| Common Name: | LOCTITE SF 7113 ACTIVATORS FOR ACRYLICS KNOWN AS LOCTITE 7113 ACCELERATOR, 19605 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 11/27/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 19TT66 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 006.0
ISSUE DATE: 11/27/2018
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE SF 7113 ACTIVATORS FOR ACRYLICS KNOWN AS LOCTITE(R*) 7113(TM)
ACCELERATOR
PRODUCT TYPE: PRIMER
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 135294
ITEM NUMBER: 19605
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
CAUSES SKIN IRRITATION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
HAZARD CLASS HAZARD CATEGORY
FLAMMABLE LIQUID 2
SKIN IRRITATION 2
EYE IRRITATION 2A
REPRODUCTIVE TOXICITY 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
ASPIRATION HAZARD 1
PICTOGRAM(S):
FLAME
HEALTH HAZARD
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT, SPARKS,
OPEN FLAMES, HOT SURFACES - NO SMOKING. KEEP CONTAINER TIGHTLY CLOSED. NO
RELEASE INTO WATER. USE EXPLOSION-PROOF EQUIPMENT. USE NON-SPARKING TOOLS.
TAKE ACTION TO PREVENT STATIC DISCHARGES. AVOID BREATHING VAPORS, MIST, OR
SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. USE ONLY OUTDOORS OR
IN A WELL-VENTILATED AREA. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE
PROTECTION.
RESPONSE:
IF SWALLOWED: IMMEDIATELY CALL A PHYSICIAN OR POISON CONTROL CENTER.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION. DO NOT INDUCE VOMITING.
IF SKIN IRRITATION OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
IN CASE OF FIRE: USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE TO EXTINGUISH.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE IN
A WELL-VENTILATED PLACE. KEEP COOL. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
HYDROCARBONS, C7, N-ALKANES, ISOALKANES, 64742-49-0 80 - 100
CYCLICS
CYCLOHEXANE 110-82-7 5 - 10
N-HEXANE 110-54-3 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE
IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE.
IF SYMPTOMS DEVELOP AND PERSIST, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN:
ASPIRATION MAY CAUSE PULMONARY EDEMA OR ASPIRATION PNEUMONIA.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WATER SHOULD BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP
AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS, TRAVEL CONSIDERABLE
DISTANCE TO SOURCE OF IGNITION, AND FLASH BACK.
HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF NITROGEN. OXIDES OF CARBON.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS. REMOVE ALL SOURCES OF
IGNITION.
CLEAN-UP METHODS:
ENSURE ADEQUATE VENTILATION. STORE IN A PARTLY FILLED, CLOSED CONTAINER
UNTIL DISPOSAL. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST).
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
STORAGE:
FOR SAFE STORAGE, STORE AT OR BELOW 49 DEG. C (120.2 DEG. F)
KEEP CONTAINER CLOSED. KEEP IN A COOL, WELL VENTILATED AREA. STORE AWAY
FROM IGNITION SOURCES.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
HYDROCARBONS, C7, N-ALKANES, NONE 100 PPM
ISOALKANES, CYCLICS (400 MG/M3) PEL
CYCLOHEXANE 100 PPM TWA 300 PPM
(1,050 MG/M3) PEL
N-HEXANE 50 PPM TWA 500 PPM
(SKIN) (1,800 MG/M3) PEL
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
HYDROCARBONS, C7, N-ALKANES, ISOALKANES, CYCLICS NONE NONE
CYCLOHEXANE NONE NONE
N-HEXANE NONE NONE
ENGINEERING CONTROLS:
LOCAL EXHAUST VENTILATION IS RECOMMENDED WHEN GENERAL VENTILATION IS NOT
SUFFICIENT TO CONTROL AIRBORNE CONTAMINATION BELOW OCCUPATIONAL EXPOSURE
LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S). OBSERVE OSHA REGULATIONS FOR RESPIRATOR USE (29 CFR 1910.134).
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: COLORLESS, CLEAR
ODOR: ALIPHATIC
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: 35 MM Hg (68 DEG. F (20 DEG. C))
BOILING POINT/RANGE: 205 - 210 DEG. F (96.1 - 98.9 DEG. C) NONE
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 0.68
VAPOR DENSITY: 3.45 HEAVIER THAN AIR.
FLASH POINT: -2 DEG. C (28.4 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 1.1%
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 6.7%
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: 2.7 (ETHER = 1)
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 99.9%; 680 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS: NO DATA
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. ACIDS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID: HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
VAPOURS MAY CAUSE DROWSINESS AND DIZZINESS. CENTRAL NERVOUS SYSTEM EFFECTS.
VAPORS MAY CAUSE HEADACHES, NAUSEA, DIZZINESS AND RESPIRATORY TRACT
IRRITATION. RESIDUE REMAINING AFTER EVAPORATION OF THE SOLVENT IS
DESTRUCTIVE TO MUCOUS MEMBRANES.
SKIN CONTACT:
CAUSES SKIN IRRITATION. RESIDUE REMAINING AFTER EVAPORATION OF THE SOLVENT
IS DESTRUCTIVE TO SKIN. REDNESS.
EYE CONTACT:
CAUSES SERIOUS EYE IRRITATION. RESIDUE REMAINING AFTER EVAPORATION OF THE
SOLVENT IS DESTRUCTIVE TO EYES.
INGESTION:
THIS PRODUCT MAY BE FATAL IF IT IS SWALLOWED. PRINCIPAL HAZARD OF INGESTION
IS ASPIRATION INTO THE LUNGS AND SUBSEQUENT PNEUMONITIS.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
HYDROCARBONS, C7, N-ALKANES, NONE NO DATA
ISOALKANES, CYCLICS
CYCLOHEXANE ORAL LD50 (RAT): IRRITANT, CENTRAL
29,820 MG/KG NERVOUS SYSTEM
ORAL LD50 (MOUSE):
1,300 MG/KG
N-HEXANE ORAL LD50 (RAT): DEVELOPMENTAL,
28,710 MG/KG IRRITANT, LUNG,
NERVOUS SYSTEM,
DERMAL LD50 (RABBIT): REPRODUCTIVE
>2,000 MG/KG
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY
REGULATED)
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY
REGULATED)
HYDROCARBONS, C7, N-ALKANES, NO NO NO
ISOALKANES, CYCLICS
CYCLOHEXANE NO NO NO
N-HEXANE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
D001: IGNITABLE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES
TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: HEPTANES
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1206
PACKING GROUP: II
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: HEPTANES
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1206
PACKING GROUP: II
EXCEPTIONS:
ID8000, (NOT MORE THAN 500 ML), MAY QUALIFY AS CONSUMER COMMODITY
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: HEPTANES
HAZARD CLASS OR DIVISION: 3
IDENTIFICATION NUMBER: UN 1206
PACKING GROUP: II
EXCEPTIONS: LIMITED QUANTITY (NOT MORE THAN 5 L).
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, FIRE
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
CYCLOHEXANE (CAS# 110-82-7).
CERCLA REPORTABLE QUANTITY:
N-HEPTANE (CAS# 142-82-5) 100 LBS. (45.4 KG)
METHYLCYCLOHEXANE (CAS# 108-87-2) 100 LBS. (45.4 KG)
OCTANE (CAS# 111-65-9) 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 11/27/2018
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN
ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF
ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY
OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED
HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER
JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND
REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE.