| Common Name: | PAINT INK BLACK 2568 |
| Manufacturer: | REINOL ITALY |
| SDS Revision Date: | 7/12/2021 |
| SDS Format: | No Format Specified |
| Item Number(s): | 19N841 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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REINOL S.R.L.
PNT00032002AB - PAINT INK BLACK 2568
REVISION NR.5
DATED: 12/07/2021
PRINTED ON: 13/07/2021
REPLACED REVISION: 4 (DATED 08/10/2020)
EN
SAFETY DATA SHEET
ACCORDING TO ANNEX II TO REACH - REGULATION 2015/830
| SECTION 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
CODE: PNT00032002AB
PRODUCT NAME: PAINT INK BLACK 2568
UFI: YA20-M05Q-R005-HS3E
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES
ADVISED AGAINST:
INTENDED USE: INK FOR VALVE MARKERS
IDENTIFIED USES INDUSTRIAL PROFESSIONAL CONSUMER
INKS (X) (X) (X)
USES ADVISED AGAINST: DO NOT USE FOR PURPOSES OTHER THAN THOSE SPECIFIED
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
NAME: REINOL S.R.L.
FULL ADDRESS: STRADA DEL FRANCESE 21
DISTRICT AND COUNTRY:
10071 BORGARO T.SE (TO)
ITALIA
TEL.: +39 011 4701510
FAX: +39 011 4703910
E-MAIL ADDRESS OF THE COMPETENT PERSON RESPONSIBLE FOR THE SAFETY DATA
SHEET: INFO@REINOL.IT
1.4. EMERGENCY TELEPHONE NUMBER:
FOR URGENT INQUIRIES REFER TO:
REINOL S.R.L. - TEL. +39 011-4701510 (H 09.00 -12.00) (H 14.00 -16.00)
WORKING DAYS
CAV "OSP. PEDIATRICO BAMBINO GESU" DIP. EMERGENZA E ACCETTAZIONE DEA -
PIAZZA SANT'ONOFRIO, 4 CAP 00165 ROMA
TEL.: 06-68593726
AZ. OSP. UNIV. FOGGIA - V.LE LUIGI PINTO, 1 CAP 71122 FOGGIA
TEL.: 800183459
AZ. OSP. A. CARDARELLI - VIA A. CARDARELLI, 9 CAP 80131 NAPOLI
TEL.: 081-5453333
CAV POLICLINICO UMBERTO I - V.LE DEL POLICLINICO, 155 CAP 00161 ROMA
TEL.: 06-49978000
CAV POLICLINICO A. GEMELLI - LARGO AGOSTINO GEMELLI, 8 CAP 00168 ROMA
TEL.: 06-3054343
AZ. OSP. CAREGGI - U.O. TOSSICOLOGIA MEDICA - LARGO BRAMBILLA, 3 CAP 50134
FIRENZE
TEL.: 055-7947819
CAV CENTRO NAZIONALE DI INFORMAZIONE TOSSICOLOGICA - VIA SALVATORE
MAUGERI, 10 CAP 27100 PAVIA
TEL.: 0382-24444
OSP. NIGUARDA CA' GRANDA - PIAZZA OSPEDALE MAGGIORE, 3 CAP 20162 MILANO
TEL.: 02-66101029
AZIENDA OSPEDALIERA PAPA GIOVANNI XXIII - PIAZZA OMS, 1 CAP 24127 BERGAMO
TEL.: 800-883300
AZIENDA OSPEDALIERA INTEGRATA VERONA - PIAZZALE ARISTIDE STEFANI,
1 - CAP 37126
TEL.: 800011858
SERVIZI OPERATIVI 24H/24H
| SECTION 2. HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
THE PRODUCT IS CLASSIFIED AS HAZARDOUS PURSUANT TO THE PROVISIONS SET
FORTH IN (EC) REGULATION 1272/2008 (CLP) (AND SUBSEQUENT AMENDMENTS AND
SUPPLEMENTS). THE PRODUCT THUS REQUIRES A SAFETY DATASHEET THAT COMPLIES
WITH THE PROVISIONS OF (EU) REGULATION 2015/830.
ANY ADDITIONAL INFORMATION CONCERNING THE RISKS FOR HEALTH AND/OR THE
ENVIRONMENT ARE GIVEN IN SECTIONS 11 AND 12 OF THIS SHEET.
HAZARD CLASSIFICATION AND INDICATION:
FLAMMABLE LIQUID, CATEGORY 3:
H226: FLAMMABLE LIQUID AND VAPOUR.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
2.2. LABEL ELEMENTS:
HAZARD LABELLING PURSUANT TO EC REGULATION 1272/2008 (CLP) AND SUBSEQUENT
AMENDMENTS AND SUPPLEMENTS.
HAZARD PICTOGRAMS:
FLAME
EXCLAMATION MARK
SIGNAL WORDS: WARNING
HAZARD STATEMENTS:
H226: FLAMMABLE LIQUID AND VAPOUR.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
EUH066: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
PRECAUTIONARY STATEMENTS:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P280:
WEAR PROTECTIVE GLOVES / PROTECTIVE CLOTHING / EYE PROTECTION / FACE
PROTECTION.
P370+P378:
IN CASE OF FIRE: USE EXTINGUISHING MEDIA APPROPRIATE TO EXTINGUISH.
P261: AVOID BREATHING DUST / FUME / GAS / MIST / VAPOURS / SPRAY.
P312:
CALL A POISON CENTRE / A DOCTOR / A CENTER SUITABLE FOR EMERGENCY MEDICAL
ADVICE IF YOU FEEL UNWELL.
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
CONTAINS:
N-BUTYL ACETATE
1-METHOXYPROPAN-2-OL
2-METHOXY-1-METHYLETHYL ACETATE
2.3. OTHER HAZARDS:
ON THE BASIS OF AVAILABLE DATA, THE PRODUCT DOES NOT CONTAIN ANY PBT OR
VPVB IN PERCENTAGE >/= THAN 0,1%.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
3.2. MIXTURES:
CONTAINS:
IDENTIFICATION X = CONC. % CLASSIFICATION
1272/2008 (CLP)
N-BUTYL ACETATE
CAS: 123-86-4 40 </= X <45 FLAM. LIQ. 3 H226,
EC: 204-658-1 STOT SE 3 H336, EUH066
INDEX: 607-025-00-1
REG. NO.: 01-2119485493-29-XXXX
1-METHOXYPROPAN-2-OL
CAS: 107-98-2 25 </= X <28 FLAM. LIQ. 3 H226,
EC: 203-539-1 STOT SE 3 H336
INDEX: 603-064-00-3
REG. NO.: 01-2119457435-35-XXXX
2-METHOXY-1-METHYLETHYL ACETATE
CAS: 108-65-6 5 </= X <7 FLAM. LIQ. 3 H226,
EC: 203-603-9 STOT SE 3 H336
INDEX: 607-195-00-7
REG. NO.: 01-2119475791-29-XXXX
THE FULL WORDING OF HAZARD (H) PHRASES IS GIVEN IN SECTION 16 OF THE SHEET.
| SECTION 4. FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
EYES:
REMOVE CONTACT LENSES, IF PRESENT. WASH IMMEDIATELY WITH PLENTY OF WATER
FOR AT LEAST 15 MINUTES, OPENING THE EYELIDS FULLY. IF PROBLEM PERSISTS,
SEEK MEDICAL ADVICE.
