| Common Name: | PURELL ADVANCED HYGIENIC HAND RUB |
| Manufacturer: | GOJO INDUSTRIES UK |
| SDS Revision Date: | 2/10/2015 |
| SDS Format: | GHS-EU |
| Item Number(s): | 19MR10 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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GOJO(R*)
SAFETY DATA SHEET
ACCORDING TO REGULATION (EC) NO. 1907/2006
PURELL(R*) ADVANCED HYGIENIC HAND RUB
VERSION: 1.3
REVISION DATE: 10.02.2015
MSDS NUMBER: 36406-00004
DATE OF LAST ISSUE: 19.12.2014
DATE OF FIRST ISSUE: 11.12.2014
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1 PRODUCT IDENTIFIER:
TRADE NAME: PURELL(R*) ADVANCED HYGIENIC HAND RUB
1.2 RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: HAND SANITIZER
RECOMMENDED RESTRICTIONS ON USE:
THIS IS A PERSONAL CARE OR COSMETIC PRODUCT THAT IS SAFE FOR CONSUMERS AND
OTHER USERS UNDER NORMAL AND REASONABLY FORESEEABLE USE. COSMETICS AND
CONSUMER PRODUCTS, SPECIFICALLY DEFINED BY REGULATIONS AROUND THE WORLD,
ARE EXEMPT FROM THE REQUIREMENT OF AN SDS FOR THE CONSUMER. WHILE THIS
MATERIAL IS NOT CONSIDERED HAZARDOUS, THIS SDS CONTAINS VALUABLE
INFORMATION CRITICAL TO THE SAFE HANDLING AND PROPER USE OF THE PRODUCT FOR
INDUSTRIAL WORKPLACE CONDITIONS AS WELL AS UNUSUAL AND UNINTENDED EXPOSURES
SUCH AS LARGE SPILLS. THIS SDS SHOULD BE RETAINED AND AVAILABLE FOR
EMPLOYEES AND OTHER USERS OF THIS PRODUCT. FOR SPECIFIC INTENDED-USE
GUIDANCE, PLEASE REFER TO THE INFORMATION PROVIDED ON THE PACKAGE OR
INSTRUCTION SHEET.
1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
GOJO INDUSTRIES-EUROPE LTD.
UNITS 5 & 6, STRATUS PARK
MK10 0DE BRINKLOW, MILTON KEYNES
TELEPHONE: +44(0) 1908588444
TELEFAX: +44(0) 1908588445
E-MAIL ADDRESS OF PERSON RESPONSIBLE FOR THE SDS: INFO@GOJO.CO.UK
1.4 EMERGENCY TELEPHONE NUMBER: +44(0) 08445605135
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (REGULATION (EC) NO 1272/2008):
FLAMMABLE LIQUIDS, CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOUR.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
CLASSIFICATION (67/548/EEC, 1999/45/EC):
FLAMMABLE:
R10: FLAMMABLE.
IRRITANT:
R36: IRRITATING TO EYES.
2.2 LABEL ELEMENTS:
LABELLING (REGULATION (EC) NO 1272/2008):
HAZARD PICTOGRAMS:
FLAME
EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
H226: FLAMMABLE LIQUID AND VAPOUR.
H319: CAUSES SERIOUS EYE IRRITATION.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/ FACE PROTECTION.
RESPONSE:
P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P337 + P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
2.3 OTHER HAZARDS: VAPOURS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2 MIXTURES:
HAZARDOUS COMPONENTS:
CHEMICAL CAS-NO. CLASSIFICATION CLASSIFICATION CONCENTRATION
NAME EC-NO. (67/548/EEC) (REGULATION (%)
REGISTRATION (EC) NO
NUMBER 1272/2008)
ETHANOL 64-17-5 F; R11 FLAM. LIQ. 2; >= 50 - <70
200-578-6 XI; R36 H225
EYE IRRIT. 2;
H319
PROPAN-2-OL 67-63-0 F; R11 FLAM. LIQ. 2; >= 3 - <10
200-661-7 XI; R36 R67 H225
EYE IRRIT. 2;
H319
STOT SE 3;
H336
FOR EXPLANATION OF ABBREVIATIONS SEE SECTION 16.
| SECTION 4: FIRST AID MEASURES | |
4.1 DESCRIPTION OF FIRST AID MEASURES:
GENERAL ADVICE:
IN THE CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE
IMMEDIATELY.
