| Common Name: | 94 ET HI STRENGTH AEROSOL SPRAY ADHESIVE LOW VOC 20%, CLEAR |
| Manufacturer: | 3M |
| SDS Revision Date: | 4/24/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 15E717 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) 94 ET HI STRENGTH AEROSOL SPRAY ADHESIVE LOW VOC 20%, CLEAR
04/24/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 29-3983-3
VERSION NUMBER: 2.00
ISSUE DATE: 04/24/15
SUPERCEDES DATE: 12/10/12
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) 94 ET HI STRENGTH AEROSOL SPRAY ADHESIVE LOW VOC 20%, CLEAR
PRODUCT IDENTIFICATION NUMBERS: 62-4870-4930-6, 62-4870-4935-5
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: AEROSOL SPRAY ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
FLAMMABLE AEROSOL: CATEGORY 1.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2B.
SIMPLE ASPHYXIANT.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (CENTRAL NERVOUS SYSTEM): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (RESPIRATORY IRRITATION): CATEGORY 3.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CAUSES EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION.
CAUSES DAMAGE TO ORGANS: CARDIOVASCULAR SYSTEM
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE.
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO.
CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF EXPOSED:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL).
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F.
KEEP COOL.
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NOTES TO PHYSICIAN:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING CONTENTS CAN
BE HARMFUL OR FATAL.
10% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
N.J.T.S. REG NO. 04499600-6848 TRADE SECRET* 15 - 25 TRADE SECRET *
PROPANE 74-98-6 5 - 10 TRADE SECRET *
DIMETHYL ETHER 115-10-6 5 - 10 TRADE SECRET *
METHYL ACETATE 79-20-9 55 - 65 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION: REMOVE PERSON TO FRESH AIR. GET MEDICAL ATTENTION.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED:
EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER
SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
USE A FIRE FIGHTING AGENT SUITABLE FOR THE SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ALDEHYDES DURING COMBUSTION
HYDROCARBONS DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
IRRITANT VAPORS OR GASES DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO
KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE
RUPTURE.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. USE ONLY
NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR.
WARNING!
A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR
VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF
THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY
PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
IF POSSIBLE, SEAL LEAKING CONTAINER. PLACE LEAKING CONTAINERS IN A
WELL-VENTILATED AREA, PREFERABLY AN OPERATING EXHAUST HOOD, OR IF NECESSARY
OUTDOORS ON AN IMPERMEABLE SURFACE UNTIL APPROPRIATE PACKAGING FOR THE
LEAKING CONTAINER OR ITS CONTENTS IS AVAILABLE. CONTAIN SPILL. COVER SPILL
AREA WITH A FIRE-EXTINGUISHING FOAM. AN APPROPRIATE AQUEOUS FILM FORMING
FOAM (AFFF) IS RECOMMENDED. WORKING FROM AROUND THE EDGES OF THE SPILL
INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE
INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS
DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL,
HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS
POSSIBLE USING NON-SPARKING TOOLS. PLACE IN A METAL CONTAINER APPROVED FOR
TRANSPORTATION BY APPROPRIATE AUTHORITIES. CLEAN UP RESIDUE WITH AN
APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED PERSON.
VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON
THE SOLVENT LABEL AND SDS. SEAL THE CONTAINER. DISPOSE OF COLLECTED
MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT PIERCE OR BURN,
EVEN AFTER USE. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET
IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING
THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH OXIDIZING
AGENTS (EG. CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT
FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F. STORE AWAY
FROM ACIDS. STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
DIMETHYL ETHER 115-10-6 AIHA TWA:
1880 MG/M3
(1000 PPM)
DIMETHYL ETHER 115-10-6 CMRG TWA: 1000 PPM
PROPANE 74-98-6 ACGIH LIMIT VALUE
NOT ESTABLISHED
PROPANE 74-98-6 OSHA TWA:
1800 MG/M3
(1000 PPM)
METHYL ACETATE 79-20-9 ACGIH TWA: 200 PPM
STEL: 250 PPM
METHYL ACETATE 79-20-9 OSHA TWA:
610 MG/M3
(200 PPM)
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
DO NOT REMAIN IN AREA WHERE AVAILABLE OXYGEN MAY BE REDUCED. USE GENERAL
DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE
EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: BUTYL RUBBER
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM.
BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING
RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR
ORGANIC VAPOR RESPIRATORS MAY HAVE SHORT SERVICE LIFE.
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: AEROSOL
ODOR, COLOR, GRADE: CLEAR - LIGHT YELLOW, SOLVENT ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: <-40 DEG. F [TEST METHOD: CLOSED CUP]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): 3.1%
FLAMMABLE LIMITS(UEL): 16%
VAPOR PRESSURE: 65 PSI [@ 70 DEG. F]
VAPOR DENSITY: 1 [REF STD: AIR=1]
SPECIFIC GRAVITY: 0.846 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 0% WEIGHT [TEST METHOD: CALCULATED]
VOLATILE ORGANIC COMPOUNDS:
18.5% [TEST METHOD: CALCULATED PER CARB TITLE 2]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: SPARKS AND/OR FLAMES
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
INTENTIONAL CONCENTRATION AND INHALATION MAY BE HARMFUL OR FATAL.
SIMPLE ASPHYXIATION:
SIGNS/SYMPTOMS MAY INCLUDE INCREASED HEART RATE, RAPID RESPIRATIONS,
DROWSINESS, HEADACHE, INCOORDINATION, ALTERED JUDGEMENT, NAUSEA, VOMITING,
LETHARGY, SEIZURES, COMA, AND MAY BE FATAL.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
DERMAL DEFATTING:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, ITCHING, DRYING AND CRACKING
OF SKIN.