SKIN:
REMOVE CONTAMINATED CLOTHING. WASH IMMEDIATELY WITH PLENTY OF WATER. IF
IRRITATION PERSISTS, GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED
CLOTHING BEFORE USING IT AGAIN.
INHALATION:
REMOVE TO OPEN AIR. IN THE EVENT OF BREATHING DIFFICULTIES, GET MEDICAL
ADVICE/ATTENTION IMMEDIATELY.
INGESTION:
GET MEDICAL ADVICE/ATTENTION. INDUCE VOMITING ONLY IF INDICATED BY THE
DOCTOR. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON, UNLESS
AUTHORISED BY A DOCTOR.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SPECIFIC INFORMATION ON SYMPTOMS AND EFFECTS CAUSED BY THE PRODUCT ARE
UNKNOWN.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: INFORMATION NOT AVAILABLE
| SECTION 5. FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING EQUIPMENT:
EXTINGUISHING SUBSTANCES ARE:
CARBON DIOXIDE, FOAM, CHEMICAL POWDER. FOR PRODUCT LOSS OR LEAKAGE THAT
HAS NOT CAUGHT FIRE, WATER SPRAY CAN BE USED TO DISPERSE FLAMMABLE VAPOURS
AND PROTECT THOSE TRYING TO STEM THE LEAK.
UNSUITABLE EXTINGUISHING EQUIPMENT:
DO NOT USE JETS OF WATER. WATER IS NOT EFFECTIVE FOR PUTTING OUT FIRES BUT
CAN BE USED TO COOL CONTAINERS EXPOSED TO FLAMES TO PREVENT EXPLOSIONS.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
HAZARDS CAUSED BY EXPOSURE IN THE EVENT OF FIRE:
EXCESS PRESSURE MAY FORM IN CONTAINERS EXPOSED TO FIRE AT A RISK OF
EXPLOSION. DO NOT BREATHE COMBUSTION PRODUCTS.
5.3. ADVICE FOR FIREFIGHTERS:
GENERAL INFORMATION:
USE JETS OF WATER TO COOL THE CONTAINERS TO PREVENT PRODUCT DECOMPOSITION
AND THE DEVELOPMENT OF SUBSTANCES POTENTIALLY HAZARDOUS FOR HEALTH. ALWAYS
WEAR FULL FIRE PREVENTION GEAR. COLLECT EXTINGUISHING WATER TO PREVENT IT
FROM DRAINING INTO THE SEWER SYSTEM. DISPOSE OF CONTAMINATED WATER USED
FOR EXTINCTION AND THE REMAINS OF THE FIRE ACCORDING TO APPLICABLE
REGULATIONS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
NORMAL FIRE FIGHTING CLOTHING I.E. FIRE KIT (BS EN 469), GLOVES (BS EN 659)
AND BOOTS (HO SPECIFICATION A29 AND A30) IN COMBINATION WITH SELF-CONTAINED
OPEN CIRCUIT POSITIVE PRESSURE COMPRESSED AIR BREATHING APPARATUS
(BS EN 137).
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
BLOCK THE LEAKAGE IF THERE IS NO HAZARD.
WEAR SUITABLE PROTECTIVE EQUIPMENT (INCLUDING PERSONAL PROTECTIVE EQUIPMENT
REFERRED TO UNDER SECTION 8 OF THE SAFETY DATA SHEET) TO PREVENT ANY
CONTAMINATION OF SKIN, EYES AND PERSONAL CLOTHING. THESE INDICATIONS APPLY
FOR BOTH PROCESSING STAFF AND THOSE INVOLVED IN EMERGENCY PROCEDURES.
SEND AWAY INDIVIDUALS WHO ARE NOT SUITABLY EQUIPPED. USE EXPLOSION-PROOF
EQUIPMENT. ELIMINATE ALL SOURCES OF IGNITION (CIGARETTES, FLAMES, SPARKS,
ETC.) FROM THE LEAKAGE SITE.
6.2. ENVIRONMENTAL PRECAUTIONS:
THE PRODUCT MUST NOT PENETRATE INTO THE SEWER SYSTEM OR COME INTO CONTACT
WITH SURFACE WATER OR GROUND WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
COLLECT THE LEAKED PRODUCT INTO A SUITABLE CONTAINER. EVALUATE THE
COMPATIBILITY OF THE CONTAINER TO BE USED, BY CHECKING SECTION 10. ABSORB
THE REMAINDER WITH INERT ABSORBENT MATERIAL.
MAKE SURE THE LEAKAGE SITE IS WELL AIRED. CONTAMINATED MATERIAL SHOULD BE
DISPOSED OF IN COMPLIANCE WITH THE PROVISIONS SET FORTH IN POINT 13.
6.4. REFERENCE TO OTHER SECTIONS:
ANY INFORMATION ON PERSONAL PROTECTION AND DISPOSAL IS GIVEN IN
SECTIONS 8 AND 13.
| SECTION 7. HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP AWAY FROM HEAT, SPARKS AND NAKED FLAMES; DO NOT SMOKE OR USE MATCHES
OR LIGHTERS. WITHOUT ADEQUATE VENTILATION, VAPOURS MAY ACCUMULATE AT GROUND
LEVEL AND, IF IGNITED, CATCH FIRE EVEN AT A DISTANCE, WITH THE DANGER OF
BACKFIRE. AVOID BUNCHING OF ELECTROSTATIC CHARGES. DO NOT EAT, DRINK OR
SMOKE DURING USE. REMOVE ANY CONTAMINATED CLOTHES AND PERSONAL PROTECTIVE
EQUIPMENT BEFORE ENTERING PLACES IN WHICH PEOPLE EAT. AVOID LEAKAGE OF THE
PRODUCT INTO THE ENVIRONMENT.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE ONLY IN THE ORIGINAL CONTAINER. STORE IN A COOL AND WELL VENTILATED
PLACE, KEEP FAR AWAY FROM SOURCES OF HEAT, NAKED FLAMES AND SPARKS AND
OTHER SOURCES OF IGNITION. KEEP CONTAINERS AWAY FROM ANY INCOMPATIBLE
MATERIALS, SEE SECTION 10 FOR DETAILS.
