| Common Name: | SLAP SHOT, 53-C 503 (500 ML), 53-C 506 (5 L), 53-C 507 (20 L), 53-C 508 (200 L) |
| Manufacturer: | WALTER SURFACE TECHNOLOGIES |
| SDS Revision Date: | 11/30/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 18C833, 328XW0, 51HM51, 51HM52 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
W
WALTER SURFACE TECHNOLOGIES
CONFORMS TO HAZCOM 2012/UNITED STATES
SAFETY DATA SHEET
SLAP SHOT
BIO-CIRCLE(R*)
A DIVISION OF WALTER SURFACE TECHNOLOGIES
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: SLAP SHOT
PRODUCT CODE:
53-C 503 (500 ML), 53-C 506 (5 L), 53-C 507 (20 L), 53-C 508 (200 L)
SDS NO.: L-40E
PRODUCT TYPE: LIQUID.
IDENTIFIED USES: INDUSTRIAL PARTS CLEANER AND DEGREASER.
MANUFACTURER:
WALTER SURFACE TECHNOLOGIES INC.
BIO-CIRCLE - A DIVISION OF WALTER SURFACE TECHNOLOGIES INC.
810 DAY HILL ROAD
WINDSOR, CT 06095
UNITED STATES
GENERAL INFORMATION: 18665925837
INFO.US@WALTER.COM
WWW.WALTER.COM
EMERGENCY TELEPHONE NUMBER (WITH HOURS OF OPERATION):
INFOTRAC(R*): 1-800-535-5053
OUTSIDE U.S.A. CALL COLLECT: 1-352-323-3500 24 HOURS/DAY, 7 DAYS/WEEK.
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE LIQUIDS: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
TOXIC TO REPRODUCTION (FERTILITY): CATEGORY 2
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (NARCOTIC EFFECTS):
CATEGORY 3
AQUATIC HAZARD (LONG-TERM): CATEGORY 3
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H319: CAUSES SERIOUS EYE IRRITATION.
H361: SUSPECTED OF DAMAGING FERTILITY.
H336: MAY CAUSE DROWSINESS AND DIZZINESS.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P281: USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
P280: WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION.
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P241:
USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING AND ALL
MATERIAL-HANDLING EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P261: AVOID BREATHING VAPOR.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
RESPONSE:
P308 + P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
P304 + P340 + P312:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE:
P405: STORE LOCKED UP.
P403: STORE IN A WELL-VENTILATED PLACE.
P235: KEEP COOL.
DISPOSAL:
P501:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
PRODUCT CODE:
53-C 503 (500 ML), 53-C 506 (5 L), 53-C 507 (20 L), 53-C 508 (200 L)
CAS NUMBER/OTHER IDENTIFIERS:
CAS NUMBER: NOT APPLICABLE.
INGREDIENT NAME % CAS NUMBER
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT 60 - 100 64742-49-0
ACETONE 10 - 30 67-64-1
N-HEXANE 1 - 5 110-54-3
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CONTINUE TO RINSE FOR AT LEAST 20 MINUTES. GET MEDICAL
ATTENTION.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION FOLLOWING EXPOSURE OR
IF FEELING UNWELL. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. CONTINUE TO RINSE FOR AT
LEAST 20 MINUTES. GET MEDICAL ATTENTION. WASH CLOTHING BEFORE REUSE. CLEAN
SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN
A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS BEEN SWALLOWED AND
THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES OF WATER TO DRINK.
STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY BE DANGEROUS. DO NOT
INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. GET MEDICAL
ATTENTION FOLLOWING EXPOSURE OR IF FEELING UNWELL. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION
AND GET MEDICAL ATTENTION IMMEDIATELY.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS AND
DIZZINESS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. IRRITATING TO MOUTH,
THROAT AND STOMACH.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IT
MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE, USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE WATER JET.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
HIGHLY FLAMMABLE LIQUID AND VAPOR. IN A FIRE OR IF HEATED, A PRESSURE
INCREASE WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A
SUBSEQUENT EXPLOSION. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD.