EYE CONTACT:
MODERATE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, PAIN, TEARING, AND BLURRED OR
HAZY VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION:
SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION,
NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND
UNCONSCIOUSNESS.
CARDIAC SENSITIZATION:
SIGNS/SYMPTOMS MAY INCLUDE IRREGULAR HEARTBEAT (ARRHYTHMIA), FAINTNESS,
CHEST PAIN, AND MAY BE FATAL.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE:
>5,000 MG/KG
METHYL ACETATE DERMAL RAT LD50: >2,000 MG/KG
METHYL ACETATE INHALATION- RAT LC50: >49 MG/L
VAPOR
(4 HOURS)
METHYL ACETATE INGESTION RAT LD50: >5,000 MG/KG
PROPANE INHALATION- RAT LC50: >200,000 PPM
GAS (4 HOURS)
N.J.T.S. REG NO. DERMAL NOT LD50: >2,000 MG/KG
04499600-6848 AVAILABLE
N.J.T.S. REG NO. INGESTION NOT LD50: >2,000 MG/KG
04499600-6848 AVAILABLE
DIMETHYL ETHER INHALATION- RAT LC50: 164,000 PPM
GAS (4 HOURS)
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
METHYL ACETATE RABBIT NO SIGNIFICANT IRRITATION
PROPANE RABBIT MINIMAL IRRITATION
N.J.T.S. REG NO. 04499600-6848 PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
METHYL ACETATE RABBIT MODERATE IRRITANT
PROPANE RABBIT MILD IRRITANT
N.J.T.S. REG NO. 04499600-6848 PROFESSIONAL NO SIGNIFICANT IRRITATION
JUDGEMENT
SKIN SENSITIZATION:
NAME SPECIES VALUE
METHYL ACETATE HUMAN NOT SENSITIZING
N.J.T.S. REG NO. 04499600-6848 NOT SENSITIZING
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
METHYL ACETATE IN VITRO NOT MUTAGENIC
METHYL ACETATE IN VIVO NOT MUTAGENIC
PROPANE IN VITRO NOT MUTAGENIC
DIMETHYL ETHER IN VITRO NOT MUTAGENIC
DIMETHYL ETHER IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
DIMETHYL ETHER INHALATION RAT NOT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
DIMETHYL ETHER INHALATION NOT TOXIC TO FEMALE REPRODUCTION
DIMETHYL ETHER INHALATION NOT TOXIC TO MALE REPRODUCTION
DIMETHYL ETHER INHALATION NOT TOXIC TO DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS
DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS
DIMETHYL ETHER RAT NOAEL: DURING
40,000 PPM ORGANOGENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
METHYL ACETATE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
METHYL ACETATE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
METHYL ACETATE INHALATION BLINDNESS SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
METHYL ACETATE INGESTION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
PROPANE INHALATION CARDIAC CAUSES DAMAGE TO ORGANS
SENSITIZATION
PROPANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
PROPANE INHALATION RESPIRATORY ALL DATA ARE NEGATIVE
IRRITATION
DIMETHYL ETHER INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR
SYSTEM DEPRESSION DIZZINESS
DIMETHYL ETHER INHALATION CARDIAC SOME POSITIVE DATA EXIST,
SENSITIZATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
METHYL ACETATE HUMAN AND NOAEL: NOT AVAILABLE
ANIMAL
METHYL ACETATE HUMAN AND NOAEL: NOT AVAILABLE
ANIMAL
METHYL ACETATE NOAEL: NOT AVAILABLE
METHYL ACETATE NOAEL: NOT AVAILABLE
PROPANE HUMAN NOAEL: NOT AVAILABLE
PROPANE HUMAN NOAEL: NOT AVAILABLE
PROPANE HUMAN NOAEL: NOT AVAILABLE
DIMETHYL ETHER RAT LOAEL: 10,000 PPM 30 MINUTES
DIMETHYL ETHER DOG NOAEL: 100,000 PPM 5 MINUTES
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
METHYL ACETATE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
METHYL ACETATE INHALATION ENDOCRINE SYSTEM SOME POSITIVE DATA
HEMATOPOIETIC EXIST, BUT THE DATA
SYSTEM ARE NOT SUFFICIENT
LIVER FOR CLASSIFICATION
IMMUNE SYSTEM
KIDNEY AND/OR
BLADDER
DIMETHYL ETHER INHALATION HEMATOPOIETIC SOME POSITIVE DATA
SYSTEM EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
DIMETHYL ETHER INHALATION LIVER SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
METHYL ACETATE RAT NOAEL: 1.1 MG/L 28 DAYS
METHYL ACETATE RAT NOAEL: 6.1 MG/L 28 DAYS
DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS
DIMETHYL ETHER RAT NOAEL: 20,000 PPM 30 WEEKS
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. FACILITY MUST BE
CAPABLE OF HANDLING AEROSOL CANS. AS A DISPOSAL ALTERNATIVE, UTILIZE AN
ACCEPTABLE PERMITTED WASTE DISPOSAL FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): D001 (IGNITABLE)
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. CLASSIFICATION
METHYL ALCOHOL TRADE SECRET DEVELOPMENTAL TOXIN
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 4
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED
FOR USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 29-3983-3
VERSION NUMBER: 2.00
ISSUE DATE: 04/24/15
SUPERCEDES DATE: 12/10/12
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM