| Common Name: | PRO-LINE WP PAINT MARKER |
| Manufacturer: | LA-CO INDUSTRIES |
| SDS Revision Date: | 10/29/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 13P062, 13P063, 13P064, 13P065, 13P066, 13P067, 13P070, 13P071 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
SAFETY DATA SHEET
LA-CO INDUSTRIES, INC.
PRO-LINE(R*) WP PAINT MARKER
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
ACCORDING TO CANADIAN HAZARDOUS PRODUCTS REGULATIONS (HPR)
DATE OF ISSUE: 07/17/2015
REVISION DATE: 10/29/2015
VERSION: 1.1
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: ARTICLE
PRODUCT NAME: PRO-LINE(R*) WP PAINT MARKER
SYNONYMS:
PRO-LINE(R*) WP PAINT MARKER - BLACK, BLUE, GREEN, ORANGE, SILVER, WHITE,
YELLOW, RED
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: PAINT.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
LA-CO INDUSTRIES, INC.
1201 PRATT BOULEVARD
ELK GROVE VILLAGE, IL. 60007-5746
PHONE: (847) 956-7600
FAX: (847) 956-9885
E-MAIL: CUSTOMER_SERVICE@LACO.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
24-HOUR EMERGENCY:
CHEMTREC - U.S.: 1-800-424-9300
INTERNATIONAL: +1-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION IN ACCORDANCE WITH THE GLOBALLY HARMONIZED STANDARD:
NOT CLASSIFIED
2.2 LABEL ELEMENTS:
GHS-US LABELLING: NO LABELLING APPLICABLE
2.3. OTHER HAZARDS:
2.4 UNKNOWN ACUTE TOXICITY (GHS US):
0.26 PERCENT OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY (ORAL)
0.26 PERCENT OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY (DERMAL)
0.26 PERCENT OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE
TOXICITY (INHALATION (DUST/MIST))
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % (W/W) GHS-US CLASSIFICATION
CYCLOHEXANONE (CAS NO): 108-94-1 19.57 WHITE FLAM. LIQ. 3, H226
23.93 YELLOW ACUTE TOX. 4
25.17 RED (INHALATION), H332
23.88 BLACK
24.64 BLUE
23.2 GREEN
24.27 ORANGE
25.25 SILVER
TERT-BUTYL (CAS NO): 540-88-5 27.9 - 28.04 FLAM. LIQ. 2, H225
ACETATE WHITE
38.6 - 38.79
YELLOW
46.27 - 46.5
RED
47.75 BLACK
49.02 - 49.27
BLUE
45.55 - 45.78
GREEN
47.81 - 48.05
ORANGE
50.22 - 50.48
SILVER
ALUMINIUM (CAS NO): 7429-90-5 5.6 - 6.23 FLAM. SOL. 1, H228
POWDER SILVER WATER-REACT. 2, H261
(STABILISED)
CARBON BLACK (CAS NO): 1333-86-4 3.55 BLACK CARC. 2, H351
4-[[4- (CAS NO): 2786-76-7 3.26 RED SKIN SENS. 1, H317
(AMINOCARBONYL)
PHENYL]AZO]-N-
(2-
ETHOXYPHENYL)-
3-HYDROXY-
NAPHTHALENE-2-
CARBOXAMIDE,
C.I. PIGMENT
RED 170
(NAPHTHOL <1%)
ETHYL ACETATE (CAS NO): 141-78-6 0.65 WHITE FLAM. LIQ. 2, H225
0.97 YELLOW EYE IRRIT. 2A, H319
0.93 RED STOT SE 3, H336
1.07 BLACK
0.96 GREEN
0.92 ORANGE
0.94 SILVER
[N,N,N',N',N"- (CAS NO): 28654-73-1 0.07 - 0.16 SKIN SENS. 1B, H317
,N''-HEXAETHYL- BLUE
29H,31H-
PHTHALOCYANINE-
TRIMETHYL-
AMINATO(2-)-
N29,N30,N31,-
N32]COPPER
FULL TEXT OF H-STATEMENTS: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ADVICE/ATTENTION IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE SKIN WITH WATER/SHOWER. REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED
CLOTHING.
FIRST-AID MEASURES AFTER EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER.
