SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. 3M(TM) FIRE BLOCK FOAM FB-FOAM 08/08/19 3M SAFETY DATA SHEET COPYRIGHT, 2019, 3M COMPANY. ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT: (1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN AGREEMENT IS OBTAINED FROM 3M, AND (2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED WITH THE INTENTION OF EARNING A PROFIT THEREON. DOCUMENT GROUP: 28-4642-6 VERSION NUMBER: 5.03 ISSUE DATE: 08/08/19 SUPERCEDES DATE: 07/26/18
1.1. PRODUCT IDENTIFIER: 3M(TM) FIRE BLOCK FOAM FB-FOAM PRODUCT IDENTIFICATION NUMBERS: 98-0400-5614-9, 98-0400-5632-1, 98-0441-1020-7 7100006734, 7010401353 1.2. RECOMMENDED USE AND RESTRICTIONS ON USE: RECOMMENDED USE: SEALANT 1.3. SUPPLIER'S DETAILS: MANUFACTURER: 3M DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION ADDRESS: 3M CENTER ST. PAUL, MN 55144-1000 USA TELEPHONE: 1-888-3M HELPS (1-888-364-3577) 1.4. EMERGENCY TELEPHONE NUMBER: 1-800-364-3577 OR (651) 737-6501 (24 HOURS)
2.1. HAZARD CLASSIFICATION: FLAMMABLE AEROSOL: CATEGORY 1. GAS UNDER PRESSURE: LIQUEFIED GAS. ACUTE TOXICITY (INHALATION): CATEGORY 4. SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A. SKIN CORROSION/IRRITATION: CATEGORY 2. RESPIRATORY SENSITIZER: CATEGORY 1. SKIN SENSITIZER: CATEGORY 1. REPRODUCTIVE TOXICITY: LACTATION. SIMPLE ASPHYXIANT. SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 1. SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): CATEGORY 3. SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1. 2.2. LABEL ELEMENTS: SIGNAL WORD: DANGER SYMBOLS: FLAME GAS CYLINDER EXCLAMATION MARK HEALTH HAZARD PICTOGRAMS: FLAME GAS CYLINDER EXCLAMATION MARK HEALTH HAZARD HAZARD STATEMENTS: EXTREMELY FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED. CAUSES SERIOUS EYE IRRITATION. CAUSES SKIN IRRITATION. MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED. MAY CAUSE AN ALLERGIC SKIN REACTION. HARMFUL IF INHALED. MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE HARM TO BREAST-FED CHILDREN. MAY DISPLACE OXYGEN AND CAUSE RAPID SUFFOCATION. CAUSES DAMAGE TO ORGANS: CARDIOVASCULAR SYSTEM | CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE: RESPIRATORY SYSTEM PRECAUTIONARY STATEMENTS: GENERAL: KEEP OUT OF REACH OF CHILDREN. PREVENTION: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. AVOID CONTACT DURING PREGNANCY/WHILE NURSING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION. WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. RESPONSE: IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IF EXPERIENCING RESPIRATORY SYMPTOMS: CALL A POISON CENTER OR DOCTOR/PHYSICIAN. IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION. IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER. IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE. IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. SPECIFIC TREATMENT (SEE NOTES TO PHYSICIAN ON THIS LABEL). STORAGE: PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F. KEEP CONTAINER TIGHTLY CLOSED. STORE LOCKED UP IN A WELL-VENTILATED PLACE. DISPOSAL: DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS. NOTES TO PHYSICIAN: EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY. SUPPLEMENTAL INFORMATION: PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES. INTENTIONAL CONCENTRATION AND INHALATION MAY BE HARMFUL OR FATAL.
INGREDIENT C.A.S. NO. % BY WT POLYOL BLEND (NJTS REG. NO. TRADE SECRET* 40 - 70 TRADE SECRET * 04499600-7192) ALKANES, C14-C17, CHLORO 85535-85-9 10 - 30 TRADE SECRET * DIMETHYL ETHER 115-10-6 5 - 10 TRADE SECRET * ISOBUTANE 75-28-5 5 - 10 TRADE SECRET * 4,4' DIPHENYLMETHANE 101-68-8 3 - 7 TRADE SECRET * DIISOCYANTE (MDI) HIGHER OLIGOMERS OF MDI (PMDI) 9016-87-9 3 - 7 TRADE SECRET * PROPANE 74-98-6 1 - 5 TRADE SECRET * NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER. *THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
4.1. DESCRIPTION OF FIRST AID MEASURES: INHALATION: REMOVE PERSON TO FRESH AIR. GET MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION. EYE CONTACT: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION. IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION. 4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED: SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS. 4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT REQUIRED: EXPOSURE MAY INCREASE MYOCARDIAL IRRITABILITY. DO NOT ADMINISTER SYMPATHOMIMETIC DRUGS UNLESS ABSOLUTELY NECESSARY.