WHEN SYMPTOMS PERSIST OR IN ALL CASES OF DOUBT SEEK MEDICAL ADVICE.
PROTECTION OF FIRST-AIDERS:
FIRST AID RESPONDERS SHOULD PAY ATTENTION TO SELF-PROTECTION, AND USE THE
RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT WHEN THE POTENTIAL FOR EXPOSURE
EXISTS.
IF INHALED:
IF INHALED, REMOVE TO FRESH AIR.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
IN CASE OF SKIN CONTACT:
WASH WITH WATER AND SOAP AS A PRECAUTION.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
IN CASE OF EYE CONTACT:
IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES.
IF EASY TO DO, REMOVE CONTACT LENS, IF WORN.
GET MEDICAL ATTENTION.
IF SWALLOWED:
IF SWALLOWED, DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
RINSE MOUTH THOROUGHLY WITH WATER.
4.2 MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
RISKS: CAUSES SERIOUS EYE IRRITATION.
4.3 INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
TREATMENT: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1 EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
WATER SPRAY
ALCOHOL-RESISTANT FOAM
DRY CHEMICAL
CARBON DIOXIDE (CO2)
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
SPECIFIC HAZARDS DURING FIRE-FIGHTING:
DO NOT USE A SOLID WATER STREAM AS IT MAY SCATTER AND SPREAD FIRE.
FLASH BACK POSSIBLE OVER CONSIDERABLE DISTANCE.
VAPOURS MAY FORM EXPLOSIVE MIXTURES WITH AIR.
EXPOSURE TO COMBUSTION PRODUCTS MAY BE A HAZARD TO HEALTH.
HAZARDOUS COMBUSTION PRODUCTS: CARBON OXIDES
5.3 ADVICE FOR FIREFIGHTERS:
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
USE PERSONAL PROTECTIVE EQUIPMENT.
SPECIFIC EXTINGUISHING METHODS:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
USE WATER SPRAY TO COOL UNOPENED CONTAINERS.
REMOVE UNDAMAGED CONTAINERS FROM FIRE AREA IF IT IS SAFE TO DO SO.
EVACUATE AREA.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
REMOVE ALL SOURCES OF IGNITION.
USE PERSONAL PROTECTIVE EQUIPMENT.
FOLLOW SAFE HANDLING ADVICE AND PERSONAL PROTECTIVE EQUIPMENT
RECOMMENDATIONS.
6.2 ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
PREVENT SPREADING OVER A WIDE AREA (E.G. BY CONTAINMENT OR OIL BARRIERS).
RETAIN AND DISPOSE OF CONTAMINATED WASH WATER.
LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE
CONTAINED.
6.3 METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CLEANING UP:
NON-SPARKING TOOLS SHOULD BE USED.
SOAK UP WITH INERT ABSORBENT MATERIAL.
SUPPRESS (KNOCK DOWN) GASES/VAPOURS/MISTS WITH A WATER SPRAY JET.
FOR LARGE SPILLS, PROVIDE DYKING OR OTHER APPROPRIATE CONTAINMENT TO KEEP
MATERIAL FROM SPREADING. IF DYKED MATERIAL CAN BE PUMPED, STORE RECOVERED
MATERIAL IN APPROPRIATE CONTAINER. CLEAN UP REMAINING MATERIALS FROM SPILL
WITH SUITABLE ABSORBENT.
LOCAL OR NATIONAL REGULATIONS MAY APPLY TO RELEASES AND DISPOSAL OF THIS
MATERIAL, AS WELL AS THOSE MATERIALS AND ITEMS EMPLOYED IN THE CLEANUP OF
RELEASES. YOU WILL NEED TO DETERMINE WHICH REGULATIONS ARE APPLICABLE.
SECTIONS 13 AND 15 OF THIS SDS PROVIDE INFORMATION REGARDING CERTAIN LOCAL
OR NATIONAL REQUIREMENTS.
6.4 REFERENCE TO OTHER SECTIONS:
SEE SECTIONS: 7, 8, 11, 12 AND 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1 PRECAUTIONS FOR SAFE HANDLING:
TECHNICAL MEASURES:
SEE ENGINEERING MEASURES UNDER EXPOSURE CONTROLS/PERSONAL PROTECTION
SECTION.
