| Common Name: | DPD INDICATOR POWDER, FREE CHLORINE INDICATOR SOLUTION, 473 ML, FREE CHLORINE BU |
| Manufacturer: | TINTOMETER |
| SDS Revision Date: | 1/3/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 15F863 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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LOVIBOND(R*)
LOVIBOND(R*) WATER TESTING
TINTOMETER GROUP
SAFETY DATA SHEET
ACC. TO OSHA HCS (HAZCOM 2012)
PRINTING DATE: 01/03/2018
REVIEWED ON: 01/03/2018
| 1 IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: DPD INDICATOR POWDER
CATALOGUE NUMBER: 530200, 4530200, 00530209, 00530219, 530201
APPLICATION OF THE SUBSTANCE / THE MIXTURE: REAGENT FOR WATER ANALYSIS
MANUFACTURER/SUPPLIER:
TINTOMETER INC.
6456 PARKLAND DRIVE
SARASOTA, FL 34243
USA
PHONE: (941) 756-6410
FAX: (941) 727-9654
WWW.LOVIBOND.US
MADE IN GERMANY
EMERGENCY TELEPHONE NUMBER: + 1 866 928 0789 (ENGLISH, FRENCH, SPANISH)
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS07: EXCLAMATION MARK
ACUTE TOX. 4:
H302: HARMFUL IF SWALLOWED.
ACUTE TOX. 4:
H312: HARMFUL IN CONTACT WITH SKIN.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
STOT SE 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE HAZARD
COMMUNICATION STANDARD (HCS).
HAZARD PICTOGRAMS:
GHS07: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD-DETERMINING COMPONENTS OF LABELING:
N,N-DIETHYL-P-PHENYLENEDIAMINE SULFATE(1:1)
HAZARD STATEMENTS:
H302+H312: HARMFUL IF SWALLOWED OR IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENTS:
P280: WEAR PROTECTIVE GLOVES.
P301+P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P312: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
OTHER HAZARDS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
DESCRIPTION: MIXTURE OF ORGANIC AND INORGANIC COMPOUNDS
COMPOSITION AND INFORMATION ON INGREDIENTS:
PERCENT RANGES ARE USED DUE TO THE CONFIDENTIAL PRODUCT INFORMATION.
CAS: 6283-63-2 N,N-DIETHYL-P-PHENYLENEDIAMINE SULFATE (1:1) 50-60%
EINECS: 228-500-6 ACUTE TOX. 4, H302; ACUTE TOX. 4, H312;
RTECS: SS 9625000 SKIN IRRIT. 2, H315; EYE IRRIT. 2A, H319;
STOT SE 3, H335
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD PHRASES REFER TO SECTION 16.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
AFTER INHALATION: SUPPLY FRESH AIR AND TO BE SURE CALL FOR A DOCTOR.
AFTER SKIN CONTACT:
IMMEDIATELY RINSE WITH PLENTY OF WATER.
CALL A DOCTOR IMMEDIATELY.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES (AT LEAST 15 MIN) UNDER RUNNING
WATER. THEN CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK 1-2 GLASSES OF WATER.
SEEK MEDICAL TREATMENT.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
IRRITATIONS
AFTER INHALATION:
MUCOSAL IRRITATIONS, COUGH, BREATHING DIFFICULTY
AFTER RESORPTION:
ALLERGIC REACTIONS
METHAEMOGLOBINAEMIA
VOMITING
SICKNESS
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
USE FIRE FIGHTING MEASURES THAT SUIT THE ENVIRONMENT.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
MIXTURE WITH COMBUSTIBLE INGREDIENTS
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
NITROUS GASES
NITROGEN OXIDES (NOX)
SULFUR OXIDES (SOX)
SODIUM MONOXIDE
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
COLLECT CONTAMINATED FIRE FIGHTING WATER SEPARATELY. IT MUST NOT ENTER
THE SEWAGE SYSTEM.
DISPOSE OF FIRE DEBRIS AND CONTAMINATED FIRE FIGHTING WATER IN ACCORDANCE
WITH OFFICIAL REGULATIONS.
AMBIENT FIRE MAY LIBERATE HAZARDOUS VAPOURS.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ADVICE FOR NON-EMERGENCY PERSONNEL:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
ADVICE FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: SEE SECTION 8
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR ANY WATER COURSE.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ENSURE ADEQUATE VENTILATION.
PICK UP MECHANICALLY.
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING: PREVENT FORMATION OF DUST.
HYGIENE MEASURES:
DO NOT INHALE DUST / SMOKE / MIST.
AVOID CONTACT WITH THE SKIN.
AVOID CONTACT WITH THE EYES.
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY: NOT REQUIRED.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
PROTECT FROM EXPOSURE TO THE LIGHT.
STORE IN DRY CONDITIONS.
PROTECT FROM HUMIDITY AND WATER.
THIS PRODUCT IS HYGROSCOPIC.
RECOMMENDED STORAGE TEMPERATURE:
20 DEG. C +/- 5 DEG. C (APPROX. 68 DEG. F)
SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
THE PRODUCT DOES NOT CONTAIN ANY RELEVANT QUANTITIES OF MATERIALS WITH
CRITICAL VALUES THAT HAVE TO BE MONITORED AT THE WORKPLACE.
ADDITIONAL INFORMATION:
THE LISTS THAT WERE VALID DURING THE CREATION WERE USED AS BASIS.
ENGINEERING MEASURES:
TECHNICAL MEASURES AND APPROPRIATE WORKING OPERATIONS SHOULD BE GIVEN
PRIORITY OVER THE USE OF PERSONAL PROTECTIVE EQUIPMENT. SEE ITEM 7.
PERSONAL PROTECTIVE EQUIPMENT:
BREATHING EQUIPMENT:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF FUMES/DUST/
AEROSOL.
