SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. LOVIBOND(R*) LOVIBOND(R*) WATER TESTING TINTOMETER(R*) GROUP SAFETY DATA SHEET ACCORDING TO 1907/2006/EC, ARTICLE 31 PRINTING DATE: 03.09.2014 VERSION NUMBER: 35 REVISION: 03.09.2014
AND OF THE COMPANY/UNDERTAKING | 1.1 PRODUCT IDENTIFIER: PRODUCT NAME: VARIO TPTZ IRON F10 ML CATALOG NUMBER: 00530559, 530550, 4530550 1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED AGAINST: NO FURTHER RELEVANT INFORMATION AVAILABLE. APPLICATION OF THE SUBSTANCE / THE PREPARATION: REAGENT FOR WATER ANALYSIS 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET: SUPPLIER: TINTOMETER GMBH SCHLEEFSTR. 8-12 DE-44287 DORTMUND MADE IN GERMANY WWW.LOVIBOND.COM PHONE: +49 (0) 231 945100 E-MAIL: SALES@TINTOMETER.DE INFORMING DEPARTMENT: E-MAIL: PRODUKTSICHERHEIT@TINTOMETER.DE PRODUCT SAFETY DEPARTMENT CONTACT FOR TECHNICAL DETAILS: TECHNICAL DEPARTMENT: E-MAIL: TECHNIK@TINTOMETER.DE 1.4 EMERGENCY TELEPHONE NUMBER: POISON CENTER BERLIN, GERMANY: PHONE: 0049-30 30686 790
| 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008: GHS05: CORROSION EYE DAM. 1: H318: CAUSES SERIOUS EYE DAMAGE. CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC OR DIRECTIVE 1999/45/EC: XN; HARMFUL R22: HARMFUL IF SWALLOWED. XI; IRRITANT R41: RISK OF SERIOUS DAMAGE TO EYES. R31: CONTACT WITH ACIDS LIBERATES TOXIC GAS. 2.2 LABEL ELEMENTS: LABELLING ACCORDING TO REGULATION (EC) NO 1272/2008: THE PRODUCT IS CLASSIFIED AND LABELLED ACCORDING TO THE CLP REGULATION. HAZARD PICTOGRAMS: GHS05 SIGNAL WORD: DANGER HAZARD-DETERMINING COMPONENTS OF LABELLING: DISODIUM DISULPHITE HAZARD STATEMENTS: H318: CAUSES SERIOUS EYE DAMAGE. PRECAUTIONARY STATEMENTS: P280: WEAR PROTECTIVE GLOVES / EYE PROTECTION. P305+P351+P338: IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. P310: IMMEDIATELY CALL A POISON CENTER/DOCTOR. ADDITIONAL INFORMATION: EUH031: CONTACT WITH ACIDS LIBERATES TOXIC GAS. CONTAINS METHENAMINE. MAY PRODUCE AN ALLERGIC REACTION.
3.2 MIXTURES: DESCRIPTION: MIXTURE OF ORGANIC AND INORGANIC COMPOUNDS DANGEROUS COMPONENTS: CAS: 7681-57-4 DISODIUM DISULPHITE 10-20% EINECS: 231-673-0 XN R22; XI R41 INDEX NUMBER: 016-063-00-2 R31 REG.NR.: 01-2119531326-45-XXXX EYE DAM. 1, H318; ACUTE TOX. 4, H302 CAS: 7775-14-6 SODIUM DITHIONITE 10-20% EINECS: 231-890-0 XN R22 INDEX NUMBER: 016-028-00-1 R7-31 REG.NR.: 01-21-19520510-57-XXXX SELF-HEAT. 1, H251; ACUTE TOX. 4, H302 CAS: 100-97-0 METHENAMINE 0.1-1.0% EINECS: 202-905-8 XI R43; F R11 INDEX NUMBER: 612-101-00-2 FLAM. SOL. 2, H228; REG.NR.: 01-2119474895-20-XXXX SKIN SENS. 1, H317 REACH - PRE-REGISTERED SUBSTANCES: ALL COMPONENTS ARE REACH PRE-REGISTERED. ADDITIONAL INFORMATION: FOR THE WORDING OF THE LISTED RISK PHRASES REFER TO SECTION 16.