FIRST-AID MEASURES AFTER INGESTION:
DO NOT INDUCE VOMITING. GET MEDICAL ADVICE/ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES: NONE KNOWN.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
ALL TREATMENTS SHOULD BE BASED ON OBSERVED SIGNS AND SYMPTOMS OF DISTRESS
IN THE PATIENT.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
CARBON DIOXIDE. DRY CHEMICAL. INERT GAS. FOAM. WATER SPRAY. WATER FOG.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD:
HIGHLY FLAMMABLE LIQUID AND VAPOUR. BURNING PRODUCES IRRITATING, TOXIC AND
NOXIOUS FUMES.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR MIXTURE.
REACTIVITY: NO DANGEROUS REACTIONS KNOWN.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO. EXERCISE CAUTION WHEN
FIGHTING ANY CHEMICAL FIRE.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION. USE SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO OPEN FLAMES. NO SMOKING. AVOID ALL EYE AND SKIN CONTACT AND DO NOT
BREATHE VAPOUR AND MIST.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
EMERGENCY PROCEDURES: VENTILATE AREA. STOP LEAK IF SAFE TO DO SO.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT: STOP LEAK IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
ABSORB AND/OR CONTAIN SPILL WITH INERT MATERIAL, THEN PLACE IN SUITABLE
CONTAINER.
6.4. REFERENCE TO OTHER SECTIONS:
SECTION 13: DISPOSAL INFORMATION.
SECTION 7: SAFE HANDLING.
SECTION 8: PERSONAL PROTECTIVE EQUIPMENT.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPOURS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
NO OPEN FLAMES. NO SMOKING. USE ONLY NON-SPARKING TOOLS. AVOID ALL EYE AND
SKIN CONTACT AND DO NOT BREATHE VAPOUR AND MIST.
HYGIENE MEASURES:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL/VENTILATING/LIGHTING/... EQUIPMENT.
STORAGE CONDITIONS:
KEEP IN FIREPROOF PLACE. KEEP CONTAINER CLOSED WHEN NOT IN USE.
INCOMPATIBLE PRODUCTS: OXIDIZER.
INCOMPATIBLE MATERIALS: HEAT SOURCES.
HEAT AND IGNITION SOURCES: KEEP AWAY FROM HEAT, SPARKS AND FLAME.
PROHIBITIONS ON MIXED STORAGE: INCOMPATIBLE MATERIALS.
STORAGE AREA: STORE IN DRY, COOL, WELL-VENTILATED AREA.
7.3. SPECIFIC END USE(S): MARKING.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
PRO-LINE(R*) WP PAINT MARKER:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
CYCLOHEXANONE (108-94-1):
ACGIH:
ACGIH TWA (MG/M3): 50 MG/M3
ACGIH:
ACGIH TWA (PPM): 20 PPM
ACGIH:
ACGIH STEL (PPM): 50 PPM
ACGIH:
REMARK (ACGIH): EYE & URT IRR
OSHA:
OSHA PEL (TWA) (MG/M3): 200 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 50 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 100 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 25 PPM
CANADA (QUEBEC):
NOTATIONS AND REMARKS: (PEAU)
TERT-BUTYL ACETATE (540-88-5):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
ETHYL ACETATE (141-78-6):
ACGIH:
ACGIH TWA (MG/M3): 1440 MG/M3
ACGIH:
ACGIH TWA (PPM): 400 PPM
ACGIH:
REMARK (ACGIH): URT & EYE IRR
OSHA:
OSHA PEL (TWA) (MG/M3): 1400 MG/M3
OSHA:
OSHA PEL (TWA) (PPM): 400 PPM
CANADA (QUEBEC):
VEMP (MG/M3): 1440 MG/M3
CANADA (QUEBEC):
VEMP (PPM): 400 PPM
CARBON BLACK (1333-86-4):
ACGIH:
ACGIH TWA (MG/M3): 3.5 MG/M3
CARBON BLACK (1333-86-4):
ACGIH:
REMARK (ACGIH): BRONCHITIS
OSHA:
OSHA PEL (TWA) (MG/M3): 3.5 MG/M3
CANADA (QUEBEC):
VEMP (MG/M3):
10 MG/M3 (FIBRES DE CARBONE ET DE GRAPHITE; POUSSIERE TOTALE)
5 MG/M3 (FIBRES DE CARBONE ET DE GRAPHITE; POUSSIERE RESPIRABLE)
3.5 MG/M3
[N,N,N',N',N'',N"-HEXAETHYL-29H,31H-PHTHALOCYANINETRIMETHYLAMINATO(2-)-
N29,N30,N31,N32]COPPER (28654-73-1):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
ALUMINIUM POWDER (STABILISED) (7429-90-5):
ACGIH:
ACGIH TWA (MG/M3): 1 MG/M3
ACGIH:
REMARK (ACGIH): PNEUMOCONIOSIS; LRT IRR
OSHA:
OSHA PEL (TWA) (MG/M3):
15 MG/M3 (TOTAL DUST)
5 MG/M3 (RESPIRABLE DUST)
CANADA (QUEBEC):
VEMP (MG/M3): 10 MG/M3
CANADA (QUEBEC):
NOTATIONS AND REMARKS: (METAL)
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
AVOID SPLASHING. ENSURE GOOD VENTILATION OF THE WORK STATION.
