| Common Name: | INSECT REPELLENT 14011 |
| Manufacturer: | CRC INDUSTRIES |
| SDS Revision Date: | 6/29/2016 |
| SDS Format: | No Format Specified |
| Item Number(s): | 19MY09 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: INSECT REPELLENT
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: 14011
REGISTRATION NUMBER:
EPA: 51147-13-55809
RECOMMENDED USE: INSECT REPELLENT
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY: COMPANY NAME CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC):
800-424-9300 (US)
703-527-3887 (INTERNATIONAL)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS:
ACUTE TOXICITY, ORAL: CATEGORY 4
ACUTE TOXICITY, DERMAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2
SENSITIZATION, SKIN: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 2
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 3
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
FLAME
GAS CYLINDER
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED. HARMFUL IF SWALLOWED. HARMFUL IN CONTACT WITH SKIN. CAUSES SKIN
IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE
IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. TOXIC TO AQUATIC LIFE.
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING. DO NOT
SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT APPLY WHILE EQUIPMENT IS
ENERGIZED. EXTINGUISH ALL FLAMES, PILOT LIGHTS AND HEATERS. VAPORS WILL
ACCUMULATE READILY AND MAY IGNITE. USE ONLY WITH ADEQUATE VENTILATION;
MAINTAIN VENTILATION DURING USE AND UNTIL ALL VAPORS ARE GONE. OPEN DOORS
AND WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR SUPPLY DURING USE AND
WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY SYMPTOMS LISTED ON THIS
LABEL, INCREASE VENTILATION OR LEAVE THE AREA. AVOID BREATHING MIST OR
VAPOR. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. CONTAMINATED
WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR EYE/FACE
PROTECTION. WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING. WASH THOROUGHLY
AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF SWALLOWED: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL. RINSE MOUTH.
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE
REUSE.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. STORE LOCKED UP. PROTECT FROM SUNLIGHT.
DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. EXPOSURE TO
HIGH TEMPERATURE MAY CAUSE CAN TO BURST.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC):
STATIC ACCUMULATING FLAMMABLE LIQUID CAN BECOME ELECTROSTATICALLY CHARGED
EVEN IN BONDED AND GROUNDED EQUIPMENT. SPARKS MAY IGNITE LIQUID AND VAPOR.
MAY CAUSE FLASH FIRE OR EXPLOSION.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
ISOPROPYL ALCOHOL 67-63-0 30 - 40
LIQUEFIED PETROLEUM GAS 68476-86-8 20 - 30
N,N-DIETHYL-M-TOLUAMIDE (DEET) 134-62-3 25
N-OCTYL BICYCLOHEPTENE 113-48-4 5
DICARBOXIMIDE
DI-N-PROPYL ISOCINCHOMERONATE 136-45-8 2.5
ACETONE 67-64-1 1 - 3
PROPYLENE GLYCOL 57-55-6 1 - 3
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN WITH SOAP AND WATER.
IN CASE OF ECZEMA OR OTHER SKIN DISORDERS: SEEK MEDICAL ATTENTION AND TAKE
ALONG THESE INSTRUCTIONS. WASH CONTAMINATED CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS AND PERSISTS.
INGESTION:
RINSE MOUTH. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH CONTENT
DOESN'T GET INTO THE LUNGS. GET MEDICAL ADVICE/ATTENTION IF YOU FEEL
UNWELL.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. KEEP VICTIM
WARM. KEEP VICTIM UNDER OBSERVATION. SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS SAFETY DATA SHEET TO THE
DOCTOR IN ATTENDANCE. WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
ALCOHOL RESISTANT FOAM. WATER FOG. CARBON DIOXIDE (CO2). DRY CHEMICAL
POWDER, CARBON DIOXIDE, SAND OR EARTH MAY BE USED FOR SMALL FIRES ONLY.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY RUPTURE WHEN EXPOSED TO
HEAT OR FLAME. THIS PRODUCT IS A POOR CONDUCTOR OF ELECTRICITY AND CAN
BECOME ELECTROSTATICALLY CHARGED. IF SUFFICIENT CHARGE IS ACCUMULATED,
IGNITION OF FLAMMABLE MIXTURES CAN OCCUR. STATIC ELECTRICITY ACCUMULATION
MAY BE SIGNIFICANTLY INCREASED BY THE PRESENCE OF SMALL QUANTITIES OF
WATER OR OTHER CONTAMINANTS. MATERIAL WILL FLOAT AND MAY IGNITE ON SURFACE
OF WATER. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
FIREFIGHTERS MUST USE STANDARD PROTECTIVE EQUIPMENT INCLUDING FLAME
RETARDANT COAT, HELMET WITH FACE SHIELD, GLOVES, RUBBER BOOTS, AND IN
ENCLOSED SPACES, SCBA.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO
SO WITHOUT RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR
PRESSURE BUILD UP.
GENERAL FIRE HAZARDS:
EXTREMELY FLAMMABLE AEROSOL. CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER
MAY RUPTURE WHEN EXPOSED TO HEAT OR FLAME.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. REMOVE ALL POSSIBLE SOURCES OF IGNITION
IN THE SURROUNDING AREA. MANY VAPORS ARE HEAVIER THAN AIR AND WILL SPREAD
ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS, BASEMENTS,
TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING CLEAN-UP.
AVOID BREATHING MIST OR VAPOR. EMERGENCY PERSONNEL NEED SELF-CONTAINED
BREATHING EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR SPILLED MATERIAL
UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE CLOSED SPACES
BEFORE ENTERING THEM. USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL
CONTAMINATION. LOCAL AUTHORITIES SHOULD BE ADVISED IF SIGNIFICANT SPILLAGES
CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
ELIMINATE ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN
IMMEDIATE AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM
SPILLED MATERIAL. THE PRODUCT IS IMMISCIBLE WITH WATER AND WILL SPREAD ON
THE WATER SURFACE. STOP THE FLOW OF MATERIAL, IF THIS IS WITHOUT RISK.
PREVENT PRODUCT FROM ENTERING DRAINS. WIPE UP WITH ABSORBENT MATERIAL
(E.G. CLOTH, FLEECE). CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL
CONTAMINATION. FOR WASTE DISPOSAL, SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE IF
SAFE TO DO SO. AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE
GROUND. INFORM APPROPRIATE MANAGERIAL OR SUPERVISORY PERSONNEL OF ALL
ENVIRONMENTAL RELEASES. USE APPROPRIATE CONTAINMENT TO AVOID ENVIRONMENTAL
CONTAMINATION.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
MINIMIZE FIRE RISKS FROM FLAMMABLE AND COMBUSTIBLE MATERIALS (INCLUDING
COMBUSTIBLE DUST AND STATIC ACCUMULATING LIQUIDS) OR DANGEROUS REACTIONS
WITH INCOMPATIBLE MATERIALS. PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN,
EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS MISSING OR DEFECTIVE. DO NOT
SPRAY ON A NAKED FLAME OR ANY OTHER INCANDESCENT MATERIAL. DO NOT SMOKE
WHILE USING OR UNTIL SPRAYED SURFACE IS THOROUGHLY DRY. DO NOT CUT, WELD,
SOLDER, DRILL, GRIND, OR EXPOSE CONTAINERS TO HEAT, FLAME, SPARKS, OR OTHER
SOURCES OF IGNITION. USE CAUTION AROUND ENERGIZED EQUIPMENT. THE METAL
CONTAINER WILL CONDUCT ELECTRICITY IF IT CONTACTS A LIVE SOURCE. THIS MAY
RESULT IN INJURY TO THE USER FROM ELECTRICAL SHOCK AND/OR FLASH FIRE. AVOID
BREATHING MIST OR VAPOR. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. DO
NOT TASTE OR SWALLOW. WHEN USING, DO NOT EAT, DRINK OR SMOKE. USE ONLY IN
WELL-VENTILATED AREAS. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH
HANDS THOROUGHLY AFTER HANDLING. OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES.
AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED CLOTHING BEFORE REUSE.
FOR PRODUCT USAGE INSTRUCTIONS, PLEASE SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
LEVEL 3 AEROSOL.
PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO
TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT PUNCTURE, INCINERATE
OR CRUSH. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES
OF IGNITION. THIS MATERIAL CAN ACCUMULATE STATIC CHARGE WHICH MAY CAUSE
SPARK AND BECOME AN IGNITION SOURCE. AVOID SPARK PROMOTERS. THESE ALONE
MAY BE INSUFFICIENT TO REMOVE STATIC ELECTRICITY. STORE IN A
WELL-VENTILATED PLACE. STORE AWAY FROM INCOMPATIBLE MATERIALS (SEE
SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) PEL 2400 MG/M3
1000 PPM
ISOPROPYL ALCOHOL PEL 980 MG/M3
(CAS 67-63-0) 400 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) STEL 500 PPM
TWA 250 PPM
ISOPROPYL ALCOHOL STEL 400 PPM
(CAS 67-63-0)
TWA 200 PPM
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
ACETONE (CAS 67-64-1) TWA 590 MG/M3
250 PPM
ISOPROPYL ALCOHOL STEL 1225 MG/M3
(CAS 67-63-0) 500 PPM
TWA 980 MG/M3
400 PPM
US. AIHA WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE FORM
PROPYLENE GLYCOL TWA 10 MG/M3 AEROSOL.
