| Common Name: | VARIO LR SILICA AMINO ACID F / F 10 ML |
| Manufacturer: | TINTOMETER GERMANY |
| SDS Revision Date: | 7/5/2018 |
| SDS Format: | GHS-EU |
| Item Number(s): | 15F910 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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TINTOMETER(R*) GROUP
WATER TESTING
SAFETY DATA SHEET
ACCORDING TO 1907/2006/EC, ARTICLE 31
PRINTING DATE: 18.07.2018
VERSION NUMBER: 11
REVISION: 05.07.2018
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
PRODUCT NAME: VARIO LR SILICA AMINO ACID F / F 10 ML
CATALOG NUMBER: 00531609, 531600, 4531600
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
APPLICATION OF THE SUBSTANCE / THE PREPARATION: REAGENT FOR WATER ANALYSIS
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER:
TINTOMETER GMBH
SCHLEEFSTRASSE 8-12
44287 DORTMUND
MADE IN GERMANY
WWW.LOVIBOND.COM
PHONE: +49 231 94510-0
E-MAIL: SALES@TINTOMETER.DE
TINTOMETER GMBH
DIVISION AQUALYTIC(R*)
SCHLEEFSTR. 12
44287 DORTMUND
MADE IN GERMANY
WWW.AQUALYTIC.DE
PHONE: +49 231 94510-755
E-MAIL: SALES@AQUALYTIC.DE
THE TINTOMETER LIMITED
LOVIBOND(R*) HOUSE
SUN RISE WAY
AMESBURY
WILTSHIRE SP4 7GR
UNITED KINGDOM
PHONE: +44 1980 664800
E-MAIL: SDS@TINTOMETER.COM
INFORMING DEPARTMENT:
E-MAIL: SDS@TINTOMETER.DE
PRODUCT SAFETY DEPARTMENT
1.4 EMERGENCY TELEPHONE NUMBER: +44 1235 239670
LANGUAGES: ENGLISH
| SECTION 2: HAZARDS IDENTIFICATION | |
|
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION ACCORDING TO REGULATION (EC) NO 1272/2008:
GHS08: HEALTH HAZARD
STOT RE 2:
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
GHS05: CORROSION
EYE DAM. 1:
H318: CAUSES SERIOUS EYE DAMAGE.
GHS09: ENVIRONMENT
AQUATIC ACUTE 1:
H400: VERY TOXIC TO AQUATIC LIFE.
AQUATIC CHRONIC 1:
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
GHS07: EXCLAMATION MARK
ACUTE TOX. 4:
H302: HARMFUL IF SWALLOWED.
SKIN SENS. 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
2.2 LABEL ELEMENTS:
LABELLING ACCORDING TO REGULATION (EC) NO 1272/2008:
THE PRODUCT IS CLASSIFIED AND LABELLED ACCORDING TO THE CLP REGULATION.
HAZARD PICTOGRAMS:
GHS05: ENVIRONMENT
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
GHS09: ENVIRONMENT
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELLING:
DISODIUM DISULPHITE
BIS(4-HYDROXY-N-METHYLANILINIUM) SULPHATE
HAZARD STATEMENTS:
H302: HARMFUL IF SWALLOWED.
H318: CAUSES SERIOUS EYE DAMAGE.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
P260: DO NOT BREATHE DUST.
P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION.
P301+P312:
IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF WATER.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P310: IMMEDIATELY CALL A DOCTOR.
ADDITIONAL INFORMATION:
EUH031: CONTACT WITH ACIDS LIBERATES TOXIC GAS.
2.3 OTHER HAZARDS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
RESULTS OF PBT AND VPVB ASSESSMENT:
THIS MIXTURE DOES NOT CONTAIN ANY SUBSTANCES THAT ARE ASSESSED TO BE
PERSISTENT, BIOACCUMULATIVE AND TOXIC (PBT) OR VERY PERSISTENT AND VERY
BIOACCUMULATIVE (VPVB), ACCORDING TO THE CRITERIA GIVEN IN ANNEX XIII OF
REGULATION (EC) NO. 1907/2006.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
DESCRIPTION: MIXTURE OF ORGANIC AND INORGANIC COMPOUNDS
DANGEROUS COMPONENTS:
CAS: 7681-57-4 DISODIUM DISULPHITE 60-70%
EINECS: 231-673-0 EYE DAM. 1, H318;
INDEX NO: 016-063-00-2 ACUTE TOX. 4, H302
REG. NR.: 01-2119531326-45-XXXX
CAS: 55-55-0 BIS(4-HYDROXY-N- 25-35%
EINECS: 200-237-1 METHYLANILINIUM) SULPHATE
INDEX NO: 650-031-00-4 STOT RE 2, H373;
AQUATIC ACUTE 1, H400 (M=10);
AQUATIC CHRONIC 1, H410 (M=1);
ACUTE TOX. 4, H302;
SKIN SENS. 1, H317
CAS: 7758-98-7 COPPER SULPHATE 0.1-1.0%
EINECS: 231-847-6 AQUATIC ACUTE 1, H400 (M=10);
INDEX NO: 029-004-00-0 AQUATIC CHRONIC 1, H410 (M=10);
ACUTE TOX. 4, H302;
SKIN IRRIT. 2, H315;
EYE IRRIT. 2, H319
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD PHRASES REFER TO SECTION 16.
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION: INSTANTLY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF SYMPTOMS.
AFTER SKIN CONTACT: INSTANTLY RINSE WITH WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR SEVERAL MINUTES (AT LEAST 15 MIN) UNDER RUNNING WATER.
CALL A DOCTOR IMMEDIATELY.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK 1-2 GLASSES OF WATER.
SEEK MEDICAL TREATMENT.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
BURNS
ALLERGIC REACTIONS
AFTER INHALATION:
IRRITATIONS
COUGHING
BREATHING DIFFICULTY
AFTER SWALLOWING:
ABSORPTION
GASTRIC OR INTESTINAL TROUBLE
MUCOUS MEMBRANE IRRITATION
AFTER SWALLOWING OF LARGE AMOUNTS:
SICKNESS
VOMITING
CARDIOVASCULAR DISORDERS
CYANOSIS
METHAEMOGLOBINAEMIA
CRAMPS
INFORMATION FOR DOCTOR: SULPHITES ARE STRONG SENSITIZERS.
DANGER: RISK OF SKIN SENSITIZATION
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: SYMPTOMS OF POISONING MAY EVEN OCCUR AFTER SEVERAL HOURS.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
USE FIRE FIGHTING MEASURES THAT SUIT THE ENVIRONMENT.
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
THE PRODUCT IS NOT COMBUSTIBLE.
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
SULPHUR OXIDES (SOX)
NITROGEN OXIDES (NOX)
SODIUM OXIDE
CARBON MONOXIDE (CO) AND CARBON DIOXIDE (CO2)
5.3 ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED BREATHING APPARATUS.
WEAR FULL PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
COLLECT CONTAMINATED FIRE FIGHTING WATER SEPARATELY. IT MUST NOT ENTER
DRAINS.
DISPOSE OF FIRE DEBRIS AND CONTAMINATED FIRE FIGHTING WATER IN ACCORDANCE
WITH OFFICIAL REGULATIONS.
AMBIENT FIRE MAY LIBERATE HAZARDOUS VAPOURS.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ADVICE FOR NON-EMERGENCY PERSONNEL:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
ADVICE FOR EMERGENCY RESPONDERS:
PUT ON BREATHING APPARATUS.
PROTECTIVE EQUIPMENT: SEE SECTION 8
6.2 ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR WATER BODIES.
INFORM RESPECTIVE AUTHORITIES IN CASE PRODUCT REACHES WATER OR SEWAGE
SYSTEM.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ENSURE ADEQUATE VENTILATION.
COLLECT MECHANICALLY.
DISPOSE OF CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
6.4 REFERENCE TO OTHER SECTIONS:
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR INFORMATION ON DISPOSAL.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
ADVICE ON SAFE HANDLING:
ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE.
PREVENT FORMATION OF DUST.
HYGIENE MEASURES:
DO NOT INHALE DUST / SMOKE / MIST.
AVOID CONTACT WITH THE SKIN.
AVOID CONTACT WITH THE EYES.
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
WASH HANDS DURING BREAKS AND AT THE END OF THE WORK.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND CONTAINERS:
STORE IN COOL LOCATION.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
DO NOT STORE TOGETHER WITH ACIDS.
STORE AWAY FROM OXIDISING AGENTS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
PROTECT FROM THE EFFECTS OF LIGHT.
STORE UNDER DRY CONDITIONS.
PROTECT FROM HUMIDITY AND KEEP AWAY FROM WATER.
