT GLOVES (BUTYL RUBBER, NITRILE RUBBER, POLYVINYL
ALCOHOL).
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: PASTE
COLOR: BLACK
ODOR: MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <5 MMHg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: NOT APPLICABLE
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.31 AT 20 DEG. C (68 DEG. F)
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: >93 DEG. C (>199.4 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT APPLICABLE
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT APPLICABLE
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: POLYMERISES IN PRESENCE OF WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 3.31%; 44.47 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE AT NORMAL CONDITIONS.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
METHYL ETHYL KETOXIME FORMED DURING CURE. OXIDES OF CARBON. OXIDES OF
SILICON. FORMALDEHYDE.
INCOMPATIBLE MATERIALS: POLYMERIZES ON CONTACT WITH WATER.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: MOISTURE.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS FROM UNCURED SEALANT MAY CAUSE RESPIRATORY TRACT
IRRITATION. WHEN HEATED TO TEMPERATURES EXCEEDING 300 DEG. F (150 DEG. C)
IN THE PRESENCE OF AIR, SILICONES MAY FORM FORMALDEHYDE VAPORS.
FORMALDEHYDE IS A POTENTIAL CANCER HAZARD AND A KNOWN SKIN AND RESPIRATORY
SENSITIZER. VAPORS IRRITATE THE EYES, NOSE AND THROAT. SAFE HANDLING
CONDITIONS MAY BE MAINTAINED BY KEEPING FORMALDEHYDE VAPOR CONCENTRATIONS
BELOW THE OSHA PERMISSIBLE LIMIT.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. MAY BE HARMFUL IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
CALCIUM CARBONATE ORAL LD50 (RAT): NUISANCE DUST
6,450 MG/KG
SILICONE RESIN NONE IRRITANT
OXIMINO SILANE NONE IRRITANT, ALLERGEN
OCTADECANOIC ACID ORAL LD50 (RAT): IRRITANT
4.6 G/KG
CARBON BLACK ORAL LD50 (RAT): RESPIRATORY, SOME EVIDENCE
>8,000 MG/KG OF CARCINOGENICITY
ALUMINUM NONE CENTRAL NERVOUS SYSTEM,
IRRITANT, LUNG
BUTAN-2-ONE O,O',O", NONE IRRITANT, ALLERGEN
O"'-SILANETETRAYL-
TETRAOXIME
3-(TRIMETHOXYSILYL) NONE IRRITANT, ALLERGEN
PROPYLAMINE
WHITE MINERAL OIL NONE IRRITANT
(PETROLEUM), HIGHLY
REFINED
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
CALCIUM CARBONATE NO NO NO
SILICONE RESIN NO NO NO
OXIMINO SILANE NO NO NO
OCTADECANOIC ACID NO NO NO
CARBON BLACK NO GROUP 2B NO
ALUMINUM NO NO NO
BUTAN-2-ONE O,O',O", NO NO NO
O"'-SILANETETRAYL-
TETRAOXIME
3-(TRIMETHOXYSILYL) NO NO NO
PROPYLAMINE
WHITE MINERAL OIL NO NO NO
(PETROLEUM), HIGHLY
REFINED
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
CURED RUBBER CAN BE INCINERATED OR LANDFILLED FOLLOWING EPA AND LOCAL
REGULATIONS.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
EXCEPTIONS: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: LOU FABRIZIO, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 04/01/2015
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.