SDS Table of Contents Click the desired link below to jump directly to that section in the SDS. HENKEL SAFETY DATA SHEET REVISION NUMBER: 007.0 ISSUE DATE: 07/27/2022
PRODUCT NAME: LOCTITE SI 5999 KNOWN AS 5999 GREY PRODUCT TYPE/USE: SILICONE RESTRICTION OF USE: NONE IDENTIFIED IDH NUMBER: 231230 ITEM NUMBER: 21744 REGION: UNITED STATES COMPANY ADDRESS: HENKEL CORPORATION ONE HENKEL WAY ROCKY HILL, CONNECTICUT 06067 CONTACT INFORMATION: TELEPHONE: +1 (860) 571-5100 MEDICAL EMERGENCY PHONE: POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711 TRANSPORT EMERGENCY PHONE: CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887 INTERNET: WWW.HENKELNA.COM
EMERGENCY OVERVIEW: DANGER MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES SERIOUS EYE IRRITATION. MAY CAUSE CANCER. MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. HAZARD CLASS HAZARD CATEGORY EYE IRRITATION 2A SKIN SENSITIZATION 1 CARCINOGENICITY 1A SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE 2 PICTOGRAM(S): HEALTH HAZARD EXCLAMATION MARK PRECAUTIONARY STATEMENTS: PREVENTION: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE DUST OR FUMES. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES, CLOTHING, EYE AND FACE PROTECTION. RESPONSE: IF ON SKIN: WASH WITH PLENTY OF WATER. IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING. IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION. IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION. IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE. STORAGE: STORE LOCKED UP. DISPOSAL: DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL AND LOCAL GOVERNMENTAL REGULATIONS. CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS (GHS). SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE* CALCIUM CARBONATE 471-34-1 10 - 30 BUTAN-2-ONE O,O',O''-(VINYLSILYLIDYNE)TRIOXIME 2224-33-1 1 - 5 SILICA, AMORPHOUS, TREATED 68909-20-6 1 - 5 2-BUTANONE OXIME 96-29-7 1 - 5 ALUMINUM 7429-90-5 0.1 - 1 QUARTZ (SiO2), <1% RESPIRABLE 14808-60-7 0.1 - 1 *EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
INHALATION: IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, OXYGEN SHOULD BE ADMINISTERED BY QUALIFIED PERSONNEL. MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, SEEK MEDICAL ADVICE. SKIN CONTACT: WIPE OFF PASTE WITH PAPER TOWEL OR CLOTH. RINSE WITH RUNNING WATER AND SOAP. REMOVE CONTAMINATED CLOTHING AND SHOES. SEEK MEDICAL ATTENTION IMMEDIATELY. WASH CONTAMINATED CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. EYE CONTACT: RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. SEEK MEDICAL ATTENTION IMMEDIATELY. SYMPTOMS: SEE SECTION 11.
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE. SPECIAL FIREFIGHTING PROCEDURES: WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH AS TURN-OUT GEAR. PREVENT INHALATION OF FUMES AND GASES. UNUSUAL FIRE OR EXPLOSION HAZARDS: CLOSED CONTAINERS MAY RUPTURE (DUE TO BUILD UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY. HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF CARBON. OXIDES OF SILICON. FORMALDEHYDE. IRRITATING ORGANIC VAPORS.
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL. ENVIRONMENTAL PRECAUTIONS: DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS. CLEAN-UP METHODS: ENSURE ADEQUATE VENTILATION. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP SPILLED MATERIAL AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL.
HANDLING: USE ONLY IN WELL-VENTILATED AREAS. USE ONLY IN AREA PROVIDED WITH APPROPRIATE EXHAUST VENTILATION. VAPORS SHOULD BE EXTRACTED TO AVOID INHALATION. PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING. WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION. REFER TO SECTION 8. DO NOT WEAR CONTACT LENSES. DO NOT HANDLE CONTACT LENSES UNTIL ALL SEALANT HAS BEEN REMOVED FROM HANDS. RESIDUAL SEALANT MAY TRANSFER TO LENSES AND CAUSE EYE IRRITATION. KEEP CONTAINER CLOSED. STORAGE: FOR SAFE STORAGE, STORE BETWEEN 8 DEG. C (46.4 DEG. F) AND 28 DEG. C (82.4 DEG. F) KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME. KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE. STORE IN A DRY AREA BELOW 90 DEG. F. FOR INFORMATION ON PRODUCT SHELF LIFE, PLEASE REVIEW LABELS ON CONTAINER OR CHECK THE TECHNICAL DATA SHEET.