7.3. SPECIFIC END USE(S): INFORMATION NOT AVAILABLE
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
REGULATORY REFERENCES:
BGR:
XXXBNRAPXXX:
HAPEXXXA NO 13 OT 30 XXXEKEMBPXXX 2003 XXXR. 3A 3AXXXTA HA PAXXXOTEXXXTE
OT PXXXCKOBE, CBXXXP3AHXXX C EKCXXXO3XXX HA XXXXMXXX AXXXEHTXXX XXXPXXX
PAXXXOTA (XXX3M. XXXB. 6P.5 OT 17 XXXHYAPXXX 2020R.)
CZE:
CESKA REPUBLIKA:
NARIZENI VLADY C. 41/2020 SB. NARIZENI VLADY, KTERYM SE MENI NARIZENI
VLADY C. 361/2007 SB., KTERYM SE SIANOVI PODMINKY OCHRANY ZDRAVI PRI
PRACI, VE ZNENI POZDEJSICH PREDPISU
DEU:
DEUTSCHLAND:
TECHNISCHEN REGELN FUR GEFAHRSTOFFE (TRGS 900) - LISTE DER
ARBEITSPLATZGRENZWERTE UND KURZZEITWERTE. MAK- UND BAT-WERTE-LISTE 2020,
STANDIGE SENATSKOMMISSION ZUR PRUFUNG GESUNDHEITSSCHADLICHER ARBEITSSTOFFE,
MITTEILUNG 56
ESP:
ESPANA:
LIMITES DE EXPOSICION PROFESIONAL PARA AGENTES QUIMICOS EN ESPANA 2019
FRA:
FRANCE:
VALEURS LIMITES D'EXPOSITION PROFESSIONNELLE AUX AGENTS CHIMIQUES EN
FRANCE. ED 984 - INRS
HUN:
MAGYARORSZAG:
AZ INNOVACIOERT ES TECHNOLOGIAERT FELELOS MINISZTER 5/2020. (II. 6.) ITM
RENDELETE A KEMIAI KOROKI TENYEZOK HATASANAK KITETT MUNKAVALLALOK
EGESZSEGENEK ES BIZTONSAGANAK VEDELMEROL
ITA:
ITALIA: DECRETO LEGISLATIVO 9 APRILE 2008, N.81
NLD:
NEDERLAND:
ARBEIDSOMSTANDIGHEDENREGELING. LIJST VAN WETTELIJKE GRENSWAARDEN OP GROND
VAN DE ARTIKELEN 4.3, EERSTE LID, EN 4.16, EERSTE LID, VAN HET
ARBEIDSOMSTANDIGHEDENBESLUIT
POL:
POLSKA:
ROZPORZADZENIE MINISTRA RODZINY, PRACY I POLITYKI SPOTECZNEJ Z DNIA 12
CZERWCA 2018 R. W SPRAWIE NAJWYZSZYCH DOPUSZCZALNYCH STEZEN I NATEZEN
CZYNNIKOW SZKODLIWYCH DLA ZDROWIA W SRODOWISKU PRACY
SWE:
SVERIGE:
HYGIENISKA GRANSVARDEN, ARBETSMILJOVERKETS FORESKRIFTER OCH ALLMANNA RAD
OM HYGIENISKA GRANSVARDEN (AFS 2018:1)
SVN:
SLOVENIJA:
PRAVILNIK O VAROVANJU DELAVCEV PRED TVEGANJI ZARADI IZPOSTAVLJENOSTI
KEMICNIM SNOVEM PRI DELU (URADNI LIST RS, ST. 100/01,39/05, 53/07, 102/10,
43/11 - ZVZD-1,38/15, 78/18 IN 78/19)
GBR:
UNITED KINGDOM: EH40/2005 WORKPLACE EXPOSURE LIMITS (FOURTH EDITION 2020)
EU:
OEL EU:
DIRECTIVE (EU) 2019/1831; DIRECTIVE (EU) 2019/130; DIRECTIVE (EU) 2019/983;
DIRECTIVE (EU) 2017/2398; DIRECTIVE (EU) 2017/164; DIRECTIVE 2009/161/EU;
DIRECTIVE 2006/15/EC; DIRECTIVE 2004/37/EC; DIRECTIVE 2000/39/EC; DIRECTIVE
98/24/EC; DIRECTIVE 91/322/EEC.
TLV-ACGIH: ACGIH 2020
N-BUTYL ACETATE:
THRESHOLD LIMIT VALUE:
TYPE COUNTRY TWA/8H STEL/15MIN REMARKS /
MG/M3 PPM MG/M3 PPM OBSERVATIONS
TLV CZE 950 196,55 1200 284,4
MAK DEU 300 62 600 124
VLA ESP 724 150 965 200
VLEP FRA 710 150 940 200
AK HUN 241 723
TGG NLD 150
NDS/NDSCH POL 240 720
NGV/KGV SWE 500 100 700 150
WEL GBR 724 150 966 200
OEL EU 241 50 723 150
TLV-ACGIH 713 150
PREDICTED NO-EFFECT CONCENTRATION - PNEC:
NORMAL VALUE IN FRESH WATER: 0,18 MG/L
NORMAL VALUE IN MARINE WATER: 0,018 MG/L
NORMAL VALUE FOR FRESH WATER SEDIMENT: 0,981 MG/KG
NORMAL VALUE FOR MARINE WATER SEDIMENT: 0,0981 MG/KG
NORMAL VALUE FOR WATER, INTERMITTENT RELEASE: 0,36 MG/L
NORMAL VALUE OF STP MICROORGANISMS: 35,6 MG/L
NORMAL VALUE FOR THE TERRESTRIAL COMPARTMENT: 0,0903 MG/KG
NORMAL VALUE FOR THE ATMOSPHERE: NPI
HEALTH - DERIVED NO-EFFECT LEVEL - DNEL / DMEL:
ROUTE OF EXPOSURE EFFECTS ON CONSUMERS
ACUTE ACUTE CHRONIC CHRONIC
LOCAL SYSTEMIC LOCAL SYSTEMIC
ORAL VND 2 MG/KG BW/D VND 2 MG/KG BW/D
INHALATION 300 MG/M3 300 MG/M3 35,7 MG/M3 35,7 MG/M3
SKIN NPI 6 MG/KG BW/D NPI 6 MG/KG BW/D
ROUTE OF EXPOSURE EFFECTS ON WORKERS
ACUTE ACUTE CHRONIC CHRONIC
LOCAL SYSTEMIC LOCAL SYSTEMIC
ORAL
INHALATION 600 MG/M3 600 MG/M3 300 MG/M3 300 MG/M3
SKIN NPI 11 MG/KG BW/D NPI 11 MG/KG BW/D
1-METHOXYPROPAN-2-OL:
THRESHOLD LIMIT VALUE:
TYPE COUNTRY TWA/8H STEL/15MIN REMARKS /
MG/M3 PPM MG/M3 PPM OBSERVATIONS
TLV BGR 375 100 568 150 SKIN
TLV CZE 270 72,09 550 146,85 SKIN
AGW DEU 370 100 740 200
MAK DEU 370 100 740 200
VLA ESP 375 100 568 150 SKIN
VLEP FRA 188 50 375 100 SKIN
AK HUN 375 568 SKIN
VLEP ITA 375 100 568 150 SKIN
TGG NLD 375 563 SKIN
NDS/NDSCH POL 180 360 SKIN
NGV/KGV SWE 190 50 568 150 SKIN
MV SVN 375 100 568 150 SKIN
WEL GBR 375 100 560 150 SKIN
OEL EU 375 100 568 150 SKIN
TLV-ACGIH 184 50 368 100
PREDICTED NO-EFFECT CONCENTRATION - PNEC:
NORMAL VALUE IN FRESH WATER: 10 MG/L
NORMAL VALUE IN MARINE WATER: 1 MG/L
NORMAL VALUE FOR FRESH WATER SEDIMENT: 52,3 MG/KG
NORMAL VALUE FOR MARINE WATER SEDIMENT: 5,2 MG/KG
NORMAL VALUE FOR WATER, INTERMITTENT RELEASE: 100 MG/L
NORMAL VALUE OF STP MICROORGANISMS: 100 MG/L
NORMAL VALUE FOR THE TERRESTRIAL COMPARTMENT: 4,59 MG/KG
NORMAL VALUE FOR THE ATMOSPHERE: NPI
HEALTH - DERIVED NO-EFFECT LEVEL - DNEL / DMEL:
ROUTE OF EXPOSURE EFFECTS ON CONSUMERS
ACUTE ACUTE CHRONIC CHRONIC
LOCAL SYSTEMIC LOCAL SYSTEMIC
ORAL VND 33 MG/KG BW/D
INHALATION NPI 43,9 MG/M3
SKIN NPI 78 MG/KG BW/D
ROUTE OF EXPOSURE EFFECTS ON WORKERS
ACUTE ACUTE CHRONIC CHRONIC
LOCAL SYSTEMIC LOCAL SYSTEMIC
ORAL
INHALATION 553,5 MG/M3 553,5 MG/M3 NPI 369 MG/M3
SKIN NPI 183 MG/KG BW/D
2-METHOXY-1-METHYLETHYL ACETATE:
THRESHOLD LIMIT VALUE:
TYPE COUNTRY TWA/8H STEL/15MIN REMARKS /
MG/M3 PPM MG/M3 PPM OBSERVATIONS
TLV BGR 275 550 SKIN
TLV CZE 270 550 SKIN
AGW DEU 270 50 270 50
MAK DEU 270 50 270 50
VLA ESP 275 50 550 100 SKIN
VLEP FRA 275 50 550 100 SKIN
AK HUN 275 550
VLEP ITA 275 50 550 100 SKIN
TGG NLD 550
NDS/NDSCH POL 260 520
NGV/KGV SWE 275 50 550 100 SKIN
WEL GBR 274 50 548 100
OEL EU 275 50 550 100 SKIN
PREDICTED NO-EFFECT CONCENTRATION - PNEC:
NORMAL VALUE IN FRESH WATER: 0,635 MG/L
NORMAL VALUE IN MARINE WATER: 0,0635 MG/L
NORMAL VALUE FOR FRESH WATER SEDIMENT: 3,29 MG/KG
NORMAL VALUE FOR MARINE WATER SEDIMENT: 0,329 MG/KG
NORMAL VALUE FOR WATER, INTERMITTENT RELEASE: 6,35 MG/L
NORMAL VALUE OF STP MICROORGANISMS: 100 MG/L
NORMAL VALUE FOR THE TERRESTRIAL COMPARTMENT: 0,29 MG/KG
NORMAL VALUE FOR THE ATMOSPHERE: NPI
HEALTH - DERIVED NO-EFFECT LEVEL - DNEL / DMEL:
ROUTE OF EXPOSURE EFFECTS ON CONSUMERS
ACUTE ACUTE CHRONIC CHRONIC
LOCAL SYSTEMIC LOCAL SYSTEMIC
ORAL 500 MG/KG BW/D VND 36 MG/KG BW/D
INHALATION 33 MG/M3 33 MG/M3
SKIN NPI 320 MG/KG BW/D
ROUTE OF EXPOSURE EFFECTS ON WORKERS
ACUTE ACUTE CHRONIC CHRONIC
LOCAL SYSTEMIC LOCAL SYSTEMIC
ORAL
INHALATION 550 MG/M3 NPI NPI 275 MG/M3
SKIN NPI 796 MG/KG BW/D
LEGEND:
(C) = CEILING
INHAL = INHALABLE FRACTION
RESP = RESPIRABLE FRACTION
THORA = THORACIC FRACTION.
VND = HAZARD IDENTIFIED BUT NO DNEL/PNEC AVAILABLE
NEA = NO EXPOSURE EXPECTED
NPI = NO HAZARD IDENTIFIED.
8.2. EXPOSURE CONTROLS:
AS THE USE OF ADEQUATE TECHNICAL EQUIPMENT MUST ALWAYS TAKE PRIORITY OVER
PERSONAL PROTECTIVE EQUIPMENT, MAKE SURE THAT THE WORKPLACE IS WELL AIRED
THROUGH EFFECTIVE LOCAL ASPIRATION.
WHEN CHOOSING PERSONAL PROTECTIVE EQUIPMENT, ASK YOUR CHEMICAL SUBSTANCE
SUPPLIER FOR ADVICE.
PERSONAL PROTECTIVE EQUIPMENT MUST BE CE MARKED, SHOWING THAT IT COMPLIES
WITH APPLICABLE STANDARDS.
