| Common Name: | LOCTITE MR 5923 KNOWN AS LOCTITE AVIATION GASKET SEAL, 1522029 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 11/29/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 16X924 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 004.0
ISSUE DATE: 11/29/2016
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE MR 5923 KNOWN AS LOCTITE(R*) AVIATION GASKET SEAL
PRODUCT TYPE: SEALANT
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 1522029
ITEM NUMBER: 1522029
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE DROWSINESS OR DIZZINESS.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 2
SKIN IRRITATION 2
EYE IRRITATION 2A
RESPIRATORY SENSITIZATION 1
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
ASPIRATION HAZARD 1
PICTOGRAM(S):
FLAME
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES - NO SMOKING. KEEP
CONTAINER TIGHTLY CLOSED. NO RELEASE INTO WATER. USE EXPLOSION-PROOF
EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE PRECAUTIONARY MEASURES AGAINST
STATIC DISCHARGE. AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED
AREA THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE. WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION. IN
CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
RESPONSE:
IF SWALLOWED: IMMEDIATELY CALL A PHYSICIAN OR POISON CONTROL CENTER.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. DO NOT INDUCE VOMITING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR PHYSICIAN. TAKE OFF CONTAMINATED CLOTHING.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A
WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
CASTOR OIL, OXIDIZED 68187-84-8 30 - 40
ROSIN 8050-09-7 20 - 30
2-PROPANOL 67-63-0 20 - 30
TALC 14807-96-6 10 - 20
QUARTZ (SiO2) 14808-60-7 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER (USING SOAP, IF AVAILABLE). IF SYMPTOMS DEVELOP AND
PERSIST, GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
VAPORS MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH
BACK.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. ALDEHYDES. CARBOXYLIC ACIDS. ACRID SMOKE AND FUMES.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. ENSURE ADEQUATE VENTILATION. KEEP
UNNECESSARY PERSONNEL AWAY. SOAK UP WITH INERT ABSORBENT MATERIAL
(E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). STORE
IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. REFER TO SECTION 8
"EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
DO NOT HANDLE CONTACT LENSES UNTIL ALL SEALANT HAS BEEN REMOVED FROM HANDS.
RESIDUAL SEALANT MAY TRANSFER TO LENSES AND CAUSE EYE IRRITATION. PREVENT
CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH
THOROUGHLY AFTER HANDLING. KEEP AWAY FROM HEAT, SPARK AND FLAME.
STORAGE:
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE, PLEASE REVIEW LABELS ON CONTAINER OR
CHECK THE TECHNICAL DATA SHEET.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
CASTOR OIL, OXIDIZED NONE NONE
ROSIN EXPOSURE BY ALL
ROUTES SHOULD BE
CAREFULLY CONTROLLED TO
LEVELS AS LOW AS POSSIBLE.
INCLUDED IN THE
REGULATION BUT WITH NO
DATA VALUES. SEE
REGULATION FOR FURTHER
DETAILS (RESPIRATORY
SENSITIZATION)
(DERMAL SENSITIZATION)
2-PROPANOL 200 PPM TWA 400 PPM
400 PPM STEL (980 MG/M3) PEL
TALC 2 MG/M3 TWA 0.1 MG/M3 TWA
RESPIRABLE FRACTION. RESPIRABLE.
0.3 MG/M3 TWA
TOTAL DUST.
2.4 MPPCF TWA
RESPIRABLE.
20 MPPCF TWA
QUARTZ (SiO2) 0.025 MG/M3 TWA 2.4 MPPCF TWA
RESPIRABLE FRACTION. RESPIRABLE.
0.1 MG/M3 TWA
RESPIRABLE.
0.05 MG/M3 PEL
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
CASTOR OIL, OXIDIZED NONE NONE
ROSIN NONE NONE
2-PROPANOL NONE NONE
TALC NONE 50 PPM
QUARTZ (SIO2) NONE NONE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. SAFETY SHOWERS AND EYE
WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE IMPERMEABLE GLOVES AND PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: BROWN
ODOR: ALCOHOLIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: 33 MMHg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: >180 DEG. F (>82.2 DEG. C)
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.12 AT 25 DEG. C (77 DEG. F)
VAPOR DENSITY: 2.07
FLASH POINT: 15 DEG. C (59 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: 7.7 (ETHER = 1)
SOLUBILITY IN WATER: PARTIALLY SOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 24.9%; 274 G/L EPA METHOD 24
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. CARBOXYLIC ACIDS. ALDEHYDES. ACRID SMOKE AND FUMES.
IRRITATING FUMES.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. ACIDS AND BASES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
EXPOSURE TO MOISTURE. HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. MAY CAUSE CENTRAL NERVOUS SYSTEM
EFFECTS WITH NAUSEA, DIZZINESS AND HEADACHE. MAY CAUSE ALLERGIC SKIN AND
RESPIRATORY TRACT REACTION. THESE SYMPTOMS, WHICH CAN INCLUDE CHEST
TIGHTNESS, WHEEZING, COUGH, SHORTNESS OF BREATH OR ASTHMA ATTACK, COULD
BE IMMEDIATE OR DELAYED (UP TO SEVERAL HOURS AFTER EXPOSURE). ABRASION OF
CURED MATERIAL SUCH AS BY SANDING OR GRINDING COULD RELEASE RESPIRABLE
PARTICLES OF SILICA QUARTZ, A CANCER HAZARD BY INHALATION. NORMAL USE OF
THIS PRODUCT CAUSES NO SUCH RELEASE.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION:
PRINCIPAL HAZARD OF INGESTION IS ASPIRATION INTO THE LUNGS AND SUBSEQUENT
PNEUMONITIS.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
CASTOR OIL, OXIDIZED NONE NO RECORDS
ROSIN NONE ALLERGEN, IRRITANT,
RESPIRATORY
2-PROPANOL ORAL LD50 (RAT): ALLERGEN, CENTRAL NERVOUS
5,045 MG/KG SYSTEM, IRRITANT
ORAL LD50 (MOUSE):
3,600 MG/KG
ORAL LD50 (RABBIT):
6,410 MG/KG
ORAL LD50 (RAT):
4.7 G/KG
ORAL LD50 (MOUSE):
4.5 G/KG
ORAL LD50 (RABBIT):
8.0 G/KG
ORAL LD50 (RABBIT):
5.03 G/KG
DERMAL LD50 (RABBIT):
12,800 MG/KG
TALC NONE IRRITANT, LUNG, SOME
EVIDENCE OF
CARCINOGENICITY
QUARTZ (SIO2) NONE IMMUNE SYSTEM, LUNG, SOME
EVIDENCE OF
CARCINOGENICITY
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED)
CASTOR OIL, OXIDIZED NO NO NO
ROSIN NO NO NO
2-PROPANOL NO NO NO
TALC NO GROUP 2B NO
QUARTZ (SiO2) KNOWN TO GROUP 1 NO
BE HUMAN
CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
D001: IGNITABLE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES
TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: RESIN SOLUTION
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1866
PACKING GROUP: II
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: RESIN SOLUTION
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1866
PACKING GROUP: II
EXCEPTIONS: (NOT MORE THAN 500 ML), CONSUMER COMMODITY, ID 8000, CLASS 9
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: RESIN SOLUTION
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1866
PACKING GROUP: II
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: BLOWN CASTOR OIL (CAS# 68187-84-8).
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH, FIRE
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CERCLA REPORTABLE QUANTITY: 2-PROPANOL (CAS# 67-63-0) 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: TIMOTHY PRATT, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 11/29/2016
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.