RECOMMENDED STORAGE TEMPERATURE: 20 DEG. C +/- 5 DEG. C
7.3 SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
CAS: 7681-57-4 DISODIUM DISULPHITE
WEL (GREAT BRITAIN):
LONG-TERM VALUE: 5 MG/M3
CAS: 7758-98-7 COPPER SULPHATE
OEL (SWEDEN):
LONG-TERM VALUE: 1* 0.2** MG/M3
SOM Cu; *TOTALDAMM **RESPIRABELT DAMM
REGULATORY INFORMATION:
WEL (GREAT BRITAIN): EH40/2011
OEL (SWEDEN): AFS2011:18
DNELS: DERIVED NO EFFECT LEVEL (DNEL)
CAS: 7681-57-4 DISODIUM DISULPHITE
INHALATIVE:
DNEL: 10 MG/M3 (WORKER / LONG-TERM /SYSTEMIC EFFECTS) (MERCK)
RECOMMENDED MONITORING PROCEDURES:
METHODS FOR MEASUREMENT OF THE WORKPLACE ATMOSPHERE HAVE TO CORRESPOND TO
THE REQUIREMENTS OF NORMS DIN EN 482 AND DIN EN 689.
PNECS: PREDICTED NO EFFECT CONCENTRATION (PNEC)
CAS: 7681-57-4 DISODIUM DISULPHITE
PNEC:
75.4 MG/L (SEWAGE TREATMENT PLANT)
0.1 MG/L (MARINE WATER)
1 MG/L (FRESH WATER)
ADDITIONAL INFORMATION:
THE LISTS THAT WERE VALID DURING THE COMPILATION WERE USED AS BASIS.
8.2 EXPOSURE CONTROLS:
ENGINEERING MEASURES:
TECHNICAL MEASURES AND APPROPRIATE WORKING OPERATIONS SHOULD BE GIVEN
PRIORITY OVER THE USE OF PERSONAL PROTECTIVE EQUIPMENT. SEE ITEM 7.
PERSONAL PROTECTIVE EQUIPMENT:
BREATHING EQUIPMENT:
USE BREATHING PROTECTION AGAINST THE EFFECTS OF FUMES/DUST/AEROSOL.
RECOMMENDED FILTER DEVICE FOR SHORT TERM USE: FILTER P2
PROTECTION OF HANDS:
PROTECTIVE GLOVES.
PREVENTIVE SKIN PROTECTION BY USE OF SKIN-PROTECTING AGENTS IS RECOMMENDED.
AFTER USE OF GLOVES APPLY SKIN-CLEANING AGENTS AND SKIN COSMETICS.
MATERIAL OF GLOVES:
NITRILE RUBBER, NBR
RECOMMENDED THICKNESS OF THE MATERIAL: >/=0.11 MM
PENETRATION TIME OF GLOVE MATERIAL:
VALUE FOR THE PERMEATION:
LEVEL: 1 (<10 MIN)
THE EXACT BREAK TROUGH TIME HAS TO BE FOUND OUT BY THE MANUFACTURER OF
THE PROTECTIVE GLOVES AND HAS TO BE OBSERVED.
EYE PROTECTION: TIGHTLY SEALED SAFETY GLASSES.
BODY PROTECTION: PROTECTIVE WORK CLOTHING.
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR WATER BODIES.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM / PHYSICAL STATE: POWDER
COLOUR: WHITE
ODOUR: ODOURLESS
ODOUR THRESHOLD: NOT APPLICABLE
PH-VALUE (4 G/L) AT 20 DEG. C: 5.3
MELTING POINT/FREEZING POINT: NOT DETERMINED
INITIAL BOILING POINT AND BOILING RANGE: NOT DETERMINED
FLASH POINT: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): THE PRODUCT IS NOT COMBUSTIBLE.
IGNITION TEMPERATURE: NOT APPLICABLE
DECOMPOSITION TEMPERATURE:
>150 DEG. C (CAS 7681-57-4)
NOT DETERMINED.
AUTO-IGNITION TEMPERATURE: PRODUCT IS NOT SELF-IGNITING.
EXPLOSIVE PROPERTIES: PRODUCT IS NOT EXPLOSIVE.
FLAMMABILITY OR EXPLOSIVE LIMITS:
LOWER: NOT APPLICABLE
UPPER: NOT APPLICABLE
OXIDISING PROPERTIES: NONE
VAPOUR PRESSURE: NOT APPLICABLE.
DENSITY AT 20 DEG. C: 1.26 G/CM3
RELATIVE DENSITY: NOT DETERMINED.
VAPOUR DENSITY: NOT APPLICABLE.
EVAPORATION RATE: NOT APPLICABLE.