(CAS 57-55-6)
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
ACETONE 25 MG/L ACETONE URINE *
(CAS 67-64-1)
ISOPROPYL ALCOHOL 40 MG/L ACETONE URINE *
(CAS 67-63-0)
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
IF EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO
AN ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER SHOULD BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: WEAR PROTECTIVE GLOVES SUCH AS: NITRILE. VITON(R*).
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON
IS RECOMMENDED.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH
AN ORGANIC VAPOR CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN
CONFINED SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO DETERMINE
ACTUAL EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. KEEP AWAY FROM FOOD AND DRINK. ALWAYS OBSERVE
GOOD PERSONAL HYGIENE MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL
AND BEFORE EATING, DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING
AND PROTECTIVE EQUIPMENT TO REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING
SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: AEROSOL.
COLOR: CLEAR. COLORLESS.
ODOR: MILD. ALCOHOLIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: -138.5 DEG. F (-94.7 DEG. C) ESTIMATED
INITIAL BOILING POINT AND BOILING RANGE:
132.9 DEG. F (56.1 DEG. C) ESTIMATED
FLASH POINT: 75 DEG. F (23.9 DEG. C) TAG CLOSED CUP
EVAPORATION RATE: MODERATE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): 2% ESTIMATED
FLAMMABILITY LIMIT - UPPER (%): 12.8% ESTIMATED
VAPOR PRESSURE: 1255.3 HPA ESTIMATED
VAPOR DENSITY: >1 (AIR = 1)
RELATIVE DENSITY: 0.8 ESTIMATED
SOLUBILITY (WATER): IMMISCIBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: 700 DEG. F (371.1 DEG. C) ESTIMATED
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY (KINEMATIC): NOT AVAILABLE.
PERCENT VOLATILE: 67.5% ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
THE PRODUCT IS STABLE AND NON-REACTIVE UNDER NORMAL CONDITIONS OF USE,
STORAGE AND TRANSPORT.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
HEAT, FLAMES AND SPARKS. CONTACT WITH INCOMPATIBLE MATERIALS.
INCOMPATIBLE MATERIALS:
ACIDS. STRONG OXIDIZING AGENTS. ISOCYANATES. CHLORINE.
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON OXIDES. NITROGEN OXIDES (NOX).
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION: MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING.
SKIN CONTACT:
HARMFUL IN CONTACT WITH SKIN. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC
SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: HARMFUL IF SWALLOWED.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
HEADACHE. MAY CAUSE DROWSINESS AND DIZZINESS. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
IN HIGH CONCENTRATIONS, VAPORS ARE ANESTHETIC AND MAY CAUSE HEADACHE,
FATIGUE, DIZZINESS AND CENTRAL NERVOUS SYSTEM EFFECTS. HARMFUL IN CONTACT
WITH SKIN. HARMFUL IF SWALLOWED. NARCOTIC EFFECTS. MAY CAUSE AN ALLERGIC
SKIN REACTION.
PRODUCT SPECIES TEST RESULTS
INSECT REPELLENT:
ACUTE:
DERMAL:
LD50 RABBIT 1388 MG/KG ESTIMATED
INHALATION:
LC50 RAT 41224 PPM, 4 HOURS ESTIMATED
ORAL:
LD50 RAT 1747 MG/KG ESTIMATED
TDL0 HUMAN 117 G/KG ESTIMATED
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY: NOT LISTED.