5.1. SUITABLE EXTINGUISHING MEDIA: USE A FIRE FIGHTING AGENT SUITABLE FOR THE SURROUNDING FIRE. 5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE: CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: SUBSTANCE CONDITION FORMALDEHYDE DURING COMBUSTION CARBON MONOXIDE DURING COMBUSTION CARBON DIOXIDE DURING COMBUSTION HYDROGEN CHLORIDE DURING COMBUSTION HYDROGEN CYANIDE DURING COMBUSTION OXIDES OF NITROGEN DURING COMBUSTION 5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS: WATER MAY NOT EFFECTIVELY EXTINGUISH FIRE; HOWEVER, IT SHOULD BE USED TO KEEP FIRE-EXPOSED CONTAINERS AND SURFACES COOL AND PREVENT EXPLOSIVE RUPTURE.
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: EVACUATE AREA. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. USE ONLY NON-SPARKING TOOLS. VENTILATE THE AREA WITH FRESH AIR. WARNING! A MOTOR COULD BE AN IGNITION SOURCE AND COULD CAUSE FLAMMABLE GASES OR VAPORS IN THE SPILL AREA TO BURN OR EXPLODE. REFER TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT. 6.2. ENVIRONMENTAL PRECAUTIONS: FOR LARGER SPILLS, COVER DRAINS AND BUILD DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER. 6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP: CONTAIN SPILL. COVER SPILL AREA WITH A FIRE-EXTINGUISHING FOAM. AN APPROPRIATE AQUEOUS FILM FORMING FOAM (AFFF) IS RECOMMENDED. POUR ISOCYANATE DECONTAMINANT SOLUTION (90% WATER, 8% CONCENTRATED AMMONIA, 2% DETERGENT) ON SPILL AND ALLOW TO REACT FOR 10 MINUTES. OR POUR WATER ON SPILL AND ALLOW TO REACT FOR MORE THAN 30 MINUTES. COVER WITH ABSORBENT MATERIAL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE USING NONSPARKING TOOLS. PLACE IN A CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES, BUT DO NOT SEAL THE CONTAINER FOR 48 HOURS TO AVOID PRESSURE BUILD-UP. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
7.1. PRECAUTIONS FOR SAFE HANDLING: DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. KEEP OUT OF REACH OF CHILDREN. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. AVOID CONTACT DURING PREGNANCY/WHILE NURSING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID ETC.) 7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50C/122F. STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM STRONG BASES. STORE AWAY FROM OXIDIZING AGENTS. STORE AWAY FROM AMINES.
8.1. CONTROL PARAMETERS: OCCUPATIONAL EXPOSURE LIMITS: IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT. INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS 4,4' DIPHENYLMETHANE 101-68-8 ACGIH TWA: 0.005 PPM DIISOCYANTE (MDI) 4,4' DIPHENYLMETHANE 101-68-8 OSHA CEIL: DIISOCYANTE (MDI) 0.2 MG/M3 (0.02 PPM) DIMETHYL ETHER 115-10-6 AIHA TWA: 1880 MG/M3 (1000 PPM) PROPANE 74-98-6 ACGIH LIMIT VALUE SIMPLE NOT ESTABLISHED: ASPHYXIANT PROPANE 74-98-6 OSHA TWA: 1800 MG/M3 (1000 PPM) ISOBUTANE 75-28-5 ACGIH STEL: 1000 PPM NATURAL GAS 75-28-5 ACGIH LIMIT VALUE SIMPLE NOT ESTABLISHED: ASPHYXIANT ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES OSHA: UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION TWA: TIME-WEIGHTED-AVERAGE STEL: SHORT TERM EXPOSURE LIMIT CEIL: CEILING 8.2. EXPOSURE CONTROLS: 8.2.1. ENGINEERING CONTROLS: DO NOT REMAIN IN AREA WHERE AVAILABLE OXYGEN MAY BE REDUCED. USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL DUST/FUME/GAS/ MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT. 8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE): EYE/FACE PROTECTION: SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED: FULL FACE SHIELD INDIRECT VENTED GOGGLES SKIN/HAND PROTECTION: SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION, PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS. CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING. NOTE: NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE DEXTERITY. GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED: FLUOROELASTOMER POLYMER LAMINATE IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED: APRON - POLYMER LAMINATE RESPIRATORY PROTECTION: AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED. IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE: HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR ORGANIC VAPORS AND PARTICULATES HALF FACEPIECE OR FULL FACEPIECE SUPPLIED-AIR RESPIRATOR FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH YOUR RESPIRATOR MANUFACTURER.