HAND PROTECTION:
PROTECT HANDS WITH CATEGORY III WORK GLOVES (SEE STANDARD EN 374).
THE FOLLOWING SHOULD BE CONSIDERED WHEN CHOOSING WORK GLOVE MATERIAL:
COMPATIBILITY, DEGRADATION, FAILURE TIME AND PERMEABILITY.
THE WORK GLOVES' RESISTANCE TO CHEMICAL AGENTS SHOULD BE CHECKED BEFORE
USE, AS IT CAN BE UNPREDICTABLE. THE GLOVES' WEAR TIME DEPENDS ON THE
DURATION AND TYPE OF USE.
SKIN PROTECTION:
WEAR CATEGORY I PROFESSIONAL LONG-SLEEVED OVERALLS AND SAFETY FOOTWEAR
(SEE REGULATION 2016/425 AND STANDARD EN ISO 20344). WASH BODY WITH SOAP
AND WATER AFTER REMOVING PROTECTIVE CLOTHING.
CONSIDER THE APPROPRIATENESS OF PROVIDING ANTISTATIC CLOTHING IN THE CASE
OF WORKING ENVIRONMENTS IN WHICH THERE IS A RISK OF EXPLOSION.
EYE PROTECTION: WEAR AIRTIGHT PROTECTIVE GOGGLES (SEE STANDARD EN 166).
RESPIRATORY PROTECTION:
IF THE THRESHOLD VALUE (E.G. TLV-TWA) IS EXCEEDED FOR THE SUBSTANCE OR ONE
OF THE SUBSTANCES PRESENT IN THE PRODUCT, USE A MASK WITH A TYPE A FILTER
WHOSE CLASS (1,2 OR 3) MUST BE CHOSEN ACCORDING TO THE LIMIT OF USE
CONCENTRATION. (SEE STANDARD EN 14387). IN THE PRESENCE OF GASES OR
VAPOURS OF VARIOUS KINDS AND/OR GASES OR VAPOURS CONTAINING PARTICULATE
(AEROSOL SPRAYS, FUMES, MISTS, ETC.) COMBINED FILTERS ARE REQUIRED.
RESPIRATORY PROTECTION DEVICES MUST BE USED IF THE TECHNICAL MEASURES
ADOPTED ARE NOT SUITABLE FOR RESTRICTING THE WORKER'S EXPOSURE TO THE
THRESHOLD VALUES CONSIDERED. THE PROTECTION PROVIDED BY MASKS IS IN ANY
CASE LIMITED.
IF THE SUBSTANCE CONSIDERED IS ODOURLESS OR ITS OLFACTORY THRESHOLD IS
HIGHER THAN THE CORRESPONDING TLV-TWA AND IN THE CASE OF AN EMERGENCY,
WEAR OPEN-CIRCUIT COMPRESSED AIR BREATHING APPARATUS (IN COMPLIANCE WITH
STANDARD EN 137) OR EXTERNAL AIR-INTAKE BREATHING APPARATUS (IN COMPLIANCE
WITH STANDARD EN 138). FOR A CORRECT CHOICE OF RESPIRATORY PROTECTION
DEVICE, SEE STANDARD EN 529.
ENVIRONMENTAL EXPOSURE CONTROLS:
THE EMISSIONS GENERATED BY MANUFACTURING PROCESSES, INCLUDING THOSE
GENERATED BY VENTILATION EQUIPMENT, SHOULD BE CHECKED TO ENSURE COMPLIANCE
WITH ENVIRONMENTAL STANDARDS.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PROPERTIES VALUE INFORMATION
APPEARANCE LIQUID
COLOUR BLACK
ODOUR CHARACTERISTIC OF SOLVENT
ODOUR THRESHOLD NOT DETERMINED
PH NOT APPLICABLE
MELTING POINT / FREEZING POINT NOT DETERMINED
INITIAL BOILING POINT NOT DETERMINED
BOILING RANGE NOT DETERMINED
FLASH POINT >23 DEG. C
EVAPORATION RATE NOT DETERMINED
FLAMMABILITY OF SOLIDS AND GASES NOT AVAILABLE
LOWER INFLAMMABILITY LIMIT NOT DETERMINED
UPPER INFLAMMABILITY LIMIT NOT DETERMINED
LOWER EXPLOSIVE LIMIT NOT DETERMINED
UPPER EXPLOSIVE LIMIT NOT DETERMINED
VAPOUR PRESSURE NOT DETERMINED
VAPOUR DENSITY NOT DETERMINED
RELATIVE DENSITY 0,950 +/- 0,050 KG/L
SOLUBILITY IMMISCIBLE WITH WATER
PARTITION COEFFICIENT NOT DETERMINED
N-OCTANOL/WATER
AUTO-IGNITION TEMPERATURE NOT DETERMINED
DECOMPOSITION TEMPERATURE NOT DETERMINED
VISCOSITY NOT DETERMINED
EXPLOSIVE PROPERTIES NOT AVAILABLE
OXIDISING PROPERTIES NOT AVAILABLE
9.2. OTHER INFORMATION:
VOC (DIRECTIVE 2010/75/EC): 73,36% - 691,97 G/LITRE
VOC (VOLATILE CARBON): 42,88% - 404,50 G/LITRE
| SECTION 10. STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THERE ARE NO PARTICULAR RISKS OF REACTION WITH OTHER SUBSTANCES IN NORMAL
CONDITIONS OF USE.
10.2. CHEMICAL STABILITY:
THE PRODUCT IS STABLE IN NORMAL CONDITIONS OF USE AND STORAGE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
THE VAPOURS MAY ALSO FORM EXPLOSIVE MIXTURES WITH THE AIR.
10.4. CONDITIONS TO AVOID:
AVOID OVERHEATING. AVOID BUNCHING OF ELECTROSTATIC CHARGES. AVOID ALL
SOURCES OF IGNITION.
10.5. INCOMPATIBLE MATERIALS: INFORMATION NOT AVAILABLE
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
IN THE EVENT OF THERMAL DECOMPOSITION OR FIRE, GASES AND VAPOURS THAT ARE
POTENTIALLY DANGEROUS TO HEALTH MAY BE RELEASED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
IN THE ABSENCE OF EXPERIMENTAL DATA FOR THE PRODUCT ITSELF, HEALTH HAZARDS
ARE EVALUATED ACCORDING TO THE PROPERTIES OF THE SUBSTANCES IT CONTAINS,
USING THE CRITERIA SPECIFIED IN THE APPLICABLE REGULATION FOR
CLASSIFICATION.