RECOMMENDED FILTER DEVICE FOR SHORT TERM USE: FILTER P2
PROTECTION OF HANDS:
PROTECTIVE GLOVES
PREVENTIVE SKIN PROTECTION BY USE OF SKIN-PROTECTING AGENTS IS RECOMMENDED.
AFTER USE OF GLOVES APPLY SKIN-CLEANING AGENTS AND SKIN COSMETICS.
MATERIAL OF GLOVES:
NITRILE RUBBER, NBR
RECOMMENDED THICKNESS OF THE MATERIAL: >/=0.11 MM
PENETRATION TIME OF GLOVE MATERIAL:
VALUE FOR THE PERMEATION: LEVEL </=1 (10 MIN)
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION:
SAFETY GLASSES
USE AGAINST THE EFFECTS OF FUMES / DUST
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR ANY WATER COURSE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM / PHYSICAL STATE: POWDER
COLOR: WHITISH
ODOR: ODORLESS
ODOR THRESHOLD: NOT APPLICABLE.
PH-VALUE (1 G/L) AT 20 DEG. C (68 DEG. F): 2.8
MELTING POINT/FREEZING POINT: NOT DETERMINED.
INITIAL BOILING POINT AND BOILING RANGE: NOT DETERMINED.
FLASH POINT: NOT APPLICABLE.
FLAMMABILITY (SOLID, GAS): NOT DETERMINED.
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
AUTO-IGNITION TEMPERATURE: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR MIXTURES
IS POSSIBLE.
FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER: NOT DETERMINED.
UPPER: NOT DETERMINED.
OXIDIZING PROPERTIES: NONE
VAPOR PRESSURE: NOT APPLICABLE.
DENSITY: NOT DETERMINED.
RELATIVE DENSITY: NOT DETERMINED.
VAPOR DENSITY: NOT APPLICABLE.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY(IES):
WATER: SOLUBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT APPLICABLE.
VISCOSITY: NOT APPLICABLE.
SOLVENT CONTENT:
ORGANIC SOLVENTS: 0.0 %
SOLIDS CONTENT: 100.0 %
OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: DUST CAN COMBINE WITH AIR TO FORM AN EXPLOSIVE MIXTURE.
CHEMICAL STABILITY:
STABLE AT AMBIENT TEMPERATURE (ROOM TEMPERATURE).
SENSITIVITY TO LIGHT
POSSIBILITY OF HAZARDOUS REACTIONS: REACTS WITH OXIDIZING AGENTS.
CONDITIONS TO AVOID: STRONG HEATING (DECOMPOSITION)
INCOMPATIBLE MATERIALS: ALUMINUM
HAZARDOUS DECOMPOSITION PRODUCTS: SEE SECTION 5
| 11 TOXICOLOGICAL INFORMATION | |
|
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: CLASSIFICATION ACCORDING TO CALCULATION PROCEDURE.
ACUTE TOXICITY ESTIMATE (ATE(MIX)) - CALCULATION METHOD:
ORAL:
GHS ATE(MIX): 884 MG/KG (.)
DERMAL:
GHS ATE(MIX): 1956 MG/KG (.)
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
CAS: 6283-63-2 N,N-DIETHYL-P-PHENYLENEDIAMINE SULFATE (1:1)
ORAL:
LD50: 497 MG/KG (RAT) (MERCK)
DERMAL:
LD50: 1100 MG/KG (ATE)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: CAUSES SKIN IRRITATION.
ON THE EYE: CAUSES SERIOUS EYE IRRITATION.
INFORMATION ON COMPONENTS:
CAS 6283-63-2: DPD MAY CAUSE ALLERGIC SKIN REACTION
SENSITIZATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
INFORMATION ON COMPONENTS:
CAS 6283-63-2: SENSITIZATION POSSIBLE IN PREDISPOSED PERSONS.
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
NONE OF THE INGREDIENTS IS LISTED.
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS IS LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS IS LISTED.
OTHER INFORMATION: SEE SECTION 8 / 15
SYNERGISTIC PRODUCTS: NONE
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
THE FOLLOWING STATEMENTS REFER TO THE MIXTURE:
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
REPRODUCTIVE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT (SPECIFIC TARGET ORGAN TOXICITY) - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION.
STOT (SPECIFIC TARGET ORGAN TOXICITY) - REPEATED EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE FOLLOWING APPLIES TO AROMATIC AMINES IN GENERAL:
SYSTEMIC EFFECT - METHAEMOGLOBINAEMIA WITH HEADACHE, CARDIA DYSRHYTHMIA,
DROP IN BLOOD PRESSURE, DYSPNOEA, SPASM, PRINCIPAL SYMPTOM: CYANOSIS (BLUE
DISCOLORATION OF THE BLOOD)
| 12 ECOLOGICAL INFORMATION | |
|
TOXICITY:
AQUATIC TOXICITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
BACTERIAL TOXICITY: SULFATES TOXIC >2.5 G/L
OTHER INFORMATION:
TOXIC FOR FISH: SULFATES >7 G/L
PERSISTENCE AND DEGRADABILITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
POW: N-OCTANOL/WASSER PARTITION COEFFICIENT
LOG POW 1-3: NOT WORTH-MENTIONING ACCUMULATING IN ORGANISMS.
CAS: 6283-63-2 N,N-DIETHYL-P-PHENYLENEDIAMINE SULFATE (1:1)
LOG POW: 2.24 (.) (CALCULATED)
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: AVOID TRANSFER INTO THE ENVIRONMENT.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM.
HAND OVER TO HAZARDOUS WASTE DISPOSERS.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
|
UN-NUMBER:
DOT, IMDG, IATA: NONE
UN PROPER SHIPPING NAME:
DOT, IMDG, IATA: NONE
TRANSPORT HAZARD CLASS(ES):
DOT, IMDG, IATA:
CLASS: NONE
PACKING GROUP:
DOT, IMDG, IATA: NONE
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
NOT DANGEROUS ACCORDING TO THE ABOVE SPECIFICATIONS.