LOCAL/TOTAL VENTILATION:
USE WITH LOCAL EXHAUST VENTILATION.
USE ONLY IN AN AREA EQUIPPED WITH EXPLOSION PROOF EXHAUST VENTILATION.
ADVICE ON SAFE HANDLING:
AVOID INHALATION OF VAPOUR OR MIST.
DO NOT SWALLOW.
DO NOT GET IN EYES.
AVOID PROLONGED OR REPEATED CONTACT WITH SKIN.
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
NON-SPARKING TOOLS SHOULD BE USED.
KEEP CONTAINER TIGHTLY CLOSED.
KEEP AWAY FROM HEAT AND SOURCES OF IGNITION.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGES.
TAKE CARE TO PREVENT SPILLS, WASTE AND MINIMIZE RELEASE TO THE ENVIRONMENT.
HYGIENE MEASURES:
ENSURE THAT EYE FLUSHING SYSTEMS AND SAFETY SHOWERS ARE LOCATED CLOSE TO
THE WORKING PLACE. WHEN USING DO NOT EAT, DRINK OR SMOKE. WASH CONTAMINATED
CLOTHING BEFORE RE-USE.
7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS FOR STORAGE AREAS AND CONTAINERS:
KEEP IN PROPERLY LABELLED CONTAINERS. KEEP TIGHTLY CLOSED.
KEEP IN A COOL, WELL-VENTILATED PLACE. STORE IN ACCORDANCE WITH THE
PARTICULAR NATIONAL REGULATIONS. KEEP AWAY FROM HEAT AND SOURCES OF
IGNITION.
ADVICE ON COMMON STORAGE:
DO NOT STORE WITH THE FOLLOWING PRODUCT TYPES:
STRONG OXIDIZING AGENTS
ORGANIC PEROXIDES
FLAMMABLE SOLIDS
PYROPHORIC LIQUIDS
PYROPHORIC SOLIDS
SELF-HEATING SUBSTANCES AND MIXTURES
SUBSTANCES AND MIXTURES, WHICH IN CONTACT WITH WATER, EMIT FLAMMABLE
GASES
EXPLOSIVES
GASES
7.3 SPECIFIC END USE(S):
SPECIFIC USE(S): NO DATA AVAILABLE
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1 CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL PARAMETERS BASIS
(FORM OF
EXPOSURE)
ETHANOL 64-17-5 TWA 1,000 PPM GB EH40
1,920 MG/M3
FURTHER INFORMATION WHERE NO SPECIFIC SHORT-TERM EXPOSURE LIMIT IS
LISTED, A FIGURE THREE TIMES THE LONG-TERM EXPOSURE
SHOULD BE USED
PROPAN-2-OL 67-63-0 TWA 400 PPM GB EH40
999 MG/M3
STEL 500 PPM GB EH40
1,250 MG/M3
DERIVED NO EFFECT LEVEL (DNEL) ACCORDING TO REGULATION (EC) NO. 1907/2006:
ETHANOL:
END USE: WORKERS
EXPOSURE ROUTES: INHALATION
POTENTIAL HEALTH EFFECTS: ACUTE LOCAL EFFECTS
VALUE: 1900 MG/M3
END USE: WORKERS
EXPOSURE ROUTES: SKIN CONTACT
POTENTIAL HEALTH EFFECTS: LONG-TERM SYSTEMIC EFFECTS
VALUE: 343 MG/KG BW/DAY
END USE: WORKERS
EXPOSURE ROUTES: INHALATION
POTENTIAL HEALTH EFFECTS: LONG-TERM SYSTEMIC EFFECTS
VALUE: 950 MG/M3
END USE: CONSUMERS
EXPOSURE ROUTES: INHALATION
POTENTIAL HEALTH EFFECTS: ACUTE LOCAL EFFECTS
VALUE: 950 MG/M3
END USE: CONSUMERS
EXPOSURE ROUTES: SKIN CONTACT
POTENTIAL HEALTH EFFECTS: LONG-TERM SYSTEMIC EFFECTS
