| Common Name: | ON & OFF HULL & BOTTOM CLEANER MK2032 |
| Manufacturer: | CRC |
| SDS Revision Date: | 4/7/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 19MZ02, 19MZ03, 19MZ04 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
CRC(R*)
SAFETY DATA SHEET
| 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER: ON & OFF HULL & BOTTOM CLEANER
OTHER MEANS OF IDENTIFICATION:
PRODUCT CODE: MK2032
RECOMMENDED USE: CLEANER FOR FIBERGLASS HULLS
RECOMMENDED RESTRICTIONS: NONE KNOWN.
MANUFACTURER/IMPORTER/SUPPLIER/DISTRIBUTOR INFORMATION:
MANUFACTURED OR SOLD BY:
COMPANY NAME: CRC INDUSTRIES, INC.
ADDRESS:
885 LOUIS DR.
WARMINSTER, PA 18974
US
TELEPHONE:
GENERAL INFORMATION: 215-674-4300
TECHNICAL ASSISTANCE: 800-521-3168
CUSTOMER SERVICE: 800-272-4620
24-HOUR EMERGENCY (CHEMTREC):
800-424-9300 (US)
703-527-3887 (INTERNATIONAL)
WEBSITE: WWW.CRCINDUSTRIES.COM
| 2. HAZARD(S) IDENTIFICATION | |
PHYSICAL HAZARDS:
CORROSIVE TO METALS: CATEGORY 1
HEALTH HAZARDS:
ACUTE TOXICITY, ORAL: CATEGORY 4
SKIN CORROSION/IRRITATION: CATEGORY 1B
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 RESPIRATORY TRACT IRRITATION
ENVIRONMENTAL HAZARDS:
HAZARDOUS TO THE AQUATIC ENVIRONMENT, ACUTE HAZARD: CATEGORY 2
HAZARDOUS TO THE AQUATIC ENVIRONMENT, LONG-TERM HAZARD: CATEGORY 3
OSHA DEFINED HAZARDS: NOT CLASSIFIED.
LABEL ELEMENTS:
CORROSION
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
MAY BE CORROSIVE TO METALS. HARMFUL IF SWALLOWED. CAUSES SEVERE SKIN BURNS
AND EYE DAMAGE. MAY CAUSE RESPIRATORY IRRITATION. TOXIC TO AQUATIC LIFE.
HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENT:
PREVENTION:
DO NOT BREATHE MIST OR VAPOR. USE WITH ADEQUATE VENTILATION. OPEN DOORS AND
WINDOWS OR USE OTHER MEANS TO ENSURE A FRESH AIR SUPPLY DURING USE AND
WHILE PRODUCT IS DRYING. IF YOU EXPERIENCE ANY SYMPTOMS LISTED ON THIS
LABEL, INCREASE VENTILATION OR LEAVE THE AREA. WASH THOROUGHLY AFTER
HANDLING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WEAR
PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
AVOID RELEASE TO THE ENVIRONMENT.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER/DOCTOR. WASH CONTAMINATED CLOTHING BEFORE REUSE. ABSORB SPILLAGE TO
PREVENT MATERIAL DAMAGE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP. STORE IN CORROSIVE RESISTANT CONTAINER.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL
REGULATIONS.
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION:
WHEN EXPOSED TO EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE TO
HARMFUL OR FATAL CORROSIVE GASES SUCH AS HYDROGEN CHLORIDE AND POSSIBLY
PHOSGENE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURES:
CHEMICAL NAME COMMON NAME CAS NUMBER %
AND SYNONYMS
WATER 7732-18-5 60 - 70
HYDROCHLORIC ACID 7647-01-0 20 - 30
PHOSPHORIC ACID 7664-38-2 5 - 10
ALCOHOLS, C12-15, 68131-39-5 1 - 3
ETHOXYLATED
OXALIC ACID 144-62-7 1 - 3
SPECIFIC CHEMICAL IDENTITY AND/OR PERCENTAGE OF COMPOSITION HAS BEEN
WITHHELD AS A TRADE SECRET.
| 4. FIRST-AID MEASURES | |
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF PERSON IS NOT BREATHING, CALL 911 OR AN AMBULANCE, THEN GIVE
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH IF POSSIBLE. IF
RESPIRATORY IRRITATION, DIZZINESS, OR UNCONSCIOUSNESS OCCURS, SEEK
IMMEDIATE MEDICAL ASSISTANCE. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF
YOU FEEL UNWELL.