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
NONE OF THE INGREDIENTS IS LISTED.
TSCA (TOXIC SUBSTANCES CONTROL ACT):
CAS NO. 6283-63-2 IS LISTED UNDER CAS NO. 6065-27-6 1,4-BENZENEDIAMINE,
N1,N1-DIETHYL-, SULFATE (1:?)
ALL REMAINING INGREDIENTS ARE LISTED.
PROPOSITION 65:
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
NEW JERSEY RIGHT-TO-KNOW LIST: NONE OF THE INGREDIENTS IS LISTED.
NEW JERSEY SPECIAL HAZARDOUS SUBSTANCE LIST:
NONE OF THE INGREDIENTS IS LISTED.
PENNSYLVANIA RIGHT-TO-KNOW LIST:
CAS: 7757-82-6 SODIUM SULPHATE
PENNSYLVANIA SPECIAL HAZARDOUS SUBSTANCE LIST:
CAS: 7757-82-6 SODIUM SULPHATE E
EPA (ENVIRONMENTAL PROTECTION AGENCY): NONE OF THE INGREDIENTS IS LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS IS LISTED.
INFORMATION ABOUT LIMITATION OF USE:
EMPLOYMENT RESTRICTIONS CONCERNING YOUNG PERSONS MUST BE OBSERVED.
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H302: HARMFUL IF SWALLOWED.
H312: HARMFUL IN CONTACT WITH SKIN.
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
DATE OF PREPARATION / LAST REVISION: 01/03/2018 / 7
ABBREVIATIONS AND ACRONYMS:
ICAO: INTERNATIONAL CIVIL AVIATION ORGANISATION
EC50: EFFECTIVE CONCENTRATION, 50 PERCENT (IN VIVO)
OECD: ORGANISATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
STOT: SPECIFIC TARGET ORGAN TOXICITY
SE: SINGLE EXPOSURE
RE: REPEATED EXPOSURE
EC50: HALF MAXIMAL EFFECTIVE CONCENTRATION
IC50: HALLF MAXIMAL INHIBITORY CONCENTRATION
NOEL OR NOEC: NO OBSERVED EFFECT LEVEL OR CONCENTRATION
ACGIH(R*): AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
A1: CONFIRMED HUMAN CARCINOGEN
A2: SUSPECTED HUMAN CARCINOGEN
A3: CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS
A4: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
A5: NOT SUSPECTED AS A HUMAN CARCINOGEN
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
GROUP 1: CARCINOGENIC TO HUMANS
GROUP 2A: PROBABLY CARCINOGENIC TO HUMANS
GROUP 2B: POSSIBLY CARCINOGENIC TO HUMANS
GROUP 3: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS
GROUP 4: PROBABLY NOT CARCINOGENIC TO HUMANS
NTP:
NATIONAL TOXICOLOGY PROGRAM, U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES
GROUP K: KNOWN TO BE HUMAN CARCINOGENS
GROUP R: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGENS
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
RID:
REGLEMENT INTERNATIONAL CONCERNANT LE TRANSPORT DES MARCHANDISES
DANGEREUSES PAR CHEMIN DE FER (REGULATIONS CONCERNING THE INTERNATIONAL
TRANSPORT OF DANGEROUS GOODS BY RAIL)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
TLV: THRESHOLD LIMIT VALUE
PEL: PERMISSIBLE EXPOSURE LIMIT
REL: RECOMMENDED EXPOSURE LIMIT
ACUTE TOX. 4: ACUTE TOXICITY - CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 3
SOURCES:
DATA ARISE FROM SAFETY DATA SHEETS, REFERENCE WORKS AND LITERATURE.
| DATA COMPARED TO THE PREVIOUS VERSION ALTERED.
US
LOVIBOND(R*)
LOVIBOND(R*) WATER TESTING
TINTOMETER(R*) GROUP
SAFETY DATA SHEET
ACC. TO OSHA HCS (HAZCOM 2012)
PRINTING DATE: 01/04/2018
REVIEWED ON: 01/04/2018
| 1 IDENTIFICATION | |
|
PRODUCT IDENTIFIER:
TRADE NAME: FREE CHLORINE INDICATOR SOLUTION, 473 ML
SDS VALID FROM LOT: P08A
CATALOGUE NUMBER: 530222, 4530222, 424488
APPLICATION OF THE SUBSTANCE / THE MIXTURE: REAGENT FOR WATER ANALYSIS
MANUFACTURER/SUPPLIER:
TINTOMETER INC.
6456 PARKLAND DRIVE
SARASOTA, FL 34243
USA
PHONE: (941) 756-6410
FAX: (941) 727-9654
WWW.LOVIBOND.US
MADE IN GERMANY
EMERGENCY TELEPHONE NUMBER: + 1 866 928 0789 (ENGLISH, FRENCH, SPANISH)
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS05: CORROSION
MET. CORR.1:
H290: MAY BE CORROSIVE TO METALS.
SKIN CORR. 1C:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
EYE DAM. 1:
H318: CAUSES SERIOUS EYE DAMAGE.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE HAZARD COMMUNICATION
STANDARD (HCS).
HAZARD PICTOGRAMS:
GHS05: CORROSION
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELING: P-TOLUENESULPHONIC ACID
HAZARD STATEMENTS:
H290: MAY BE CORROSIVE TO METALS.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
PRECAUTIONARY STATEMENTS:
P234: KEEP ONLY IN ORIGINAL CONTAINER.
P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P310: IMMEDIATELY CALL A DOCTOR.
P390: ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE.
OTHER HAZARDS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
DESCRIPTION: AQUEOUS SOLUTION
COMPOSITION AND INFORMATION ON INGREDIENTS:
PERCENT RANGES ARE USED DUE TO THE CONFIDENTIAL PRODUCT INFORMATION.
