| Common Name: | FIRE BARRIER RATED FOAM, FIP 1-STEP KIT |
| Manufacturer: | 3M |
| SDS Revision Date: | 4/21/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 19UC77 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) FIRE BARRIER RATED FOAM, FIP 1-STEP KIT
04/21/15
3M
SAFETY DATA SHEET
COPYRIGHT, 2015, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 31-5229-5
VERSION NUMBER: 2.02
ISSUE DATE: 04/21/15
SUPERCEDES DATE: 02/26/15
PRODUCT IDENTIFIER: 3M(TM) FIRE BARRIER RATED FOAM, FIP 1-STEP KIT
ID NUMBER(S): 70-0067-7078-1, 98-0400-5645-3
RECOMMENDED USE: PASSIVE FIRE PROTECTION
SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
THIS PRODUCT IS A KIT OR A MULTIPART PRODUCT WHICH CONSISTS OF MULTIPLE,
INDEPENDENTLY PACKAGED COMPONENTS. A SAFETY DATA SHEET (SDS), ARTICLE
INFORMATION SHEET (AIS), OR ARTICLE INFORMATION LETTER (AIL) FOR EACH OF
THESE COMPONENTS IS INCLUDED. PLEASE DO NOT SEPARATE THE COMPONENT
DOCUMENTS FROM THIS COVER SHEET.
THE DOCUMENT NUMBERS FOR COMPONENTS OF THIS PRODUCT ARE:
31-5458-0, 31-5236-0
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) FIRE BARRIER RATED FOAM, FIP 1-STEP PART A
04/21/14
3M
SAFETY DATA SHEET
COPYRIGHT, 2014, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 31-5458-0
VERSION NUMBER: 2.00
ISSUE DATE: 04/21/14
SUPERCEDES DATE: 08/08/13
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) FIRE BARRIER RATED FOAM, FIP 1-STEP PART A
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: PASSIVE FIRE PROTECTION
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER, ST.
PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
NOT CLASSIFIED AS HAZARDOUS ACCORDING TO OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
2.2. LABEL ELEMENTS:
SIGNAL WORD: NOT APPLICABLE.
SYMBOLS: NOT APPLICABLE.
PICTOGRAMS: NOT APPLICABLE.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED: NONE.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYMER NJTSRN 04499600-6935 TRADE SECRET* 30 - 60 TRADE SECRET *
NON-HALOGEN FLAME RETARDANT NJTSRN TRADE SECRET* 10 - 30 TRADE SECRET *
04499600-6939
PHOSPHATE NJTSRN 04499600-6938 TRADE SECRET* 10 - 30 TRADE SECRET *
SMOKE SUPPRESSANT NJTSRN TRADE SECRET* 1 - 10 TRADE SECRET *
04499600-6941
WAX NJTSRN 04499600-6936 TRADE SECRET* 1 - 10 TRADE SECRET *
WATER 7732-18-5 <5
CATALYST NJTSRN 04499600-6940 TRADE SECRET* <5 TRADE SECRET *
SILOXANES NJTSRN 04499600-6937 TRADE SECRET* <5 TRADE SECRET *
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION: NO NEED FOR FIRST AID IS ANTICIPATED.
SKIN CONTACT:
WASH WITH SOAP AND WATER. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
AMMONIA DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
VENTILATE THE AREA WITH FRESH AIR. REFER TO OTHER SECTIONS OF THIS SDS FOR
INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS, RESPIRATORY PROTECTION,
VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS: AVOID RELEASE TO THE ENVIRONMENT.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
AVOID BREATHING OF DUST CREATED BY CUTTING, SANDING, GRINDING OR MACHINING.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER
HANDLING. AVOID CONTACT WITH OXIDIZING AGENTS (EG. CHLORINE, CHROMIC ACID
ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED TO PREVENT CONTAMINATION WITH WATER OR AIR.