SKIN CONTACT:
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. WASH WITH SOAP AND PLENTY
OF WATER FOR 15 MINUTES. CALL A PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY. CHEMICAL BURNS MUST BE TREATED BY A PHYSICIAN. WASH
CONTAMINATED CLOTHING BEFORE REUSE.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. CALL A
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
INGESTION:
CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. DRINK 1 OR 2 GLASSES
OF WATER. RINSE MOUTH. DO NOT INDUCE VOMITING WITHOUT ADVICE FROM POISON
CONTROL CENTER. NEVER GIVE ANYTHING BY MOUTH TO A VICTIM WHO IS UNCONSCIOUS
OR IS HAVING CONVULSIONS. IF VOMITING OCCURS, KEEP HEAD LOW SO THAT STOMACH
CONTENT DOESN'T GET INTO THE LUNGS. PROBABLE MUCOSAL DAMAGE MAY
CONTRAINDICATE THE USE OF GASTRIC LAVAGE.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
BURNING PAIN AND SEVERE CORROSIVE SKIN DAMAGE. CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. PERMANENT EYE DAMAGE INCLUDING BLINDNESS COULD RESULT. MAY CAUSE
RESPIRATORY IRRITATION.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY.
CHEMICAL BURNS:
FLUSH WITH WATER IMMEDIATELY. WHILE FLUSHING, REMOVE CLOTHES WHICH DO NOT
ADHERE TO AFFECTED AREA. CALL AN AMBULANCE. CONTINUE FLUSHING DURING
TRANSPORT TO HOSPITAL. KEEP VICTIM WARM. KEEP VICTIM UNDER OBSERVATION.
SYMPTOMS MAY BE DELAYED.
GENERAL INFORMATION:
ENSURE THAT MEDICAL PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED, AND
TAKE PRECAUTIONS TO PROTECT THEMSELVES. SHOW THIS SAFETY DATA SHEET TO THE
DOCTOR IN ATTENDANCE.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE (CO2).
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET AS AN EXTINGUISHER, AS THIS WILL SPREAD THE FIRE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
WHEN EXPOSED TO EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE TO
HARMFUL OR FATAL CORROSIVE GASES SUCH AS HYDROGEN CHLORIDE AND POSSIBLY
PHOSGENE.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING MUST BE
WORN IN CASE OF FIRE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT RISK.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. WEAR APPROPRIATE PROTECTIVE EQUIPMENT
AND CLOTHING DURING CLEAN-UP. DO NOT BREATHE MIST OR VAPOR. DO NOT TOUCH
DAMAGED CONTAINERS OR SPILLED MATERIAL UNLESS WEARING APPROPRIATE
PROTECTIVE CLOTHING. ENSURE ADEQUATE VENTILATION. LOCAL AUTHORITIES SHOULD
BE ADVISED IF SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL
PROTECTION, SEE SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
THIS PRODUCT IS MISCIBLE IN WATER. THIS MATERIAL IS CLASSIFIED AS A WATER
POLLUTANT UNDER THE CLEAN WATER ACT AND SHOULD BE PREVENTED FROM
CONTAMINATING SOIL OR FROM ENTERING SEWAGE AND DRAINAGE SYSTEMS WHICH LEAD
TO WATERWAYS. SHOULD NOT BE RELEASED INTO THE ENVIRONMENT. USE A
NON-COMBUSTIBLE MATERIAL LIKE VERMICULITE, SAND OR EARTH TO SOAK UP THE
PRODUCT AND PLACE INTO A CONTAINER FOR LATER DISPOSAL. FOR LARGER SPILLS,
NEUTRALIZE WITH SODIUM CARBONATE OR ABSORB ON FIRE RETARDANT MATERIAL.
CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
NEVER RETURN SPILLS TO ORIGINAL CONTAINERS FOR RE-USE. FOR WASTE DISPOSAL,
SEE SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. PREVENT FURTHER LEAKAGE OR SPILLAGE IF
SAFE TO DO SO. DO NOT CONTAMINATE WATER. AVOID DISCHARGE INTO DRAINS, WATER
COURSES OR ONTO THE GROUND. INFORM APPROPRIATE MANAGERIAL OR SUPERVISORY
PERSONNEL OF ALL ENVIRONMENTAL RELEASES.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
NEVER USE WITH CHLORINE PRODUCTS. CAN REACT TO GIVE CHLORINE GAS. NEVER USE
OR MIX WITH OTHER CLEANERS OR CHEMICALS. DO NOT USE ON ANY SURFACE THAT CAN
BE DAMAGED BY ACID MATERIALS. DO NOT BREATHE MIST OR VAPOR. DO NOT GET IN
EYES, ON SKIN, OR ON CLOTHING. AVOID PROLONGED EXPOSURE. DO NOT TASTE OR
SWALLOW. WHEN USING, DO NOT EAT, DRINK OR SMOKE. PROVIDE ADEQUATE
VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH HANDS
THOROUGHLY AFTER HANDLING. AVOID RELEASE TO THE ENVIRONMENT. OBSERVE GOOD
INDUSTRIAL HYGIENE PRACTICES. USE CARE IN HANDLING/STORAGE. FOR PRODUCT
USAGE INSTRUCTIONS, PLEASE SEE THE PRODUCT LABEL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN A COOL, DRY PLACE OUT OF DIRECT SUNLIGHT. STORE IN CORROSIVE
RESISTANT CONTAINER. KEEP CONTAINER TIGHTLY CLOSED. STORE IN A
WELL-VENTILATED PLACE. STORE AWAY FROM INCOMPATIBLE MATERIALS
(SEE SECTION 10 OF THE SDS).
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
US. OSHA TABLE Z-1 LIMITS FOR AIR CONTAMINANTS (29 CFR 1910.1000):
COMPONENTS TYPE VALUE
HYDROCHLORIC ACID (CAS 7647-01-0) CEILING 7 MG/M3
5 PPM
OXALIC ACID (CAS 144-62-7) PEL 1 MG/M3
PHOSPHORIC ACID (CAS 7664-38-2) PEL 1 MG/M3
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
HYDROCHLORIC ACID (CAS 7647-01-0) CEILING 2 PPM
OXALIC ACID (CAS 144-62-7) STEL 2 MG/M3
TWA 1 MG/M3
PHOSPHORIC ACID (CAS 7664-38-2) STEL 3 MG/M3
TWA 1 MG/M3
US. NIOSH: POCKET GUIDE TO CHEMICAL HAZARDS
COMPONENTS TYPE VALUE
HYDROCHLORIC ACID (CAS 7647-01-0) CEILING 7 MG/M3
5 PPM
OXALIC ACID (CAS 144-62-7) STEL 2 MG/M3
TWA 1 MG/M3
PHOSPHORIC ACID (CAS 7664-38-2) STEL 3 MG/M3
TWA 1 MG/M3
BIOLOGICAL LIMIT VALUES:
NO BIOLOGICAL EXPOSURE LIMITS NOTED FOR THE INGREDIENT(S).
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL. EYE WASH FACILITIES AND EMERGENCY SHOWER MUST BE
AVAILABLE WHEN HANDLING THIS PRODUCT.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES) AND A FACE SHIELD.
SKIN PROTECTION:
HAND PROTECTION:
WEAR PROTECTIVE GLOVES SUCH AS: NEOPRENE. LATEX.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED.