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES: APPEARANCE: PHYSICAL STATE: LIQUID COLOR: OFF-WHITE, YELLOW ODOR: SLIGHT HYDROCARBON ODOR THRESHOLD: NO DATA AVAILABLE PH: NO DATA AVAILABLE MELTING POINT: NO DATA AVAILABLE BOILING POINT: -33.3 - -11.7 DEG. C [DETAILS.LIQUEFIED PETROLEUM GAS (HYDROCARBON, HC) COMPONENTS BOIL BETWEEN -33.3 TO -11.7C. OTHER COMPONENTS BOIL AT TEMPERATURES GREATER THAN 93.3C] FLASH POINT: -156 DEG. F [TEST METHOD: ESTIMATED] EVAPORATION RATE: NO DATA AVAILABLE FLAMMABILITY (SOLID, GAS): NOT APPLICABLE FLAMMABLE LIMITS(LEL): NO DATA AVAILABLE FLAMMABLE LIMITS(UEL): NO DATA AVAILABLE VAPOR PRESSURE: >/=345 KPA [DETAILS: CONTENTS UNDER PRESSURE HAVE VAPOR PRESSURE GREATER THAN 345KPA. AFTER RELEASE FROM CONTAINER, THE PRESSURE IS VERY LOW.] VAPOR DENSITY: NOT APPLICABLE DENSITY: 1.1 G/ML SPECIFIC GRAVITY: 1.1 [REF STD: WATER=1] SOLUBILITY IN WATER: NIL [DETAILS:REACTS SLOWLY WITH WATER DURING CURE] SOLUBILITY-NON-WATER: NO DATA AVAILABLE PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE VISCOSITY: NO DATA AVAILABLE VOC LESS H2O & EXEMPT SOLVENTS: 165 G/L
10.1. REACTIVITY: THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION. 10.2. CHEMICAL STABILITY: STABLE. DO NOT STORE ABOVE 50C 10.3. POSSIBILITY OF HAZARDOUS REACTIONS: HAZARDOUS POLYMERIZATION WILL NOT OCCUR. 10.4. CONDITIONS TO AVOID: HEAT 10.5. INCOMPATIBLE MATERIALS: ALCOHOLS STRONG BASES AMINES STRONG OXIDIZING AGENTS 10.6. HAZARDOUS DECOMPOSITION PRODUCTS: SUBSTANCE CONDITION NONE KNOWN. REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING COMBUSTION.
