| Common Name: | SPRAY ADHESIVE NO. 03018 (ITEM 1003268) |
| Manufacturer: | CRC INDUSTRIES |
| SDS Revision Date: | 8/29/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 13P445 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: SPRAY ADHESIVE
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: NO. 03018 (ITEM# 1003268)
RECOMMENDED USE: GENERAL PURPOSE AEROSOL ADHESIVE
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME:
CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-EOUR EMERGENCY (CEEMTREC): 800-424-9300 (US)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. EAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS:
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
REPRODUCTIVE TOXICITY: CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 RESPIRATORY TRACT IRRITATION
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY, REPEATED EXPOSURE: CATEGORY 2
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 3
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 3
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS. SUSPECTED OF DAMAGING FERTILITY OR THE
UNBORN CHILD. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED
EXPOSURE. HARMFUL TO AQUATIC LIFE. HARMFUL TO AQUATIC LIFE WITH LONG
LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER
IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT BREATHE MIST OR VAPOR. DO NOT
APPLY WHILE EQUIPMENT IS ENERGIZED. EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS. VAPORS WILL ACCUMULATE READILY AND MAY IGNITE. USE ONLY WITH
ADEQUATE VENTILATION; MAINTAIN VENTILATION DURING USE AND UNTIL ALL VAPORS
ARE GONE. OPEN DOORS AND WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR
SUPPLY DURING USE AND WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY
SYMPTOMS LISTED ON THIS LABEL, INCREASE VENTILATION OR LEAVE THE AREA.
WASH THOROUGHLY AFTER HANDLING. WEAR PROTECTIVE GLOVES/PROTECTIVE
CLOTHING/EYE PROTECTION/FACE PROTECTION. AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL. IF IN EYES: RINSE CAUTIOUSLY WITH
WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO
DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ADVICE/ATTENTION. IF EXPOSED OR CONCERNED: GET MEDICAL
ADVICE/ATTENTION.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. STORE LOCKED UP. PROTECT FROM SUNLIGHT.
DO NOT EXPOSE TO TEMPERATURES EXCEEDING DEG. C/122 DEG. F. EXPOSURE TO HIGH
TEMPERATURE MAY CAUSE CAN TO BURST.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (ENOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
ACETONE 67-64-1 30 - 40
METHYL ACETATE 79-20-9 10 - 20
PETROLEUM DISTILLATES 8030-30-6 1 - 10
TOLUENE 108-88-3 1 - 10
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. PROVIDE OXYGEN
OR ARTIFICIAL RESPIRATION IF NEEDED. IF PERSON IS NOT BREATHING, CALL
911 OR AN AMBULANCE.
SKIN CONTACT:
WASH OFF IMMEDIATELY WITH SOAP AND PLENTY OF WATER. GET MEDICAL ATTENTION
IF SYMPTOMS OCCUR.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE
CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. CALL A PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO A VICTIM WHO IS UNCONSCIOUS OR
IS HAVING CONVULSIONS. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH
CONTENT DOESN'T GET INTO THE LUNGS.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. MAY CAUSE RESPIRATORY IRRITATION. PROLONGED EXPOSURE MAY
CAUSE CHRONIC EFFECTS.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED:
GET MEDICAL ADVICE/ATTENTION. ENSURE THAT MEDICAL PERSONNEL ARE AWARE
OF THE MATERIAL(S) INVOLVED, AND TAKE PRECAUTIONS TO PROTECT THEMSELVES.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. DRY CHEMICALS. FOAM. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND SPREAD FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY RUPTURE WHEN EXPOSED TO
HEAT OR FLAME. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO
WITHOUT RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR
PRESSURE BUILD UP. USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE
HAZARDS OF OTHER INVOLVED MATERIALS. IN THE EVENT OF FIRE AND/OR EXPLOSION
DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS:
EXTREMELY FLAMMABLE AEROSOL. CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER
MAY RUPTURE WHEN EXPOSED TO HEAT OR FLAME.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. MANY GASES ARE HEAVIER THAN AIR AND WILL
SPREAD ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
BASEMENTS, TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING
DURING CLEAN-UP. DO NOT BREATHE MIST OR VAPOR. EMERGENCY PERSONNEL NEED
SELF-CONTAINED BREATHING EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE
CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE
SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. PREVENT PRODUCT FROM ENTERING DRAINS. STOP THE FLOW OF
MATERIAL, IF THIS IS WITHOUT RISK. WIPE UP WITH ABSORBENT MATERIAL (E.G.