IF CONTAMINATION IS SUSPECTED, DO NOT RESEAL CONTAINER. STORE AWAY FROM
HEAT. STORE AWAY FROM ACIDS. STORE AWAY FROM STRONG BASES. STORE AWAY FROM
OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
CATALYST NJTSRN TRADE SECRET AMER CONF OF TWA(RESPIRABLE
04499600-6940 GOV. INDUST. FRACTION):
HYG. 1 MG/M3
SMOKE SUPPRESSANT TRADE SECRET AMER CONF OF TWA(RESPIRABLE
NJTSRN GOV. INDUST. FRACTION):
04499600-6941 HYG. 1 MG/M3
AMER CONF OF GOV. INDUST. HYG.:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AMERICAN INDUST. HYGIENE ASSOC: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CHEMICAL MANUFACTURER REC GUID:
CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
US DEPT OF LABOR - OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
NITRILE RUBBER
RESPIRATORY PROTECTION
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: RED-BROWN WITH EARTHY ODOR
PH: 6 - 8 [@ 20 ]
FLASH POINT: NO FLASH POINT
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
SPECIFIC GRAVITY: 1.3
SOLUBILITY IN WATER: NEGLIGIBLE
VISCOSITY: 250 - 350 MPA-S
VOLATILE ORGANIC COMPOUNDS: <1
VOC LESS H2O & EXEMPT SOLVENTS: <10 G/L
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS:
ALCOHOLS
AMINES
STRONG ACIDS
STRONG BASES
STRONG OXIDIZING AGENTS
WATER
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
THIS PRODUCT MAY HAVE A CHARACTERISTIC ODOR; HOWEVER, NO ADVERSE HEALTH
EFFECTS ARE ANTICIPATED.
SKIN CONTACT:
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
EYE CONTACT:
CONTACT WITH THE EYES DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE; CALCULATED
DUST/MIST ATE >12.5 MG/L
(4 HR)
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE >5,000 MG/KG
PHOSPHATE NJTSRN DERMAL RAT LD50 >5,000 MG/KG
04499600-6938
PHOSPHATE NJTSRN INHALATION- RAT LC50 >5.1 MG/L
04499600-6938 DUST/MIST
(4 HOURS)
PHOSPHATE NJTSRN INGESTION RAT LD50 4,740 MG/KG
04499600-6938
SMOKE SUPPRESSANT DERMAL LD50 ESTIMATED TO
NJTSRN 04499600-6941 BE >5,000 MG/KG
SMOKE SUPPRESSANT INGESTION RAT LD50 >5,000 MG/KG
NJTSRN 04499600-6941
CATALYST NJTSRN DERMAL RABBIT LD50 >2,000 MG/KG
04499600-6940
CATALYST NJTSRN INHALATION- RAT LC50 >4.57 MG/L
04499600-6940 DUST/MIST
(4 HOURS)
CATALYST NJTSRN INGESTION RAT LD50 >5,000 MG/KG
04499600-6940
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
SMOKE SUPPRESSANT NJTSRN 04499600-6941 RABBIT NO SIGNIFICANT IRRITATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
SMOKE SUPPRESSANT NJTSRN 04499600-6941 RABBIT NO SIGNIFICANT IRRITATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
SMOKE SUPPRESSANT NJTSRN 04499600-6941 GUINEA PIG NOT SENSITIZING
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
SMOKE SUPPRESSANT NOT MULTIPLE ANIMAL NOT CARCINOGENIC
NJTSRN 04499600-6941 SPECIFIED SPECIES
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
SMOKE SUPPRESSANT INGESTION NOT TOXIC TO RAT NOAEL 768 DURING
NJTSRN DEVELOPMENT MG/KG/DAY ORGANO-
04499600-6941 GENESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE SPECIES TEST RESULT EXPOSURE
DURATION
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE SPECIES TEST RESULT EXPOSURE
DURATION
ASPIRATION HAZARD:
NAME VALUE
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
PRIOR TO DISPOSAL, CONSULT ALL APPLICABLE AUTHORITIES AND REGULATIONS TO
INSURE PROPER CLASSIFICATION. DISPOSE OF WASTE PRODUCT IN A PERMITTED
INDUSTRIAL WASTE FACILITY. AS A DISPOSAL ALTERNATIVE, INCINERATE IN A
PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION MAY REQUIRE THE
USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. EMPTY AND CLEAN
PRODUCT CONTAINERS MAY BE DISPOSED AS NON-HAZARDOUS WASTE. CONSULT YOUR
SPECIFIC REGULATIONS AND SERVICE PROVIDERS TO DETERMINE AVAILABLE OPTIONS
AND REQUIREMENTS.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT HTTP://3M.COM/TRANSPORTINFO OR CALL
1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 1
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) III) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) III RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) III PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN
COATINGS ASSOCIATION (ACA).
