| Common Name: | LOCTITE AA 312 REAR VIEW MIRROR ADHESIVE KNOWN AS LOCTITE 312 ADH WIP 10, 700332 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 7/8/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 19TT95 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 005.1
ISSUE DATE: 07/08/2015
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME:
LOCTITE AA 312 REAR VIEW MIRROR ADHESIVE KNOWN AS LOCTITE 312 ADH WIP# 10ML
IDH NUMBER: 235807
PRODUCT TYPE: ANAEROBIC ADHESIVE
ITEM NUMBER: 7003321
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
HARMFUL IF INHALED.
HAZARD CLASS HAZARD CATEGORY
ACUTE TOXICITY INHALATION 4
SKIN CORROSION 1B
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
PICTOGRAM(S):
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE VAPORS, MIST, OR SPRAY. WASH THOROUGHLY AFTER HANDLING. USE
ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING
SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES, EYE
PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
IF ON SKIN (OR HAIR): TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON CONTROL
CENTER OR PHYSICIAN.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
HYDROXYALKYL METHACRYLATE 27813-02-1 30 - 60
POLYURETHANE METHACRYLATE RESIN UNKNOWN 30 - 60
POLYURETHANE METHACRYLATE RESIN UNKNOWN 10 - 30
ACRYLIC ACID 79-10-7 5 - 10
CUMENE HYDROPEROXIDE 80-15-9 1 - 5
POLYGLYCOL DIMETHACRYLATE PROPRIETARY 1 - 5
METHACRYLIC ACID 79-41-4 1 - 5
AMINE PROPRIETARY 0.1 - 1
SUBSITUTED SILANE PROPRIETARY 0.1 - 1
HYDROXYALKYL METHACRYLATE PROPRIETARY 0.1 - 1
CUMENE 98-82-8 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE. GET
MEDICAL ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
UNCONTROLLED POLYMERIZATION MAY OCCUR AT HIGH TEMPERATURES RESULTING IN
EXPLOSIONS OR RUPTURE OF STORAGE CONTAINERS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. IRRITATING ORGANIC VAPOURS.
ISOCYANATES. HYDROGEN CYANIDE. AMINES.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEAN-UP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP AS MUCH MATERIAL AS
POSSIBLE. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. REFER
TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE AT OR BELOW 38 DEG. C (100.4 DEG. F)
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
HYDROXYALKYL NONE NONE NONE 1 PPM TWA
METHACRYLATE 3 PPM STEL
POLYURETHANE NONE NONE NONE NONE
METHACRYLATE RESIN
POLYURETHANE NONE NONE NONE NONE
METHACRYLATE RESIN
ACRYLIC ACID 2 PPM TWA NONE NONE 1 PPM TWA
(SKIN) 3 PPM STEL
(SKIN)
CUMENE HYDROPEROXIDE NONE NONE 1 PPM NONE
(6 MG/M3)
TWA
(SKIN)
POLYGLYCOL NONE NONE NONE NONE
DIMETHACRYLATE
METHACRYLIC ACID 20 PPM TWA NONE NONE NONE
AMINE NONE NONE NONE NONE
SUBSITUTED SILANE NONE NONE NONE NONE
HYDROXYALKYL NONE NONE NONE 3 PPM
METHACRYLATE CEILING
CUMENE 50 PPM TWA 50 PPM NONE NONE
(245 MG/M3)
PEL (SKIN)
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT. NEOPRENE GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: CLEAR, AMBER
ODOR: SHARP
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <10 MMHg (27 DEG. C (80.6 DEG. F))
BOILING POINT/RANGE: >149 DEG. C (>300.2 DEG. F)
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.08
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: >93.4 DEG. C (>200.12 DEG. F) TAGLIABUE CLOSED CUP
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: <3%; 30 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
NONE UNDER NORMAL PROCESSING. POLYMERIZATION MAY OCCUR AT ELEVATED
TEMPERATURE OR IN THE PRESENCE OF INCOMPATIBLE MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. PHENOLICS. IRRITATING ORGANIC
VAPOURS. ISOCYANATES. HYDROGEN CYANIDE. AMINES.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. STRONG REDUCING AGENTS. AMINES. STRONG ACIDS.