CLOTH, FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
FOR WASTE DISPOSAL, SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. INFORM APPROPRIATE MANAGERIAL OR
SUPERVISORY PERSONNEL OF ALL ENVIRONMENTAL RELEASES. PREVENT FURTHER
LEAKAGE OR SPILLAGE IF SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS, WATER
COURSES OR ONTO THE GROUND.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS
MISSING OR DEFECTIVE. DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER
INCANDESCENT MATERIAL. DO NOT SMOKE WHILE USING OR UNTIL SPRAYED SURFACE
IS THOROUGHLY DRY. DO NOT CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE
CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER SOURCES OF IGNITION. USE
CAUTION AROUND ENERGIZED EQUIPMENT. THE METAL CONTAINER WILL CONDUCT
ELECTRICITY IF IT CONTACTS A LIVE SOURCE. THIS MAY RESULT IN INJURY TO
THE USER FROM ELECTRICAL SHOCK AND/OR FLASH FIRE. AVOID CONTACT WITH EYES.
AVOID PROLONGED EXPOSURE. PREGNANT OR BREASTFEEDING WOMEN MUST NOT HANDLE
THIS PRODUCT. SHOULD BE HANDLED IN CLOSED SYSTEMS, IF POSSIBLE. USE ONLY
IN WELL-VENTILATED AREAS. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT.
AVOID RELEASE TO THE ENVIRONMENT. OBSERVE GOOD INDUSTRIAL HYGIENE
PRACTICES. FOR PRODUCT USAGE INSTRUCTIONS, SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 3 AEROSOL.
PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT PUNCTURE, INCINERATE
OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES
OF IGNITION. THIS MATERIAL CAN ACCUMULATE STATIC CHARGE WHICH MAY CAUSE
SPARK AND BECOME AN IGNITION SOURCE. STORE IN TIGHTLY CLOSED CONTAINER.
STORE IN A WELL-VENTILATED PLACE. STORED CONTAINERS SHOULD BE PERIODICALLY
CHECKED FOR GENERAL CONDITION AND LEAKAGE. STORE AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
THE FOLLOWING CONSTITUENTS ARE THE ONLY CONSTITUENTS OF THE PRODUCT WHICH
HAVE A PEL, TLV OR OTHER RECOMMENDED EXPOSURE LIMIT. AT THIS TIME, THE
OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) PEL 2400 MG/M3
1000 PPM
METHYL ACETATE PEL 610 MG/M3
(CAS 79-20-9) 200 PPM
PETROLEUM DISTILLATES PEL 400 MG/M3
(CAS 8030-30-6) 100 PPM
US. OSHA TABLE Z-2 (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
TOLUENE (CAS 108-88-3) CEILING 300 PPM
TWA 200 PPM
US. ACGH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) STEL 500 PPM
TWA 250 PPM
METHYL ACETATE STEL 250 PPM
(CAS 79-20-9) TWA 200 PPM
TOLUENE (CAS 108-88-3) TWA 20 PPM
US. NIOSE POCKET GUIDE TO CHEMICAL EAZARDS:
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) TWA 590 MG/M3
250 PPM
METHYL ACETATE STEL 760 MG/M3
(CAS 79-20-9) 250 PPM
TWA 610 MG/M3
200 PPM
PETROLEUM DISTILLATES TWA 400 MG/M3
(CAS 8030-30-6) 100 PPM
TOLUENE (CAS 108-88-3) STEL 560 MG/M3
150 PPM
TWA 375 MG/M3
100 PPM
BIOLOGICAL LIMIT VALUES:
ACGH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING
TIME
ACETONE (CAS 67-64-1) 25 MG/L ACETONE URINE *
TOLUENE (CAS 108-88-3) 0.3 MG/G O-CRESOL, WITH CREATININE IN *
HYDROLYSIS URINE
0.03 MG/L TOLUENE URINE *
0.02 MG/L TOLUENE BLOOD *
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
EXPOSURE GUIDELINES:
US - CALIFORNIA OELS SKIN DESIGNATION
TOLUENE (CAS 108-88-3) CAN BE ABSORBED THROUGH THE SKIN.
US - MINNESOTA EAZ SUBS SKIN DESIGNATION APPLIES
TOLUENE (CAS 108-88-3) SKIN DESIGNATION APPLIES.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO
AN ACCEPTABLE LEVEL. PROVIDE EYEWASH STATION.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: LAMINATE FILM.
OTHER: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN
CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO DETERMINE
ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
OBSERVE ANY MEDICAL SURVEILLANCE REQUIREMENTS. WHEN USING DO NOT SMOKE.
ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER
HANDLING THE MATERIAL AND BEFORE EATING, DRINKING, AND/OR SMOKING.
ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO REMOVE
CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: AEROSOL.
