| Common Name: | LOCTITE SI 593 BK AE KNOWN AS 593 RTV BLACK 190ML AE, 40464 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 3/31/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 12Z252 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 004.0
ISSUE DATE: 03/31/2015
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE SI 593 BK AE KNOWN AS 593 RTV BLACK 190ML AE
IDH NUMBER: 743519
PRODUCT TYPE: SILICONE SEALANT
ITEM NUMBER: 40464
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CONTENTS UNDER PRESSURE.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
GASES UNDER PRESSURE LIQ. GAS
PICTOGRAM(S):
EXCLAMATION MARK
GAS CYLINDER
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR
EYE AND FACE PROTECTION. WEAR PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DISTILLATES (PETROLEUM), HYDROTREATED PROPRIETARY 5 - 10
MIDDLE
SILICON DIOXIDE 7631-86-9 5 - 10
NORFLURANE 811-97-2 5 - 10
SILICONE RESIN PROPRIETARY 1 - 5
SUBSTITUTED SILANE PROPRIETARY 1 - 5
ACETIC ACID 64-19-7 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
WIPE OFF PASTE WITH PAPER TOWEL OR CLOTH. WASH WITH SOAP AND WATER. IF SKIN
IRRITATION PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
INGESTION:
DO NOT INDUCE VOMITING. IF A PERSON FEELS UNWELL OR SYMPTOMS OF SKIN
IRRITATION APPEAR, CONSULT A PHYSICIAN.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR FULL PROTECTIVE CLOTHING. PREVENT INHALATION OF FUMES AND GASES.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
COOL AEROSOL CONTAINERS WITH JET OF WATER. CONTAINERS MAY EXPLODE.
HAZARDOUS COMBUSTION PRODUCTS:
ACRID SMOKE AND FUMES. FORMALDEHYDE. IRRITATING ORGANIC VAPOURS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND WATER SYSTEM.
CLEAN-UP METHODS:
MAINTAIN GOOD VENTILATION FOR LARGE SPILLS. SCRAPE UP AS MUCH MATERIAL AS
POSSIBLE. SPILLED MATERIAL WILL SOLIDIFY. STORE IN A CLOSED CONTAINER UNTIL
READY FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING. DO
NOT HANDLE CONTACT LENSES UNTIL ALL SEALANT HAS BEEN REMOVED FROM HANDS.
RESIDUAL SEALANT MAY TRANSFER TO LENSES AND CAUSE EYE IRRITATION.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
DISTILLATES 5 MG/M3 TWA 5 MG/M3 PEL NONE NONE
(PETROLEUM), INHALABLE MIST.
HYDROTREATED MIDDLE FRACTION.
SILICON DIOXIDE 6 MG/M3 TWA 20 MPPCF TWA NONE 3 MG/M3 TWA
0.8 MG/M3 TWA RESPIRABLE
FRACTION.
NORFLURANE NONE NONE 1,000 PPM NONE
(4,240
MG/M3) TWA
SILICONE RESIN NONE NONE NONE NONE
SUBSTITUTED SILANE NONE NONE NONE NONE
ACETIC ACID 15 PPM STEL 10 PPM NONE NONE
10 PPM TWA (25 MG/M3)
PEL
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: AEROSOL, PASTE
COLOR: BLACK
ODOR: ACETIC ACID
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: <10 MMHg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.01 AT 20 DEG. C (68 DEG. F) BASE ONLY
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT:
>93 DEG. C (>199.4 DEG. F) TAGLIABUE CLOSED CUP; THIS PRODUCT EXHIBITS NO
FLASHBACK WHEN TESTED FOR FLAME EXTENSION.
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 4% (ACETIC ACID)
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 19.9% (ACETIC ACID)
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: SLOWER THAN ETHER.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: <4%; <40 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
ACETIC ACID IS LIBERATED SLOWLY UPON CONTACT WITH MOISTURE. FORMALDEHYDE.
OXIDES OF CARBON. OXIDES OF SILICON.
INCOMPATIBLE MATERIALS: ACIDS. BASES. OXIDIZING AGENTS. WATER.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
PROLONGED HEATING AT TEMPERATURES ABOVE 150 DEG. C. EXPOSURE TO MOISTURE.
| 11. TOXICOLOGICAL INFORMATION | |
PRODUCT TOXICITY DATA:
HENKEL IS NOT AWARE OF ANY TOXICITY DATA ON THE SPECIFIC MIXTURE OF
CHEMICAL COMPONENTS CONTAINED IN THIS PRODUCT.
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
ACETIC ACID PRODUCED DURING CURE MAY IRRITATE EYES, NOSE AND THROAT. WHEN
HEATED TO TEMPERATURES EXCEEDING 300 DEG. F (150 DEG. C) IN THE PRESENCE OF
AIR, SILICONES MAY FORM FORMALDEHYDE VAPORS. FORMALDEHYDE IS A POTENTIAL
CANCER HAZARD AND A KNOWN SKIN AND RESPIRATORY SENSITIZER. VAPORS IRRITATE
THE EYES, NOSE AND THROAT. SAFE HANDLING CONDITIONS MAY BE MAINTAINED BY
KEEPING FORMALDEHYDE VAPOR CONCENTRATIONS BELOW THE OSHA PERMISSIBLE LIMIT.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. NOT EXPECTED TO BE HARMFUL BY
INGESTION.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
DISTILLATES NONE IRRITANT
(PETROLEUM),
HYDROTREATED MIDDLE
SILICON DIOXIDE ORAL LD50 (RAT): NUISANCE DUST
>22,500 MG/KG
NORFLURANE NONE CARDIAC, CENTRAL NERVOUS
SYSTEM, IRRITANT,
RESPIRATORY, SKIN
SILICONE RESIN NONE IRRITANT
SUBSTITUTED SILANE NONE IRRITANT, ALLERGEN
ACETIC ACID ORAL LD50 (RABBIT): ALLERGEN, CORROSIVE, EYES,
1,200 MG/KG GASTROINTESTINAL, IMMUNE
SYSTEM, IRRITANT, KIDNEY
ORAL LD50 (RAT):
3.53 G/KG
ORAL LD50 (RAT):
3.31 G/KG
DERMAL LD50 (RABBIT):
1,060 MG/KG
INHALATION LC50
(RAT, 4 H): 11.4 MG/L
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
DISTILLATES NO NO NO
(PETROLEUM),
HYDROTREATED MIDDLE
SILICON DIOXIDE NO NO NO
NORFLURANE NO NO NO
SILICONE RESIN NO NO NO
SUBSTITUTED SILANE NO NO NO
ACETIC ACID NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
CURED RUBBER CAN BE INCINERATED OR LANDFILLED FOLLOWING EPA AND LOCAL
REGULATIONS.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.2
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: AEROSOLS, NON-FLAMMABLE
HAZARD CLASS OR DIVISION: 2.2
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.2
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: CATHERINE BIMLER, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 03/31/2015
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.