SOLUBILITY(IES):
WATER: SOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT APPLICABLE.
VISCOSITY: NOT APPLICABLE.
SOLVENT CONTENT:
ORGANIC SOLVENTS: 0.0%
SOLIDS CONTENT: 100.0%
9.2 OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY: SEE SECTION 10.3
10.2 CHEMICAL STABILITY:
STABLE AT AMBIENT TEMPERATURE (ROOM TEMPERATURE).
SENSITIVITY TO LIGHT
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
IN CONTACT WITH NITRITES, NITRATES OR NITROUS ACID POSSIBLE RELEASE OF
NITROSAMINES (CARCINOGENIC)!
CONTACT WITH ACIDS RELEASES TOXIC GASES
REACTS WITH ACIDS RELEASING SULPHUR DIOXIDE
REACTS WITH OXIDIZING AGENTS
10.4 CONDITIONS TO AVOID: STRONG HEATING (DECOMPOSITION)
10.5 INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
SULPHUR DIOXIDE
SEE SECTION 5
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
CLASSIFICATION ACCORDING TO CALCULATION PROCEDURE: HARMFUL IF SWALLOWED.
ACUTE TOXICITY ESTIMATE (ATE(MIX)) - CALCULATION METHOD:
ORAL:
ATE(MIX): 594 MG/KG (.)
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
CAS: 7681-57-4 DISODIUM DISULPHITE
ORAL:
LD50: 1540 MG/KG (RAT) (OECD 401)
(MERCK)
DERMAL:
LD50: >2000 MG/KG (RAT)
(RTECS)
CAS: 55-55-0 BIS(4-HYDROXY-N-METHYLANILINIUM) SULPHATE
ORAL:
LD50: 237 MG/KG (RAT)
DERMAL:
LD50: >1000 MG/KG (RAT)
CAS: 7758-98-7 COPPER SULPHATE
ORAL:
LD50: 481 MG/KG (RAT) (OECD 401)
(MERCK)
LDLO: 50 MG/KG (HUMAN)
PRIMARY IRRITANT EFFECT:
SKIN CORROSION/IRRITATION:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SERIOUS EYE DAMAGE/IRRITATION:
CAUSES SERIOUS EYE DAMAGE.
RISK OF CORNEAL CLOUDING.
INFORMATION ON COMPONENTS:
CAS: 7681-57-4 DISODIUM DISULPHITE
IRRITATION OF SKIN:
OECD 404: (RABBIT: NO IRRITATION)
IRRITATION OF EYES:
OECD 405: (RABBIT: SEVERE IRRITATIONS)
RESPIRATORY OR SKIN SENSITISATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
INFORMATION ON COMPONENTS:
CAS 55-55-0:
SENSITIZING EFFECT BY INHALATION AND SKIN CONTACT IS POSSIBLE BY PROLONGED
EXPOSURE.
CAS: 7681-57-4 DISODIUM DISULPHITE
SENSITISATION:
OECD 406: (GUINEA PIG: NEGATIVE)
CMR EFFECTS (CARCINOGENITY, MUTAGENICITY AND TOXICITY FOR REPRODUCTION):
THE FOLLOWING STATEMENTS REFER TO THE MIXTURE:
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
REPRODUCTIVE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT (SPECIFIC TARGET ORGAN TOXICITY) - SINGLE EXPOSURE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
STOT (SPECIFIC TARGET ORGAN TOXICITY) - REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
INFORMATION ON COMPONENTS:
CAS 7681-57-4:
DID NOT SHOW CARCINOGENIC EFFECTS IN ANIMAL EXPERIMENTS (IUCLID).
CAS 7681-57-4:
NO IMPAIRMENT OF REPRODUCTIVE PERFORMANCE IN ANIMAL EXPERIMENTS (IUCLID).
CAS 7681-57-4: DID NOT SHOW TERATOGENIC EFFECTS IN ANIMAL EXPERIENTS.