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE. 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS: SIGNS AND SYMPTOMS OF EXPOSURE: BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY PRODUCE THE FOLLOWING HEALTH EFFECTS: INHALATION: HARMFUL IF INHALED. SIMPLE ASPHYXIATION: SIGNS/SYMPTOMS MAY INCLUDE INCREASED HEART RATE, RAPID RESPIRATIONS, DROWSINESS, HEADACHE, INCOORDINATION, ALTERED JUDGEMENT, NAUSEA, VOMITING, LETHARGY, SEIZURES, COMA, AND MAY BE FATAL. RESPIRATORY TRACT IRRITATION: SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE, HOARSENESS, AND NOSE AND THROAT PAIN. ALLERGIC RESPIRATORY REACTION: SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND TIGHTNESS OF CHEST. MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW). SKIN CONTACT: SKIN IRRITATION: SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS, CRACKING, BLISTERING, AND PAIN. ALLERGIC SKIN REACTION (NON-PHOTO INDUCED): SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING. EYE CONTACT: SEVERE EYE IRRITATION: SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING, CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION. INGESTION: GASTROINTESTINAL IRRITATION: SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING AND DIARRHEA. MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW). ADDITIONAL HEALTH EFFECTS: SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS: CENTRAL NERVOUS SYSTEM (CNS) DEPRESSION: SIGNS/SYMPTOMS MAY INCLUDE HEADACHE, DIZZINESS, DROWSINESS, INCOORDINATION, NAUSEA, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS, AND UNCONSCIOUSNESS. SINGLE EXPOSURE, ABOVE RECOMMENDED GUIDELINES, MAY CAUSE: CARDIAC SENSITIZATION: SIGNS/SYMPTOMS MAY INCLUDE IRREGULAR HEARTBEAT (ARRHYTHMIA), FAINTNESS, CHEST PAIN, AND MAY BE FATAL. PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS: RESPIRATORY EFFECTS: SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS, WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE. REPRODUCTIVE/DEVELOPMENTAL TOXICITY: CONTAINS A CHEMICAL OR CHEMICALS WHICH MAY INTERFERE WITH LACTATION OR BE HARMFUL TO BREASTFED CHILDREN. ADDITIONAL INFORMATION: PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES. TOXICOLOGICAL DATA: IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION. ACUTE TOXICITY: NAME ROUTE SPECIES VALUE OVERALL PRODUCT INHALATION- NO DATA AVAILABLE; DUST/MIST CALCULATED ATE1 - 5 MG/L (4 HR) OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED ATE >5,000 MG/KG ALKANES, C14-C17, DERMAL ESTIMATED TO BE CHLORO >5,000 MG/KG ALKANES, C14-C17, INHALATION- ESTIMATED TO BE CHLORO DUST/MIST >12.5 MG/L ALKANES, C14-C17, INHALATION- ESTIMATED TO BE >50 MG/L CHLORO VAPOR ALKANES, C14-C17, INGESTION ESTIMATED TO BE CHLORO >5,000 MG/KG ISOBUTANE INHALATION- RAT LC50: 276,000 PPM GAS (4 HOURS) DIMETHYL ETHER INHALATION- RAT LC50: 164,000 PPM GAS (4 HOURS) PROPANE INHALATION- RAT LC50: >200,000 PPM GAS (4 HOURS) 4,4' DIPHENYLMETHANE DERMAL RABBIT LD50: >5,000 MG/KG DIISOCYANTE (MDI) HIGHER OLIGOMERS OF DERMAL RABBIT LD50: >5,000 MG/KG MDI (PMDI) 4,4' DIPHENYLMETHANE INHALATION- RAT LC50: 0.368 MG/L DIISOCYANTE (MDI) DUST/MIST (4 HOURS) 4,4' DIPHENYLMETHANE INGESTION RAT LD50: 31,600 MG/KG DIISOCYANTE (MDI) HIGHER OLIGOMERS OF INHALATION- RAT LC50: 0.368 MG/L MDI (PMDI) DUST/MIST (4 HOURS) HIGHER OLIGOMERS OF INGESTION RAT LD50: 31,600 MG/KG MDI (PMDI) ATE = ACUTE