| Common Name: | A/C EASYSEAL (4050-06, 4050-01, 4050-02, 4050-10) |
| Manufacturer: | NU-CALGON |
| SDS Revision Date: | 12/18/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 13D662, 13D663, 13D664 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
NU-CALGON
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: A/C EASYSEAL (4050-06, 4050-01, 4050-02, 4050-10)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: LEAK SEALANT FOR REFRIGERATION AND AC SYSTEMS
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER INFORMATION:
NU-CALGON
2611 SCHUETZ ROAD
ST. LOUIS, MO 63043
US
PHONE: 314-469-7000 / 800-554-5499
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
SUPPLIER: SEE ABOVE.
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SENSITIZATION, SKIN: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
WHMIS 2015 DEFINED HAZARDS: NOT CLASSIFIED
LABEL ELEMENTS:
FLAME
GAS CYLINDER
CORROSION
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SKIN IRRITATION. MAY
CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. CAUSES
SERIOUS EYE DAMAGE.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION
SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT BREATHE GAS. WASH
THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING,
EYE PROTECTION AND FACE PROTECTION. CONTAMINATED WORK CLOTHING SHOULD NOT
BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. SPECIFIC TREATMENT (SEE INFORMATION ON THIS LABEL).
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER OR DOCTOR. GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL AND
INTERNATIONAL REGULATIONS.
WHMIS 2015:
HEALTH HAZARD(S) NOT OTHERWISE CLASSIFIED (HHNOC): NONE KNOWN
WHMIS 2015:
PHYSICAL HAZARD(S) NOT OTHERWISE CLASSIFIED (PHNOC): NONE KNOWN
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
1,1-DIFLUOROETHANE 75-37-6 65-85*
1-PROPANAMINE, 3- 919-30-2 1-5*
(TRIETHOXYSILYL)-
2-BUTANONE, O,O',O"- 22984-54-9 5-10*
(METHYLSILYLIDYNE)TRIOXIME
METHYL TRIETHOXYSILANE 2031-67-6 10-30*
ALL CONCENTRATIONS ARE IN PERCENT BY WEIGHT UNLESS INGREDIENT IS A GAS.
GAS CONCENTRATIONS ARE IN PERCENT BY VOLUME.
COMPOSITION COMMENTS:
US GHS:
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET IN ACCORDANCE WITH PARAGRAPH (I) OF SUBSECTION 1910.1200.
*CANADA GHS:
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD
AS A TRADE SECRET.
| 4. FIRST AID MEASURES | |
INHALATION:
IF SYMPTOMS DEVELOP MOVE VICTIM TO FRESH AIR. IF SYMPTOMS PERSIST, OBTAIN
MEDICAL ATTENTION.
SKIN CONTACT
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER. TAKE
OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. IMMEDIATELY CALL A POISON CENTER OR DOCTOR. SPECIFIC
TREATMENT (SEE INFORMATION ON THIS LABEL).
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CENTER
OR DOCTOR.
INGESTION:
NOT A NORMAL ROUTE OF EXPOSURE. DO NOT INDUCE VOMITING. IF VOMITING OCCURS
NATURALLY, HAVE VICTIM LEAN FORWARD TO REDUCE RISK OF ASPIRATION. NEVER
GIVE ANYTHING BY MOUTH IF VICTIM IS UNCONSCIOUS OR IS CONVULSING. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
DIZZINESS. BURNING PAIN AND SEVERE CORROSIVE SKIN DAMAGE. CAUSES SERIOUS
EYE DAMAGE. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. PERMANENT EYE DAMAGE INCLUDING BLINDNESS COULD RESULT.
PROLONGED EXPOSURE MAY CAUSE CHRONIC EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. SYMPTOMS
MAY BE DELAYED.
GENERAL INFORMATION:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS SAFETY DATA SHEET TO
THE DOCTOR IN ATTENDANCE. WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID
CONTACT WITH EYES AND SKIN. KEEP OUT OF REACH OF CHILDREN.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA: NOT AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED
TO HEAT OR FLAME. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
NOT AVAILABLE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE: STOP LEAK IF SAFE TO DO SO. DO NOT MOVE CARGO OR VEHICLE
IF CARGO HAS BEEN EXPOSED TO HEAT. MOVE CONTAINERS FROM FIRE AREA IF YOU
CAN DO SO WITHOUT RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT
VAPOR PRESSURE BUILD UP.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. COOL CONTAINERS EXPOSED TO FLAMES WITH WATER UNTIL WELL AFTER THE
FIRE IS OUT. IN THE EVENT OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS:
EXTREMELY FLAMMABLE AEROSOL. CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER
MAY EXPLODE WHEN EXPOSED TO HEAT OR FLAME.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON. OXIDES OF NITROGEN.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. MANY GASES ARE HEAVIER THAN AIR AND
WILL SPREAD ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
BASEMENTS, TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING
DURING CLEAN-UP. DO NOT BREATHE GAS. EMERGENCY PERSONNEL NEED
SELF-CONTAINED BREATHING EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING.
VENTILATE CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD
BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL
PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. STOP
LEAK IF YOU CAN DO SO WITHOUT RISK. MOVE THE CYLINDER TO A SAFE AND OPEN
AREA IF THE LEAK IS IRREPARABLE. ISOLATE AREA UNTIL GAS HAS DISPERSED.
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL.
LARGE SPILLS:
DIKE THE SPILLED MATERIAL, WHERE THIS IS POSSIBLE. COVER WITH PLASTIC
SHEET TO PREVENT SPREADING. ABSORB IN VERMICULITE, DRY SAND OR EARTH
AND PLACE INTO CONTAINERS. SCOOP UP USED ABSORBENT INTO DRUMS OR OTHER
APPROPRIATE CONTAINER. FOLLOWING PRODUCT RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
DO NOT DISCHARGE INTO LAKES, STREAMS, PONDS OR PUBLIC WATERS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
SMOKE WHILE USING OR UNTIL SPRAYED SURFACE IS THOROUGHLY DRY. PRESSURIZED
CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY
BUTTON IS MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. ALL
EQUIPMENT USED WHEN HANDLING THE PRODUCT MUST BE GROUNDED. CLOSE VALVE
AFTER EACH USE AND WHEN EMPTY. USE ONLY PROPERLY SPECIFIED EQUIPMENT
WHICH IS SUITABLE FOR THIS PRODUCT, ITS SUPPLY PRESSURE AND TEMPERATURE.
CONTACT YOUR GAS SUPPLIER IF IN DOUBT. DO NOT BREATHE GAS. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING. USE ONLY IN WELL-VENTILATED AREAS. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH THOROUGHLY AFTER HANDLING.
USE GOOD INDUSTRIAL HYGIENE PRACTICES IN HANDLING THIS MATERIAL. WHEN
USING DO NOT EAT OR DRINK.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT
EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. KEEP AWAY FROM HEAT,
SPARKS AND OPEN FLAME. THIS MATERIAL CAN ACCUMULATE STATIC CHARGE WHICH MAY
CAUSE SPARK AND BECOME AN IGNITION SOURCE. PREVENT ELECTROSTATIC CHARGE
BUILD-UP BY USING COMMON BONDING AND GROUNDING TECHNIQUES. STORE IN A
WELL-VENTILATED PLACE. CYLINDERS SHOULD BE STORED UPRIGHT, WITH VALVE
PROTECTION CAP IN PLACE, AND FIRMLY SECURED TO PREVENT FALLING OR BEING
KNOCKED OVER. STORED CONTAINERS SHOULD BE PERIODICALLY CHECKED FOR GENERAL
CONDITION AND LEAKAGE. KEEP OUT OF REACH OF CHILDREN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. AIHA WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE
1,1-DIFLUOROETHANE (CAS 75-37-6) TWA 2700 MG/M3
1000 PPM
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS
TO AN ACCEPTABLE LEVEL.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND A FACE SHIELD.
SKIN PROTECTION:
HAND PROTECTION:
WEAR APPROPRIATE CHEMICAL RESISTANT GLOVES. SUITABLE GLOVES CAN BE
RECOMMENDED BY THE GLOVE SUPPLIER.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS
APRON IS RECOMMENDED. AS REQUIRED BY EMPLOYER CODE.
RESPIRATORY PROTECTION:
IN CASE OF INSUFFICIENT VENTILATION, WEAR SUITABLE RESPIRATORY EQUIPMENT.
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR.
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES,
SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING,
AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO
REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WHEN USING DO NOT EAT OR DRINK.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: COMPRESSED LIQUEFIED GAS.
PHYSICAL STATE: GAS.
FORM: AEROSOL.
COLOR: COLORLESS
ODOR: AMINE
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE
FLASH POINT: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: NOT AVAILABLE.
SOLUBILITY(IES): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
OXIDIZING PROPERTIES: NOT OXIDIZING.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: HEAT. DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO:
OXIDES OF CARBON. OXIDES OF NITROGEN.
| 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: INHALATION. INGESTION. SKIN CONTACT. EYE CONTACT.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: MAY CAUSE STOMACH DISTRESS, NAUSEA OR VOMITING.
INHALATION:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE
BY INHALATION. MAY CAUSE IRRITATION TO THE RESPIRATORY SYSTEM.
SKIN CONTACT:
CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
DIZZINESS. CAUSES SERIOUS EYE DAMAGE. SYMPTOMS MAY INCLUDE STINGING,
TEARING, REDNESS, SWELLING, AND BLURRED VISION. PERMANENT EYE DAMAGE
INCLUDING BLINDNESS COULD RESULT.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: MAY CAUSE AN ALLERGIC SKIN REACTION.
COMPONENTS SPECIES TEST RESULTS
1,1-DIFLUOROETHANE (CAS 75-37-6):
ACUTE:
DERMAL:
LD50 NOT AVAILABLE
INHALATION:
LC50 RAT >437500 PPM, 4 HOURS,
ECHA
>64000 PPM
ORAL:
LD50 RAT >1500 MG/KG
1-PROPANAMINE, 3-(TRIETHOXYSILYL)- (CAS 919-30-2):
ACUTE:
DERMAL:
LD50 RABBIT >6 ML/KG, 24 HOURS
4 ML/KG, ECHA
RAT 8 - 16 ML/KG, 24 HOURS
INHALATION:
LC50 RAT >7.4 MG/L, ECHA
>7.4 MG/L, 4 HOURS
>5 PPM, 6 HOURS
ORAL:
LD50 MOUSE 530 MG/KG
RAT 1780 MG/KG, SIGMA
ALDRICH
4.2 ML/KG, ECHA
1.6 ML/KG
2-BUTANONE, O,O',O"-(METHYLSILYLIDYNE)TRIOXIME (CAS 22984-54-9):
ACUTE:
DERMAL:
LD50 RAT >2000 MG/KG, ECHA
>2000 MG/KG, 24 HOURS
ORAL:
LD50 RAT 2650 MG/KG, ECHA, FEMALE
2453 MG/KG
2260 MG/KG, ECHA, MALE
METHYL TRIETHOXYSILANE (CAS 2031-67-6):
ACUTE:
DERMAL:
LD50 RABBIT >14240 MG/KG, ECHA,
FEMALE
11837 MG/KG, ECHA, MALE
11837 MG/KG, 24 HOURS
RAT >2007 MG/KG, 24 HOURS
INHALATION:
LC50 NOT AVAILABLE
RAT >13500 MG/M3, 4 HOURS
ORAL:
LD50 RAT >2007 MG/KG
10057 MG/KG, ECHA, MALE
7627 MG/KG, ECHA, FEMALE
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE DAMAGE.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT
AT GREATER THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NOT CLASSIFIED.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: NOT LIKELY, DUE TO THE FORM OF THE PRODUCT.
CHRONIC EFFECTS:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
MOBILITY IN SOIL:
MOBILITY IN GENERAL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL. DO NOT RE-USE
EMPTY CONTAINERS.
| 14. TRANSPORT INFORMATION | |
TRANSPORT OF DANGEROUS GOODS (TDG) PROOF OF CLASSIFICATION:
CLASSIFICATION METHOD:
CLASSIFIED AS PER PART 2, SECTIONS 2.1 - 2.8 OF THE TRANSPORTATION OF
DANGEROUS GOODS REGULATIONS. IF APPLICABLE, THE TECHNICAL NAME AND THE
CLASSIFICATION OF THE PRODUCT WILL APPEAR BELOW.