HEAVY METALS. PEROXIDES. FREE RADICAL INITIATORS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
ELEVATED TEMPERATURES. HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION: HARMFUL IF INHALED. MAY CAUSE NOSE, THROAT AND LUNG IRRITATION.
SKIN CONTACT:
CORROSIVE TO SKIN. CAUSES SKIN BURNS. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
HYDROXYALKYL NONE IRRITANT, ALLERGEN
METHACRYLATE
POLYURETHANE NONE IRRITANT, ALLERGEN
METHACRYLATE RESIN
POLYURETHANE NONE IRRITANT, ALLERGEN
METHACRYLATE RESIN
ACRYLIC ACID ORAL LD50 (RAT): ALLERGEN, CORROSIVE,
33.5 MG/KG IRRITANT, KIDNEY, LIVER
ORAL LD50 (RAT):
2.5 G/KG
ORAL LD50 (RAT):
193 MG/KG
ORAL LD50 (RAT):
1,250 MG/KG
INHALATION LC50
(RAT, 4 H):
1,200 MG/L
CUMENE HYDROPEROXIDE NONE ALLERGEN, CENTRAL NERVOUS
SYSTEM, CORROSIVE, IRRITANT,
MUTAGEN
POLYGLYCOL NONE IRRITANT, ALLERGEN
DIMETHACRYLATE
METHACRYLIC ACID ORAL LD50 (RABBIT): CORROSIVE, IRRITANT,
1,200 MG/KG ALLERGEN
ORAL LD50 (RAT):
1,060 MG/KG
ORAL LD50 (RAT):
2,224 MG/KG
DERMAL LD50 (RABBIT):
500 MG/KG
INHALATION LC50
(RAT, 4 H): 7.1 MG/L
AMINE NONE ALLERGEN, CENTRAL NERVOUS
SYSTEM, CORROSIVE, IRRITANT
SUBSITUTED SILANE NONE IRRITANT, ALLERGEN
HYDROXYALKYL ORAL LD50 (RAT): IRRITANT, ALLERGEN
METHACRYLATE 11.2 G/KG
ORAL LD50 (RAT):
5,050 MG/KG
CUMENE ORAL LD50 (RAT): CENTRAL NERVOUS SYSTEM,
2.91 G/KG IRRITANT, LUNG
ORAL LD50 (RAT):
1,400 MG/KG
INHALATION LC50
(RAT, 4 H): 8000 PPM
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
HYDROXYALKYL NO NO NO
METHACRYLATE
POLYURETHANE NO NO NO
METHACRYLATE RESIN
POLYURETHANE NO NO NO
METHACRYLATE RESIN
ACRYLIC ACID NO NO NO
CUMENE HYDROPEROXIDE NO NO NO
POLYGLYCOL NO NO NO
DIMETHACRYLATE
METHACRYLIC ACID NO NO NO
AMINE NO NO NO
SUBSITUTED SILANE NO NO NO
HYDROXYALKYL NO NO NO
METHACRYLATE
CUMENE REASONABLY GROUP 2B NO
ANTICIPATED TO
BE A HUMAN
CARCINOGEN.
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). ACRYLIC ACID
(CAS# 79-10-7). CUMENE HYDROPEROXIDE (CAS# 80-15-9).
CERCLA REPORTABLE QUANTITY:
CUMENE HYDROPEROXIDE (CAS# 80-15-9): 10 LBS. (4.54 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ONE OR MORE COMPONENTS ARE NOT LISTED ON, AND ARE NOT EXEMPT FROM LISTING
ON EITHER THE DOMESTIC SUBSTANCES LIST OR THE NON-DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT. 11
PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 07/08/2015
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.