PERSONAL PROTECTIVE EQUIPMENT: AVOID ALL UNNECESSARY EXPOSURE.
HAND PROTECTION: NONE UNDER NORMAL USE.
EYE PROTECTION: NONE UNDER NORMAL USE.
RESPIRATORY PROTECTION: NONE UNDER NORMAL USE.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: SOLID MARKER CONTAINING LIQUID COLORED PAINT.
COLOUR: VARIABLE.
ODOUR: SOLVENT.
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 97.8 DEG. C
FLASH POINT: 16.6 - 22.2 DEG. C
AUTO-IGNITION TEMPERATURE: 426 DEG. C
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: 0.96 - 1.34
SOLUBILITY: INSOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDISING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 50 - 80 %
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO DANGEROUS REACTIONS KNOWN.
10.2. CHEMICAL STABILITY:
HIGHLY FLAMMABLE LIQUID AND VAPOUR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOUR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: OPEN FLAME. DIRECT SUNLIGHT.
10.5. INCOMPATIBLE MATERIALS: OXIDIZER.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
MAY RELEASE FLAMMABLE GASES. BURNING PRODUCES IRRITATING, TOXIC AND
NOXIOUS FUMES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
INHALATION:
DUST, MIST: NOT CLASSIFIED.
CYCLOHEXANONE (108-94-1):
ATE CLP (DUST, MIST): 1.500 MG/L/4H
TERT-BUTYL ACETATE (540-88-5):
LD50 ORAL RAT: 4100 MG/KG
LD50 DERMAL RABBIT: >2000 MG/KG
LC50 INHALATION RAT (PPM): 4211 PPM 6 H
ATE CLP (ORAL): 4100.000 MG/KG BODYWEIGHT
ETHYL ACETATE (141-78-6):
LD50 ORAL RAT: 5620 MG/KG
LD50 DERMAL RABBIT: >20000 MG/KG
LC50 INHALATION RAT (MG/L): >18 MG/L/4H
ATE CLP (ORAL): 5620.000 MG/KG BODYWEIGHT
CARBON BLACK (1333-86-4):
LD50 ORAL RAT: >8000 MG/KG
LC50 INHALATION RAT (MG/L): >4.6 MG/M3 4 H
[N,N,N',N',N'',N"-HEXAETHYL-29H,31H-PHTHALOCYANINETRIMETHYLAMINATO(2-)-
N29,N30,N31,N32]COPPER (28654-73-1):
LD50 ORAL RAT: >10000 MG/KG
LD50 DERMAL RAT: >2500 MG/KG
ALUMINIUM POWDER (STABILISED) (7429-90-5):
LD50 ORAL RAT: >15900 MG/KG
LC50 INHALATION RAT (MG/L):
>2.3 MG/L/4H NO MORTALITY OBSERVED IN THIS STUDY.
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
LD50 ORAL RAT: >15000 MG/KG
LC50 INHALATION RAT (MG/L): >1580 MG/M3 4 H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
RESPIRATORY OR SKIN SENSITISATION: NOT CLASSIFIED.
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED.