RESPIRATORY PROTECTION:
IF ENGINEERING CONTROLS ARE NOT FEASIBLE OR IF EXPOSURE EXCEEDS THE
APPLICABLE EXPOSURE LIMITS, USE A NIOSH-APPROVED CARTRIDGE RESPIRATOR WITH
AN ACID GAS CARTRIDGE. USE A SELF-CONTAINED BREATHING APPARATUS IN CONFINED
SPACES AND FOR EMERGENCIES. AIR MONITORING IS NEEDED TO DETERMINE ACTUAL
EMPLOYEE EXPOSURE LEVELS.
THERMAL HAZARDS:
WEAR APPROPRIATE THERMAL PROTECTIVE CLOTHING, WHEN NECESSARY.
GENERAL HYGIENE CONSIDERATIONS:
KEEP AWAY FROM FOOD AND DRINK. ALWAYS OBSERVE GOOD PERSONAL HYGIENE
MEASURES, SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING,
DRINKING, AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE
EQUIPMENT TO REMOVE CONTAMINANTS.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
FORM: LIQUID.
COLOR: WHITE.
ODOR: ACID.
ODOR THRESHOLD: NOT AVAILABLE.
PH: <1
MELTING POINT/FREEZING POINT: <0 DEG. F (<-17.8 DEG. C)
INITIAL BOILING POINT AND BOILING RANGE: 185 DEG. F (85 DEG. C)
FLASH POINT: NONE (TAG CLOSED CUP)
EVAPORATION RATE: SLOW.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: 15.9 HPA ESTIMATED
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 1.16
SOLUBILITY (WATER): COMPLETELY SOLUBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY (KINEMATIC): NOT AVAILABLE.
PERCENT VOLATILE: 67.4% ESTIMATED
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
REACTS VIOLENTLY WITH STRONG ALKALINE SUBSTANCES. THIS PRODUCT MAY REACT
WITH REDUCING AGENTS. MAY BE CORROSIVE TO METALS.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CONDITIONS TO AVOID:
DO NOT MIX WITH OTHER CHEMICALS. CONTACT WITH INCOMPATIBLE MATERIALS. WHEN
EXPOSED TO EXTREME HEAT OR HOT SURFACES, VAPORS MAY DECOMPOSE TO HARMFUL
OR FATAL CORROSIVE GASES SUCH AS HYDROGEN CHLORIDE AND POSSIBLY PHOSGENE.
INCOMPATIBLE MATERIALS:
CHLORINE. ALKALIES. STRONG OXIDIZING AGENTS. REDUCING AGENTS. METALS.
AMINES.
HAZARDOUS DECOMPOSITION PRODUCTS: HYDROGEN CHLORIDE. PHOSGENE.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION:
MAY CAUSE IRRITATION TO THE RESPIRATORY SYSTEM. PROLONGED INHALATION MAY BE
HARMFUL.
SKIN CONTACT: CAUSES SEVERE SKIN BURNS.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: CAUSES DIGESTIVE TRACT BURNS. HARMFUL IF SWALLOWED.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
BURNING PAIN AND SEVERE CORROSIVE SKIN DAMAGE. CAUSES SERIOUS EYE DAMAGE.
SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND BLURRED
VISION. PERMANENT EYE DAMAGE INCLUDING BLINDNESS COULD RESULT. MAY CAUSE
RESPIRATORY IRRITATION.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
IN HIGH CONCENTRATIONS, VAPORS ARE ANESTHETIC AND MAY CAUSE HEADACHE,
FATIGUE, DIZZINESS AND CENTRAL NERVOUS SYSTEM EFFECTS. HARMFUL IF
SWALLOWED. MAY CAUSE RESPIRATORY IRRITATION.
PRODUCT SPECIES TEST RESULTS
ON & OFF HULL & BOTTOM CLEANER:
ACUTE:
DERMAL:
LD50 RABBIT >2000 MG/KG CALCULATED
INHALATION:
LC50 RAT >20 MG/L, 4 HOURS CALCULATED
ORAL:
LD50 RAT >930 MG/KG CALCULATED
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
SKIN CORROSION/IRRITATION: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE DAMAGE.
RESPIRATORY SENSITIZATION: NOT AVAILABLE.