COLOR: BEIGE.
ODOR: SOLVENT.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -144.4 DEG. F (-98 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE: 95 DEG. F (35 DEG. C) ESTIMATED
FLASH POINT: -4 DEG. F (-20 DEG. C) ESTIMATED
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 1.3% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 16% ESTIMATED
VAPOR PRESSURE: 1689.6 HPA ESTIMATED
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 0.76
SOLUBILITY(IES):
SOLUBILITY (WATER): INSOLUBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 550 DEG. F (287.8 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
PERCENT VOLATILE: 72.5% ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG ACIDS. STRONG ALKALIS.
HAZARDOUS DECOMPOSITION PRODUCTS: CARBON OXIDES. HYDROCARBONS. FUMES.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. MAY CAUSE
IRRITATION TO THE RESPIRATORY SYSTEM. PROLONGED INHALATION MAY BE HARMFUL.
SKIN CONTACT: NO ADVERSE EFFECTS DUE TO SKIN CONTACT ARE EXPECTED.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. MAY CAUSE RESPIRATORY IRRITATION.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT KNOWN.
PRODUCT SPECIES TEST RESULTS
SPRAY ADHESIVE:
ACUTE:
DERMAL:
LD50 RABBIT 10880 MG/KG
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
ACUTE:
DERMAL:
LD50 RABBIT >15800 MG/KG
20000 MG/KG
INHALATION:
LC50 RAT 76 MG/L, 4 HOURS
ORAL:
LD50 RAT 5800 MG/KG
METHYL ACETATE (CAS 79-20-9):
ACUTE:
ORAL:
LD50 RABBIT 3.7 G/KG
PETROLEUM DISTILLATES (CAS 8030-30-6):
ACUTE:
INHALATION:
LC50 RAT 61 MG/L, 4 HOURS
TOLUENE (CAS 108-88-3):
ACUTE:
DERMAL:
LD50 RABBIT >5000 MG/KG
INHALATION:
LC50 RAT 12.5 MG/L, 4 HOURS
ORAL:
LD50 RAT 5580 MG/KG
SKIN CORROSION/IRRITATION:
PROLONGED SKIN CONTACT MAY CAUSE TEMPORARY IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
TOLUENE (CAS 108-88-3): 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
REPRODUCTIVE TOXICITY: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CHRONIC EFFECTS:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRODUCT SPECIES TEST RESULTS
SPRAY ADHESIVE:
AQUATIC:
FISH LC50 FISH 154.3469 MG/L, 96 HOURS ESTIMATED
COMPONENTS SPECIES TEST RESULTS
METHYL ACETATE (CAS 79-20-9):
AQUATIC:
FISH LC50 FATHEAD MINNOW 295 - 348 MG/L, 96 HOURS
(PIMEPHALES PROMELAS)
PETROLEUM DISTILLATES (CAS 8030-30-6):
AQUATIC:
CRUSTACEA EC50 WATER FLEA 2.7 - 5.1 MG/L, 48 HOURS
(DAPHNIA PULEX)
FISH LC50 RAINBOW TROUT, 8.8 MG/L, 96 HOURS
DONALDSON TROUT
(ONCORHYNCHUS MYKISS)
TOLUENE (CAS 108-88-3):
ACUTE:
OTHER EC50 PSEUDOKIRCHNERELLA 433 MG/L, 96 HOURS
SUBCAPITATA 12.5 MG/L, 72 HOURS
AQUATIC:
ACUTE:
FISH LC50 COHO SALMON, 5.5 MG/L, 96 HOURS
SILVER SALMON
(ONCORHYNCHUS KISUTCH)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF ANY INGREDIENTS IN THE
MIXTURE.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
ACETONE: -0.24
METHYL ACETATE: 0.18
TOLUENE: 2.73
BIOCONCENTRATION FACTOR (BCF):
TOLUENE: 90
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE.
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
D001: WASTE FLAMMABLE MATERIAL WITH A FLASH POINT <140 F
F003: WASTE NON-HALOGENATED SOLVENT - SPENT NON-HALOGENATED SOLVENT
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ERG CODE: 10L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO.
EMS: NOT AVAILABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
DOT; IMDG: LIMITED QUANTITY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1052):
NOT REGULATED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
TOLUENE (CAS 108-88-3)
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
ACETONE (CAS 67-64-1): LISTED.
METHYL ACETATE (CAS 79-20-9): LISTED.
PETROLEUM DISTILLATES (CAS 8030-30-6): LISTED.
TOLUENE (CAS 108-88-3): LISTED.