CAS: 6192-52-5 P-TOLUENESULPHONIC ACID 5-10%
EINECS: 203-180-0 SKIN CORR. 1C, H314;
INDEX NUMBER: 016-030-00-2 EYE DAM. 1, H318; STOT SE 3, H335
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD PHRASES REFER TO SECTION 16.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
CALL A DOCTOR IMMEDIATELY.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES (AT LEAST 15 MIN) UNDER RUNNING
WATER.
CALL A DOCTOR IMMEDIATELY.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK 1-2 GLASSES OF WATER.
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: BURNS
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
IF SWALLOWED OR IN CASE OF VOMITING, DANGER OF ENTERING THE LUNGS.
LATER OBSERVATION FOR PNEUMONIA AND PULMONARY EDEMA.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
USE FIRE FIGHTING MEASURES THAT SUIT THE ENVIRONMENT.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
THE PRODUCT IS NOT COMBUSTIBLE.
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
SULFUR OXIDES (SOX)
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
COLLECT CONTAMINATED FIRE FIGHTING WATER SEPARATELY. IT MUST NOT ENTER THE
SEWAGE SYSTEM.
DISPOSE OF FIRE DEBRIS AND CONTAMINATED FIRE FIGHTING WATER IN ACCORDANCE
WITH OFFICIAL REGULATIONS.
AMBIENT FIRE MAY LIBERATE HAZARDOUS VAPOURS.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ADVICE FOR NON-EMERGENCY PERSONNEL:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
ADVICE FOR EMERGENCY RESPONDERS: PROTECTIVE EQUIPMENT: SEE SECTION 8
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR ANY WATER COURSE.
PREVENT SEEPAGE INTO SEWAGE SYSTEM, WORKPITS AND CELLARS.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ENSURE ADEQUATE VENTILATION.
ABSORB WITH LIQUID-BINDING MATERIAL (SAND, DIATOMITE, UNIVERSAL BINDERS).
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE.
HYGIENE MEASURES:
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE SKIN.
AVOID CONTACT WITH THE EYES.
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM METALS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
PROTECT FROM EXPOSURE TO THE LIGHT.
PROTECT FROM HUMIDITY AND WATER.
RECOMMENDED STORAGE TEMPERATURE:
20 DEG. C +/- 5 DEG. C (APPROX. 68 DEG. F)
SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
|
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
THE PRODUCT DOES NOT CONTAIN ANY RELEVANT QUANTITIES OF MATERIALS WITH
CRITICAL VALUES THAT HAVE TO BE MONITORED AT THE WORKPLACE.
ENGINEERING MEASURES:
TECHNICAL MEASURES AND APPROPRIATE WORKING OPERATIONS SHOULD BE GIVEN
PRIORITY OVER THE USE OF PERSONAL PROTECTIVE EQUIPMENT.
SEE ITEM 7.
PERSONAL PROTECTIVE EQUIPMENT:
BREATHING EQUIPMENT:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
RECOMMENDED FILTER DEVICE FOR SHORT TERM USE: FILTER P2
PROTECTION OF HANDS:
PROTECTIVE GLOVES
PREVENTIVE SKIN PROTECTION BY USE OF SKIN-PROTECTING AGENTS IS
RECOMMENDED.
AFTER USE OF GLOVES APPLY SKIN-CLEANING AGENTS AND SKIN COSMETICS.
MATERIAL OF GLOVES:
NITRILE RUBBER, NBR
RECOMMENDED THICKNESS OF THE MATERIAL: >/=0.11 MM
PENETRATION TIME OF GLOVE MATERIAL:
VALUE FOR THE PERMEATION: LEVEL </=1 (10 MIN)
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR ANY WATER COURSE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM / PHYSICAL STATE: FLUID
COLOR: COLORLESS
ODOR: ODORLESS
ODOR THRESHOLD: NOT APPLICABLE.
PH-VALUE AT 20 DEG. C (68 DEG. F): <1
MELTING POINT/FREEZING POINT: NOT DETERMINED.
INITIAL BOILING POINT AND BOILING RANGE: NOT DETERMINED.
FLASH POINT: NOT APPLICABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
DECOMPOSITION TEMPERATURE: >170 DEG. C (>338 DEG. F) (CAS 6192-52-5)
AUTO-IGNITION TEMPERATURE: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER: NOT APPLICABLE.
UPPER: NOT APPLICABLE.
OXIDIZING PROPERTIES: NONE
VAPOR PRESSURE: NOT DETERMINED.
DENSITY AT 20 DEG. C (68 DEG. F): 1.02 G/CM3 (8.51 LBS/GAL)
RELATIVE DENSITY: NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT DETERMINED.
SOLUBILITY(IES):
WATER: FULLY MISCIBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY: NOT DETERMINED.
SOLVENT CONTENT:
ORGANIC SOLVENTS: 0.0 %
WATER: >90 %
SOLIDS CONTENT: <10 %
OTHER INFORMATION:
CORROSION RATE OF METAL:
ACC. TO "RECOMMENDATIONS ON THE TRANSPORT OF DANGEROUS GOODS, MANUAL OF
TESTS AND CRITERIA, FIFTH REVISED EDITION"
STEEL: 29.32 MM/A
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: SEE SECTION "POSSIBILITY OF HAZARDOUS REACTIONS"
CHEMICAL STABILITY: STABLE AT AMBIENT TEMPERATURE (ROOM TEMPERATURE).
POSSIBILITY OF HAZARDOUS REACTIONS:
CORROSIVE ACTION ON METALS.
REACTS WITH STRONG OXIDIZING AGENTS.
REACTS WITH ACIDS AND ALKALI (LYES).
CONDITIONS TO AVOID: STRONG HEATING
INCOMPATIBLE MATERIALS: METALS
HAZARDOUS DECOMPOSITION PRODUCTS: SEE SECTION 5
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
CAS: 6192-52-5 P-TOLUENESULPHONIC ACID
ORAL:
LD50: 2570 MG/KG (RAT) (RTECS)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: CAUSES SEVERE SKIN BURNS.
