| Common Name: | LOCTITE EA 11C A KNOWN AS LOCTITE HYS 11C 4OZ PTA, 1373435_1284593, LOCTITE EA 1 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 1/18/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 19TT84 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 004.0
ISSUE DATE: 01/18/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE EA 11C A KNOWN AS LOCTITE HYS 11C 4OZ PTA
PRODUCT TYPE: EPOXY RESIN
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 1373723
ITEM NUMBER: 1373435_1284593
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE RESPIRATORY IRRITATION.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S): EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE
GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
TALC 14807-96-6 40 - 50
EPICHLOROHYDRIN-4,4'-ISOPROPYLIDENE DIPHENOL RESIN 25068-38-6 30 - 40
PHENOL POLYMER WITH FORMALDEHYDE, GLYCIDYL ETHER 28064-14-4 10 - 20
CARBON BLACK 1333-86-4 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO
EXTREME HEAT. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. PHENOLICS. ALDEHYDES. TOXIC FUMES. IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL
AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL. REFER TO SECTION 8 "EXPOSURE
CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
STORE IN ORIGINAL CONTAINER UNTIL READY TO USE. KEEP CONTAINER TIGHTLY
CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE
MATERIALS. KEEP AWAY FROM HEAT, SPARK AND FLAME. PROTECT FROM DIRECT
SUNLIGHT.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
TALC 2 MG/M3 TWA 0.1 MG/M3 NONE 50 PPM
RESPIRABLE TWA
FRACTION. RESPIRABLE.
0.3 MG/M3
TWA TOTAL
DUST.
2.4 MPPCF
TWA
RESPIRABLE.
20 MPPCF
TWA
EPICHLOROHYDRIN- NONE NONE NONE NONE
4,4'-ISOPROPYLIDENE
DIPHENOL RESIN
PHENOL POLYMER WITH NONE NONE NONE NONE
FORMALDEHYDE,
GLYCIDYL ETHER
CARBON BLACK 3 MG/M3 TWA 3.5 MG/M3 NONE NONE
INHALABLE PEL
FRACTION.
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: BLACK
ODOR: NONE
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: >260.2 DEG. C (>500.4 DEG. F)
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.58
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93 DEG. C (>199.4 DEG. F) PENSKY MARTENS CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: INSOLUBLE
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0.05 G/L EPA METHOD 24
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. IRRITATING VAPORS.
INCOMPATIBLE MATERIALS: OXIDIZING AGENTS. ACIDS AND BASES. AMINES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. PROTECT
FROM DIRECT SUNLIGHT.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. INHALATION OF VAPORS OR MISTS OF
THE PRODUCT MAY BE IRRITATING TO THE RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
TALC NONE IRRITANT, LUNG, SOME EVIDENCE OF
CARCINOGENICITY
EPICHLOROHYDRIN-4,4'- NONE ALLERGEN, IRRITANT
ISOPROPYLIDENE
DIPHENOL RESIN
PHENOL POLYMER WITH NONE ALLERGEN, IRRITANT
FORMALDEHYDE,
GLYCIDYL ETHER
CARBON BLACK ORAL LD50 (RAT): RESPIRATORY, SOME EVIDENCE
>8,000 MG/KG OF CARCINOGENICITY
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
TALC NO GROUP 2B NO
EPICHLOROHYDRIN- NO NO NO
4,4'-ISOPROPYLIDENE
DIPHENOL RESIN
PHENOL POLYMER WITH NO NO NO
FORMALDEHYDE,
GLYCIDYL ETHER
CARBON BLACK NO GROUP 2B NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES
TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (BISPHENOL-A
EPICHLORHYDRIN RESIN)
HAZARD CLASS OR DIVISION: 9
IDENTIFICATION NUMBER: UN 3082
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: REBECCA COONS, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 01/18/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 005.0