VALUE: 206 MG/KG BW/DAY
END USE: CONSUMERS
EXPOSURE ROUTES: INHALATION
POTENTIAL HEALTH EFFECTS: LONG-TERM SYSTEMIC EFFECTS
VALUE: 114 MG/M3
END USE: CONSUMERS
EXPOSURE ROUTES: INGESTION
POTENTIAL HEALTH EFFECTS: LONG-TERM SYSTEMIC EFFECTS
VALUE: 87 MG/KG BW/DAY
PROPAN-2-OL:
END USE: WORKERS
EXPOSURE ROUTES: INHALATION
POTENTIAL HEALTH EFFECTS: LONG-TERM SYSTEMIC EFFECTS
VALUE: 500 MG/M3
END USE: WORKERS
EXPOSURE ROUTES: SKIN CONTACT
POTENTIAL HEALTH EFFECTS: LONG-TERM SYSTEMIC EFFECTS
VALUE: 888 MG/KG BW/DAY
END USE: CONSUMERS
EXPOSURE ROUTES: INHALATION
POTENTIAL HEALTH EFFECTS: LONG-TERM SYSTEMIC EFFECTS
VALUE: 89 MG/M3
END USE: CONSUMERS
EXPOSURE ROUTES: SKIN CONTACT
POTENTIAL HEALTH EFFECTS: LONG-TERM SYSTEMIC EFFECTS
VALUE: 319 MG/KG BW/DAY
END USE: CONSUMERS
EXPOSURE ROUTES: INGESTION
POTENTIAL HEALTH EFFECTS: LONG-TERM SYSTEMIC EFFECTS
VALUE: 26 MG/KG BW/DAY
PREDICTED NO EFFECT CONCENTRATION (PNEC) ACCORDING TO REGULATION (EC) NO.
1907/2006:
ETHANOL:
FRESH WATER:
VALUE: 0.96 MG/L
MARINE WATER:
VALUE: 0.79 MG/L
INTERMITTENT USE/RELEASE:
VALUE: 2.75 MG/L
SEWAGE TREATMENT PLANT:
VALUE: 580 MG/L
FRESH WATER SEDIMENT:
VALUE: 3.6 MG/KG
MARINE SEDIMENT:
VALUE: 2.9 MG/KG
SOIL:
VALUE: 0.63 MG/KG
ORAL:
VALUE: 720 MG/KG
PROPAN-2-OL:
FRESH WATER:
VALUE: 140.9 MG/L
MARINE WATER:
VALUE: 140.9 MG/L
INTERMITTENT USE/RELEASE:
VALUE: 140.9 MG/L
SEWAGE TREATMENT PLANT:
VALUE: 2251 MG/L
FRESH WATER SEDIMENT:
VALUE: 552 MG/KG
MARINE SEDIMENT:
VALUE: 552 MG/KG
SOIL:
VALUE: 28 MG/KG
ORAL:
VALUE: 160 MG/KG
8.2 EXPOSURE CONTROLS:
ENGINEERING MEASURES:
MINIMIZE WORKPLACE EXPOSURE CONCENTRATIONS.
USE ONLY IN AN AREA EQUIPPED WITH EXPLOSION PROOF EXHAUST VENTILATION.
USE WITH LOCAL EXHAUST VENTILATION.
PERSONAL PROTECTIVE EQUIPMENT:
EYE PROTECTION:
WEAR THE FOLLOWING PERSONAL PROTECTIVE EQUIPMENT: SAFETY GOGGLES
HAND PROTECTION:
MATERIAL:
IMPERVIOUS GLOVES
FLAME RETARDANT GLOVES
REMARKS:
CHOOSE GLOVES TO PROTECT HANDS AGAINST CHEMICALS DEPENDING ON THE
CONCENTRATION AND QUANTITY OF THE HAZARDOUS SUBSTANCE AND SPECIFIC TO
PLACE OF WORK. BREAKTHROUGH TIME IS NOT DETERMINED FOR THE PRODUCT.
CHANGE GLOVES OFTEN!
FOR SPECIAL APPLICATIONS, WE RECOMMEND CLARIFYING THE RESISTANCE TO
CHEMICALS OF THE AFOREMENTIONED PROTECTIVE GLOVES WITH THE GLOVE
MANUFACTURER. WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
SKIN AND BODY PROTECTION:
SELECT APPROPRIATE PROTECTIVE CLOTHING BASED ON CHEMICAL RESISTANCE DATA
AND AN ASSESSMENT OF THE LOCAL EXPOSURE POTENTIAL.