ON THE EYE:
CAUSES SERIOUS EYE DAMAGE.
RISK OF BLINDNESS!
SENSITIZATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
INFORMATION ON COMPONENTS:
CAS: 6192-52-5 P-TOLUENESULPHONIC ACID
SENSITIZATION:
OECD 406:
(GUINEA PIG: NEGATIVE)
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
NONE OF THE INGREDIENTS IS LISTED.
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS IS LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS IS LISTED.
OTHER INFORMATION: SEE SECTION 8 / 15
SYNERGISTIC PRODUCTS: NONE
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
THE FOLLOWING STATEMENTS REFER TO THE MIXTURE:
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
REPRODUCTIVE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT (SPECIFIC TARGET ORGAN TOXICITY) -SINGLE EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT (SPECIFIC TARGET ORGAN TOXICITY) -REPEATED EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
INFORMATION ON COMPONENTS:
OECD 414: TERATOGENICITY TESTING
OECD 473: MUTAGENICITY TESTING
OECD 471, 474, 476, 487: GERM CELL MUTAGENICITY TESTING
CAS: 6192-52-5 P-TOLUENESULPHONIC ACID
OECD 471: (NEGATIVE)
ADDITIONAL TOXICOLOGICAL INFORMATION:
SWALLOWING WILL LEAD TO A STRONG CAUSTIC EFFECT ON MOUTH AND THROAT AND
TO THE DANGER OF PERFORATION OF ESOPHAGUS AND STOMACH.
OTHER DANGEROUS PROPERTIES CAN NOT BE EXCLUDED.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY:
CAS: 6192-52-5 P-TOLUENESULPHONIC ACID
EC50:
>500 MG/L/96H (DAPHNIA MAGNA)
(ANHYDROUS SUBSTANCE; IUCLID)
IC50:
245 MG/L/96 H (CHLORELLA VULGARIS)
(ANHYDROUS SUBSTANCE; IUCLID)
LC50:
>500 MG/L/96H (BLUEGILL)
(ANHYDROUS SUBSTANCE; IUCLID)
PERSISTENCE AND DEGRADABILITY:
CAS: 6192-52-5 P-TOLUENESULPHONIC ACID
OECD 302 B:
79 % / 25 D (READILY ELIMINATED FROM WATER) (ZAHN-WELLENS / EMPA TEST)
(ANHYDROUS SUBSTANCE)
BIOACCUMULATIVE POTENTIAL:
POW: N-OCTANOL/WASSER PARTITION COEFFICIENT
LOG POW <1: DOES NOT ACCUMULATE IN ORGANISMS.
CAS: 6192-52-5 P-TOLUENESULPHONIC ACID
LOG POW: -0.62 (.) (CALCULATED)
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS:
HARMFUL EFFECT DUE TO PH SHIFT.
AVOID TRANSFER INTO THE ENVIRONMENT.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM.
HAND OVER TO HAZARDOUS WASTE DISPOSERS.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
RECOMMENDED CLEANSING AGENT: WATER, IF NECESSARY WITH CLEANSING AGENTS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER:
DOT, IMDG, IATA: UN2586
UN PROPER SHIPPING NAME:
DOT: ARYL SULFONIC ACIDS, LIQUID
IMDG, IATA: ARYLSULPHONIC ACIDS, LIQUID
TRANSPORT HAZARD CLASS(ES):
DOT: CORROSIVE, CLASS/DIVISION 8
CLASS: 8 CORROSIVE SUBSTANCES
LABEL: 8
IMDG, IATA: CLASS 8, CORROSIVES
CLASS: 8 CORROSIVE SUBSTANCES
LABEL: 8
PACKING GROUP:
DOT, IMDG, IATA: III
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
WARNING: CORROSIVE SUBSTANCES
DANGER CODE (KEMLER): 80
EMS NUMBER: F-A,S-B
SEGREGATION GROUPS: ACIDS
STOWAGE CATEGORY: B
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
DOT:
QUANTITY LIMITATIONS:
ON PASSENGER AIRCRAFT/RAIL: 5 L
ON CARGO AIRCRAFT ONLY: 60 L
LIMITED QUANTITY (LQ): 5L
EXCEPTED QUANTITIES (EQ):
CODE: E1
MAXIMUM NET QUANTITY PER INNER PACKAGING: 30 ML
MAXIMUM NET QUANTITY PER OUTER PACKAGING: 1000 ML
IMDG:
LIMITED QUANTITIES (LQ): 5L
EXCEPTED QUANTITIES (EQ):
CODE: E1
MAXIMUM NET QUANTITY PER INNER PACKAGING: 30 ML
MAXIMUM NET QUANTITY PER OUTER PACKAGING: 1000 ML
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
NONE OF THE INGREDIENTS IS LISTED.
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65:
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
NEW JERSEY RIGHT-TO-KNOW LIST: NONE OF THE INGREDIENTS IS LISTED.
NEW JERSEY SPECIAL HAZARDOUS SUBSTANCE LIST:
NONE OF THE INGREDIENTS IS LISTED.
PENNSYLVANIA RIGHT-TO-KNOW LIST: NONE OF THE INGREDIENTS IS LISTED.
PENNSYLVANIA SPECIAL HAZARDOUS SUBSTANCE LIST:
NONE OF THE INGREDIENTS IS LISTED.
EPA (ENVIRONMENTAL PROTECTION AGENCY): NONE OF THE INGREDIENTS IS LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS IS LISTED.
INFORMATION ABOUT LIMITATION OF USE:
EMPLOYMENT RESTRICTIONS CONCERNING YOUNG PERSONS MUST BE OBSERVED.
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H318: CAUSES SERIOUS EYE DAMAGE.