SAFETY DATA SHEET
HENKEL
REVISION NUMBER: 006.0
ISSUE DATE: 11/21/2014
| 1. PRODUCT AND COMPANY IDENTIFICATION | |
PRODUCT NAME: 40 GRAM NF LABELED
IDH NUMBER: 926373
PRODUCT TYPE: ACCELERATOR
RESTRICTION OF USE: NONE IDENTIFIED
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
WARNING:
CONTENTS UNDER PRESSURE.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
MAY CAUSE DROWSINESS OR DIZZINESS.
HAZARD CLASS HAZARD CATEGORY
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE 3
PICTOGRAM(S): EXCLAMATION
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING MIST OR SPRAY. WASH THOROUGHLY AFTER HANDLING. USE ONLY
OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING SHOULD
NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR EYE AND FACE PROTECTION. WEAR
PROTECTIVE GLOVES.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO REMOVE. CONTINUE RINSING. CALL A POISON CONTROL CENTER
OR PHYSICIAN IF YOU FEEL UNWELL.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
TRICHLOROETHYLENE 79-01-6 60 - 100
2-PROPANOL 67-63-0 5 - 10
CARBON DIOXIDE 124-38-9 1 - 5
BUTANAL, REACTION PRODUCTS WITH 68411-19-8 1 - 5
BUTYLAMINE
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED TO
ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE. GET
MEDICAL ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. IF CONSCIOUS, DRINK PLENTY OF WATER. GET MEDICAL ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. WATER SHOULD BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO
EXTREME HEAT.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
VAPORS MAY ACCUMULATE IN LOW OR CONFINED AREAS, TRAVEL CONSIDERABLE
DISTANCE TO SOURCE OF IGNITION, AND FLASH BACK. CONTENTS UNDER PRESSURE.
EXPOSURE TO TEMPERATURES ABOVE 49 DEG. C (120 DEG. F) MAY CAUSE CONTAINER
TO BURST. DO NOT PUNCTURE OR INCINERATE PRESSURIZED CONTAINERS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON. HYDROGEN CHLORIDE. PHOSGENE. IRRITATING ORGANIC VAPOURS.
TOXIC CHLORIDES.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. ENSURE ADEQUATE VENTILATION. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. KEEP UNNECESSARY PERSONNEL AWAY.
WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING DURING CLEAN-UP. SOAK UP
WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA GEL, ACID BINDER,
UNIVERSAL BINDER, SAWDUST). SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. STORE
IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. REFER TO SECTION 8
"EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
PREVENT CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE VAPOR AND
MIST. WASH THOROUGHLY AFTER HANDLING.
DURING USE AND UNTIL ALL VAPORS ARE GONE:
KEEP AREA VENTILATED - DO NOT SMOKE; EXTINGUISH ALL FLAMES, PILOT LIGHTS,
AND HEATERS; TURN OFF STOVES, ELECTRICAL TOOLS AND APPLIANCES, AND ANY
OTHER SOURCES OF IGNITION. DO NOT PUNCTURE OR INCINERATE PRESSURIZED
CONTAINERS. REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE AT OR BELOW 49 DEG. C (120.2 DEG. F)