DOCUMENT GROUP: 31-5458-0
VERSION NUMBER: 2.00
ISSUE DATE: 04/21/14
SUPERCEDES DATE: 08/08/13
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION. 3M PROVIDES INFORMATION
IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS. DUE TO THE REMOTE
POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN ERRORS, OMISSIONS
OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO REPRESENTATIONS AS TO ITS
COMPLETENESS OR ACCURACY. IN ADDITION, INFORMATION OBTAINED FROM A DATABASE
MAY NOT BE AS CURRENT AS THE INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM
3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM
3M(TM) FIRE BARRIER RATED FOAM, FIP 1-STEP PART B
04/21/15
3M
SAFETY DATA SHEET
COPYRIGHT,2015,3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR THE
PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 31-5236-0
VERSION NUMBER: 2.01
ISSUE DATE: 04/21/15
SUPERCEDES DATE: 04/21/14
| SECTION 1: IDENTIFICATION | |
1.1. PRODUCT IDENTIFIER:
3M(TM) FIRE BARRIER RATED FOAM, FIP 1-STEP PART B
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: PASSIVE FIRE PROTECTION
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER,
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
ACUTE TOXICITY (INHALATION): CATEGORY 4.
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 2A.
SKIN CORROSION/IRRITATION: CATEGORY 2.
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (RESPIRATORY IRRITATION): CATEGORY 3.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: EXCLAMATION MARK | HEALTH HAZARD |
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
CAUSES SERIOUS EYE IRRITATION.
CAUSES SKIN IRRITATION.
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
HARMFUL IF INHALED.
MAY CAUSE RESPIRATORY IRRITATION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM |
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES AND EYE/FACE PROTECTION.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
STORAGE:
KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
POLYMETHYLENE POLYPHENYLENE ISOCYANATE 9016-87-9 60 - 100 TRADE SECRET *
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF
EASY TO DO. CONTINUE RINSING. GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
IN CASE OF FIRE:
USE A FIRE FIGHTING AGENT SUITABLE FOR ORDINARY COMBUSTIBLE MATERIAL SUCH
AS WATER OR FOAM TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY BUILD PRESSURE AND EXPLODE.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CYANIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR SPILLS IN CONFINED
SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR EXHAUST VAPORS, IN
ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER TO OTHER SECTIONS
OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH HAZARDS,
RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. POUR ISOCYANATE DECONTAMINANT SOLUTION (90% WATER, 8%
CONCENTRATED AMMONIA, 2% DETERGENT) ON SPILL AND ALLOW TO REACT FOR 10
MINUTES. OR POUR WATER ON SPILL AND ALLOW TO REACT FOR MORE THAN 30
MINUTES. COVER WITH ABSORBENT MATERIAL. WORKING FROM AROUND THE EDGES OF
THE SPILL INWARD, COVER WITH BENTONITE, VERMICULITE, OR COMMERCIALLY
AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL
IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A
PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED
MATERIAL AS POSSIBLE. PLACE IN A CONTAINER APPROVED FOR TRANSPORTATION BY
APPROPRIATE AUTHORITIES, BUT DO NOT SEAL THE CONTAINER FOR 48 HOURS TO
AVOID PRESSURE BUILD-UP. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT
SELECTED BY A QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH
FRESH AIR. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS.
DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
DO NOT USE IN A CONFINED AREA WITH MINIMAL AIR EXCHANGE. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED TO PREVENT
LOSS OF STABILIZING MATERIALS. KEEP CONTAINER TIGHTLY CLOSED TO PREVENT
CONTAMINATION WITH WATER OR AIR. IF CONTAMINATION IS SUSPECTED, DO NOT
RESEAL CONTAINER. STORE AWAY FROM HEAT. STORE AWAY FROM ACIDS. STORE AWAY
FROM STRONG BASES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
BENZENE, 1,1'- 9016-87-9 ACGIH TWA:0.005 PPM
METHYLENEBIS
[4-ISOCYANATO-
BENZENE, 1,1'- 9016-87-9 OSHA CEIL: 0.2 MG/M3
METHYLENEBIS (0.02 PPM)
[4-ISOCYANATO-
FREE ISOCYANATES 9016-87-9 MANUFACTURER TWA: 0.005 PPM;
DETERMINED STEL: 0.02 PPM
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR CONTROL
DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE, USE
RESPIRATORY PROTECTION EQUIPMENT. PROVIDE VENTILATED ENCLOSURE FOR HEAT
CURING. CURING ENCLOSURES MUST BE EXHAUSTED TO OUTDOORS OR TO A SUITABLE
EMISSION CONTROL DEVICE.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT. THE FOLLOWING EYE/FACE PROTECTION(S) ARE
RECOMMENDED: INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
BUTYL RUBBER
NITRILE RUBBER
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING
PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - BUTYL RUBBER
APRON - NITRILE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: BROWN WITH EARTHY ODOR
PH: NOT APPLICABLE
BOILING POINT: 330 DEG. C
FLASH POINT: >/=220 DEG. C [TEST METHOD: CLOSED CUP]
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
SPECIFIC GRAVITY: 1.22 [REF STD: WATER=1]
SOLUBILITY IN WATER: NEGLIGIBLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS: <1% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS: <1 G/L
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION MAY OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS:
ALCOHOLS
AMINES
STRONG ACIDS
STRONG BASES
WATER
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
HARMFUL IF INHALED.