THIS MATERIAL IS HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS. FIRE
WATER CONTAMINATED WITH THIS MATERIAL MUST BE CONTAINED AND PREVENTED FROM
BEING DISCHARGED TO ANY WATERWAY, SEWER OR DRAIN.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
MOVE CONTAINERS FROM FIRE AREA IF THIS CAN BE DONE WITHOUT RISK. USE WATER
SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE
OPERATED IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
SHUT OFF ALL IGNITION SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE
ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR). WATER POLLUTING MATERIAL. MAY BE HARMFUL TO THE ENVIRONMENT IF
RELEASED IN LARGE QUANTITIES.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA A
LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). AVOID
EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. AVOID EXPOSURE DURING
PREGNANCY. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND
UNDERSTOOD. DO NOT GET IN EYES OR ON SKIN OR CLOTHING. DO NOT INGEST. AVOID
BREATHING VAPOR OR MIST. AVOID RELEASE TO THE ENVIRONMENT. USE ONLY WITH
ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION IS
INADEQUATE. DO NOT ENTER STORAGE AREAS AND CONFINED SPACES UNLESS
ADEQUATELY VENTILATED. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED
ALTERNATIVE MADE FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT
IN USE. STORE AND USE AWAY FROM HEAT, SPARKS, OPEN FLAME OR ANY OTHER
IGNITION SOURCE. USE EXPLOSION-PROOF ELECTRICAL (VENTILATING, LIGHTING AND
MATERIAL HANDLING) EQUIPMENT. USE ONLY NON-SPARKING TOOLS. TAKE
PRECAUTIONARY MEASURES AGAINST ELECTROSTATIC DISCHARGES. EMPTY CONTAINERS
RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. SEE ALSO SECTION 8 FOR ADDITIONAL
INFORMATION ON HYGIENE MEASURES. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN A SEGREGATED AND
APPROVED AREA. STORE IN ORIGINAL CONTAINER PROTECTED FROM DIRECT SUNLIGHT
IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10) AND FOOD AND DRINK. STORE LOCKED UP. ELIMINATE ALL
IGNITION SOURCES. SEPARATE FROM OXIDIZING MATERIALS. KEEP CONTAINER
TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS THAT HAVE BEEN
OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO PREVENT LEAKAGE. DO
NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE CONTAINMENT TO AVOID
ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
ACETONE ACGIH TLV (UNITED STATES, 4/2014).
STEL: 1782 MG/M3 15 MINUTES.
STEL: 750 PPM 15 MINUTES.
TWA: 1188 MG/M3 8 HOURS.
TWA: 500 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 590 MG/M3 10 HOURS.
TWA: 250 PPM 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 2400 MG/M3 8 HOURS.
TWA: 1000 PPM 8 HOURS.
N-HEXANE ACGIH TLV (UNITED STATES, 4/2014).
ABSORBED THROUGH SKIN.
TWA: 50 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2013).
TWA: 180 MG/M3 10 HOURS.
TWA: 50 PPM 10 HOURS.
OSHA PEL (UNITED STATES, 2/2013).
TWA: 1800 MG/M3 8 HOURS.
TWA: 500 PPM 8 HOURS.
OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 50 PPM 8 HOURS.
TWA: 180 MG/M3 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
NO PERSONAL RESPIRATORY PROTECTIVE EQUIPMENT NORMALLY REQUIRED. AVOID
BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY. WHEN WORKERS ARE FACING
CONCENTRATIONS ABOVE THE EXPOSURE LIMIT THEY MUST USE APPROPRIATE CERTIFIED
RESPIRATORS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED
TO ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: CHEMICAL SPLASH GOGGLES.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
RECOMMENDED: NITRILE GLOVES. (PERMEATION TIME >8 HOURS)
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A NIOSH/MSHA APPROVED RESPIRATOR IF THERE IS A RISK OF EXPOSURE AT
LEVELS EXCEEDING THE EXPOSURE LIMITS. ADVICE SHOULD BE SOUGHT FROM
RESPIRATORY PROTECTION SPECIALISTS.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: COLORLESS AND CLEAR.
ODOR: CHARACTERISTIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE.
MELTING POINT: <-24 DEG. C (<-11.2 DEG. F)
BOILING POINT: >60 DEG. C (>140 DEG. F)
FLASH POINT:
CLOSED CUP: -24 DEG. C (-11.2 DEG. F)
EVAPORATION RATE: NOT APPLICABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 0.8%
UPPER: 13%
VAPOR PRESSURE: 20 KPA (150.01 MMHg) [@ 20 DEG. C (68 DEG. F)]
VAPOR DENSITY: 0.72 [AIR = 1]
DENSITY: 0.72 G/ML @ 20 DEG. C (68 DEG. F)
SOLUBILITY:
VERY SLIGHTLY SOLUBLE IN THE FOLLOWING MATERIALS: COLD WATER AND HOT WATER.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: >260 DEG. C (>500 DEG. F)
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
VOC CONTENT (G/L): 720
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME). DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT OR
SOURCES OF IGNITION.
INCOMPATIBLE MATERIALS:
REACTIVE OR INCOMPATIBLE WITH THE FOLLOWING MATERIALS:
OXIDIZING MATERIALS, ACIDS AND ALKALIS.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
ACETONE LD50 ORAL RAT 5800 MG/KG
N-HEXANE LC50 INHALATION RAT 48000 PPM 4 HOURS
GAS.
LD50 ORAL RAT 15840 MG/KG
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
ACETONE EYES: HUMAN 186300 PPM
MILD
IRRITANT
EYES: RABBIT 10 (MICRO)L
MILD
IRRITANT
EYES: RABBIT 24 HOURS
MODERATE 20 MG
IRRITANT
EYES: RABBIT 20 MG
SEVERE
IRRITANT
SKIN: RABBIT 24 HOURS
MILD 500 MG
IRRITANT
SKIN: RABBIT 395 MG
MILD
IRRITANT
N-HEXANE EYES: RABBIT 10 MG
MILD
IRRITANT
SENSITIZATION: THERE IS NO DATA AVAILABLE.
CARCINOGENICITY:
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP ACGIH EPA NIOSH
ACETONE A4
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
ACETONE CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
N-HEXANE CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
N-HEXANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ASPIRATION HAZARD:
NAME RESULT
NAPHTHA (PETROLEUM), HYDROTREATED LIGHT ASPIRATION HAZARD - CATEGORY 1
N-HEXANE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
DERMAL CONTACT. EYE CONTACT. INHALATION. INGESTION.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INHALATION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. MAY CAUSE DROWSINESS AND
DIZZINESS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION:
CAN CAUSE CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION. IRRITATING TO MOUTH,
THROAT AND STOMACH.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
NAUSEA OR VOMITING
HEADACHE
DROWSINESS/FATIGUE
DIZZINESS/VERTIGO
UNCONSCIOUSNESS
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
REDUCED FETAL WEIGHT
INCREASE IN FETAL DEATHS
SKELETAL MALFORMATIONS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL DELAYED EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL DELAYED EFFECTS:
NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
POTENTIAL CHRONIC HEALTH EFFECTS:
GENERAL: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: SUSPECTED OF DAMAGING FERTILITY.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES: THERE IS NO DATA AVAILABLE.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
ACETONE ACUTE EC50: ALGAE - ULVA PERTUSA 96 HOURS
20.565 MG/L
MARINE WATER
ACUTE LC50: CRUSTACEANS - GAMMARUS 48 HOURS
6000000 (MICRO)G/L PULEX
FRESH WATER
ACUTE LC50: DAPHNIA - DAPHNIA MAGNA 48 HOURS
10000 (MICRO)G/L
FRESH WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
100 MG/L PROMELAS - JUVENILE
FRESH WATER (FLEDGLING, HATCHLING,
WEANLING)
CHRONIC NOEC: ALGAE - ULVA PERTUSA 96 HOURS
4.95 MG/L
MARINE WATER
CHRONIC NOEC: CRUSTACEANS - 21 DAYS
0.016 ML/L DAPHNIIDAE
FRESH WATER
CHRONIC NOEC: DAPHNIA - DAPHNIA 21 DAYS
0.1 ML/L MAGNA - NEONATE
FRESH WATER
N-HEXANE ACUTE LC50: FISH - OREOCHROMIS 96 HOURS
113000 (MICRO)G/L MOSSAMBICUS
FRESH WATER
PERSISTENCE AND DEGRADABILITY: THERE IS NO DATA AVAILABLE.
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
NAPHTHA (PETROLEUM), 2.2 TO 5.2 10 TO 2500 HIGH
HYDROTREATED LIGHT
ACETONE -0.23 LOW
N-HEXANE 4 501.187 HIGH
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD COMPLY WITH
THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL LEGISLATION
AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF SURPLUS AND
NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL CONTRACTOR. WASTE
SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS FULLY COMPLIANT
WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION. WASTE PACKAGING
SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE CONSIDERED WHEN
RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED
OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING EMPTY CONTAINERS THAT
HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY CONTAINERS OR LINERS MAY RETAIN
SOME PRODUCT RESIDUES. VAPOR FROM PRODUCT RESIDUES MAY CREATE A HIGHLY
FLAMMABLE OR EXPLOSIVE ATMOSPHERE INSIDE THE CONTAINER. DO NOT CUT, WELD
OR GRIND USED CONTAINERS UNLESS THEY HAVE BEEN CLEANED THOROUGHLY
INTERNALLY. AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT
WITH SOIL, WATERWAYS, DRAINS AND SEWERS.