US. NATIONAL TOXICOLOGY PROGRAM (NTP) REPORT ON CARCINOGENS: NOT LISTED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT AN ASPIRATION HAZARD.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
TOXIC TO AQUATIC LIFE. HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS SPECIES TEST RESULTS
ACETONE (CAS 67-64-1):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 10294 - 17704 MG/L,
48 HOURS
FISH LC50 RAINBOW TROUT,DONALDSON TROUT 4740 - 6330 MG/L,
(ONCORHYNCHUS MYKISS) 96 HOURS
ISOPROPYL ALCOHOL (CAS 67-63-0):
AQUATIC:
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 7550 - 13299 MG/L,
48 HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES 9640 MG/L, 96 HOURS
PROMELAS)
N,N-DIETHYL-M-TOLUAMIDE (DEET) (CAS 134-62-3):
AQUATIC:
FISH LC50 FATHEAD MINNOW (PIMEPHALES 106 - 114 MG/L,
PROMELAS) 96 HOURS
PROPYLENE GLYCOL (CAS 57-55-6):
AQUATIC:
FISH LC50 FATHEAD MINNOW (PIMEPHALES 710 MG/L, 96 HOURS
PROMELAS)
ACUTE:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 4850 - 34000 MG/L,
48 HOURS
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
PARTITION COEFFICIENT N-OCTANOL / WATER (LOG KOW):
ACETONE: -0.24
ISOPROPYL ALCOHOL: 0.05
N,N-DIETHYL-M-TOLUAMIDE (DEET): 2.02
PROPYLENE GLYCOL: -0.92
BIOCONCENTRATION FACTOR (BCF):
ISOPROPYL ALCOHOL: 3.16
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL OF WASTE FROM RESIDUES / UNUSED PRODUCTS:
IF DISCARDED, THIS PRODUCT IS CONSIDERED A RCRA IGNITABLE WASTE, D001.
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER SUPPLIES.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
D001: WASTE FLAMMABLE MATERIAL WITH A FLASH POINT <140 F
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
LABEL(S): 2.1
PACKING GROUP: NOT APPLICABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
IATA:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, FLAMMABLE, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2.1
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ERG CODE: 10L
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
OTHER INFORMATION:
PASSENGER AND CARGO AIRCRAFT: ALLOWED WITH RESTRICTIONS.
CARGO AIRCRAFT ONLY: ALLOWED WITH RESTRICTIONS.
IMDG:
UN NUMBER: UN1950
UN PROPER SHIPPING NAME: AEROSOLS, LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 2
SUBSIDIARY RISK:
PACKING GROUP: NOT APPLICABLE.
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO.
EMS: NOT AVAILABLE.
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
NOT REGULATED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT REGULATED.
US EPCRA (SARA TITLE III) SECTION 313 - LISTED SUBSTANCE
TOXIC CHEMICAL
DI-N-PROPYL ISOCINCHOMERONATE (CAS 136-45-8)
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
ACETONE (CAS 67-64-1) LISTED.
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
ACETONE (CAS 67-64-1) 5000 LBS
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE
ITS RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
NOT REGULATED.
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS (21 CFR
1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
ACETONE (CAS 67-64-1): 6532
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL MIXTURES
(21 CFR 1310.12(C)):
ACETONE (CAS 67-64-1): 35%WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
ACETONE (CAS 67-64-1): 6532
FEMA PRIORITY SUBSTANCES RESPIRATORY HEALTH AND SAFETY IN THE FLAVOR
MANUFACTURING WORKPLACE:
ACETONE (CAS 67-64-1): LOW PRIORITY
ISOPROPYL ALCOHOL (CAS 67-63-0): LOW PRIORITY
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
US EPA FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT (FIFRA):
FIFRA INFORMATION:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE UNITED STATES
ENVIRONMENTAL PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING
REQUIREMENTS UNDER FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM
THE CLASSIFICATION CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA
SHEETS (SDS), AND FOR WORKPLACE LABELS OF NON-PESTICIDE CHEMICALS. THE
HAZARD INFORMATION REQUIRED ON THE PESTICIDE LABEL IS REPRODUCED BELOW.
THE PESTICIDE LABEL ALSO INCLUDES OTHER IMPORTANT INFORMATION, INCLUDING
DIRECTIONS FOR USE.
SIGNAL WORD: WARNING.
HAZARD STATEMENT:
HARMFUL IF SWALLOWED. CAUSES SUBSTANTIAL BUT TEMPORARY EYE INJURY.