CAS: 7681-57-4 DISODIUM DISULPHITE
OECD 471: (NEGATIVE) (BACTERIAL REVERSE MUTATION TEST - AMES TEST)
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
AQUATIC TOXICITY:
CAS: 7681-57-4 DISODIUM DISULPHITE
EC50: 89 MG/L/48H (DAPHNIA MAGNA) (OECD 202)
(MERCK)
IC50: 48 MG/L/72H (DESMODESMUS SUBSPICATUS) (OECD 201)
(MERCK)
LC50: 150 - 220 MG/L/96H (RAINBOW TROUT) (DIN 38412 TEIL 15)
(MERCK)
CAS: 55-55-0 BIS(4-HYDROXY-N-METHYLANILINIUM) SULPHATE
EC50: 0.019 MG/L/96H (DAPHNIA MAGNA)
(MERCK)
CAS: 7758-98-7 COPPER SULPHATE
EC50: 0.02 MG/L/48H (DAPHNIA MAGNA)
(ECOTOX)
LC50: 0.11 MG/L/96H (RAINBOW TROUT)
(ECOTOX)
BACTERIAL TOXICITY:
SULPHATES TOXIC: >2.5 G/L
CAS: 7681-57-4 DISODIUM DISULPHITE
EC50: 56 MG/L (PSEUDOMONAS PUTIDA) (17H)
(IUCLID)
OTHER INFORMATION:
TOXIC FOR FISH:
SULPHATES: >7 G/L
COPPER IONS AT CONCENTRATION BELOW: 1 MG/L
12.2 PERSISTENCE AND DEGRADABILITY:
CAS 55-55-0: NOT EASILY BIODEGRADABLE
CAS: 55-55-0 BIS(4-HYDROXY-N-METHYLANILINIUM) SULPHATE
OECD 301 D: APPROX. 30% (.) (CLOSED BOTTLE TEST)
12.3 BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.4 MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
12.5 RESULTS OF PBT AND VPVB ASSESSMENT:
THIS MIXTURE DOES NOT CONTAIN ANY SUBSTANCES THAT ARE ASSESSED TO BE
PERSISTENT, BIOACCUMULATIVE AND TOXIC (PBT) OR VERY PERSISTENT AND VERY
BIOACCUMULATIVE (VPVB), ACCORDING TO THE CRITERIA GIVEN IN ANNEX XIII OF
REGULATION (EC) NO. 1907/2006.
12.6 OTHER ADVERSE EFFECTS: AVOID TRANSFER INTO THE ENVIRONMENT.
WATER HAZARD:
DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER BODIES OR SEWAGE SYSTEM,
EVEN IN SMALL QUANTITIES.
DANGER TO DRINKING WATER IF EVEN EXTREMELY SMALL QUANTITIES LEAK INTO SOIL.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM.
HAND OVER TO DISPOSERS OF HAZARDOUS WASTE.
EUROPEAN WASTE CATALOGUE:
16 05 06*:
LABORATORY CHEMICALS, CONSISTING OF OR CONTAINING HAZARDOUS SUBSTANCES,
INCLUDING MIXTURES OF LABORATORY CHEMICALS
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
RECOMMENDED CLEANING AGENT: WATER, IF NECESSARY WITH CLEANING AGENT.
| SECTION 14: TRANSPORT INFORMATION | |
14.1 UN-NUMBER:
ADR, IMDG, IATA: UN3077
14.2 UN PROPER SHIPPING NAME:
ADR:
3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(BIS(4-HYDROXY-N-METHYLANILINIUM) SULPHATE, COPPER SULPHATE)
IMDG:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(BIS(4-HYDROXY-N-METHYLANILINIUM) SULPHATE, COPPER SULPHATE), MARINE
POLLUTANT
IATA:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(BIS(4-HYDROXY-N-METHYLANILINIUM) SULPHATE, COPPER SULPHATE)
14.3 TRANSPORT HAZARD CLASS(ES):
ADR:
CLASS 9, MISCELLANEOUS PRODUCTS, SUBSTANCES, OR ORGANISMS
ENVIRONMENT
CLASS: 9 (M7) MISCELLANEOUS DANGEROUS SUBSTANCES AND ARTICLES.
LABEL: 9
IMDG, IATA:
CLASS 9 - MISCELLANEOUS
ENVIRONMENT
CLASS 9, CLASS/DIVISION 9 PACKING GROUP III
ENVIRONMENT
CLASS: 9 MISCELLANEOUS DANGEROUS SUBSTANCES AND ARTICLES.
LABEL: 9
14.4 PACKING GROUP:
ADR, IMDG, IATA: III
14.5 ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: SYMBOL (FISH AND TREE)
SPECIAL MARKING (ADR): SYMBOL (FISH AND TREE)
SPECIAL MARKING (IATA): SYMBOL (FISH AND TREE)
14.6 SPECIAL PRECAUTIONS FOR USER:
WARNING: MISCELLANEOUS DANGEROUS SUBSTANCES AND ARTICLES.