UNITED STATES - RCRA TOXIC HAZARDOUS WASTE "U" LIST:
INGREDIENT CAS # STATUS REFERENCE NUMBER
ACETONE 67-64-1 LISTED U002
| SECTION 14. TRANSPORT INFORMATION | |
DOT CLASSIFICATION IMDG IATA
UN NUMBER UN1993 UN1993 UN1993
UN PROPER FLAMMABLE LIQUIDS, FLAMMABLE LIQUIDS, FLAMMABLE LIQUIDS,
SHIPPING NAME N.O.S. (NAPHTHA N.O.S. (NAPHTHA N.O.S. (NAPHTHA
(PETROLEUM), (PETROLEUM), (PETROLEUM),
HYDROTREATED LIGHT, HYDROTREATED HYDROTREATED LIGHT,
ACETONE) LIGHT, ACETONE) ACETONE)
RQ (ACETONE)
TRANSPORT 3 3 3
HAZARD
CLASS(ES) FLAMMABLE LIQUID, CLASS 3 - CLASS 3, FLAMMABLE
CLASS/DIVISION FLAMMABLE LIQUIDS LIQUIDS
3.1, 3.2, 3.3
PACKING GROUP II II II
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL REPORTABLE
INFORMATION QUANTITY:
19230.8 LBS /
8730.8 KG
[3203.4 GAL /
12126.1 L]
PACKAGE SIZES
SHIPPED IN
QUANTITIES LESS
THAN THE PRODUCT
REPORTABLE
QUANTITY ARE
NOT SUBJECT TO
THE RQ
(REPORTABLE
QUANTITY)
TRANSPORTATION
REQUIREMENTS.
AERG: 128
DOT-RQ DETAILS:
ACETONE: 5000 LBS / 2270 KG [758.12 GAL / 2869.8 L]
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE. PROTECT FROM FREEZING. FREEZING WILL DAMAGE PRODUCT
AND RENDER IT UNUSABLE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION: NOT DETERMINED
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
DEA LIST I CHEMICALS (PRECURSOR CHEMICALS): NOT LISTED
DEA LIST II CHEMICALS (ESSENTIAL CHEMICALS): LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION:
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE (ACUTE) (CHRONIC)
OF HEALTH HEALTH
PRESSURE HAZARD HAZARD
NAPHTHA 60 - 100 YES. NO. NO. NO. NO.
(PETROLEUM),
HYDROTREATED
LIGHT
ACETONE 10 - 30 YES. NO. NO. YES. NO.
N-HEXANE 1 - 5 YES. NO. NO. YES. YES.
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING REQUIREMENTS:
N-HEXANE 110-54-3 1 - 5
SUPPLIER NOTIFICATION:
N-HEXANE 110-54-3 1 - 5
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: N-HEXANE; ACETONE
NEW YORK:
THE FOLLOWING COMPONENTS ARE LISTED: N-HEXANE; ACETONE
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED: N-HEXANE; ACETONE
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED: N-HEXANE; ACETONE
CALIFORNIA PROP. 65: NO PRODUCTS WERE FOUND.
INTERNATIONAL LISTS:
NATIONAL INVENTORY:
AUSTRALIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CANADA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
CHINA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
EUROPE: ALL COMPONENTS ARE LISTED OR EXEMPTED.
MALAYSIA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
NEW ZEALAND: ALL COMPONENTS ARE LISTED OR EXEMPTED.
PHILIPPINES: ALL COMPONENTS ARE LISTED OR EXEMPTED.
REPUBLIC OF KOREA: ALL COMPONENTS ARE LISTED OR EXEMPTED.
| SECTION 16. OTHER INFORMATION | |
HISTORY:
DATE OF ISSUE MM/DD/YYYY: 11/30/2015
DATE OF PREVIOUS ISSUE: 01/30/2015
VERSION: 1.1
REVISED SECTION(S): 2, 8, 16.
PREPARED BY: KMK REGULATORY SERVICES INC.
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS,
1973 AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.
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