CYCLOHEXANONE (108-94-1):
IARC GROUP: 3 - NOT CLASSIFIABLE
CARBON BLACK (1333-86-4):
IARC GROUP: 2B - POSSIBLY CARCINOGENIC TO HUMANS, INHALATION OF DUST
NATIONAL TOXICOLOGY PROGRAM (NTP) STATUS:
NOT LISTED IN CARCINOGENICITY CLASS
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
LIKELY ROUTES OF EXPOSURE: INHALATION; SKIN AND EYE CONTACT
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
TERT-BUTYL ACETATE (540-88-5):
LC50 FISH 1: 240 MG/L 96 H
EC50 DAPHNIA 1: 410 MG/L 24 H
ETHYL ACETATE (141-78-6):
LC50 FISH 1: 220 MG/L
EC50 DAPHNIA 1: 1200 MG/L
NOEC CHRONIC FISH: <9.35 MG/L
[N,N,N',N',N",N"-HEXAETHYL-29H,31H-PHTHALOCYANINETRIMETHYLAMINATO(2-)-
N29,N30,N31,N32]COPPER (28654-73-1):
LC50 FISH 1: >146 MG/L 96 H
EC50 DAPHNIA 1: >100 MG/L 48 H
ALUMINIUM POWDER (STABILISED) (7429-90-5):
LC50 FISH 1:
>218.64 MG/L ASTM 2000
TEST MATERIAL: ALUMINIUM CHLORIDE HEXAHYDRATE; PIMEPHALES PROMELAS
EC50 DAPHNIA 1:
1.4 MG/L OECD GUIDELINE 202
TEST MATERIAL: ALUMINIUM HYDROXIDE
LOEC (ACUTE): 72.89 MG/L
NOEC (ACUTE): 37.2 MG/L
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
LC50 FISH 1: >500 MG/L 96 H
EC50 DAPHNIA 1: >110 MG/L 48 H
12.2. PERSISTENCE AND DEGRADABILITY:
TERT-BUTYL ACETATE (540-88-5):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
BIODEGRADATION: 50% 28 D
ETHYL ACETATE (141-78-6):
PERSISTENCE AND DEGRADABILITY: READILY BIODEGRADABLE.
CARBON BLACK (1333-86-4):
PERSISTENCE AND DEGRADABILITY: NOT READILY BIODEGRADABLE.
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
PERSISTENCE AND DEGRADABILITY: NOT READILY BIODEGRADABLE.
BIODEGRADATION: 0% 28 D
12.3. BIOACCUMULATIVE POTENTIAL:
TERT-BUTYL ACETATE (540-88-5):
BCF FISH 1: 5.61
LOG POW: 1.64
ETHYL ACETATE (141-78-6):
BIOACCUMULATIVE POTENTIAL: NOT EXPECTED TO BIOACCUMULATE.
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
BCF FISH 1: 53 L/KG
LOG POW: 1.28
12.4. MOBILITY IN SOIL: NO ADDITIONAL INFORMATION AVAILABLE
12.5. OTHER ADVERSE EFFECTS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
SEWAGE DISPOSAL RECOMMENDATIONS: DO NOT DISPOSE OF WASTE INTO SEWER.