IT IS THEREFORE NECESSARY TO TAKE INTO ACCOUNT THE CONCENTRATION OF THE
INDIVIDUAL HAZARDOUS SUBSTANCES INDICATED IN SECTION 3, TO EVALUATE THE
TOXICOLOGICAL EFFECTS OF EXPOSURE TO THE PRODUCT.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
METABOLISM, TOXICOKINETICS, MECHANISM OF ACTION AND OTHER INFORMATION:
INFORMATION NOT AVAILABLE
INFORMATION ON LIKELY ROUTES OF EXPOSURE: INFORMATION NOT AVAILABLE
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE: INFORMATION NOT AVAILABLE
INTERACTIVE EFFECTS: INFORMATION NOT AVAILABLE
ACUTE TOXICITY:
ATE (INHALATION) OF THE MIXTURE: NOT CLASSIFIED (NO SIGNIFICANT COMPONENT)
ATE (ORAL) OF THE MIXTURE: NOT CLASSIFIED (NO SIGNIFICANT COMPONENT)
ATE (DERMAL) OF THE MIXTURE: NOT CLASSIFIED (NO SIGNIFICANT COMPONENT)
2-METHOXY-1-METHYLETHYL ACETATE:
LD50 (ORAL): >5000 MG/KG RAT (FISCHER 344) - OECD GUIDELINE 401
LD50 (DERMAL): >2000 MG/KG RAT (FISCHER 344) - OECD GUIDELINE 402
N-BUTYL ACETATE:
LD50 (ORAL): >10760 MG/KG RAT (SPRAGUE-DAWLEY) - OECD GUIDELINE 423
LD50 (DERMAL): >14112 MG/KG RABBIT (NEW ZEALAND WHITE) - OECD GUIDELINE 402
LC50 (INHALATION): >6,6 MG/L/4H RAT (WISTAR) - OECD GUIDELINE 403
1-METHOXYPROPAN-2-OL:
LD50 (ORAL): 4016 MG/KG RAT (FISCHER 344) - EU METHOD B.1
LD50 (DERMAL): >2000 MG/KG RAT (FISCHER 344) - EU METHOD B.3
LC50 (INHALATION):
<6000 PPM/6H MOUSE (B6C3F1) (FEMALE) - OECD GUIDELINE 403
SKIN CORROSION / IRRITATION:
REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
SERIOUS EYE DAMAGE / IRRITATION:
DOES NOT MEET THE CLASSIFICATION CRITERIA FOR THIS HAZARD CLASS
RESPIRATORY OR SKIN SENSITISATION:
DOES NOT MEET THE CLASSIFICATION CRITERIA FOR THIS HAZARD CLASS
GERM CELL MUTAGENICITY:
DOES NOT MEET THE CLASSIFICATION CRITERIA FOR THIS HAZARD CLASS
CARCINOGENICITY:
DOES NOT MEET THE CLASSIFICATION CRITERIA FOR THIS HAZARD CLASS
REPRODUCTIVE TOXICITY:
DOES NOT MEET THE CLASSIFICATION CRITERIA FOR THIS HAZARD CLASS
STOT - SINGLE EXPOSURE: MAY CAUSE DROWSINESS OR DIZZINESS
STOT - REPEATED EXPOSURE:
DOES NOT MEET THE CLASSIFICATION CRITERIA FOR THIS HAZARD CLASS
ASPIRATION HAZARD:
DOES NOT MEET THE CLASSIFICATION CRITERIA FOR THIS HAZARD CLASS
| SECTION 12. ECOLOGICAL INFORMATION | |
USE THIS PRODUCT ACCORDING TO GOOD WORKING PRACTICES. AVOID LITTERING.
INFORM THE COMPETENT AUTHORITIES, SHOULD THE PRODUCT REACH WATERWAYS OR
CONTAMINATE SOIL OR VEGETATION.
12.1. TOXICITY:
2-METHOXY-1-METHYLETHYL ACETATE:
LC50 - FOR FISH: >100 MG/L/96H ONCORHYNCHUS MYKISS - OECD GUIDELINE 203
EC50 - FOR CRUSTACEA:
>500 MG/L/48H DAPHNIA MAGNA - EU METHOD C.2 (ACUTE TOXICITY FOR DAPHNIA)
EC50 - FOR ALGAE / AQUATIC PLANTS:
>1000 MG/L/72H PSEUDOKIRCHNERELLA SUBCAPITATA - OECD GUIDELINE 201
CHRONIC NOEC FOR FISH:
47,5 MG/L ORYZIAS LATIPES - OECD GUIDELINE 204 - TOTAL EXPOSURE DURATION:
14 D
CHRONIC NOEC FOR CRUSTACEA:
100 MG/L DAPHNIA MAGNA - OECD GUIDELINE 211 - TOTAL EXPOSURE DURATION: 21 D
CHRONIC NOEC FOR ALGAE / AQUATIC PLANTS:
1000 MG/L PSEUDOKIRCHNERELLA SUBCAPITATA - OECD GUIDELINE 201 - TOTAL
DURATION EXPOSURE: 72H
N-BUTYL ACETATE:
LC50 - FOR FISH: 18 MG/L/96H PIMEPHALES PROMELAS - OECD GUIDELINE 203
EC50 - FOR CRUSTACEA: 44 MG/L/48H DAPHNIA SP. - OECD GUIDELINE 202
EC50 - FOR ALGAE / AQUATIC PLANTS:
397 MG/L PSEUDOKIRCHNERIELLA SUBCAPITATA - OECD GUIDELINE 201
CHRONIC NOEC FOR CRUSTACEA:
23,2 MG/L DAPHNIA MAGNA - OECD GUIDELINE 211 - TOTAL EXPOSURE DURATION:
21 D
CHRONIC NOEC FOR ALGAE / AQUATIC PLANTS:
196 MG/L PSEUDOKIRCHNERIELLA SUBCAPITATA - OECD GUIDELINE 201 - TOTAL
EXPOSURE DURATION: 72 H
1-METHOXYPROPAN-2-OL:
LC50 - FOR FISH: 6812 MG/L/96H LEUCISCUS IDUS - DIN 38 412, PART L15
EC50 - FOR CRUSTACEA: 2954 MG/L/48H ACARTIA TONSA - ISO TC147/SC5/WG2
EC50 - FOR ALGAE / AQUATIC PLANTS:
6745 MG/L/72H SKELETONEMA COSTATUM - ISO 10253
12.2. PERSISTENCE AND DEGRADABILITY:
2-METHOXY-1-METHYLETHYL ACETATE:
SOLUBILITY IN WATER: >10000 MG/L
RAPIDLY DEGRADABLE:
N-BUTYL ACETATE:
SOLUBILITY IN WATER: 1000 - 10000 MG/L
RAPIDLY DEGRADABLE:
BIODEGRADATION:
83% (28 D) - METHOD: OECD GUIDELINE 301 D
1-METHOXYPROPAN-2-OL:
RAPIDLY DEGRADABLE:
12.3. BIOACCUMULATIVE POTENTIAL:
2- METHOXY-1-METHYLETHYL ACETATE:
PARTITION COEFFICIENT N-OCTANOL/WATER: 1,2
N-BUTYL ACETATE:
PARTITION COEFFICIENT N-OCTANOL/WATER: 2,3
BCF: 15,3
12.4. MOBILITY IN SOIL:
N-BUTYL ACETATE:
PARTITION COEFFICIENT SOIL/WATER: <3
12.5. RESULTS OF PBT AND VPVB ASSESSMENT:
ON THE BASIS OF AVAILABLE DATA, THE PRODUCT DOES NOT CONTAIN ANY PBT OR
VPVB IN PERCENTAGE >/= THAN 0,1%.
12.6. OTHER ADVERSE EFFECTS: INFORMATION NOT AVAILABLE
| SECTION 13. DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
REUSE, WHEN POSSIBLE. PRODUCT RESIDUES SHOULD BE CONSIDERED SPECIAL
HAZARDOUS WASTE. THE HAZARD LEVEL OF WASTE CONTAINING THIS PRODUCT SHOULD
BE EVALUATED ACCORDING TO APPLICABLE REGULATIONS.
DISPOSAL MUST BE PERFORMED THROUGH AN AUTHORISED WASTE MANAGEMENT FIRM,
IN COMPLIANCE WITH NATIONAL AND LOCAL REGULATIONS.
WASTE TRANSPORTATION MAY BE SUBJECT TO ADR RESTRICTIONS.
CONTAMINATED PACKAGING:
CONTAMINATED PACKAGING MUST BE RECOVERED OR DISPOSED OF IN COMPLIANCE WITH
NATIONAL WASTE MANAGEMENT REGULATIONS.
| SECTION 14. TRANSPORT INFORMATION | |
14.1. UN NUMBER:
ADR / RID, IMDG, IATA: 1263
14.2. UN PROPER SHIPPING NAME:
ADR / RID: PAINT OR PAINT RELATED MATERIAL
IMDG: PAINT OR PAINT RELATED MATERIAL
IATA: PAINT OR PAINT RELATED MATERIAL
14.3. TRANSPORT HAZARD CLASS(ES):
ADR/RID:
CLASS: 3
LABEL: 3 Y
CLASS 3, FLAMMABLE LIQUIDS
IMDG:
CLASS: 3
LABEL: 3 Y
CLASS 3 - FLAMMABLE LIQUIDS
IATA:
CLASS: 3
LABEL: 3 Y
CLASS 3, FLAMMABLE LIQUIDS
14.4. PACKING GROUP:
ADR / RID, IMDG, IATA: III
14.5. ENVIRONMENTAL HAZARDS:
ADR / RID: NO
IMDG: NO
IATA: NO
14.6. SPECIAL PRECAUTIONS FOR USER:
ADR / RID:
HIN - KEMLER: 30
LIMITED QUANTITIES: 5 L
TUNNEL RESTRICTION CODE: (D/E)
SPECIAL PROVISION:
IMDG:
EMS: F-E, S-E
LIMITED QUANTITIES: 5 L
IATA:
CARGO:
MAXIMUM QUANTITY: 220 L
PACKAGING INSTRUCTIONS: 366
PASS.:
MAXIMUM QUANTITY: 60 L
PACKAGING INSTRUCTIONS: 355
SPECIAL PROVISION: A3, A72, A192
14.7. TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
INFORMATION NOT RELEVANT
| SECTION 15. REGULATORY INFORMATION | |
15.1. SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC
FOR THE SUBSTANCE OR MIXTURE:
SEVESO CATEGORY - DIRECTIVE 2012/18/EC: P5C
RESTRICTIONS RELATING TO THE PRODUCT OR CONTAINED SUBSTANCES PURSUANT
TO ANNEX XVII TO EC REGULATION 1907/2006:
PRODUCT:
POINT: 3 - 40
CONTAINED SUBSTANCE:
POINT: 75 CARBON BLACK
REG. NO.: 01-2119384822-32-XXXX
POINT: 72 FORMALDEHYDE
REG. NO.: 01-2119488953-20-XXXX
REGULATION (EC) NO. 2019/1148 - ON THE MARKETING AND USE OF EXPLOSIVES
PRECURSORS: NOT APPLICABLE
SUBSTANCES IN CANDIDATE LIST (ART. 59 REACH):
ON THE BASIS OF AVAILABLE DATA, THE PRODUCT DOES NOT CONTAIN ANY SVHC
IN PERCENTAGE >/= THAN 0,1%.
SUBSTANCES SUBJECT TO AUTHORISATION (ANNEX XIV REACH): NONE
SUBSTANCES SUBJECT TO EXPORTATION REPORTING PURSUANT TO (EC) REG. 649/2012:
NONE
SUBSTANCES SUBJECT TO THE ROTTERDAM CONVENTION: NONE
SUBSTANCES SUBJECT TO THE STOCKHOLM CONVENTION: NONE
HEALTHCARE CONTROLS:
WORKERS EXPOSED TO THIS CHEMICAL AGENT MUST NOT UNDERGO HEALTH CHECKS,
PROVIDED THAT AVAILABLE RISK-ASSESSMENT DATA PROVE THAT THE RISKS RELATED
TO THE WORKERS' HEALTH AND SAFETY ARE MODEST AND THAT THE 98/24/EC
DIRECTIVE IS RESPECTED.
15.2. CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN PERFORMED FOR THE PREPARATION/FOR
THE SUBSTANCES INDICATED IN SECTION 3.
| SECTION 16. OTHER INFORMATION | |
TEXT OF HAZARD (H) INDICATIONS MENTIONED IN SECTION 2-3 OF THE SHEET:
FLAM. LIQ. 3: FLAMMABLE LIQUID, CATEGORY 3
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, CATEGORY 3
H226: FLAMMABLE LIQUID AND VAPOUR.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
EUH066: REPEATED EXPOSURE MAY CAUSE SKIN DRYNESS OR CRACKING.