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
ACETONE (CAS 67-64-1) 5000 LBS
METHYL ACETATE (CAS 79-20-9) 100 LBS
PETROLEUM DISTILLATES (CAS 8030-30-6) 100 LBS
TOLUENE (CAS 108-88-3) 1000 LBS
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE
ITS RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
TOLUENE (CAS 108-88-3)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
(40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS
(21 CFR 1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
ACETONE (CAS 67-64-1): 6532
TOLUENE (CAS 108-88-3): 6594
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL
MIXTURES (21 CFR 1310.12(C)):
ACETONE (CAS 67-64-1): 35% WV
TOLUENE (CAS 108-88-3) 35% WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
ACETONE (CAS 67-64-1): 6532
TOLUENE (CAS 108-88-3): 594
FEMA PRIORITY SUBSTANCES RESPIRATORY HEALTH AND SAFETY IN THE FLAVOR
MANUFACTURING WORKPLACE:
ACETONE (CAS 67-64-1): LOW PRIORITY
METHYL ACETATE (CAS 79-20-9): LOW PRIORITY
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
CLASSIFIED HAZARD CATEGORIES:
FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS)
GAS UNDER PRESSURE
ACUTE TOXICITY (ANY ROUTE OF EXPOSURE)
SERIOUS EYE DAMAGE OR EYE IRRITATION REPRODUCTIVE TOXICITY
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NOT LISTED.
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
TOLUENE 108-88-3 1 - 10
US STATE REGULATIONS:
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
ACETONE (CAS 67-64-1)
METHYL ACETATE (CAS 79-20-9)
PETROLEUM DISTILLATES (CAS 8030-30-6)
TOLUENE (CAS 108-88-3)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
ACETONE (CAS 67-64-1)
METHYL ACETATE (CAS 79-20-9)
PETROLEUM DISTILLATES (CAS 8030-30-6)
TOLUENE (CAS 108-88-3)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
ACETONE (CAS 67-64-1)
METHYL ACETATE (CAS 79-20-9)
PETROLEUM DISTILLATES (CAS 8030-30-6)
TOLUENE (CAS 108-88-3)
US. RHODE ISLAND RTK:
ACETONE (CAS 67-64-1)
METHYL ACETATE (CAS 79-20-9)
PETROLEUM DISTILLATES (CAS 8030-30-6)
TOLUENE (CAS 108-88-3)
CALIFORNIA PROPOSITION 65:
WARNING: CANCER AND REPRODUCTIVE HARM - WWW.P65WARNINGS.CA.GOV
CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/CARCINOGENIC SUBSTANCE
BENZENE (CAS 71-43-2) LISTED: FEBRUARY 27, 1987
ETHYLBENZENE (CAS 100-41-4) LISTED: JUNE 11, 2004
CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/DEVELOPMENTAL TOXIN
BENZENE (CAS 71-43-2) LISTED: DECEMBER 26, 1997
TOLUENE (CAS 108-88-3) LISTED: JANUARY 1, 1991
CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/MALE REPRODUCTIVE TOXIN
BENZENE (CAS 71-43-2) LISTED: DECEMBER 26, 1997
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
ACETONE (CAS 67-64-1)
PETROLEUM DISTILLATES (CAS 8030-30-6)
TOLUENE (CAS 108-88-3)
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 35.8%
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS REGULATED AS A WEB SPRAY ADHESIVE. THIS PRODUCT IS
COMPLIANT FOR USE IN ALL 50 STATES.
VOC CONTENT (CA): 35.8%
VOC CONTENT (OTC): 35.8%
INTERNATIONAL INVENTORIES:
COUNTRY(S) INVENTORY NAME ON INVENTORY
OR REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL NO
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) NO
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL NO
SUBSTANCES IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING COMMERCIAL NO
CHEMICAL SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL NO
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) NO
NEW ZEALAND NEW ZEALAND INVENTORY NO
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND NO
CHEMICAL SUBSTANCES (PICCS)
TAIWAN TAIWAN TOXIC CHEMICAL SUBSTANCES (TCSI) NO
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF | |
PREPARATION OR LAST REVISION
ISSUE DATE: 08-25-2014
REVISION DATE: 08-29-2018
PREPARED BY: ALLISON YOON
VERSION #: 04
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC'S KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY CRC TO BE
ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND DIRECTIONS ON THE
LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION CONTAINED ON THIS
(M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY PROFESSIONAL, OR CRC
INDUSTRIES, INC.
REVISION INFORMATION:
THIS DOCUMENT HAS UNDERGONE SIGNIFICANT CHANGES AND SHOULD BE REVIEWED IN
ITS ENTIRETY.
MATERIAL NAME: SPRAY ADHESIVE
SDS: US