SKIN SENSITIZATION:
THIS PRODUCT IS NOT EXPECTED TO CAUSE SKIN SENSITIZATION.
GERM CELL MUTAGENICITY:
NO DATA AVAILABLE TO INDICATE PRODUCT OR ANY COMPONENTS PRESENT AT GREATER
THAN 0.1% ARE MUTAGENIC OR GENOTOXIC.
CARCINOGENICITY:
THIS PRODUCT IS NOT CONSIDERED TO BE A CARCINOGEN BY IARC, ACGIH, NTP, OR
OSHA.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
HYDROCHLORIC ACID (CAS 7647-01-0):
3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
MAY CAUSE RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT EXPECTED TO BE AN ASPIRATION HAZARD.
CHRONIC EFFECTS: PROLONGED INHALATION MAY BE HARMFUL.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
TOXIC TO AQUATIC LIFE. HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
BECAUSE OF THE LOW PH OF THIS PRODUCT, IT WOULD BE EXPECTED TO PRODUCE
SIGNIFICANT ECOTOXICITY UPON EXPOSURE TO AQUATIC ORGANISMS AND AQUATIC
SYSTEMS.
PRODUCT SPECIES TEST RESULTS
ON & OFF HULL & BOTTOM CLEANER:
AQUATIC:
ACUTE:
CRUSTACEA EC50 DAPHNIA 14.7335 MG/L, 48 HOURS ESTIMATED
FISH LC50 FISH 99.4512 MG/L, 96 HOURS ESTIMATED
COMPONENTS SPECIES TEST RESULTS
ALCOHOLS, C12-15, ETHOXYLATED (CAS 68131-39-5):
AQUATIC:
ACUTE:
CRUSTACEA EC50 WATER FLEA 0.4 - 0.75 MG/L, 48 HOURS
(DAPHNIA MAGNA)
FISH LC50 FATHEAD MINNOW 2.7 MG/L, 96 HOURS
(PIMEPHALES
PROMELAS)
HYDROCHLORIC ACID (CAS 7647-01-0):
AQUATIC:
FISH LC50 WESTERN 282 MG/L, 96 HOURS
MOSQUITOFISH
(GAMBUSIA
AFFINIS)
OXALIC ACID (CAS 144-62-7):
AQUATIC:
CRUSTACEA EC50 WATER FLEA 125 - 150 MG/L, 48 HOURS
(DAPHNIA MAGNA)
* ESTIMATES FOR PRODUCT MAY BE BASED ON ADDITIONAL COMPONENT DATA NOT
SHOWN.
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
MOBILITY IN SOIL: NO DATA AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL OF WASTE FROM RESIDUES / UNUSED PRODUCTS:
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF AS HAZARDOUS WASTE.
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. DO NOT ALLOW THIS MATERIAL TO DRAIN INTO SEWERS/WATER
SUPPLIES. DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR
USED CONTAINER. DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
D002: WASTE CORROSIVE MATERIAL [PH <=2 OR =>12.5, OR CORROSIVE TO STEEL]
CONTAMINATED PACKAGING:
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL. SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE,
FOLLOW LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
| 14. TRANSPORT INFORMATION | |
DOT:
UN NUMBER: UN3264
UN PROPER SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC ACID RQ = 24510
LBS, PHOSPHORIC ACID RQ = 73529 LBS), LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 8
SUBSIDIARY RISK:
LABEL(S): 8
PACKING GROUP: II
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
SPECIAL PROVISIONS: B2, IB2, T11, TP2, TP27
PACKAGING EXCEPTIONS: 154
PACKAGING NON BULK: 202
PACKAGING BULK: 242
IATA:
AIR: NOT PERMITTED FOR SHIPMENT BY AIR.
IMDG:
UN NUMBER: UN3264
UN PROPER SHIPPING NAME:
CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC ACID, PHOSPHORIC
ACID), LIMITED QUANTITY
TRANSPORT HAZARD CLASS(ES):
CLASS: 8
SUBSIDIARY RISK:
PACKING GROUP: II
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO.