WEAR THE FOLLOWING PERSONAL PROTECTIVE EQUIPMENT:
FLAME RETARDANT ANTISTATIC PROTECTIVE CLOTHING.
SKIN CONTACT MUST BE AVOIDED BY USING IMPERVIOUS PROTECTIVE CLOTHING
(GLOVES, APRONS, BOOTS, ETC).
RESPIRATORY PROTECTION:
USE RESPIRATORY PROTECTION UNLESS ADEQUATE LOCAL EXHAUST VENTILATION IS
PROVIDED OR EXPOSURE ASSESSMENT DEMONSTRATES THAT EXPOSURES ARE WITHIN
RECOMMENDED EXPOSURE GUIDELINES.
FILTER TYPE: ORGANIC VAPOUR TYPE (A)
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE: LIQUID
COLOUR: CLEAR
ODOUR: ALCOHOL-LIKE
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: 6.5 - 8.5
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
INITIAL BOILING POINT AND BOILING RANGE: NO DATA AVAILABLE
FLASH POINT: 24 DEG. C
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE
DENSITY: 0.88 G/CM3
SOLUBILITY(IES):
WATER SOLUBILITY: SOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT APPLICABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED SELF-REACTIVE.
VISCOSITY:
VISCOSITY, KINEMATIC: 6,000 - 17,000 MM2/S (20 DEG. C)
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE
OXIDIZING PROPERTIES:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS OXIDIZING.
9.2 OTHER INFORMATION: NO DATA AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1 REACTIVITY: NOT CLASSIFIED AS A REACTIVITY HAZARD.
10.2 CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3 POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS REACTIONS:
FLAMMABLE LIQUID AND VAPOUR.
VAPOURS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
CAN REACT WITH STRONG OXIDIZING AGENTS.
10.4 CONDITIONS TO AVOID:
CONDITIONS TO AVOID: HEAT, FLAMES AND SPARKS.
10.5 INCOMPATIBLE MATERIALS:
MATERIALS TO AVOID: OXIDIZING AGENTS
10.6 HAZARDOUS DECOMPOSITION PRODUCTS:
NO HAZARDOUS DECOMPOSITION PRODUCTS ARE KNOWN.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1 INFORMATION ON TOXICOLOGICAL EFFECTS:
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
INGESTION
EYE CONTACT
ACUTE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHANOL:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): 124.7 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
PROPAN-2-OL:
ACUTE ORAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
ACUTE INHALATION TOXICITY:
LC50 (RAT): 72.6 MG/L
EXPOSURE TIME: 4 H
TEST ATMOSPHERE: VAPOUR
ACUTE DERMAL TOXICITY:
LD50 (RAT): >5,000 MG/KG
SKIN CORROSION/IRRITATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
RESULT: NO SKIN IRRITATION
COMPONENTS:
ETHANOL:
SPECIES: RABBIT
METHOD: OECD TEST GUIDELINE 404
RESULT: NO SKIN IRRITATION
PROPAN-2-OL:
SPECIES: RABBIT
RESULT: NO SKIN IRRITATION
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
COMPONENTS:
ETHANOL:
SPECIES: RABBIT
METHOD: OECD TEST GUIDELINE 405
RESULT: IRRITATION TO EYES, REVERSING WITHIN 21 DAYS
PROPAN-2-OL:
SPECIES: RABBIT
RESULT: IRRITATION TO EYES, REVERSING WITHIN 21 DAYS
RESPIRATORY OR SKIN SENSITISATION:
SKIN SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
RESPIRATORY SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
PRODUCT:
ASSESSMENT: DOES NOT CAUSE SKIN SENSITISATION.
COMPONENTS:
ETHANOL:
TEST TYPE: LOCAL LYMPH NODE ASSAY (LLNA)
EXPOSURE ROUTES: SKIN CONTACT
SPECIES: MOUSE
RESULT: NEGATIVE
PROPAN-2-OL:
TEST TYPE: BUEHLER TEST
EXPOSURE ROUTES: SKIN CONTACT
SPECIES: GUINEA PIG
METHOD: OECD TEST GUIDELINE 406
RESULT: NEGATIVE
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHANOL:
GENOTOXICITY IN VITRO:
TEST TYPE: IN VITRO MAMMALIAN CELL GENE MUTATION TEST
RESULT: NEGATIVE
GENOTOXICITY IN VIVO:
TEST TYPE: RODENT DOMINANT LETHAL TEST (GERM CELL) (IN VIVO)
SPECIES: MOUSE
APPLICATION ROUTE: INGESTION
RESULT: NEGATIVE
PROPAN-2-OL:
GENOTOXICITY IN VITRO:
TEST TYPE: BACTERIAL REVERSE MUTATION ASSAY (AMES)
RESULT: NEGATIVE
GENOTOXICITY IN VIVO:
TEST TYPE:
MAMMALIAN ERYTHROCYTE MICRONUCLEUS TEST (IN VIVO CYTOGENETIC ASSAY)
SPECIES: MOUSE
APPLICATION ROUTE: INTRAPERITONEAL INJECTION
RESULT: NEGATIVE
CARCINOGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
PROPAN-2-OL:
SPECIES: RAT
APPLICATION ROUTE: INHALATION (VAPOUR)
EXPOSURE TIME: 104 WEEKS
METHOD: OECD TEST GUIDELINE 451
RESULT: NEGATIVE
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
ETHANOL:
EFFECTS ON FERTILITY:
TEST TYPE: TWO-GENERATION REPRODUCTION TOXICITY STUDY
SPECIES: MOUSE
APPLICATION ROUTE: INGESTION
METHOD: OECD TEST GUIDELINE 416
RESULT: NEGATIVE
PROPAN-2-OL:
EFFECTS ON FERTILITY:
TEST TYPE: TWO-GENERATION REPRODUCTION TOXICITY STUDY
SPECIES: RAT
APPLICATION ROUTE: INGESTION
RESULT: NEGATIVE
EFFECTS ON FOETAL DEVELOPMENT:
TEST TYPE: EMBRYO-FOETAL DEVELOPMENT
SPECIES: RAT
APPLICATION ROUTE: INGESTION
RESULT: NEGATIVE
STOT - SINGLE EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
PROPAN-2-OL:
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
STOT - REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
REPEATED DOSE TOXICITY:
COMPONENTS:
ETHANOL:
SPECIES: RAT
NOAEL: 2,400 MG/KG
APPLICATION ROUTE: INGESTION
EXPOSURE TIME: 2 Y
PROPAN-2-OL:
SPECIES: RAT
NOAEL: 5000 PPM
APPLICATION ROUTE: INHALATION (VAPOUR)
EXPOSURE TIME: 104 W
METHOD: OECD TEST GUIDELINE 413
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1 TOXICITY:
COMPONENTS:
ETHANOL:
TOXICITY TO FISH:
LC50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): >1,000 MG/L
EXPOSURE TIME: 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): >1,000 MG/L
EXPOSURE TIME: 48 H
TOXICITY TO ALGAE:
EC50 (CHLORELLA VULGARIS (FRESH WATER ALGAE)): 275 MG/L
EXPOSURE TIME: 72 H
METHOD: OECD TEST GUIDELINE 201
TOXICITY TO BACTERIA:
EC50 (PHOTOBACTERIUM PHOSPHOREUM): 32.1 MG/L
EXPOSURE TIME: 0.25 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEC: 9.6 MG/L
EXPOSURE TIME: 9 D
SPECIES: DAPHNIA MAGNA (WATER FLEA)
PROPAN-2-OL:
TOXICITY TO FISH:
LC50 (PIMEPHALES PROMELAS (FATHEAD MINNOW)): 10,000 MG/L
EXPOSURE TIME: 96 H
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (DAPHNIA MAGNA (WATER FLEA)): >10,000 MG/L
EXPOSURE TIME: 24 H
TOXICITY TO ALGAE:
ERC50 (SCENEDESMUS QUADRICAUDA (GREEN ALGAE)): >1,800
MG/L EXPOSURE TIME: 8 D
TOXICITY TO BACTERIA:
EC50 (PSEUDOMONAS PUTIDA): >1,050 MG/L
EXPOSURE TIME: 16 H
12.2 PERSISTENCE AND DEGRADABILITY:
COMPONENTS:
ETHANOL:
BIODEGRADABILITY:
RESULT: READILY BIODEGRADABLE
BIODEGRADATION: 84%
EXPOSURE TIME: 20 D
PROPAN-2-OL:
BIODEGRADABILITY:
RESULT: RAPIDLY DEGRADABLE
12.3 BIOACCUMULATIVE POTENTIAL
COMPONENTS:
ETHANOL:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: -0.35
PROPAN-2-OL:
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 0.05
12.4 MOBILITY IN SOIL: NO DATA AVAILABLE
12.5 RESULTS OF PBT AND VPVB ASSESSMENT: NOT RELEVANT
12.6 OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1 WASTE TREATMENT METHODS:
PRODUCT:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS.
ACCORDING TO THE EUROPEAN WASTE CATALOGUE, WASTE CODES ARE NOT PRODUCT
SPECIFIC, BUT APPLICATION SPECIFIC.
WASTE CODES SHOULD BE ASSIGNED BY THE USER, PREFERABLY IN DISCUSSION WITH
THE WASTE DISPOSAL AUTHORITIES.
CONTAMINATED PACKAGING:
DISPOSE OF AS UNUSED PRODUCT.
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
DO NOT BURN, OR USE A CUTTING TORCH ON, THE EMPTY DRUM.
| SECTION 14: TRANSPORT INFORMATION | |
14.1 UN NUMBER:
ADN: UN 1987
ADR: UN 1987
RID: UN 1987
IMDG: UN 1987
IATA: UN 1987
14.2 UN PROPER SHIPPING NAME:
ADN: ALCOHOLS, N.O.S. (ETHANOL, PROPAN-2-OL)
ADR: ALCOHOLS, N.O.S. (ETHANOL, PROPAN-2-OL)
RID: ALCOHOLS, N.O.S. (ETHANOL, PROPAN-2-OL)
IMDG: ALCOHOLS, N.O.S. (ETHANOL, PROPAN-2-OL)
IATA: ALCOHOLS, N.O.S. (ETHANOL, PROPAN-2-OL)
14.3 TRANSPORT HAZARD CLASS(ES):
ADN: 3
ADR: 3
RID: 3
IMDG: 3
IATA: 3
14.4 PACKING GROUP:
ADN:
PACKING GROUP: III
CLASSIFICATION CODE: F1
HAZARD IDENTIFICATION NUMBER: 30
LABELS: 3
ADR:
PACKING GROUP: III
CLASSIFICATION CODE: F1
HAZARD IDENTIFICATION NUMBER: 30
LABELS: 3
TUNNEL RESTRICTION CODE: (D/E)
RID:
PACKING GROUP: III
CLASSIFICATION CODE: F1
HAZARD IDENTIFICATION NUMBER: 30
LABELS: 3
IMDG:
PACKING GROUP: III
LABELS: 3
EMS CODE: F-E, S-D
IATA:
PACKING INSTRUCTION (CARGO AIRCRAFT): 366
PACKING INSTRUCTION (PASSENGER AIRCRAFT): 355
PACKING INSTRUCTION (LQ): Y344
PACKING GROUP: III
LABELS: FLAMMABLE LIQUIDS
14.5 ENVIRONMENTAL HAZARDS:
ADN:
ENVIRONMENTALLY HAZARDOUS: NO
ADR:
ENVIRONMENTALLY HAZARDOUS: NO
RID:
ENVIRONMENTALLY HAZARDOUS: NO
IMDG:
MARINE POLLUTANT: NO
14.6 SPECIAL PRECAUTIONS FOR USER: NOT APPLICABLE
14.7 TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC
CODE:
REMARKS: NOT APPLICABLE FOR PRODUCT AS SUPPLIED.