KEMLER NUMBER: 90
EMS NUMBER: F-A, S-F
STOWAGE CATEGORY: A
STOWAGE CODE:
SW23: WHEN TRANSPORTED IN BK3 BULK CONTAINER, SEE 7.6.2.12 AND 7.7.3.9.
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
ADR:
LIMITED QUANTITIES (LQ): 5 KG
EXCEPTED QUANTITIES (EQ):
CODE: E1
MAXIMUM NET QUANTITY PER INNER PACKAGING: 30 G
MAXIMUM NET QUANTITY PER OUTER PACKAGING: 1000 G
TRANSPORT CATEGORY: 3
TUNNEL RESTRICTION CODE: E
IMDG:
LIMITED QUANTITIES (LQ): 5 KG
EXCEPTED QUANTITIES (EQ):
CODE: E1
MAXIMUM NET QUANTITY PER INNER PACKAGING: 30 G
MAXIMUM NET QUANTITY PER OUTER PACKAGING: 1000 G
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC
FOR THE SUBSTANCE OR MIXTURE:
REGULATION (EC) NO 1005/2009 ON SUBSTANCES THAT DEPLETE THE OZONE LAYER:
NONE OF THE INGREDIENTS IS LISTED.
DIRECTIVE 2012/18/EU (SEVESO MI):
NAMED DANGEROUS SUBSTANCES - ANNEX I: NONE OF THE INGREDIENTS IS LISTED.
SEVESO CATEGORY:
E1: HAZARDOUS TO THE AQUATIC ENVIRONMENT
QUALIFYING QUANTITY (TONNES) FOR THE APPLICATION OF LOWER-TIER
REQUIREMENTS: 100 T
QUALIFYING QUANTITY (TONNES) FOR THE APPLICATION OF UPPER-TIER
REQUIREMENTS: 200 T
INFORMATION ABOUT LIMITATION OF USE:
OBSERVE EMPLOYMENT RESTRICTIONS FOR PREGNANT AND NURSING MOTHERS ACCORDING
TO THE 'MOTHER PROTECTION GUIDELINE' (92/85/EEC).
EMPLOYMENT RESTRICTIONS CONCERNING YOUNG PERSONS MUST BE OBSERVED.
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| SECTION 16: OTHER INFORMATION | |
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THESE DATA ARE BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THEY SHALL NOT
CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL NOT
ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
RELEVANT PHRASES:
H302: HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H318: CAUSES SERIOUS EYE DAMAGE.
H319: CAUSES SERIOUS EYE IRRITATION.
H373: MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
H400: VERY TOXIC TO AQUATIC LIFE.
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
TRAINING HINTS:
PROVIDE ADEQUATE INFORMATION, INSTRUCTION AND TRAINING FOR OPERATORS.
ABBREVIATIONS AND ACRONYMS:
OECD: ORGANISATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
STOT: SPECIFIC TARGET ORGAN TOXICITY
SE: SINGLE EXPOSURE
RE: REPEATED EXPOSURE
EC50: HALF MAXIMAL EFFECTIVE CONCENTRATION
IC50: HALLF MAXIMAL INHIBITORY CONCENTRATION
NOEL OR NOEC: NO OBSERVED EFFECT LEVEL OR CONCENTRATION
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
RID:
REGLEMENT INTERNATIONAL CONCERNANT LE TRANSPORT DES MARCHANDISES
DANGEREUSES PAR CHEMIN DE FER (REGULATIONS CONCERNING THE INTERNATIONAL
TRANSPORT OF DANGEROUS GOODS BY RAIL)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
GHS:
GLOBALLY HARMONISED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
DNEL: DERIVED NO-EFFECT LEVEL (REACH)
PNEC: PREDICTED NO-EFFECT CONCENTRATION (REACH)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
ACUTE TOX. 4: ACUTE TOXICITY - CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2
SKIN SENS. 1: SKIN SENSITISATION - CATEGORY 1
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - CATEGORY 2
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTE AQUATIC HAZARD - CATEGORY 1
AQUATIC CHRONIC 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - LONG-TERM AQUATIC
HAZARD - CATEGORY 1
SOURCES:
DATA ARISE FROM SAFETY DATA SHEETS, REFERENCE WORKS AND LITERATURE.
ECOTOX DATABASE
IUCLID (INTERNATIONAL UNIFORM CHEMICAL INFORMATION DATABASE)
RTECS (REGISTRY OF TOXIC EFFECTS OF CHEMICAL SUBSTANCES)
GB