TOXICITY ESTIMATE SKIN CORROSION/IRRITATION: NAME SPECIES VALUE ISOBUTANE PROFESSIONAL NO SIGNIFICANT IRRITATION JUDGEMENT PROPANE RABBIT MINIMAL IRRITATION 4,4' DIPHENYLMETHANE OFFICIAL IRRITANT DIISOCYANTE (MDI) CLASSIFICATION HIGHER OLIGOMERS OF MDI OFFICIAL IRRITANT (PMDI) CLASSIFICATION SERIOUS EYE DAMAGE/IRRITATION: NAME SPECIES VALUE ISOBUTANE PROFESSIONAL NO SIGNIFICANT IRRITATION JUDGEMENT PROPANE RABBIT MILD IRRITANT 4,4' DIPHENYLMETHANE OFFICIAL SEVERE IRRITANT DIISOCYANTE (MDI) CLASSIFICATION HIGHER OLIGOMERS OF MDI OFFICIAL SEVERE IRRITANT (PMDI) CLASSIFICATION SKIN SENSITIZATION: NAME SPECIES VALUE 4,4' DIPHENYLMETHANE OFFICIAL SENSITIZING DIISOCYANTE (MDI) CLASSIFICATION HIGHER OLIGOMERS OF MDI OFFICIAL SENSITIZING (PMDI) CLASSIFICATION RESPIRATORY SENSITIZATION: NAME SPECIES VALUE 4,4' DIPHENYLMETHANE HUMAN SENSITIZING DIISOCYANTE (MDI) HIGHER OLIGOMERS OF MDI HUMAN SENSITIZING (PMDI) GERM CELL MUTAGENICITY: NAME ROUTE VALUE ISOBUTANE IN VITRO NOT MUTAGENIC DIMETHYL ETHER IN VITRO NOT MUTAGENIC DIMETHYL ETHER IN VIVO NOT MUTAGENIC PROPANE IN VITRO NOT MUTAGENIC 4,4' DIPHENYLMETHANE IN VITRO SOME POSITIVE DATA EXIST, BUT DIISOCYANTE (MDI) THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION HIGHER OLIGOMERS OF MDI IN VITRO SOME POSITIVE DATA EXIST, BUT (PMDI) THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION CARCINOGENICITY: NAME ROUTE SPECIES VALUE DIMETHYL ETHER INHALATION RAT NOT CARCINOGENIC 4,4' DIPHENYLMETHANE INHALATION RAT SOME POSITIVE DATA EXIST, DIISOCYANTE (MDI) BUT THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION HIGHER OLIGOMERS OF INHALATION RAT SOME POSITIVE DATA EXIST, BUT MDI (PMDI) BUT THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION REPRODUCTIVE TOXICITY: REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS: NAME ROUTE VALUE DIMETHYL ETHER INHALATION NOT CLASSIFIED FOR DEVELOPMENT 4,4' DIPHENYLMETHANE INHALATION NOT CLASSIFIED FOR DEVELOPMENT DIISOCYANTE (MDI) HIGHER OLIGOMERS OF MDI INHALATION NOT CLASSIFIED FOR DEVELOPMENT (PMDI) NAME SPECIES TEST RESULT EXPOSURE DURATION DIMETHYL ETHER RAT NOAEL: DURING ORGANOGENESIS 40,000 PPM 4,4' DIPHENYLMETHANE RAT NOAEL: DURING ORGANOGENESIS DIISOCYANTE (MDI) 0.004 MG/L HIGHER OLIGOMERS OF MDI RAT NOAEL: DURING ORGANOGENESIS (PMDI) 0.004 MG/L TARGET ORGAN(S): SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE: NAME ROUTE TARGET ORGAN(S) VALUE ISOBUTANE INHALATION CARDIAC CAUSES DAMAGE TO ORGANS SENSITIZATION ISOBUTANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR SYSTEM DEPRESSION DIZZINESS ISOBUTANE INHALATION RESPIRATORY NOT CLASSIFIED IRRITATION DIMETHYL ETHER INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR SYSTEM DEPRESSION DIZZINESS DIMETHYL ETHER INHALATION CARDIAC SOME POSITIVE DATA SENSITIZATION EXIST, BUT THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION PROPANE INHALATION CARDIAC CAUSES DAMAGE TO ORGANS SENSITIZATION PROPANE INHALATION CENTRAL NERVOUS MAY CAUSE DROWSINESS OR SYSTEM DEPRESSION DIZZINESS PROPANE INHALATION RESPIRATORY NOT CLASSIFIED IRRITATION 4,4' INHALATION RESPIRATORY MAY CAUSE RESPIRATORY DIPHENYLMETHANE IRRITATION IRRITATION DIISOCYANTE (MDI) HIGHER OLIGOMERS INHALATION RESPIRATORY MAY CAUSE RESPIRATORY OF MDI (PMDI) IRRITATION IRRITATION NAME SPECIES TEST RESULT EXPOSURE DURATION ISOBUTANE MULTIPLE NOAEL: ANIMAL NOT AVAILABLE SPECIES ISOBUTANE HUMAN AND NOAEL: ANIMAL NOT AVAILABLE ISOBUTANE MOUSE NOAEL: NOT AVAILABLE DIMETHYL ETHER RAT LOAEL: 30 MINUTES 10,000 PPM DIMETHYL ETHER DOG NOAEL: 5 MINUTES 100,000 PPM PROPANE HUMAN NOAEL: NOT AVAILABLE PROPANE HUMAN NOAEL: NOT AVAILABLE PROPANE HUMAN NOAEL: NOT AVAILABLE 4,4' DIPHENYLMETHANE OFFICIAL NOAEL: DIISOCYANTE (MDI) CLASSIFICATION NOT AVAILABLE HIGHER OLIGOMERS OF OFFICIAL NOAEL: MDI (PMDI) CLASSIFICATION NOT AVAILABLE SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NAME ROUTE TARGET ORGAN(S) VALUE ISOBUTANE INHALATION KIDNEY AND/OR NOT CLASSIFIED BLADDER DIMETHYL ETHER INHALATION HEMATOPOIETIC NOT CLASSIFIED SYSTEM DIMETHYL ETHER INHALATION LIVER NOT CLASSIFIED 4,4' DIPHENYLMETHANE INHALATION RESPIRATORY SYSTEM CAUSES DAMAGE TO DIISOCYANTE (MDI) ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE HIGHER OLIGOMERS OF INHALATION RESPIRATORY SYSTEM CAUSES DAMAGE TO MDI (PMDI) ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE NAME SPECIES TEST RESULT EXPOSURE DURATION ISOBUTANE RAT NOAEL: 4,500 PPM 13 WEEKS DIMETHYL ETHER RAT NOAEL: 25,000 PPM 2 YEARS DIMETHYL ETHER RAT NOAEL: 20,000 PPM 30 WEEKS 4,4' DIPHENYLMETHANE RAT LOAEL: 0.004 MG/L 13 WEEKS DIISOCYANTE (MDI) HIGHER OLIGOMERS OF RAT LOAEL: 0.004 MG/L 13 WEEKS MDI (PMDI) ASPIRATION HAZARD: FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION. 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15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION. EPCRA 311/312 HAZARD CLASSIFICATIONS: PHYSICAL HAZARDS: FLAMMABLE (GASES, AEROSOLS, LIQUIDS, OR SOLIDS) GAS UNDER PRESSURE HEALTH HAZARDS: ACUTE TOXICITY REPRODUCTIVE TOXICITY RESPIRATORY OR SKIN SENSITIZATION SERIOUS EYE DAMAGE OR EYE IRRITATION SIMPLE ASPHYXIANT SKIN CORROSION OR IRRITATION SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE) SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT SECTION AND 40 CFR PART 372 (EPCRA): INGREDIENT C.A.S. NO % BY WT 4,4' DIPHENYLMETHANE DIISOCYANTE (MDI) 101-68-8 TRADE SECRET 3 - 7 4,4' DIPHENYLMETHANE DIISOCYANTE (MDI) 101-68-8 3 - 7 (BENZENE,1,1'-METHYLENEBIS[4-ISOCYANATO-) 4,4' DIPHENYLMETHANE DIISOCYANTE (MDI) 101-68-8 3 - 7 (DIISOCYANATES (CERTAIN CHEMICALS ONLY)) HIGHER OLIGOMERS OF MDI (PMDI) 9016-87-9 TRADE SECRET 3 - 7 HIGHER OLIGOMERS OF MDI (PMDI) 9016-87-9 3 - 7 (DIISOCYANATES (CERTAIN CHEMICALS ONLY)) THIS MATERIAL CONTAINS A CHEMICAL WHICH REQUIRES EXPORT NOTIFICATION UNDER TSCA SECTION 12[B]: INGREDIENT C.A.S. NO REGULATION STATUS (CATEGORY IF APPLICABLE) ALKANES, C14-C17, CHLORO 85535-85-9 TOXIC SUBSTANCES APPLICABLE CONTROL ACT (TSCA) 5 SNUR OR CONSENT ORDER CHEMICALS THIS MATERIAL CONTAINS A CHEMICAL SUBJECT TO A PROPOSED EPA SIGNIFICANT NEW USE RULE (TSCA SECTION 5): INGREDIENT (CATEGORY IF APPLICABLE) C.A.S. NO REFERENCE ALKANES, C14-C17, CHLORO 85535-85-9 40 CFR 721.11076 15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION. 15.3. CHEMICAL INVENTORIES: THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME (NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION. THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE NOTIFICATION REQUIREMENTS OF CEPA. THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY. CONTACT 3M FOR MORE INFORMATION. 15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION. THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200.
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