ISSUE DATE: 11/10/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: LOCTITE EA 11C B KNOWN AS LOCTITE HYS 11C 4OZ PTB
PRODUCT TYPE: EPOXY HARDENER
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 1373722
ITEM NUMBER: 1373435_1320207
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING
DIFFICULTIES IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
MAY CAUSE CANCER.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
HAZARD CLASS HAZARD CATEGORY
SKIN CORROSION 1B
SERIOUS EYE DAMAGE 1
RESPIRATORY SENSITIZATION 1
SKIN SENSITIZATION 1
CARCINOGENICITY 1A
REPRODUCTIVE TOXICITY 2
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 1
PICTOGRAM(S):
HEALTH HAZARD
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE VAPORS, MIST, OR
SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR
SMOKE WHEN USING THIS PRODUCT. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE PROTECTION. IN
CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
TALC 14807-96-6 40 - 50
BISPHENOL A, EPICHLOROHYDRIN POLYMER, 68610-56-0 20 - 30
DIETHYLENETRIAMINE ADDUCT
QUARTZ (SiO2) 14808-60-7 10 - 20
DIETHYLENETRIAMINE 111-40-0 10 - 20
4,4'-ISOPROPYLIDENEDIPHENOL 80-05-7 1 - 5
2-(3,4-EPOXYCYCLOHEXYL)- 3388-04-3 0.1 - 1
ETHYLTRIMETHOXYSILANE
N-AMINOETHYLPIPERAZINE 140-31-8 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. IMMEDIATELY FLUSH SKIN WITH
PLENTY OF WATER (USING SOAP, IF AVAILABLE). GET MEDICAL ATTENTION. WASH
CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET IMMEDIATE
MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY. CLOSED CONTAINERS
MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF SILICON. AMINES. AMMONIA.
IRRITATING VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL
PROTECTION" PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL
(E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE
UP SPILLED MATERIAL AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING. USE ONLY WITH ADEQUATE VENTILATION.
KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
STORE IN ORIGINAL CONTAINER UNTIL READY TO USE. KEEP CONTAINER TIGHTLY
CLOSED AND IN A COOL, WELL-VENTILATED PLACE AWAY FROM INCOMPATIBLE
MATERIALS. KEEP AWAY FROM HEAT, SPARK AND FLAME.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA OTHER
WEEL
TALC 2 MG/M3 TWA 0.1 MG/M3 TWA NONE 50 PPM
RESPIRABLE RESPIRABLE.
FRACTION. 2.4 MPPCF TWA
RESPIRABLE.
20 MPPCF TWA
BISPHENOL A, NONE NONE NONE NONE
EPICHLOROHYDRIN
POLYMER,
DIETHYLENETRIAMINE
ADDUCT
QUARTZ (SiO2) 0.025 MG/M3 2.4 MPPCF NONE NONE
TWA TWA
RESPIRABLE RESPIRABLE.
FRACTION. 0.1 MG/M3
TWA
RESPIRABLE.
0.05 MG/M3
TWA
(RESPIRABLE
DUST.)
(RESPIRABLE
DUST.)
0.025 MG/M3
OSHA_ACT
(RESPIRABLE
DUST.)
0.05 MG/M3
PEL
RESPIRABLE
DUST.
DIETHYLENETRIAMINE (SKIN) NONE NONE NONE
1 PPM TWA
4,4'-ISOPROPYLI- NONE NONE NONE NONE
DENEDIPHENOL
2-(3,4- NONE NONE NONE NONE
EPOXYCYCLOHEXYL)-
ETHYLTRIMETHOXY-
SILANE
N-AMINOETHYL- NONE NONE NONE NONE
PIPERAZINE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE A NIOSH APPROVED RESPIRATOR IF VENTILATION IS INADEQUATE.
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID, VISCOUS
COLOR: GREEN
ODOR: AMMONIACAL, STRONG
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.65
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >100 DEG. C (>212 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0.57 G/L EPA METHOD 24
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
POLYMERIZATION IS A HIGHLY EXOTHERMIC REACTION AND MAY GENERATE SUFFICIENT
HEAT TO CAUSE THERMAL DECOMPOSITION AND/OR RUPTURE CONTAINERS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. OXIDES OF SILICON. AMINES. AMMONIA.
IRRITATING VAPORS.
INCOMPATIBLE MATERIALS:
STRONG ACIDS. STRONG BASES. STRONG OXIDIZING AGENTS. METALS. ACRYLATES.