| SECTION 15: REGULATORY INFORMATION | |
15.1 SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR
THE SUBSTANCE OR MIXTURE:
REGULATION (EC) NO 649/2012 OF THE EUROPEAN PARLIAMENT AND THE COUNCIL
CONCERNING THE EXPORT AND IMPORT OF DANGEROUS CHEMICALS: NOT APPLICABLE
REACH - CANDIDATE LIST OF SUBSTANCES OF VERY HIGH CONCERN FOR AUTHORISATION
(ARTICLE 59).: NOT APPLICABLE
REGULATION (EC) NO 1005/2009 ON SUBSTANCES THAT DEPLETE THE OZONE LAYER:
NOT APPLICABLE
REGULATION (EC) NO 850/2004 ON PERSISTENT ORGANIC POLLUTANTS:
NOT APPLICABLE
SEVESO II - DIRECTIVE 2003/105/EC AMENDING COUNCIL DIRECTIVE 96/82/EC ON
THE CONTROL OF MAJOR-ACCIDENT HAZARDS INVOLVING DANGEROUS SUBSTANCES:
QUANTITY 1 QUANTITY 2
6 FLAMMABLE. 5,000 T 50,000 T
SEVESO III:
DIRECTIVE 2012/18/EU OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL ON THE
CONTROL OF MAJOR-ACCIDENT HAZARDS INVOLVING DANGEROUS SUBSTANCES.
P5C FLAMMABLE LIQUIDS 5,000 T 50,000 T
34 PETROLEUM PRODUCTS: 2,500 T 25,000 T
(A) GASOLINES AND NAPHTHAS,
(B) KEROSENES (INCLUDING JET FUELS),
(C) GAS OILS (INCLUDING DIESEL FUELS,
HOME HEATING OILS AND GAS OIL BLENDING
STREAMS), (D) HEAVY FUEL OILS (E)
ALTERNATIVE FUELS SERVING THE SAME
PURPOSES AND WITH SIMILAR PROPERTIES
AS REGARDS FLAMMABILITY AND
ENVIRONMENTAL HAZARDS AS THE PRODUCTS
REFERRED TO IN POINTS (A) TO (D)
VOLATILE ORGANIC COMPOUNDS:
DIRECTIVE 2010/75/EU OF 24 NOVEMBER 2010 ON INDUSTRIAL EMISSIONS
(INTEGRATED POLLUTION PREVENTION AND CONTROL) VOLATILE ORGANIC COMPOUNDS
(VOC) CONTENT: <75%
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
AICS: ALL INGREDIENTS LISTED OR EXEMPT.
INVENTORIES:
AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION),
ENCS (JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS
(PHILIPPINES), NECSI (TAIWAN), TSCA (USA)
15.2 CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| SECTION 16: OTHER INFORMATION | |
FULL TEXT OF R-PHRASES:
R11: HIGHLY FLAMMABLE.
R36: IRRITATING TO EYES.
R67: VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS.
FULL TEXT OF H-STATEMENTS:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOUR.
H319: CAUSES SERIOUS EYE IRRITATION.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
FULL TEXT OF OTHER ABBREVIATIONS:
EYE IRRIT.: EYE IRRITATION
FLAM. LIQ.: FLAMMABLE LIQUIDS
STOT SE: SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE
GB EH40: UK. EH40 WEL - WORKPLACE EXPOSURE LIMITS
GB EH40 / TWA: LONG-TERM EXPOSURE LIMIT (8-HOUR TWA REFERENCE PERIOD)
GB EH40 / STEL: SHORT-TERM EXPOSURE LIMIT (15-MINUTE REFERENCE PERIOD)
FURTHER INFORMATION:
SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET:
INTERNAL TECHNICAL DATA, DATA FROM RAW MATERIAL SDSS, OECD ECHEM PORTAL
SEARCH RESULTS AND EUROPEAN CHEMICALS AGENCY, HTTP://ECHA.EUROPA.EU/
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING, USE,
PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND SHALL NOT BE
CONSIDERED A WARRANTY OR QUALITY SPECIFICATION OF ANY TYPE. THE INFORMATION
PROVIDED RELATES ONLY TO THE SPECIFIC MATERIAL IDENTIFIED AT THE TOP OF
THIS SDS AND MAY NOT BE VALID WHEN THE SDS MATERIAL IS USED IN COMBINATION
WITH ANY OTHER MATERIALS OR IN ANY PROCESS, UNLESS SPECIFIED IN THE TEXT.
MATERIAL USERS SHOULD REVIEW THE INFORMATION AND RECOMMENDATIONS IN THE
SPECIFIC CONTEXT OF THEIR INTENDED MANNER OF HANDLING, USE, PROCESSING AND
STORAGE, INCLUDING AN ASSESSMENT OF THE APPROPRIATENESS OF THE SDS MATERIAL
IN THE USER'S END PRODUCT, IF APPLICABLE.
GB / EN