4.1 DESCRIPTION OF FIRST AID MEASURES GENERAL INFORMATION: INSTANTLY REMOVE ANY CLOTHING SOILED BY THE PRODUCT. AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF SYMPTOMS. AFTER SKIN CONTACT: INSTANTLY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY. AFTER EYE CONTACT: RINSE OPENED EYE FOR SEVERAL MINUTES (AT LEAST 10 MIN) UNDER RUNNING WATER. CALL A DOCTOR IMMEDIATELY. AFTER SWALLOWING: RINSE OUT MOUTH AND THEN DRINK 1-2 GLASSES OF WATER. SEEK IMMEDIATE MEDICAL ADVICE. 4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: AFTER INHALATION: BREATHING DIFFICULTY COUGHING MUCOUS MEMBRANE IRRITATION AFTER SWALLOWING: ALLERGIC REACTIONS HEADACHE SICKNESS VOMITING GASTRIC OR INTESTINAL TROUBLE DIARRHOEA INFORMATION FOR DOCTOR: SULPHITES ARE STRONG SENSITIZERS. 4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 5.1 EXTINGUISHING MEDIA: SUITABLE EXTINGUISHING AGENTS: FIRE-EXTINGUISHING POWDER DRY SAND CARBON DIOXIDE (CO2) FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: WATER. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE. MIXTURE WITH COMBUSTIBLE INGREDIENTS SULPHUR OXIDES (SOX) 5.3 ADVICE FOR FIREFIGHTERS: PROTECTIVE EQUIPMENT: WEAR SELF-CONTAINED BREATHING APPARATUS. WEAR FULL PROTECTIVE SUIT. ADDITIONAL INFORMATION: COLLECT CONTAMINATED FIRE FIGHTING WATER SEPARATELY. IT MUST NOT ENTER DRAINS. DISPOSE OF FIRE DEBRIS AND CONTAMINATED FIRE FIGHTING WATER IN ACCORDANCE WITH OFFICIAL REGULATIONS. AMBIENT FIRE MAY LIBERATE HAZARDOUS VAPOURS.
| 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: PUT ON BREATHING APPARATUS. WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY. AVOID CAUSING DUST. 6.2 ENVIRONMENTAL PRECAUTIONS: DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR WATER BODIES. 6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: ENSURE ADEQUATE VENTILATION. COLLECT MECHANICALLY. DISPOSE OF CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13. 6.4 REFERENCE TO OTHER SECTIONS: SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT. SEE SECTION 13 FOR INFORMATION ON DISPOSAL.
7.1 PRECAUTIONS FOR SAFE HANDLING: THOROUGH DEDUSTING. INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES: PROTECT FROM HEAT. SUBSTANCE/PRODUCT IS AUTO-EXTINGUISHING, BUT CAN BURN WHEN COMBINED WITH FLAMMABLE MATERIAL. 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES: STORAGE: REQUIREMENTS TO BE MET BY STOREROOMS AND CONTAINERS: STORE IN COOL LOCATION. INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY: DO NOT STORE TOGETHER WITH ACIDS. STORE AWAY FROM OXIDISING AGENTS. FURTHER INFORMATION ABOUT STORAGE CONDITIONS: PROTECT FROM HEAT AND DIRECT SUNLIGHT. STORE UNDER DRY CONDITIONS. PROTECT FROM HUMIDITY AND KEEP AWAY FROM WATER. PROTECT FROM THE EFFECTS OF LIGHT. RECOMMENDED STORAGE TEMPERATURE: 20 DEG. C +/- 5 DEG. C STORAGE CLASS: 13 7.3 SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL SYSTEMS: NO FURTHER DATA; SEE ITEM 7. 8.1 CONTROL PARAMETERS: COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE: 7681-57-4 DISODIUM DISULPHITE (10-20%): WEL (GREAT BRITAIN): LONG-TERM VALUE: 5 MG/M3 100-97-0 METHENAMINE (0.1-1.0%): OEL (SWEDEN): SHORT-TERM VALUE: 5 MG/M3 LONG-TERM VALUE: 3 MG/M3 S DNELS: 7681-57-4 DISODIUM DISULPHITE: INHALATIVE: WORKER DNEL / LONGTERM / SYSTEMIC EFFECTS: 10 MG/M3 (HUMAN) ADDITIONAL INFORMATION: THE LISTS THAT WERE VALID DURING THE COMPILATION WERE USED AS BASIS. 8.2 EXPOSURE CONTROLS: PERSONAL PROTECTIVE EQUIPMENT: GENERAL PROTECTIVE AND HYGIENIC MEASURES: AVOID CONTACT WITH THE EYES AND SKIN. TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING WASH HANDS DURING BREAKS AND AT THE END OF THE WORK. DO NOT EAT, DRINK OR SMOKE WHILE WORKING. KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FOOD. BREATHING EQUIPMENT: USE BREATHING PROTECTION AGAINST THE EFFECTS OF FUMES/DUST/AEROSOL. RECOMMENDED FILTER DEVICE FOR SHORT TERM USE: FILTER P2 PROTECTION OF HANDS: PROTECTIVE GLOVES. AFTER USE OF GLOVES APPLY SKIN-CLEANING AGENTS AND SKIN COSMETICS. MATERIAL OF GLOVES: NITRILE RUBBER, NBR RECOMMENDED THICKNESS OF THE MATERIAL: >/=0.11 MM PENETRATION TIME OF GLOVE MATERIAL: VALUE FOR THE PERMEATION: LEVEL: 1 (<10 MIN) THE EXACT BREAK TROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED. EYE PROTECTION: TIGHTLY SEALED SAFETY GLASSES. USE AGAINST THE EFFECTS OF FUMES / DUST BODY PROTECTION: PROTECTIVE WORK CLOTHING.