LEGEND:
ADR: EUROPEAN AGREEMENT CONCERNING THE CARRIAGE OF DANGEROUS GOODS BY ROAD
CAS NUMBER: CHEMICAL ABSTRACT SERVICE NUMBER
CE50: EFFECTIVE CONCENTRATION (REQUIRED TO INDUCE A 50% EFFECT)
CE NUMBER: IDENTIFIER IN ESIS (EUROPEAN ARCHIVE OF EXISTING SUBSTANCES)
CLP: EC REGULATION 1272/2008
DNEL: DERIVED NO EFFECT LEVEL
EMS: EMERGENCY SCHEDULE
GHS: GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
IATA DGR:
INTERNATIONAL AIR TRANSPORT ASSOCIATION DANGEROUS GOODS REGULATION
IC50: IMMOBILIZATION CONCENTRATION 50%
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
IMO: INTERNATIONAL MARITIME ORGANIZATION
INDEX NUMBER: IDENTIFIER IN ANNEX VI OF CLP
LC50: LETHAL CONCENTRATION 50%
LD50: LETHAL DOSE 50%
OEL: OCCUPATIONAL EXPOSURE LEVEL
PBT: PERSISTENT BIOACCUMULATIVE AND TOXIC AS REACH REGULATION
PEC: PREDICTED ENVIRONMENTAL CONCENTRATION
PEL: PREDICTED EXPOSURE LEVEL
PNEC: PREDICTED NO EFFECT CONCENTRATION
REACH: EC REGULATION 1907/2006
RID:
REGULATION CONCERNING THE INTERNATIONAL TRANSPORT OF DANGEROUS GOODS
BY TRAIN
TLV: THRESHOLD LIMIT VALUE
TLV CEILING:
CONCENTRATION THAT SHOULD NOT BE EXCEEDED DURING ANY TIME OF OCCUPATIONAL
EXPOSURE.
TWA STEL: SHORT-TERM EXPOSURE LIMIT
TWA: TIME-WEIGHTED AVERAGE EXPOSURE LIMIT
VOC: VOLATILE ORGANIC COMPOUNDS
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE AS FOR REACH REGULATION
WGK: WATER HAZARD CLASSES (GERMAN).
GENERAL BIBLIOGRAPHY:
1. REGULATION (EC) 1907/2006 (REACH) OF THE EUROPEAN PARLIAMENT
2. REGULATION (EC) 1272/2008 (CLP) OF THE EUROPEAN PARLIAMENT
3. REGULATION (EU) 790/2009 (I ATP. CLP) OF THE EUROPEAN PARLIAMENT
4. REGULATION (EU) 2015/830 OF THE EUROPEAN PARLIAMENT
5. REGULATION (EU) 286/2011 (II ATP. CLP) OF THE EUROPEAN PARLIAMENT
6. REGULATION (EU) 618/2012 (III ATP. CLP) OF THE EUROPEAN PARLIAMENT
7. REGULATION (EU) 487/2013 (IV ATP. CLP) OF THE EUROPEAN PARLIAMENT
8. REGULATION (EU) 944/2013 (V ATP. CLP) OF THE EUROPEAN PARLIAMENT
9. REGULATION (EU) 605/2014 (VI ATP. CLP) OF THE EUROPEAN PARLIAMENT
10. REGULATION (EU) 2015/1221 (VII ATP. CLP) OF THE EUROPEAN PARLIAMENT
11. REGULATION (EU) 2016/918 (VIII ATP. CLP) OF THE EUROPEAN PARLIAMENT
12. REGULATION (EU) 2016/1179 (IX ATP. CLP)
13. REGULATION (EU) 2017/776 (X ATP. CLP)
14. REGULATION (EU) 2018/669 (XI ATP. CLP)
15. REGULATION (EU) 2018/1480 (XIII ATP. CLP)
16. REGULATION (EU) 2019/521 (XII ATP. CLP)
17. REGULATION (EU) 2019/1148
18. REGULATION (EU) 2020/217 (XIV ATP. CLP)
THE MERCK INDEX. - 10TH EDITION
HANDLING CHEMICAL SAFETY
INRS - FICHE TOXICOLOGIQUE (TOXICOLOGICAL SHEET)
PATTY - INDUSTRIAL HYGIENE AND TOXICOLOGY
N.I. SAX - DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS-7, 1989 EDITION
IFA GESTIS WEBSITE
ECHA WEBSITE
DATABASE OF SDS MODELS FOR CHEMICALS - MINISTRY OF HEALTH AND ISS
(ISTITUTO SUPERIORE DI SANITA) - ITALY
NOTE FOR USERS:
THE INFORMATION CONTAINED IN THE PRESENT SHEET ARE BASED ON OUR OWN
KNOWLEDGE ON THE DATE OF THE LAST VERSION. USERS MUST VERIFY THE
SUITABILITY AND THOROUGHNESS OF PROVIDED INFORMATION ACCORDING TO EACH
SPECIFIC USE OF THE PRODUCT.
THIS DOCUMENT MUST NOT BE REGARDED AS A GUARANTEE ON ANY SPECIFIC PRODUCT
PROPERTY.
THE USE OF THIS PRODUCT IS NOT SUBJECT TO OUR DIRECT CONTROL; THEREFORE,
USERS MUST, UNDER THEIR OWN RESPONSIBILITY, COMPLY WITH THE CURRENT HEALTH
AND SAFETY LAWS AND REGULATIONS. THE PRODUCER IS RELIEVED FROM ANY
LIABILITY ARISING FROM IMPROPER USES.
PROVIDE APPOINTED STAFF WITH ADEQUATE TRAINING ON HOW TO USE CHEMICAL
PRODUCTS.
CALCULATION METHODS FOR CLASSIFICATION:
CHEMICAL AND PHYSICAL HAZARDS:
PRODUCT CLASSIFICATION DERIVES FROM CRITERIA ESTABLISHED BY THE CLP
REGULATION, ANNEX I, PART 2. THE DATA FOR EVALUATION OF CHEMICAL-PHYSICAL
PROPERTIES ARE REPORTED IN SECTION 9.
HEALTH HAZARDS:
PRODUCT CLASSIFICATION IS BASED ON CALCULATION METHODS AS PER ANNEX I OF
CLP, PART 3, UNLESS DETERMINED OTHERWISE IN SECTION 11.
ENVIRONMENTAL HAZARDS:
PRODUCT CLASSIFICATION IS BASED ON CALCULATION METHODS AS PER ANNEX I OF
CLP, PART 4, UNLESS DETERMINED OTHERWISE IN SECTION 12.
CHANGES TO PREVIOUS REVIEW:
THE FOLLOWING SECTIONS WERE MODIFIED: 01 / 08 / 09 / 15.
(C) EPY 10.5.2-SDS 1004.13