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
FOR INFORMATION ON PRODUCT SHELF LIFE CONTACT HENKEL CUSTOMER SERVICE AT
(800) 243-4874.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
TRICHLOROETHYLENE 10 PPM TWA 100 PPM TWA NONE NONE
25 PPM STEL
200 PPM CEILING
300 PPM MAX.
CONC 5 MINUTES
IN ANY 2 HOURS
2-PROPANOL 200 PPM TWA 400 PPM NONE NONE
400 PPM STEL (980 MG/M3)
PEL
CARBON DIOXIDE 5,000 PPM TWA 5,000 PPM NONE NONE
30,000 PPM STEL (9,000 MG/M3)
PEL
BUTANAL, REACTION NONE NONE NONE NONE
PRODUCTS WITH
BUTYLAMINE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER AN
APRON OR BODY SUIT TO PREVENT SKIN CONTACT. SOLVENT RESISTANT GLOVES SUCH
AS VITON, POLY (VINYL ALCOHOL), OR EQUIVALENT IS RECOMMENDED. SILVER SHIELD
GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: AEROSOL
COLOR: AMBER
ODOR: SHARP
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: 100 MMHg (21 DEG. C (69.8 DEG. F)) APPROXIMATELY
BOILING POINT/RANGE: 77 - 82 DEG. C (170.6 - 179.6 DEG. F)
MELTING POINT/ RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.3 AT 26.6 DEG. C (79.88 DEG. F)
VAPOR DENSITY: 4.5 APPROXIMATELY
FLASH POINT: 76 DEG. C (168.8 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 95.6%; 1,243 G/L EPA METHOD 24
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. PHOSGENE. HYDROGEN CHLORIDE. IRRITATING ORGANIC VAPOURS.
TOXIC CHLORIDES.
INCOMPATIBLE MATERIALS:
STRONG OXIDIZING AGENTS. BASES. METALS. REDUCING AGENTS. STRONG ALKALIS.
CAUSTICS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
DO NOT PUNCTURE, INCINERATE, OR EXPOSE TO TEMPERATURES ABOVE 48.9 DEG. C
(120 DEG. F). HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION. STORE
AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
MAY CAUSE DIZZINESS, INCOORDINATION, HEADACHE, NAUSEA, AND VOMITING.
INHALATION OF VAPORS OR MISTS OF THE PRODUCT MAY BE IRRITATING TO THE
RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
TRICHLOROETHYLENE ORAL LD50 (RAT): BEHAVIORAL, CARDIAC, CENTRAL
4,920 MG/KG NERVOUS SYSTEM, IRRITANT,
KIDNEY, LIVER, SOME EVIDENCE
INHALATION LC50 OF CARCINOGENICITY
(RAT, 4 H):
12000 PPM
INHALATION LC50
(RAT, 1 H):
26000 PPM
2-PROPANOL ORAL LD50 (RAT): ALLERGEN, BLOOD, BRAIN,
5,045 MG/KG CENTRAL NERVOUS SYSTEM,
IRRITANT, KIDNEY, LIVER,
ORAL LD50 (RABBIT): SPLEEN
6,410 MG/KG
ORAL LD50 (RAT):
4.7 G/KG
ORAL LD50 (RABBIT):
8.0 G/KG
ORAL LD50 (RABBIT):
5.03 G/KG
DERMAL LD50
(RABBIT):
12,800 MG/KG
CARBON DIOXIDE NONE CENTRAL NERVOUS SYSTEM
BUTANAL, REACTION NONE NO RECORDS
PRODUCTS WITH
BUTYLAMINE
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
TRICHLOROETHYLENE REASONABLY GROUP 1 NO
ANTICIPATED TO
BE A HUMAN
CARCINOGEN.
2-PROPANOL NO NO NO
CARBON DIOXIDE NO NO NO
BUTANAL, REACTION NO NO NO
PRODUCTS WITH
BUTYLAMINE
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER:
THIS PRODUCT CONTAINS A COMPONENT OR COMPONENTS IDENTIFIED AS HAZARDOUS
UNDER 40 CFR 261.24.
D040: TRICHLOROETHYLENE
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.2 (6.1)
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME:
AEROSOLS, NON-FLAMMABLE, CONTAINING SUBSTANCES IN DIVISION 6.1, PACKING
GROUP III
HAZARD CLASS OR DIVISION: 2.2 (6.1)
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: AEROSOLS (TRICHLOROETHYLENE)
HAZARD CLASS OR DIVISION: 2.2 (6.1)
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
EXCEPTIONS: LIMITED QUANTITY (NOT MORE THAN 120 ML)
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). TRICHLOROETHYLENE
(CAS# 79-01-6).
CERCLA REPORTABLE QUANTITY:
TRICHLOROETHYLENE (CAS# 79-01-6): 100 LBS. (45.4 KG)
2-PROPANOL (CAS# 67-63-0): 100 LBS. (45.4 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: CATHERINE BIMLER, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 11/21/2014
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.