H335: MAY CAUSE RESPIRATORY IRRITATION.
DATE OF PREPARATION / LAST REVISION: 01/04/2018 / 7
ABBREVIATIONS AND ACRONYMS:
ICAO: INTERNATIONAL CIVIL AVIATION ORGANISATION
EC50: EFFECTIVE CONCENTRATION, 50 PERCENT (IN VIVO)
OECD: ORGANISATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
STOT: SPECIFIC TARGET ORGAN TOXICITY
SE: SINGLE EXPOSURE
RE: REPEATED EXPOSURE
EC50: HALF MAXIMAL EFFECTIVE CONCENTRATION
IC50: HALLF MAXIMAL INHIBITORY CONCENTRATION
NOEL OR NOEC: NO OBSERVED EFFECT LEVEL OR CONCENTRATION
ACGIH(R*): AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
A1: CONFIRMED HUMAN CARCINOGEN
A2: SUSPECTED HUMAN CARCINOGEN
A3: CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS
A4: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
A5: NOT SUSPECTED AS A HUMAN CARCINOGEN
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
GROUP 1: CARCINOGENIC TO HUMANS
GROUP 2A: PROBABLY CARCINOGENIC TO HUMANS
GROUP 2B: POSSIBLY CARCINOGENIC TO HUMANS
GROUP 3: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS
GROUP 4: PROBABLY NOT CARCINOGENIC TO HUMANS
NTP:
NATIONAL TOXICOLOGY PROGRAM, U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES
GROUP K: KNOWN TO BE HUMAN CARCINOGENS
GROUP R: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGENS
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
RID:
REGLEMENT INTERNATIONAL CONCERNANT LE TRANSPORT DES MARCHANDISES
DANGEREUSES PAR CHEMIN DE FER (REGULATIONS CONCERNING THE INTERNATIONAL
TRANSPORT OF DANGEROUS GOODS BY RAIL)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
TLV: THRESHOLD LIMIT VALUE
PEL: PERMISSIBLE EXPOSURE LIMIT
REL: RECOMMENDED EXPOSURE LIMIT
MET. CORR.1: CORROSIVE TO METALS - CATEGORY 1
SKIN CORR. 1C: SKIN CORROSION/IRRITATION - CATEGORY 1C
EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 3
SOURCES:
DATA ARISE FROM SAFETY DATA SHEETS, REFERENCE WORKS AND LITERATURE.
RTECS (REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES)
IUCLID (INTERNATIONAL UNIFORM CHEMICAL INFORMATION DATABASE)
| DATA COMPARED TO THE PREVIOUS VERSION ALTERED.
US
LOVIBOND(R*)
LOVIBOND(R*) WATER TESTING
TINTOMETER(R*) GROUP
SAFETY DATA SHEET
ACC. TO OSHA HCS (HAZCOM 2012)
PRINTING DATE: 01/05/2018
REVIEWED ON: 01/05/2018
| 1 IDENTIFICATION | |
PRODUCT IDENTIFIER:
TRADE NAME: FREE CHLORINE BUFFER SOLUTION, 473 ML
SDS VALID FROM LOT: P03A
CATALOGUE NUMBER: 530223, 4530223, 424489
APPLICATION OF THE SUBSTANCE / THE MIXTURE: REAGENT FOR WATER ANALYSIS
MANUFACTURER/SUPPLIER:
TINTOMETER INC.
6456 PARKLAND DRIVE
SARASOTA, FL 34243
USA
PHONE: (941) 756-6410
FAX: (941) 727-9654
WWW.LOVIBOND.US
MADE IN GERMANY
EMERGENCY TELEPHONE NUMBER: + 1 866 928 0789 (ENGLISH, FRENCH, SPANISH)
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS07: EXCLAMATION MARK
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
EYE IRRIT. 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
STOT SE 3:
H335: MAY CAUSE RESPIRATORY IRRITATION.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE HAZARD
COMMUNICATION STANDARD (HCS).
HAZARD PICTOGRAMS:
GHS07: EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD-DETERMINING COMPONENTS OF LABELING:
LITHIUM MALEATE
LITHIUM BIMALEATE
HAZARD STATEMENTS:
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
PRECAUTIONARY STATEMENTS:
P261: AVOID BREATHING MIST/VAPOURS/SPRAY.
P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
OTHER HAZARDS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
DESCRIPTION: AQUEOUS SOLUTION
COMPOSITION AND INFORMATION ON INGREDIENTS:
PERCENT RANGES ARE USED DUE TO THE CONFIDENTIAL PRODUCT INFORMATION.
CAS: 50977-65-6 LITHIUM MALEATE SKIN IRRIT. 2, H315; 10-20%
EYE IRRIT. 2A, H319;
STOT SE 3, H335
CAS: 85796-96-9 LITHIUM BIMALEATE SKIN IRRIT. 2, H315; 5-10%
EYE IRRIT. 2A, H319;
STOT SE 3, H335
CAS: 57-55-6 METHYL GLYCOL 2.5-5%
EINECS: 200-338-0
RTECS: TY 2000000
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD PHRASES REFER TO SECTION 16.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
AFTER SKIN CONTACT:
IMMEDIATELY RINSE WITH PLENTY OF WATER.
IF SKIN IRRITATION CONTINUES, CONSULT A DOCTOR.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES (AT LEAST 15 MIN) UNDER RUNNING
WATER. THEN CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK 1-2 GLASSES OF WATER.
SEEK MEDICAL TREATMENT.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
IRRITATIONS
AFTER SWALLOWING:
VOMITING
DROWSINESS
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
USE FIRE FIGHTING MEASURES THAT SUIT THE ENVIRONMENT.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
THE PRODUCT IS NOT COMBUSTIBLE.
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
CARBON MONOXIDE (CO) AND CARBON DIOXIDE (CO2)
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
COLLECT CONTAMINATED FIRE FIGHTING WATER SEPARATELY. IT MUST NOT ENTER
THE SEWAGE SYSTEM.
DISPOSE OF FIRE DEBRIS AND CONTAMINATED FIRE FIGHTING WATER IN ACCORDANCE
WITH OFFICIAL REGULATIONS.
AMBIENT FIRE MAY LIBERATE HAZARDOUS VAPOURS.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ADVICE FOR NON-EMERGENCY PERSONNEL:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
ADVICE FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT: SEE SECTION 8
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR ANY WATER COURSE.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ENSURE ADEQUATE VENTILATION.
ABSORB WITH LIQUID-BINDING MATERIAL (SAND, DIATOMITE, UNIVERSAL BINDERS).
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE.
PREVENT FORMATION OF AEROSOLS.
HYGIENE MEASURES:
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE SKIN.
AVOID CONTACT WITH THE EYES.
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY: NOT REQUIRED.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
KEEP RECEPTACLE TIGHTLY SEALED.
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
PROTECT FROM EXPOSURE TO THE LIGHT.
PROTECT FROM HUMIDITY AND WATER.
RECOMMENDED STORAGE TEMPERATURE:
20 DEG. C +/- 5 DEG. C (APPROX. 68 DEG. F)
SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
AT THIS TIME, THE OTHER CONSTITUENTS HAVE NO KNOWN EXPOSURE LIMITS.
CAS: 57-55-6 METHYL GLYCOL
WEEL (USA):
LONG-TERM VALUE: 10 MG/M3
EV (CANADA):
LONG-TERM VALUE: 155* 10** MG/M3, 50* PPM
*VAPOUR AND AEROSOL
**AEROSOL ONLY
ADDITIONAL INFORMATION:
THE LISTS THAT WERE VALID DURING THE CREATION WERE USED AS BASIS.
ENGINEERING MEASURES:
TECHNICAL MEASURES AND APPROPRIATE WORKING OPERATIONS SHOULD BE GIVEN
PRIORITY OVER THE USE OF PERSONAL PROTECTIVE EQUIPMENT. SEE ITEM 7.
PERSONAL PROTECTIVE EQUIPMENT:
BREATHING EQUIPMENT:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
RECOMMENDED FILTER DEVICE FOR SHORT TERM USE: COMBINATION FILTER A-P2
PROTECTION OF HANDS:
PROTECTIVE GLOVES
PREVENTIVE SKIN PROTECTION BY USE OF SKIN-PROTECTING AGENTS IS RECOMMENDED.
AFTER USE OF GLOVES APPLY SKIN-CLEANING AGENTS AND SKIN COSMETICS.
MATERIAL OF GLOVES:
NITRILE RUBBER, NBR
RECOMMENDED THICKNESS OF THE MATERIAL: >/=0.11 MM
PENETRATION TIME OF GLOVE MATERIAL:
VALUE FOR THE PERMEATION: LEVEL </=1 (10 MIN)
THE EXACT BREAK THROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR ANY WATER COURSE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM / PHYSICAL STATE: FLUID
COLOR: LIGHT YELLOW
ODOR: MILD
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE AT 20 DEG. C (68 DEG. F): 6.1
MELTING POINT/FREEZING POINT: NOT DETERMINED.
INITIAL BOILING POINT AND BOILING RANGE: NOT DETERMINED.
FLASH POINT: NOT APPLICABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
AUTO-IGNITION TEMPERATURE: PRODUCT IS NOT SELF-IGNITING.
DANGER OF EXPLOSION: PRODUCT DOES NOT PRESENT AN EXPLOSION HAZARD.
FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER: NOT APPLICABLE.
UPPER: NOT APPLICABLE.
OXIDIZING PROPERTIES: NONE
VAPOR PRESSURE: NOT DETERMINED.
DENSITY AT 20 DEG. C (68 DEG. F): 1.13 G/CM3 (9.43 LBS/GAL)
RELATIVE DENSITY: NOT DETERMINED.
VAPOR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT DETERMINED.
SOLUBILITY(IES):
WATER: FULLY MISCIBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY: NOT DETERMINED.
SOLVENT CONTENT:
ORGANIC SOLVENTS: <5 %
WATER: >70 %
SOLIDS CONTENT: <25 %
OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: SEE SECTION "POSSIBILITY OF HAZARDOUS REACTIONS"
CHEMICAL STABILITY: STABLE AT AMBIENT TEMPERATURE (ROOM TEMPERATURE).
POSSIBILITY OF HAZARDOUS REACTIONS:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
CONDITIONS TO AVOID: STRONG HEATING (DECOMPOSITION)
INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS: SEE SECTION 5
| 11 TOXICOLOGICAL INFORMATION | |
|
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
CAS: 57-55-6 METHYL GLYCOL
ORAL LD50: 19400-36000 MG/KG (RAT)
DERMAL LD50: 20800 MG/KG (RABBIT)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: CAUSES SKIN IRRITATION.
ON THE EYE: CAUSES SERIOUS EYE IRRITATION.
SENSITIZATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
NONE OF THE INGREDIENTS IS LISTED.
NTP (NATIONAL TOXICOLOGY PROGRAM):
NONE OF THE INGREDIENTS IS LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS IS LISTED.
OTHER INFORMATION: SEE SECTION 8 / 15
SYNERGISTIC PRODUCTS: NONE
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
THE FOLLOWING STATEMENTS REFER TO THE MIXTURE:
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
REPRODUCTIVE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT (SPECIFIC TARGET ORGAN TOXICITY) -SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION.