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPOURS ARE FLAMMABLE.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT AND TDG:
TRANSPORT DOCUMENT DESCRIPTION:
UN1263 PAINT (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS,
VARNISH, POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE), 3, II
UN-NO.(DOT): UN1263
PROPER SHIPPING NAME (DOT):
PAINT INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS, VARNISH,
POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE
TRANSPORT HAZARD CLASS(ES) (DOT): 3 - FLAMMABLE LIQUID
PACKING GROUP (DOT): II - MEDIUM DANGER
ADR:
TRANSPORT DOCUMENT DESCRIPTION: UN 1263 PAINT, 3, II, (D/E)
PROPER SHIPPING NAME (ADR): PAINT
PACKING GROUP (ADR): II
TRANSPORT HAZARD CLASS(ES) (ADR): 3
TRANSPORT BY SEA:
UN-NO. (IMDG): UN 1263
PROPER SHIPPING NAME (IMDG): PAINT
TRANSPORT HAZARD CLASS(ES) (IMDG): 3
PACKING GROUP (IMDG): II
AIR TRANSPORT:
UN-NO. (IATA): UN 1263
PROPER SHIPPING NAME (IATA): PAINT
TRANSPORT HAZARD CLASS(ES) (IATA): 3
PACKING GROUP (IATA): II
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
CYCLOHEXANONE (108-94-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
TERT-BUTYL ACETATE (540-88-5):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
ETHYL ACETATE (141-78-6):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
RQ (REPORTABLE QUANTITY, SECTION 304 OF EPA'S LIST OF LISTS): 5000 LB
CARBON BLACK (1333-86-4):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
[N,N,N',N',N",N"-HEXAETHYL-29H,31H-PHTHALOCYANINETRIMETHYLAMINATO(2-)-
N29,N30,N31,N32]COPPER (28654-73-1):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
ALUMINIUM POWDER (STABILISED) (7429-90-5):
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
CYCLOHEXANONE (108-94-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
TERT-BUTYL ACETATE (540-88-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
ETHYL ACETATE (141-78-6):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
CARBON BLACK (1333-86-4):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
[N,N,N',N',N",N"-HEXAETHYL-29H,31H-PHTHALOCYANINETRIMETHYLAMINATO(2-)-
N29,N30,N31,N32]COPPER (28654-73-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
ALUMINUM POWDER (STABILISED) (7429-90-5):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST) INVENTORY.
EU-REGULATIONS:
CYCLOHEXANONE (108-94-1):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
TERT-BUTYL ACETATE (540-88-5):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
ETHYL ACETATE (141-78-6):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CARBON BLACK (1333-86-4):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
[N,N,N',N',N",N"-HEXAETHYL-29H,31H-PHTHALOCYANINETRIMETHYLAMINATO(2-)-
N29,N30,N31,N32]COPPER (28654-73-1):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
ALUMINUM POWDER (STABILISED) (7429-90-5):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
4-[[4-(AMINOCARBONYL)PHENYL]AZO]-N-(2-ETHOXYPHENYL)-3-HYDROXYNAPHTHALENE-
2-CARBOXAMIDE, C.I. PIGMENT RED 170 (NAPHTHOL <1%) (2786-76-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
NATIONAL REGULATIONS:
PRO-LINE(R*) WP PAINT MARKER:
ALL COMPONENTS ARE LISTED ON THE EEC INVENTORY EUROPEAN INVENTORY OF
EXISTING COMMERCIAL CHEMICAL SUBSTANCES (EINECS).
ALL INGREDIENTS ARE LISTED ON THE CANADIAN DOMESTIC SUBSTANCES LIST (DSL)
OR NON-DOMESTIC SUBSTANCES LIST (NDSL).
ALL INGREDIENTS ARE LISTED IN THE TOXIC SUBSTANCES CONTROL ACT (TSCA).
15.3. US STATE REGULATIONS:
PRO-LINE(R*) WP PAINT MARKER:
STATE OR LOCAL REGULATIONS:
THE CARBON BLACK IN THIS PRODUCT IS BOUND AND IS NOT RESPIRABLE. CALIFORNIA
PROP. 65 WARNINGS ARE NOT REQUIRED.
CARBON BLACK (1333-86-4):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: YES
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NON-SIGNIFICANT RISK LEVEL (NSRL):
CYCLOHEXANONE (108-94-1):
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
U.S. - NEW YORK - RIGHT TO KNOW LIST OF HAZARDOUS CHEMICALS
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST
TERT-BUTYL ACETATE (540-88-5):
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - NEW YORK - RIGHT TO KNOW LIST OF HAZARDOUS CHEMICALS
U.S. - PENNSYLVANIA - LIST OF HAZARDOUS SUBSTANCES
ETHYL ACETATE (141-78-6):
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - LIST OF HAZARDOUS SUBSTANCES
CARBON BLACK (1333-86-4):
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
ALUMINIUM POWDER (STABILISED) (7429-90-5):
U.S. - MINNESOTA - HAZARDOUS SUBSTANCE LIST
U.S. - NEW YORK - RIGHT TO KNOW LIST OF HAZARDOUS CHEMICALS
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
| SECTION 16: OTHER INFORMATION | |
INDICATION OF CHANGES: SECTION 15.
DATA SOURCES:
ACGIH (AMERICAN CONFERENCE OF GOVERNMENT INDUSTRIAL HYGIENISTS).