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE EQUIPMENT FOR EACH TASK PERFORMED. HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER CALCIUM CARBONATE 3 MG/M3 TWA 5 MG/M3 PEL NONE NONE RESPIRABLE RESPIRABLE PARTICLES. FRACTION. 10 MG/M3 TWA 15 MG/M3 PEL INHALABLE TOTAL DUST. PARTICLES. 5 MG/M3 PEL RESPIRABLE FRACTION. 15 MG/M3 TWA TOTAL DUST. 50 MPPCF TWA TOTAL DUST. 15 MPPCF TWA RESPIRABLE FRACTION. 5 MG/M3 TWA RESPIRABLE FRACTION. BUTAN-2-ONE O,O',O''- NONE NONE NONE NONE (VINYLSILYLIDYNE)- TRIOXIME SILICA, AMORPHOUS, 10 MG/M3 TWA 6 MG/M3 TWA NONE NONE TREATED INHALABLE DUST. 2-BUTANONE OXIME NONE NONE 10 PPM NONE (36 MG/M3) TWA (SKIN SENSITIZER.) ALUMINUM 1 MG/M3 TWA 15 MG/M3 PEL NONE NONE RESPIRABLE (AS AL) FRACTION. TOTAL DUST. 5 MG/M3 PEL (AS Al) RESPIRABLE FRACTION. 15 MPPCF TWA RESPIRABLE FRACTION. 50 MPPCF TWA TOTAL DUST. 5 MG/M3 TWA RESPIRABLE FRACTION. 15 MG/M3 TWA TOTAL DUST. QUARTZ (SiO2), <1% 0.025 MG/M3 0.05 MG/M3 NONE NONE RESPIRABLE TWA TWA RESPIRABLE (RESPIRABLE FRACTION. DUST.) (RESPIRABLE DUST.) 0.025 MG/M3 OSHA_ACT (RESPIRABLE DUST.) 0.05 MG/M3 PEL RESPIRABLE DUST. 2.4 MPPCF TWA RESPIRABLE. 0.1 MG/M3 TWA RESPIRABLE. ENGINEERING CONTROLS: PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE BELOW EXPOSURE LIMITS. RESPIRATORY PROTECTION: USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE LIMIT(S). EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE. SKIN PROTECTION: USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT.
PHYSICAL STATE: PASTE COLOR: GRAY ODOR: MILD ODOR THRESHOLD: NOT AVAILABLE. PH: 7 - 9 VAPOR PRESSURE: <5 MMHg <6.67 HPA (20 DEG. C (68 DEG. F)) BOILING POINT/RANGE: >200 DEG. C (>392 DEG. F) MELTING POINT/RANGE: >400 DEG. C (>752 DEG. F) SPECIFIC GRAVITY: 1.5 AT 20 DEG. C (68 DEG. F) VAPOR DENSITY: NOT APPLICABLE, PRODUCT IS A SOLID. FLASH POINT: NOT APPLICABLE FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE. FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE. AUTOIGNITION TEMPERATURE: NOT AVAILABLE. FLAMMABILITY: THE PRODUCT IS NOT FLAMMABLE. EVAPORATION RATE: NOT AVAILABLE. SOLUBILITY IN WATER: POLYMERIZES IN PRESENCE OF WATER. PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE. VOC CONTENT: 4.16%; 59.55 G/L VISCOSITY: NOT AVAILABLE. DECOMPOSITION TEMPERATURE: >100 DEG. C
STABILITY: STABLE AT NORMAL CONDITIONS. HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING. HAZARDOUS DECOMPOSITION PRODUCTS: FORMALDEHYDE. METHYL ETHYL KETOXIME FORMED DURING CURE. OXIDES OF SILICON. OXIDES OF CARBON. IRRITATING FUMES. INCOMPATIBLE MATERIALS: POLYMERIZES ON CONTACT WITH WATER. OXIDIZING AGENTS. ACIDS AND BASES. AMINES. REACTIVITY: NOT AVAILABLE. CONDITIONS TO AVOID: KEEP AWAY FROM HEAT, IGNITION SOURCES AND INCOMPATIBLE MATERIALS. PROTECT FROM DIRECT SUNLIGHT. MOISTURE.