| 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES: APPEARANCE: FORM: POWDER COLOUR: WHITE ODOUR: ODOURLESS PH-VALUE (10.4 G/L) AT 20 DEG. C: 3.4 MELTING POINT/MELTING RANGE: NOT DETERMINED BOILING POINT/BOILING RANGE: NOT DETERMINED FLASH POINT: NOT APPLICABLE DANGER OF EXPLOSION: PRODUCT IS NOT EXPLOSIVE. DENSITY: NOT DETERMINED VAPOUR DENSITY: NOT APPLICABLE. EVAPORATION RATE: NOT APPLICABLE. SOLUBILITY IN / MISCIBILITY WITH WATER: SOLUBLE SOLVENT CONTENT: ORGANIC SOLVENTS: 0.0% SOLIDS CONTENT: 100.0% 9.2 OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| REACTIVITY: THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED: STRONG HEATING POSSIBILITY OF HAZARDOUS REACTIONS: CONTACT WITH ACIDS RELEASES TOXIC GASES CONDITIONS TO AVOID: NO FURTHER RELEVANT INFORMATION AVAILABLE. INCOMPATIBLE MATERIALS: ACIDS SODIUM NITRITE SODIUM CHLORITE WATER OXIDIZING AGENTS HAZARDOUS DECOMPOSITION PRODUCTS: SULPHUR OXIDES (SOX) SODIUM MONOXIDE SEE CHAPTER 5
| 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS: ACUTE TOXICITY: QUANTITATIVE DATA ON THE TOXICITY OF THE PREPARATION ARE NOT AVAILABLE. THE FOLLOWING STATEMENTS REFER TO THE INDIVIDUAL COMPONENTS. LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION: 7681-57-4 DISODIUM DISULPHITE: ORAL: LD50: 1540 MG/KG (RAT) (MERCK) DERMAL: LD50: >2000 MG/KG (RAT) (RTECS) 7775-14-6 SODIUM DITHIONITE: ORAL: LD50: 500 MG/KG (ATE) (FOR CALCULATION) 2500 MG/KG (RAT) IUCLID PRIMARY IRRITANT EFFECT: ON THE SKIN: SLIGHT IRRITATIONS POSSIBLE ON THE EYE: STRONG IRRITANT WITH THE DANGER OF SEVERE EYE INJURY. SENSITISATION: SENSITIZING EFFECT BY INHALATION AND SKIN CONTACT IS POSSIBLE BY PROLONGED EXPOSURE. CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION): NO DATA AVAILABLE
| 12.1 TOXICITY: AQUATIC TOXICITY: 7681-57-4 DISODIUM DISULPHITE: EC50: 89 MG/L/48H (DAPHNIA MAGNA) (MERCK) LC50: 150-220 MG/L/96H (ONCORHYNCHUS MYKISS) (MERCK) 7775-14-6 SODIUM DITHIONITE: EC50: 98 MG/L/48H (DAPHNIA MAGNA) MERCK LC50: 46-68 MG/L/96H (LEUCISCUS IDUS) UICLID 12.2 PERSISTENCE AND DEGRADABILITY: NO FURTHER RELEVANT INFORMATION AVAILABLE. OTHER INFORMATION: QUANTITATIVE DATA ON THE ECOLOGICAL EFFECT OF THIS PRODUCT ARE NOT AVAILABLE. THE FOLLOWING STATEMENTS REFER TO THE INDIVIDUAL COMPONENTS. 12.3 BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE. BEHAVIOUR IN ENVIRONMENTAL SYSTEMS: 7775-14-6 SODIUM DITHIONITE: LOG P(O/W): <-4.7 (.) 12.4 MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE. ECOTOXICAL EFFECTS: REMARK: TOXIC FOR FISH: SULPHATES: >7 G/L ALGEA TOXICITY: 7681-57-4 DISODIUM DISULPHITE: IC50: 48 MG/L/72H (DESMODESMUS SUBSPICATUS) (MERCK) 7775-14-6 SODIUM DITHIONITE: IC50: 206 MG/L/72H (DESMODESMUS SUBSPICATUS) MERCK BACTERIAL TOXICITY: SULPHATES TOXIC: >2.5 G/L 7681-57-4 DISODIUM DISULPHITE: EC50: 56 MG/L/17H (PSEUDOMONAS PUTIDA) (IUCLID) 7775-14-6 SODIUM DITHIONITE: EC50: 107 MG/L/17H (PSEUDOMONAS PUTIDA) IUCLID ADDITIONAL ECOLOGICAL INFORMATION: COD-VALUE: 7681-57-4 DISODIUM DISULPHITE: COD: 0.165 G/G (.) (MERCK) 7775-14-6 SODIUM DITHIONITE: COD: 0.21 G/G (.) GENERAL NOTES: WATER HAZARD CLASS 1 (GERMAN REGULATION) (SELF-ASSESSMENT ACC. VWVWS ANNEX 4): SLIGHTLY HAZARDOUS FOR WATER. DO NOT ALLOW UNDILUTED PRODUCT OR LARGE QUANTITIES OF IT TO REACH GROUND WATER, WATER BODIES OR SEWAGE SYSTEM. MUST NOT REACH SEWAGE WATER OR DRAINAGE DITCH UNDILUTED OR UNNEUTRALISED. 12.5 RESULTS OF PBT AND VPVB ASSESSMENT: NO DATA AVAILABLE VPVB ASSESSMENTS: NO DATA AVAILABLE 12.6 OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