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST. MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
SEVERE EYE IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE SIGNIFICANT REDNESS, SWELLING, PAIN, TEARING,
CLOUDY APPEARANCE OF THE CORNEA, AND IMPAIRED VISION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE
10 - 20 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE
>5,000 MG/KG
POLYMETHYLENE POLYPHENYLENE INHALATION- LC50 ESTIMATED TO BE
ISOCYANATE VAPOR 10 - 20 MG/L
POLYMETHYLENE POLYPHENYLENE DERMAL RABBIT LD50 >5,000 MG/KG
ISOCYANATE
POLYMETHYLENE POLYPHENYLENE INHALATION- RAT LC50 0.369 MG/L
ISOCYANATE DUST/MIST
(4 HOURS)
POLYMETHYLENE POLYPHENYLENE INGESTION RAT LD50 31,600 MG/KG
ISOCYANATE
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
POLYMETHYLENE POLYPHENYLENE ISOCYANATE OFFICIAL IRRITANT
CLASSIFICATION
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
POLYMETHYLENE POLYPHENYLENE ISOCYANATE OFFICIAL SEVERE IRRITANT
CLASSIFICATION
SKIN SENSITIZATION:
NAME SPECIES VALUE
POLYMETHYLENE POLYPHENYLENE ISOCYANATE OFFICIAL SENSITIZING
CLASSIFICATION
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
POLYMETHYLENE POLYPHENYLENE ISOCYANATE HUMAN SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
POLYMETHYLENE POLYPHENYLENE IN VITRO SOME POSITIVE DATA EXIST, BUT THE
ISOCYANATE DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
POLYMETHYLENE POLYPHENYLENE INHALATION RAT SOME POSITIVE DATA EXIST,
ISOCYANATE BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
POLYMETHYLENE INHALATION SOME POSITIVE RAT NOAEL DURING
POLYPHENYLENE DEVELOPMENTAL 0.004 MG/L ORGANO-
ISOCYANATE DATA EXIST, BUT GENESIS
THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET VALUE SPECIES
ORGAN(S)
POLYMETHYLENE INHALATION RESPIRATORY MAY CAUSE OFFICIAL
POLYPHENYLENE IRRITATION RESPIRATORY CLASSIFICATION
ISOCYANATE IRRITATION
NAME TEST RESULT EXPOSURE
DURATION
POLYMETHYLENE POLYPHENYLENE ISOCYANATE NOAEL NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET VALUE SPECIES TEST EXPOSURE
ORGAN(S) RESULT DURATION
POLYMETHYLENE INHALATION RESPIRA- CAUSES RAT LOAEL 13 WEEKS
POLYPHENYLENE TORY DAMAGE 0.004
ISOCYANATE SYSTEM TO ORGANS MG/L
THROUGH
PROLONGED
OR
REPEATED
EXPOSURE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
INCINERATE IN A PERMITTED WASTE INCINERATION FACILITY. PROPER DESTRUCTION
MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING INCINERATION PROCESSES. AS A
DISPOSAL ALTERNATIVE, UTILIZE AN ACCEPTABLE PERMITTED WASTE DISPOSAL
FACILITY. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING
HAZARDOUS CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED
AS HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT HTTP://3M.COM/TRANSPORTINFO OR CALL
1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: NO
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
POLYMETHYLENE POLYPHENYLENE ISOCYANATE 9016-87-9 60 - 100
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS:
CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH *2
FLAMMABILITY 1
PHYSICAL HAZARD 1
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) III) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) III RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) III PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN
COATINGS ASSOCIATION (ACA).
DOCUMENT GROUP: 31-5236-0
VERSION NUMBER: 2.01
ISSUE DATE: 04/21/15
SUPERCEDES DATE: 04/21/14
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION. 3M PROVIDES INFORMATION
IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS. DUE TO THE REMOTE
POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN ERRORS, OMISSIONS
OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO REPRESENTATIONS AS TO ITS
COMPLETENESS OR ACCURACY. IN ADDITION, INFORMATION OBTAINED FROM A DATABASE
MAY NOT BE AS CURRENT AS THE INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM
3M
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