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION POTENTIAL HEALTH EFFECTS/SYMPTOMS: INHALATION: WHEN HEATED TO TEMPERATURES EXCEEDING 300 DEG. F (150 DEG. C) IN THE PRESENCE OF AIR, SILICONES MAY FORM FORMALDEHYDE VAPORS. FORMALDEHYDE IS A POTENTIAL CANCER HAZARD AND A KNOWN SKIN AND RESPIRATORY SENSITIZER. VAPORS IRRITATE THE EYES, NOSE AND THROAT. SAFE HANDLING CONDITIONS MAY BE MAINTAINED BY KEEPING FORMALDEHYDE VAPOR CONCENTRATIONS BELOW THE OSHA PERMISSIBLE LIMIT. INHALATION OF VAPORS FROM UNCURED SEALANT MAY CAUSE RESPIRATORY TRACT IRRITATION. CAN CAUSE CENTRAL NERVOUS SYSTEM EFFECTS LIKE DIZZINESS, DROWSINESS, HEADACHE, AND NAUSEA. ABRASION OF CURED MATERIAL SUCH AS BY SANDING OR GRINDING COULD RELEASE RESPIRABLE PARTICLES OF SILICA QUARTZ, A CANCER HAZARD BY INHALATION. NORMAL USE OF THIS PRODUCT CAUSES NO SUCH RELEASE. SKIN CONTACT: MAY CAUSE SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION. EYE CONTACT: CAUSES SERIOUS EYE IRRITATION. INGESTION: NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED. HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH EFFECTS CALCIUM CARBONATE ORAL LD50 (RAT): NUISANCE DUST 6,450 MG/KG ORAL LD50 (MOUSE): 6,450 MG/KG INHALATION LC50 (RAT, 4 H): >3 MG/L BUTAN-2-ONE O,O',O''- NONE IRRITANT, ALLERGEN (VINYLSILYLIDYNE)TRIOXIME SILICA, AMORPHOUS, TREATED NONE NO TARGET ORGANS 2-BUTANONE OXIME INHALATION LC50 ALLERGEN, BLOOD, (RAT, 4 H): >4.83 MG/L CENTRAL NERVOUS SYSTEM, EYES, IRRITANT, SOME EVIDENCE OF CARCINOGENICITY ALUMINUM INHALATION LC50 CENTRAL NERVOUS (RAT, 4 H): >0.888 MG/L SYSTEM, IRRITANT, INHALATION LC50 LUNG (RAT, 4 H): >2.3 MG/L QUARTZ (SiO2), <1% NONE IMMUNE SYSTEM, LUNG, RESPIRABLE SOME EVIDENCE OF CARCINOGENICITY HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN CARCINOGEN CARCINOGEN (SPECIFICALLY REGULATED) CALCIUM CARBONATE NO NO NO BUTAN-2-ONE O,O',O''- NO NO NO (VINYLSILYLIDYNE)TRIOXIME SILICA, AMORPHOUS, TREATED NO NO NO 2-BUTANONE OXIME NO NO NO ALUMINUM NO NO NO QUARTZ (SiO2), <1% RESPIRABLE KNOWN TO BE GROUP 1 YES HUMAN CARCINOGEN.
ECOLOGICAL INFORMATION: NOT AVAILABLE.
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY. RECOMMENDED METHOD OF DISPOSAL: FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY PACKAGE/CONFIGURATION. U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR): PROPER SHIPPING NAME: NOT REGULATED HAZARD CLASS OR DIVISION: NONE IDENTIFICATION NUMBER: NONE PACKING GROUP: NONE INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA): PROPER SHIPPING NAME: NOT REGULATED HAZARD CLASS OR DIVISION: NONE IDENTIFICATION NUMBER: NONE PACKING GROUP: NONE WATER TRANSPORTATION (IMO/IMDG): PROPER SHIPPING NAME: NOT REGULATED HAZARD CLASS OR DIVISION: NONE IDENTIFICATION NUMBER: NONE PACKING GROUP: NONE EXCEPTIONS: NONE
UNITED STATES REGULATORY INFORMATION: TSCA 8 (B) INVENTORY STATUS: ALL COMPONENTS ARE LISTED AS ACTIVE OR ARE EXEMPT FROM LISTING ON THE TOXIC SUBSTANCES CONTROL ACT (TSCA) INVENTORY. TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS. CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS. CALIFORNIA PROPOSITION 65: THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM. CANADA REGULATORY INFORMATION: CEPA DSL/NDSL STATUS: CONTAINS ONE OR MORE COMPONENTS LISTED ON THE NON-DOMESTIC SUBSTANCES LIST. ALL OTHER COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE DOMESTIC SUBSTANCES LIST. COMPONENTS LISTED ON THE NDSL MUST BE TRACKED BY ALL CANADIAN IMPORTERS OF RECORD AS REQUIRED BY ENVIRONMENT CANADA. THEY MAY BE IMPORTED INTO CANADA IN LIMITED QUANTITIES. PLEASE CONTACT REGULATORY AFFAIRS FOR ADDITIONAL DETAILS. ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN DOMESTIC SUBSTANCES LIST.
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN SECTIONS: 2,9 PREPARED BY: PRODUCT SAFETY AND REGULATORY AFFAIRS ISSUE DATE: 07/27/2022 DISCLAIMER: THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES ("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS. THIS SAFETY DATA SHEET HAS BEEN GENERATED BASED ON OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200) AND PROVIDES INFORMATION IN ACCORDANCE WITH U.S. FEDERAL LAW ONLY. NO WARRANTY OR REPRESENTATION OF ANY KIND IS GIVEN WITH RESPECT TO THE SUBSTANTIVE OR EXPORT LAWS OF ANY OTHER JURISDICTION OR COUNTRY. PLEASE CONFIRM THAT THE INFORMATION PROVIDED HEREIN CONFORMS TO THE SUBSTANTIVE EXPORT OR OTHER LAW OF ANY OTHER JURISDICTION PRIOR TO EXPORT. PLEASE CONTACT HENKEL PRODUCT SAFETY AND REGULATORY AFFAIRS FOR ADDITIONAL ASSISTANCE. |