13.1 WASTE TREATMENT METHODS: RECOMMENDATION: MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM. HAND OVER TO DISPOSERS OF HAZARDOUS WASTE. EUROPEAN WASTE CATALOGUE: 16 05 06: LABORATORY CHEMICALS, CONSISTING OF OR CONTAINING DANGEROUS SUBSTANCES, INCLUDING MIXTURES OF LABORATORY CHEMICALS UNCLEANED PACKAGINGS: RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS. RECOMMENDED CLEANING AGENT: WATER, IF NECESSARY WITH CLEANING AGENT.
| 14.1 UN-NUMBER: ADR, ADN, IMDG, IATA: VOID 14.2 UN PROPER SHIPPING NAME: ADR, ADN, IMDG, IATA: VOID 14.3 TRANSPORT HAZARD CLASS(ES): ADR, ADN, IMDG, IATA: CLASS: VOID 14.4 PACKING GROUP: ADR, IMDG, IATA: VOID 14.5 ENVIRONMENTAL HAZARDS: MARINE POLLUTANT: NO 14.6 SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE. 14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE: NOT APPLICABLE. TRANSPORT/ADDITIONAL INFORMATION: NOT DANGEROUS ACCORDING TO THE ABOVE SPECIFICATIONS.
| 15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE SUBSTANCE OR MIXTURE: INFORMATION ABOUT LIMITATION OF USE: OBSERVE EMPLOYMENT RESTRICTIONS FOR PREGNANT AND NURSING MOTHERS ACCORDING TO THE 'MOTHER PROTECTION GUIDELINE' (92/85/EEC). EMPLOYMENT RESTRICTIONS CONCERNING YOUNG PERSONS MUST BE OBSERVED. 15.2 CHEMICAL SAFETY ASSESSMENT: A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| THESE DATA ARE BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THEY SHALL NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP. RELEVANT PHRASES: H228: FLAMMABLE SOLID. H251: SELF-HEATING: MAY CATCH FIRE. H302: HARMFUL IF SWALLOWED. H317: MAY CAUSE AN ALLERGIC SKIN REACTION. H318: CAUSES SERIOUS EYE DAMAGE. R11: HIGHLY FLAMMABLE. R22: HARMFUL IF SWALLOWED. R31: CONTACT WITH ACIDS LIBERATES TOXIC GAS. R41: RISK OF SERIOUS DAMAGE TO EYES. R43: MAY CAUSE SENSITISATION BY SKIN CONTACT. R7: MAY CAUSE FIRE. ABBREVIATIONS AND ACRONYMS: EC50: EFFECTIVE CONCENTRATION, 50 PERCENT (IN VIVO) ADR: ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE (EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD) IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION GHS: GLOBALLY HARMONISED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY) DNEL: DERIVED NO-EFFECT LEVEL (REACH) LC50: LETHAL CONCENTRATION, 50 PERCENT LD50: LETHAL DOSE, 50 PERCENT FLAM. SOL. 2: FLAMMABLE SOLIDS, HAZARD CATEGORY 2 SELF-HEAT. 1: SELF-HEATING SUBSTANCES AND MIXTURES, HAZARD CATEGORY 1 ACUTE TOX. 4: ACUTE TOXICITY, HAZARD CATEGORY 4 EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 1 SKIN SENS. 1: SENSITISATION - SKIN, HAZARD CATEGORY 1 SOURCES: DATA ARISE FROM REFERENCE WORKS AND LITERATURE. INTERNATIONAL CHEMICAL SAFETY CARDS (ICSCS) IUCLID (INTERNATIONAL UNIFORM CHEMICAL INFORMATION DATABASE) | DATA COMPARED TO THE PREVIOUS VERSION ALTERED. GB |