U.S. DEPARTMENT OF TRANSPORTATION (DOT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY)
HAZARD CLASS: LIMITED QUANTITY - US
SPECIAL PROVISIONS: N82
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - CANADA
SPECIAL PROVISIONS: 80, 107
IATA/ICAO (AIR):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE
HAZARD CLASS: LIMITED QUANTITY - IATA
IMDG (MARINE TRANSPORT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS: LIMITED QUANTITY - IMDG
DOT; IMDG; TDG:
LIMITED QUANTITTY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA
OF THE HPR AND THE SDS CONTAINS ALL THE INFORMATION REQUIRED BY THE HPR.
CANADA CEPA SCHEDULE I: LISTED SUBSTANCE
1,1-DIFLUOROETHANE (CAS 75-37-6): LISTED.
EXPORT CONTROL LIST (CEPA 1999, SCHEDULE 3): NOT LISTED.
GREENHOUSE GASES:
1,1-DIFLUOROETHANE (CAS 75-37-6)
PRECURSOR CONTROL REGULATIONS: NOT REGULATED.
WHMIS 2015 EXEMPTIONS: NOT APPLICABLE
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
ALL CHEMICALS USED ARE ON THE TSCA INVENTORY.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4): NOT LISTED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING): NOT REGULATED.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130):
1,1-DIFLUOROETHANE (CAS 75-37-6)
US STATE REGULATIONS: SEE BELOW
US - NEW JERSEY RTK - SUBSTANCES: LISTED SUBSTANCE
1,1-DIFLUOROETHANE (CAS 75-37-6)
US - TEXAS EFFECTS SCREENING LEVELS: LISTED SUBSTANCE
1,1-DIFLUOROETHANE (CAS 75-37-6): LISTED.
1- PROPANAMINE, 3-(TRIETHOXYSILYL)- (CAS 919-30-2): LISTED.
2- BUTANONE, O,O',O''-(METHYLSILYLIDYNE)TRIOXIME (CAS 22984-54-9): LISTED.
METHYL TRIETHOXYSILANE (CAS 2031-67-6): LISTED.
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
1,1-DIFLUOROETHANE (CAS 75-37-6)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
1,1-DIFLUOROETHANE (CAS 75-37-6)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
NOT LISTED.
US. RHODE ISLAND RTK: NOT REGULATED.
US. CALIFORNIA PROPOSITION 65: NOT LISTED.
INVENTORY STATUS:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH
THE INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
LEGEND:
SEVERE 4
SERIOUS 3
MODERATE 2
SLIGHT 1
MINIMAL 0
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
2
4
0
DISCLAIMER:
THE INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE BEST KNOWLEDGE AND
EXPERIENCE CURRENTLY AVAILABLE. INFORMATION CONTAINED HEREIN WAS OBTAINED
FROM SOURCES CONSIDERED TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY
EFFORT HAS BEEN MADE TO ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN
SOME CASES DATA IS NOT AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF
ACTUAL PRODUCT USE ARE BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT
USERS OF THIS MATERIAL HAVE BEEN FULLY TRAINED ACCORDING TO THE
REQUIREMENTS OF ALL APPLICABLE LEGISLATION AND REGULATORY INSTRUMENTS. NO
WARRANTY, EXPRESSED OR IMPLIED, IS MADE AND SUPPLIER WILL NOT BE LIABLE
FOR ANY LOSSES, INJURIES OR CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM
THE USE OF OR RELIANCE ON ANY INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 18-DECEMBER-2018
VERSION #: 02
EFFECTIVE DATE: 18-DECEMBER-2018
PREPARED BY:
NU-CALGON TECHNICAL SERVICE PHONE: (314) 469-7000
OTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED IN
SECTION 1 OF THIS DOCUMENT.
#25119
4050-06, 4050-01, 4050-02, 4050-10 (CANADA/US GHS)