EUROPEAN CHEMICALS AGENCY (ECHA) C&L INVENTORY DATABASE. ACCESSED AT
HTTP://ECHA.EUROPA.EU/WEB/GUEST/INFORMATION-ON-CHEMICALS/CL-INVENTORY-
DATABASE.
KRISTER FORSBERG AND S.Z. MANSDORF, "QUICK SELECTION GUIDE TO CHEMICAL
PROTECTIVE CLOTHING", FIFTH EDITION.
NATIONAL FIRE PROTECTION ASSOCIATION. FIRE PROTECTION GUIDE TO HAZARDOUS
MATERIALS; 10TH EDITION.
OSHA 29CFR 1910.1200 HAZARD COMMUNICATION STANDARD.
TSCA CHEMICAL SUBSTANCE INVENTORY. ACCESSED AT
HTTP://WWW.EPA.GOV/OPPT/EXISTINGCHEMICALS/PUBS/TSCAINVENTORY/HOWTO.HTML.
ABBREVIATIONS AND ACRONYMS:
ATE: ACUTE TOXICITY ESTIMATE.
CAS: (CHEMICAL ABSTRACTS SERVICE) NUMBER.
CLP: CLASSIFICATION, LABELLING, PACKAGING.
EC50:
ENVIRONMENTAL CONCENTRATION ASSOCIATED WITH A RESPONSE BY 50% OF THE TEST
POPULATION.
GHS:
GLOBALLY HARMONIZED SYSTEM (OF CLASSIFICATION AND LABELING OF CHEMICALS).
LD50: LETHAL DOSE FOR 50% OF THE TEST POPULATION.
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION.
PBT: PERSISTENT, BIOACCUMULATIVE, TOXIC.
TWA: TIME WEIGHT AVERAGE.
TSCA: TOXIC SUBSTANCES CONTROL ACT.
OTHER INFORMATION: NONE.
NFPA HEALTH HAZARD 1 - EXPOSURE COULD CAUSE IRRITATION BUT ONLY MINOR
RESIDUAL INJURY EVEN IF NO TREATMENT IS GIVEN.
NFPA FIRE HAZARD 1 - MUST BE PREHEATED BEFORE IGNITION CAN OCCUR.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND NOT REACTIVE WITH WATER.
FULL TEXT OF H-STATEMENTS:
ACUTE TOX. 4 (INHALATION): ACUTE TOXICITY (INHAL.), CATEGORY 4
CARC. 2: CARCINOGENICITY, CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION, CATEGORY 2A
FLAM. LIQ. 2: FLAMMABLE LIQUIDS, CATEGORY 2
FLAM. LIQ. 3: FLAMMABLE LIQUIDS, CATEGORY 3
FLAM. SOL. 1: FLAMMABLE SOLIDS, CATEGORY 1
SKIN SENS. 1: SENSITISATION - SKIN, CATEGORY 1
SKIN SENS. 1B: SENSITISATION - SKIN, CATEGORY 1B
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3, NARCOSIS
WATER-REACT. 2:
SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES,
CATEGORY 2
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR
H226: FLAMMABLE LIQUID AND VAPOUR
H228: FLAMMABLE SOLID
H261: IN CONTACT WITH WATER RELEASES FLAMMABLE GASES
H317: MAY CAUSE AN ALLERGIC SKIN REACTION
H319: CAUSES SERIOUS EYE IRRITATION
H332: HARMFUL IF INHALED
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H351: SUSPECTED OF CAUSING CANCER
SDS PREPARED BY:
THE REDSTONE GROUP, LLC
6077 FRANTZ RD.
SUITE 206
DUBLIN, OH 43016
USA
T: 614-923-7472
WWW.REDSTONEGRP.COM
LACO NA GHS SDS
THIS INFORMATION IS BASED ON OUR CURRENT KNOWLEDGE AND IS INTENDED TO
DESCRIBE THE PRODUCT FOR THE PURPOSES OF HEALTH, SAFETY AND ENVIRONMENTAL
REQUIREMENTS ONLY. IT SHOULD NOT THEREFORE BE CONSTRUED AS GUARANTEEING ANY
SPECIFIC PROPERTY OF THE PRODUCT
EN (ENGLISH)
SDS REF.: LACO1507029