THIS PRODUCT IS REGISTERED IN ALL 50 UNITED STATES AND PUERTO RICO. THIS
PRODUCT IS NOT REGISTERED OUTSIDE OF THE UNITED STATES AND PUERTO RICO.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SECTION 311/312:
IMMEDIATE HAZARD: YES
HAZARD CATEGORIES:
DELAYED HAZARD: NO
FIRE HAZARD: YES
PRESSURE HAZARD: YES
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
US STATE REGULATIONS:
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
ACETONE (CAS 67-64-1)
DI-N-PROPYL ISOCINCHOMERONATE (CAS 136-45-8)
ISOPROPYL ALCOHOL (CAS 67-63-0)
LIQUEFIED PETROLEUM GAS (CAS 68476-86-8)
US. CALIFORNIA CONTROLLED SUBSTANCES. CA DEPARTMENT OF JUSTICE (CALIFORNIA
HEALTH AND SAFETY CODE SECTION 11100): NOT LISTED.
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
ACETONE (CAS 67-64-1)
PROPYLENE GLYCOL (CAS 57-55-6)
DI-N-PROPYL ISOCINCHOMERONATE (CAS 136-45-8)
ISOPROPYL ALCOHOL (CAS 67-63-0)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
ACETONE (CAS 67-64-1)
ISOPROPYL ALCOHOL (CAS 67-63-0)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
ACETONE (CAS 67-64-1)
ISOPROPYL ALCOHOL (CAS 67-63-0)
PROPYLENE GLYCOL (CAS 57-55-6)
US. RHODE ISLAND RTK:
ACETONE (CAS 67-64-1)
DI-N-PROPYL ISOCINCHOMERONATE (CAS 136-45-8)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/CARCINOGENIC SUBSTANCE
BENZENE (CAS 71-43-2) LISTED: FEBRUARY 27, 1987
CUMENE (CAS 98-82-8) LISTED: APRIL 6, 2010
DI-N-PROPYL ISOCINCHOMERONATE LISTED: MAY 1, 1996
(CAS 136-45-8)
ETHANAL (CAS 75-07-0) LISTED: APRIL 1, 1988
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/DEVELOPMENTAL TOXIN
BENZENE (CAS 71-43-2) LISTED: DECEMBER 26, 1997
TOLUENE (CAS 108-88-3) LISTED: JANUARY 1, 1991
US - CALIFORNIA PROPOSITION 65 - CRT LISTED DATE/MALE REPRODUCTIVE
TOXIN
BENZENE (CAS 71-43-2) LISTED: DECEMBER 26, 1997
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): 64.9%
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS:
THIS PRODUCT IS REGULATED AS AN INSECT REPELLENT. THIS PRODUCT IS COMPLIANT
FOR USE IN ALL 50 STATES.
VOC CONTENT (CA): 64.9%
VOC CONTENT (OTC): 64.9%
INTERNATIONAL INVENTORIES:
COUNTRY(S) INVENTORY NAME ON INVENTORY
OR REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES NO
IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING COMMERCIAL YES
CHEMICAL SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL NO
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) NO
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND NO
CHEMICAL SUBSTANCES (PICCS)
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
& PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 05-21-2015
REVISION DATE: 06-29-2016
PREPARED BY: ALLISON CHO
VERSION #: 02
FURTHER INFORMATION: CRC # 926
HMIS(R*) RATINGS:
HEALTH 1
FLAMMABILITY 3
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
NFPA RATINGS:
HEALTH 1
FLAMMABILITY 3
INSTABILITY 0
NFPA RATINGS:
1
3
0
DISCLAIMER:
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC INDUSTRIES' KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY
CRC TO BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND
DIRECTIONS ON THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION
CONTAINED ON THIS (M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY
PROFESSIONAL, OR CRC INDUSTRIES.
REVISION INFORMATION:
HAZARD(S) IDENTIFICATION: SUPPLEMENTAL LABEL INFORMATION
COMPOSITION / INFORMATION ON INGREDIENTS: INGREDIENTS
FIRE-FIGHTING MEASURES: SUITABLE EXTINGUISHING MEDIA
EXPOSURE CONTROLS/PERSONAL PROTECTION: APPROPRIATE ENGINEERING CONTROLS
PHYSICAL & CHEMICAL PROPERTIES: MULTIPLE PROPERTIES
TOXICOLOGICAL INFORMATION: TOXICOLOGICAL DATA
ECOLOGICAL INFORMATION: ECOTOXICITY
DISPOSAL CONSIDERATIONS: HAZARDOUS WASTE CODE
TRANSPORT INFORMATION:
AGENCY NAME, PACKAGING TYPE, AND TRANSPORT MODE SELECTION
REGULATORY INFORMATION: UNITED STATES
GHS: CLASSIFICATION
MATERIAL NAME: INSECT REPELLENT
SDS US