STOT (SPECIFIC TARGET ORGAN TOXICITY) -REPEATED EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE FOLLOWING APPLIES TO LITHIUM COMPOUNDS IN GENERAL:
AFTER ABSORPTION:
CNS DISORDERS, ATAXIA (IMPAIRED LOCOMOTOR COORDINATION) DUE TO DISTURBED
ELECTROLYTE BALANCE
OTHER DANGEROUS PROPERTIES CAN NOT BE EXCLUDED.
| 12 ECOLOGICAL INFORMATION | |
|
TOXICITY:
AQUATIC TOXICITY:
CAS: 57-55-6 METHYL GLYCOL
EC50: 34400 MG/L/48H (DAPHNIA MAGNA)
NOEC: 52930 MG/L/96H (PPM)
NOEC: 13020 MG/L/48 H (DAPHNIA MAGNA)
IC50: 19000 MG/L/96 H (PSEUDOKIRCHNERIELLA SUBCAPITATA) (OECD 201)
LC50: 51600 MG/L/96H (RAINBOW TROUT) (OECD 203)
BACTERIAL TOXICITY:
CAS: 57-55-6 METHYL GLYCOL
EC50: 26800 MG/L (PHOTOBACTERIUM PHOSPHOREUM) (30 MIN)
OTHER INFORMATION:
THE FOLLOWING APPLIES FOR LITHIUM COMPOUNDS IN GENERAL:
FISH TOXIC FROM 100 MG/L, DAPHNIA TOXIC FROM 16 MG/L, PLANTS TOXIC FROM
0,2 MG/L
PERSISTENCE AND DEGRADABILITY:
CAS: 57-55-6 METHYL GLYCOL
OECD 301 C: 87-92 % / 28 D (READILY BIODEGRADABLE)
OECD 301 D: 86 % / 20 D (READILY BIODEGRADABLE)
BIOACCUMULATIVE POTENTIAL:
CAS: 57-55-6 METHYL GLYCOL
LOG POW: -0.92 (.) (EXPERIMENTAL)
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: AVOID TRANSFER INTO THE ENVIRONMENT.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM.
HAND OVER TO HAZARDOUS WASTE DISPOSERS.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
|
UN-NUMBER:
DOT, IMDG, IATA: NONE
UN PROPER SHIPPING NAME:
DOT, IMDG, IATA: NONE
TRANSPORT HAZARD CLASS(ES):
DOT, IMDG, IATA:
CLASS: NONE
PACKING GROUP:
DOT, IMDG, IATA: NONE
ENVIRONMENTAL HAZARDS: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
NOT DANGEROUS ACCORDING TO THE ABOVE SPECIFICATIONS.
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS IS LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
NONE OF THE INGREDIENTS IS LISTED.
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED.
PROPOSITION 65:
CHEMICALS KNOWN TO CAUSE CANCER: NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS IS LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS IS LISTED.
NEW JERSEY RIGHT-TO-KNOW LIST:
CAS: 57-55-6 METHYL GLYCOL
NEW JERSEY SPECIAL HAZARDOUS SUBSTANCE LIST:
NONE OF THE INGREDIENTS IS LISTED.
PENNSYLVANIA RIGHT-TO-KNOW LIST:
CAS: 57-55-6 METHYL GLYCOL
PENNSYLVANIA SPECIAL HAZARDOUS SUBSTANCE LIST:
NONE OF THE INGREDIENTS IS LISTED.
EPA (ENVIRONMENTAL PROTECTION AGENCY):
NONE OF THE INGREDIENTS IS LISTED.
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
NONE OF THE INGREDIENTS IS LISTED.
US-VOC CONTENT: 326.3 G/L / 2.72 LB/GL
INFORMATION ABOUT LIMITATION OF USE:
EMPLOYMENT RESTRICTIONS CONCERNING YOUNG PERSONS MUST BE OBSERVED.
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H315: CAUSES SKIN IRRITATION.
H319: CAUSES SERIOUS EYE IRRITATION.
H335: MAY CAUSE RESPIRATORY IRRITATION.
DATE OF PREPARATION / LAST REVISION: 01/05/2018 / 4
ABBREVIATIONS AND ACRONYMS:
STOT: SPECIFIC TARGET ORGAN TOXICITY
SE: SINGLE EXPOSURE
RE: REPEATED EXPOSURE
EC50: HALF MAXIMAL EFFECTIVE CONCENTRATION
IC50: HALLF MAXIMAL INHIBITORY CONCENTRATION
NOEL OR NOEC: NO OBSERVED EFFECT LEVEL OR CONCENTRATION
ACGIH(R*): AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
A1: CONFIRMED HUMAN CARCINOGEN
A2: SUSPECTED HUMAN CARCINOGEN
A3: CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS
A4: NOT CLASSIFIABLE AS A HUMAN CARCINOGEN
A5: NOT SUSPECTED AS A HUMAN CARCINOGEN
IARC: INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
GROUP 1: CARCINOGENIC TO HUMANS
GROUP 2A: PROBABLY CARCINOGENIC TO HUMANS
GROUP 2B: POSSIBLY CARCINOGENIC TO HUMANS
GROUP 3: NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS
GROUP 4: PROBABLY NOT CARCINOGENIC TO HUMANS
NTP:
NATIONAL TOXICOLOGY PROGRAM, U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES
GROUP K: KNOWN TO BE HUMAN CARCINOGENS
GROUP R: REASONABLY ANTICIPATED TO BE HUMAN CARCINOGENS
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
RID:
REGLEMENT INTERNATIONAL CONCERNANT LE TRANSPORT DES MARCHANDISES
DANGEREUSES PAR CHEMIN DE FER (REGULATIONS CONCERNING THE INTERNATIONAL
TRANSPORT OF DANGEROUS GOODS BY RAIL)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY
OSHA: OCCUPATIONAL SAFETY & HEALTH
TLV: THRESHOLD LIMIT VALUE
PEL: PERMISSIBLE EXPOSURE LIMIT
REL: RECOMMENDED EXPOSURE LIMIT
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 3
SOURCES DATA ARISE FROM SAFETY DATA SHEETS, REFERENCE WORKS AND LITERATURE.
| DATA COMPARED TO THE PREVIOUS VERSION ALTERED.
US