EMS: F-A, S-B
SPECIAL PRECAUTIONS FOR USER:
READ SAFETY INSTRUCTIONS, SDS AND EMERGENCY PROCEDURES BEFORE HANDLING.
| 15. REGULATORY INFORMATION | |
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL COMPONENTS ARE ON THE U.S. EPA TSCA INVENTORY LIST.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
OXALIC ACID (CAS 144-62-7): 1.0% ONE-TIME EXPORT NOTIFICATION ONLY.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
NOT LISTED.
SARA 304 EMERGENCY RELEASE NOTIFICATION: NOT REGULATED.
US EPCRA (SARA TITLE III) SECTION 313 - TOXIC CHEMICAL LISTED SUBSTANCE
NOT LISTED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
HYDROCHLORIC ACID (CAS 7647-01-0): LISTED.
PHOSPHORIC ACID (CAS 7664-38-2): LISTED.
CERCLA HAZARDOUS SUBSTANCES REPORTABLE QUANTITY
HYDROCHLORIC ACID (CAS 7647-01-0) 5000 LBS
PHOSPHORIC ACID (CAS 7664-38-2) 5000 LBS
SPILLS OR RELEASES RESULTING IN THE LOSS OF ANY INGREDIENT AT OR ABOVE ITS
RQ REQUIRE IMMEDIATE NOTIFICATION TO THE NATIONAL RESPONSE CENTER
(800-424-8802) AND TO YOUR LOCAL EMERGENCY PLANNING COMMITTEE.
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
HYDROCHLORIC ACID (CAS 7647-01-0)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION
40 CFR 68.130): NOT REGULATED.
SAFE DRINKING WATER ACT (SDWA): NOT REGULATED.
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 2, ESSENTIAL CHEMICALS
(21 CFR 1310.02(B) AND 1310.04(F)(2) AND CHEMICAL CODE NUMBER:
HYDROCHLORIC ACID (CAS 7647-01-0): 6545
DRUG ENFORCEMENT ADMINISTRATION (DEA). LIST 1 & 2 EXEMPT CHEMICAL MIXTURES
(21 CFR 1310.12(C)):
HYDROCHLORIC ACID (CAS 7647-01-0): 20 %WV
DEA EXEMPT CHEMICAL MIXTURES CODE NUMBER:
HYDROCHLORIC ACID (CAS 7647-01-0): 6545
FOOD AND DRUG ADMINISTRATION (FDA): NOT REGULATED.
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
SECTION 311/312 HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: NO
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
US STATE REGULATIONS:
US. CALIFORNIA. CANDIDATE CHEMICALS LIST. SAFER CONSUMER PRODUCTS
REGULATIONS (CAL. CODE REGS, TIT. 22, 69502.3, SUBD. (A)):
HYDROCHLORIC ACID (CAS 7647-01-0)
PHOSPHORIC ACID (CAS 7664-38-2)
US. CALIFORNIA CONTROLLED SUBSTANCES. CA DEPARTMENT OF JUSTICE
(CALIFORNIA HEALTH AND SAFETY CODE SECTION 11100): NOT LISTED.
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
OXALIC ACID (CAS 144-62-7)
PHOSPHORIC ACID (CAS 7664-38-2)
HYDROCHLORIC ACID (CAS 7647-01-0)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
HYDROCHLORIC ACID (CAS 7647-01-0)
OXALIC ACID (CAS 144-62-7)
PHOSPHORIC ACID (CAS 7664-38-2)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
HYDROCHLORIC ACID (CAS 7647-01-0)
PHOSPHORIC ACID (CAS 7664-38-2)
OXALIC ACID (CAS 144-62-7)
US. RHODE ISLAND RTK:
HYDROCHLORIC ACID (CAS 7647-01-0)
PHOSPHORIC ACID (CAS 7664-38-2)
US. CALIFORNIA PROPOSITION 65:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986
(PROPOSITION 65):
THIS MATERIAL IS NOT KNOWN TO CONTAIN ANY CHEMICALS CURRENTLY LISTED AS
CARCINOGENS OR REPRODUCTIVE TOXINS.
VOLATILE ORGANIC COMPOUNDS (VOC) REGULATIONS:
EPA:
VOC CONTENT (40 CFR 51.100(S)): NOT DETERMINED
CONSUMER PRODUCTS (40 CFR 59, SUBPT. C): NOT REGULATED
STATE:
CONSUMER PRODUCTS: NOT REGULATED
VOC CONTENT (CA): <0.5%
VOC CONTENT (OTC): <0.5%
INTERNATIONAL INVENTORIES:
COUNTRY(S) INVENTORY NAME ON INVENTORY
OR REGION (YES/NO)*
AUSTRALIA AUSTRALIAN INVENTORY OF CHEMICAL YES
SUBSTANCES (AICS)
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
CHINA INVENTORY OF EXISTING CHEMICAL SUBSTANCES YES
IN CHINA (IECSC)
EUROPE EUROPEAN INVENTORY OF EXISTING COMMERCIAL NO
CHEMICAL SUBSTANCES (EINECS)
EUROPE EUROPEAN LIST OF NOTIFIED CHEMICAL NO
SUBSTANCES (ELINCS)
JAPAN INVENTORY OF EXISTING AND NEW CHEMICAL YES
SUBSTANCES (ENCS)
KOREA EXISTING CHEMICALS LIST (ECL) YES
NEW ZEALAND NEW ZEALAND INVENTORY YES
PHILIPPINES PHILIPPINE INVENTORY OF CHEMICALS AND YES
CHEMICAL SUBSTANCES (PICCS)
UNITED STATES & TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
A "NO" INDICATES THAT ONE OR MORE COMPONENTS OF THE PRODUCT ARE NOT LISTED
OR EXEMPT FROM LISTING ON THE INVENTORY ADMINISTERED BY THE GOVERNING
COUNTRY(S).
| 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION | |
OR LAST REVISION
ISSUE DATE: 04-07-2015
PREPARED BY: ALLISON CHO
VERSION #: 01
FURTHER INFORMATION: NOT AVAILABLE.
HMIS(R*) RATINGS:
HEALTH 3
FLAMMABILITY 0
PHYSICAL HAZARD 1
PERSONAL PROTECTION D
NFPA RATINGS:
HEALTH 3
FLAMMABILITY 0
INSTABILITY 1
NFPA RATINGS:
3
0
1
DISCLAIMER:
CRC CANNOT ANTICIPATE ALL CONDITIONS UNDER WHICH THIS INFORMATION AND ITS
PRODUCT, OR THE PRODUCTS OF OTHER MANUFACTURERS IN COMBINATION WITH ITS
PRODUCT, MAY BE USED. IT IS THE USER'S RESPONSIBILITY TO ENSURE SAFE
CONDITIONS FOR HANDLING, STORAGE AND DISPOSAL OF THE PRODUCT, AND TO
ASSUME LIABILITY FOR LOSS, INJURY, DAMAGE OR EXPENSE DUE TO IMPROPER USE.
THE INFORMATION CONTAINED IN THIS DOCUMENT APPLIES TO THIS SPECIFIC
MATERIAL AS SUPPLIED. IT MAY NOT BE VALID FOR THIS MATERIAL IF IT IS USED
IN COMBINATION WITH ANY OTHER MATERIALS. THIS INFORMATION IS ACCURATE TO
THE BEST OF CRC INDUSTRIES' KNOWLEDGE OR OBTAINED FROM SOURCES BELIEVED BY
CRC TO BE ACCURATE. BEFORE USING ANY PRODUCT, READ ALL WARNINGS AND
DIRECTIONS ON THE LABEL. FOR FURTHER CLARIFICATION OF ANY INFORMATION
CONTAINED ON THIS (M)SDS CONSULT YOUR SUPERVISOR, A HEALTH & SAFETY
PROFESSIONAL, OR CRC INDUSTRIES.
MATERIAL NAME: ON & OFF HULL & BOTTOM CLEANER
SDS: US