ALCOHOLS. ALDEHYDES. KETONES. NITRITES.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 38 DEG. C (100 DEG. F). KEEP AWAY FROM HEAT,
IGNITION SOURCES AND INCOMPATIBLE MATERIALS. KEEP AWAY FROM HEAT, SPARK
AND FLAME.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM. MAY CAUSE ALLERGIC RESPIRATORY REACTION. THESE
SYMPTOMS, WHICH CAN INCLUDE CHEST TIGHTNESS, WHEEZING, COUGH, SHORTNESS OF
BREATH OR ASTHMA ATTACK, COULD BE IMMEDIATE OR DELAYED (UP TO SEVERAL HOURS
AFTER EXPOSURE). ABRASION OF CURED MATERIAL SUCH AS BY SANDING OR GRINDING
COULD RELEASE RESPIRABLE PARTICLES OF SILICA QUARTZ, A CANCER HAZARD BY
INHALATION. NORMAL USE OF THIS PRODUCT CAUSES NO SUCH RELEASE. MAY IRRITATE
THE NOSE AND RESPIRATORY SYSTEM.
SKIN CONTACT:
CORROSIVE TO SKIN. CAUSES SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
IRRITATION AND CORROSIVE ACTION CAN OCCUR IN THE MOUTH, STOMACH TISSUE AND
DIGESTIVE TRACT IF SWALLOWED. MAY CAUSE BURNS OF MOUTH AND THROAT IF
SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
TALC NONE IRRITANT, LUNG, SOME
EVIDENCE OF CARCINOGENICITY
BISPHENOL A, NONE NO RECORDS
EPICHLOROHYDRIN POLYMER,
DIETHYLENETRIAMINE ADDUCT
QUARTZ (SiO2) NONE IMMUNE SYSTEM, LUNG, SOME
EVIDENCE OF CARCINOGENICITY
DIETHYLENETRIAMINE ORAL LD50 (RAT): ALLERGEN, IRRITANT, EYES
APPROXIMATE
1,140 MG/KG
ORAL LD50 (RAT):
1,080 MG/KG
ORAL LD50 (RAT):
2.33 G/KG
4,4'-ISOPROPYLIDENEDIPHENOL ORAL LD50 (RAT): ALLERGEN, BLOOD, IRRITANT,
4,100 MG/KG KIDNEY, REPRODUCTIVE, SPLEEN
ORAL LD50 (RAT):
3,300 MG/KG
ORAL LD50
(MOUSE):
5,280 MG/KG
ORAL LD50
(MOUSE):
2,500 MG/KG
ORAL LD50
(MOUSE):
4,100 MG/KG
2-(3,4-EPOXYCYCLOHEXYL)- NONE IRRITANT, ALLERGEN
ETHYLTRIMETHOXYSILANE
N-AMINOETHYLPIPERAZINE NONE IRRITANT, CORROSIVE,
ALLERGEN
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
TALC NO GROUP 2B NO
BISPHENOL A, NO NO NO
EPICHLOROHYDRIN
POLYMER,
DIETHYLENETRIAMINE
ADDUCT
QUARTZ (SiO2) KNOWN TO BE GROUP 1 YES
HUMAN
CARCINOGEN.
DIETHYLENETRIAMINE NO NO NO
4,4'-ISOPROPYLIDENE- NO NO NO
DIPHENOL
2-(3,4- NO NO NO
EPOXYCYCLOHEXYL)-
ETHYLTRIMETHOXYSILANE
N-AMINOETHYLPIPERAZINE NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE IF AN ITEM IS HAZARDOUS
AS DEFINED IN THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) AT THE TIME
OF DISPOSAL. PRODUCT USES, TRANSFORMATIONS, MIXTURES, PROCESSES, ETC., MAY
RENDER THE RESULTING MATERIAL HAZARDOUS, UNDER THE CRITERIA OF
IGNITABILITY, CORROSIVITY, REACTIVITY AND TOXICITY CHARACTERISTICS OF THE
TOXICITY CHARACTERISTICS LEACHING PROCEDURE (TCLP) 40 CFR 261.20-24.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: III
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: III
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME:
AMINES, LIQUID, CORROSIVE, N.O.S. (DIETHYLENETRIAMINE)
HAZARD CLASS OR DIVISION: 8
IDENTIFICATION NUMBER: UN 2735
PACKING GROUP: III
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT: INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
4,4'-ISOPROPYLIDENEDIPHENOL (CAS# 80-05-7).
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2,3
PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS
ISSUE DATE: 11/10/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.