| Common Name: | HARDHT SSPR 6PK 2100 GLS POST OFFICE BLU, A212836830 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 9/11/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 1BW39 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 9/11/2018
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: HARDHT SSPR 6PK 2100 GLS POST OFFICE BLU
PRODUCT IDENTIFIER: A212836830
RECOMMENDED USE: TOPCOAT/AEROSOLS
REVISION DATE: 9/11/2018
SUPERCEDES DATE: 8/6/2018
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
RUST-OLEUM CANADA (ROCA)
200 CONFEDERATION PARKWAY
CONCORD, ON L4K 4T8
CANADA
EMERGENCY PHONE: 800-387-3625
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT:
FLAME
EXCLAMATION MARK
HEALTH HAZARD
GAS CYLINDER
SIGNAL WORD: DANGER
POSSIBLE HAZARDS:
30% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN ACUTE TOXICITY.
GHS HAZARD STATEMENTS:
FLAMMABLE AEROSOL, CATEGORY 1:
H222: EXTREMELY FLAMMABLE AEROSOL.
COMPRESSED GAS:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CARCINOGENICITY, CATEGORY 2:
H351: SUSPECTED OF CAUSING CANCER.
STOT, SINGLE EXPOSURE, CATEGORY 3, NE:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
EYE IRRITATION, CATEGORY 2:
H319: CAUSES SERIOUS EYE IRRITATION.
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
GHS LABEL PRECAUTIONARY STATEMENTS:
P210:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING.
P211: DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION SOURCE.
P251: DO NOT PIERCE OR BURN, EVEN AFTER USE.
P410+P412:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C / 122 DEG. F.
P410+P403: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE
PROTECTION.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL
AND NATIONAL REGULATIONS.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P304+P340:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P312: CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
P403+P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P264: WASH HANDS THOROUGHLY AFTER HANDLING.
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
P272:
CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P321: FOR SPECIFIC TREATMENT SEE LABEL
GHS SDS PRECAUTIONARY STATEMENTS:
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% RANGE
ACETONE 67-64-1 23
PROPANE 74-98-6 17
N-BUTYL ACETATE 123-86-4 15
METHYL ETHYL KETONE 78-93-3 8.1
N-BUTANE 106-97-8 8.0
PROPYLENE GLYCOL MONOBUTYL ETHER 5131-66-8 3.5
XYLENES (O-, M-, P- ISOMERS) 1330-20-7 3.0
TITANIUM DIOXIDE 13463-67-7 1.0
ETHYLBENZENE 100-41-4 0.7
METHYL ETHYL KETOXIME 96-29-7 0.2
STODDARD SOLVENT 8052-41-3 0.2
SOLVENT NAPHTHA, LIGHT AROMATIC 64742-95-6 0.1
CARBON BLACK 1333-86-4 0.1
NAPHTHA, HYDROTREATED HEAVY 64742-48-9 0.1
CHEMICAL NAME GHS SYMBOLS GHS STATEMENTS
ACETONE GHS02-GHS07 H225-319-332-336
PROPANE GHS04 H280
N-BUTYL ACETATE GHS02-GHS07 H226-336
METHYL ETHYL KETONE GHS02-GHS07 H225-319-332-336
N-BUTANE GHS04 H280
PROPYLENE GLYCOL MONOBUTYL GHS07 H302-315-319
ETHER
XYLENES (O-, M-, P- ISOMERS) GHS02-GHS07 H226-315-319-332
TITANIUM DIOXIDE NOT AVAILABLE NOT AVAILABLE
ETHYLBENZENE GHS02-GHS07-GHS08 H225-304-332-351-373
METHYL ETHYL KETOXIME GHS05-GHS06-GHS08 H302-312-317-318-331-
351
STODDARD SOLVENT GHS08 H304-372
SOLVENT NAPHTHA, LIGHT GHS07-GHS08 H304-332
AROMATIC
CARBON BLACK NOT AVAILABLE NOT AVAILABLE
NAPHTHA, HYDROTREATED HEAVY GHS08 H304
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
IF YOU EXPERIENCE DIFFICULTY IN BREATHING, LEAVE THE AREA TO OBTAIN FRESH
AIR. IF CONTINUED DIFFICULTY IS EXPERIENCED, GET MEDICAL ASSISTANCE
IMMEDIATELY. REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL
ATTENTION. DO NOT USE MOUTH-TO-MOUTH RESUSCITATION.
FIRST AID - INGESTION:
ASPIRATION HAZARD:
DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH BECAUSE THIS MATERIAL
CAN ENTER THE LUNGS AND CAUSE SEVERE LUNG DAMAGE. GET IMMEDIATE MEDICAL
ATTENTION. IF SWALLOWED, GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
FLASH POINT IS LESS THAN 20 DEG. F. EXTREMELY FLAMMABLE LIQUID AND VAPOR!
WATER SPRAY MAY BE INEFFECTIVE. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT. VAPORS MAY FORM EXPLOSIVE MIXTURES WITH AIR. VAPORS CAN
TRAVEL TO A SOURCE OF IGNITION AND FLASH BACK. KEEP CONTAINERS TIGHTLY
CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME.
PERFORATION OF THE PRESSURIZED CONTAINER MAY CAUSE BURSTING OF THE CAN.
CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT DUE TO BUILDUP
OF STEAM. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
EVACUATE AREA AND FIGHT FIRE FROM A SAFE DISTANCE. FULL PROTECTIVE
EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED.
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILDUP
AND POSSIBLE AUTOIGNITION OR EXPLOSION. USE WATER SPRAY TO KEEP
FIRE-EXPOSED CONTAINERS COOL. CONTAINERS MAY EXPLODE WHEN HEATED.
SPECIAL FIRE AND EXPLOSION HAZARD (COMBUSTIBLE DUST): NO INFORMATION
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
CONTAIN SPILLED LIQUID WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIALS
SUCH AS SAWDUST. REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA AND REMOVE
WITH INERT ABSORBENT AND NONSPARKING TOOLS. DISPOSE OF ACCORDING TO LOCAL,
STATE (PROVINCIAL) AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED
CONTAINERS. ISOLATE THE HAZARD AREA AND DENY ENTRY TO UNNECESSARY AND
UNPROTECTED PERSONNEL. VENTILATE AREA, ISOLATE SPILLED MATERIAL, AND REMOVE
WITH INERT ABSORBENT. DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND
UNUSED CONTENTS IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. USE ONLY IN A
WELL-VENTILATED AREA. FOLLOW ALL SDS AND LABEL PRECAUTIONS EVEN AFTER
CONTAINER IS EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID
BREATHING FUMES, VAPORS, OR MIST. REMOVE CONTAMINATED CLOTHING AND LAUNDER
BEFORE REUSE. USE ONLY WITH ADEQUATE VENTILATION. AVOID CONTACT WITH EYES,
SKIN AND CLOTHING.
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS AND OPEN FLAME. CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE
120 DEG. F. STORE LARGE QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR
STORAGE OF FLAMMABLE AEROSOLS. CONTENTS UNDER PRESSURE. DO NOT EXPOSE TO
HEAT OR STORE ABOVE 120 DEG. F. PRODUCT SHOULD BE STORED IN TIGHTLY SEALED
CONTAINERS AND PROTECTED FROM HEAT, MOISTURE, AND FOREIGN MATERIALS. STORE
IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN
USE. KEEP AWAY FROM HEAT, SPARKS, FLAME AND SOURCES OF IGNITION. AVOID
EXCESS HEAT.
ADVICE ON SAFE HANDLING OF COMBUSTIBLE DUST: NO INFORMATION
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
ACETONE 67-64-1 25.0
PROPANE 74-98-6 20.0
N-BUTYL ACETATE 123-86-4 15.0
METHYL ETHYL KETONE 78-93-3 10.0
N-BUTANE 106-97-8 10.0
PROPYLENE GLYCOL MONOBUTYL ETHER 5131-66-8 5.0
XYLENES (O-, M-, P- ISOMERS) 1330-20-7 5.0
TITANIUM DIOXIDE 13463-67-7 5.0
ETHYLBENZENE 100-41-4 1.0
METHYL ETHYL KETOXIME 96-29-7 1.0
STODDARD SOLVENT 8052-41-3 1.0
SOLVENT NAPHTHA, LIGHT AROMATIC 64742-95-6 1.0
CARBON BLACK 1333-86-4 1.0
NAPHTHA, HYDROTREATED HEAVY 64742-48-9 1.0
CHEMICAL NAME ACGIH ACGIH OSHA OSHA PEL-
TLV-TWA TLV-STEL PEL-TWA CEILING
ACETONE 250 PPM 500 PPM 1000 PPM N.E.
PROPANE N.E. N.E. 1000 PPM N.E.
N-BUTYL ACETATE 50 PPM 150 PPM 150 PPM N.E.
METHYL ETHYL KETONE 200 PPM 300 PPM 200 PPM N.E.
N-BUTANE N.E. 1000 PPM N.E. N.E.
PROPYLENE GLYCOL N.E. N.E. N.E. N.E.
MONOBUTYL ETHER
XYLENES (O-, M-, P- 100 PPM 150 PPM 100 PPM N.E.
ISOMERS)
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
ETHYLBENZENE 20 PPM N.E. 100 PPM N.E.
METHYL ETHYL KETOXIME 10 PPM N.E. N.E. N.E.
STODDARD SOLVENT 100 PPM N.E. 500 PPM N.E.
SOLVENT NAPHTHA, N.E. N.E. N.E. N.E.
LIGHT AROMATIC
CARBON BLACK 3 MG/M3 N.E. 3.5 MG/M3 N.E.
NAPHTHA, HYDROTREATED N.E. N.E. N.E. N.E.
HEAVY
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
USE EXPLOSION-PROOF VENTILATION EQUIPMENT. PREVENT BUILD-UP OF VAPORS BY
OPENING ALL DOORS AND WINDOWS TO ACHIEVE CROSS-VENTILATION. PROVIDE
GENERAL DILUTION OF LOCAL EXHAUST VENTILATION IN VOLUME AND PATTERN TO
KEEP TLV OF HAZARDOUS INGREDIENTS BELOW ACCEPTABLE LIMITS.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS.
SKIN PROTECTION:
USE IMPERVIOUS GLOVES TO PREVENT SKIN CONTACT AND ABSORPTION OF THIS
MATERIAL THROUGH THE SKIN. NITRILE OR NEOPRENE GLOVES MAY AFFORD ADEQUATE
SKIN PROTECTION. USE GLOVES TO PREVENT PROLONGED SKIN CONTACT.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION. REFER TO
SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE REGARDING
TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
ENGINEERING MEASURES FOR COMBUSTIBLE DUST: NO INFORMATION
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: AEROSOLIZED MIST
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 0.770
PH: N.A.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSTION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: -37 - 537
EXPLOSIVE LIMITS, VOL%: 1.0 - 13.0
FLAMMABILITY: SUPPORTS COMBUSTION
FLASH POINT, DEG. C: -96
EVAPORATION RATE: FASTER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID:
AVOID TEMPERATURES ABOVE 120 DEG. F (49 DEG. C). AVOID ALL POSSIBLE SOURCES
OF IGNITION.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES. CONTAINS
SOLVENTS WHICH MAY FORM CARBON MONOXIDE, CARBON DIOXIDE, AND
FORMALDEHYDE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT: CAUSES SERIOUS EYE IRRITATION
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION. PROLONGED OR REPEATED CONTACT
MAY CAUSE SKIN IRRITATION. MAY CAUSE SKIN IRRITATION. ALLERGIC REACTIONS
ARE POSSIBLE.
EFFECTS OF OVEREXPOSURE - INHALATION:
HARMFUL IF INHALED. HIGH GAS, VAPOR, MIST OR DUST CONCENTRATIONS MAY BE
HARMFUL IF INHALED. AVOID BREATHING FUMES, SPRAY, VAPORS, OR MIST. HIGH
VAPOR CONCENTRATIONS ARE IRRITATING TO THE EYES, NOSE, THROAT AND LUNGS.
PROLONGED OR EXCESSIVE INHALATION MAY CAUSE RESPIRATORY TRACT IRRITATION.
EFFECTS OF OVEREXPOSURE - INGESTION:
ASPIRATION HAZARD IF SWALLOWED; CAN ENTER LUNGS AND CAUSE DAMAGE. HARMFUL
IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
OVEREXPOSURE TO XYLENE IN LABORATORY ANIMALS HAS BEEN ASSOCIATED WITH
LIVER ABNORMALITIES, KIDNEY, LUNG, SPLEEN, EYE AND BLOOD DAMAGE AS WELL AS
REPRODUCTIVE DISORDERS. EFFECTS IN HUMANS, DUE TO CHRONIC OVEREXPOSURE,
HAVE INCLUDED LIVER, CARDIAC ABNORMALITIES AND NERVOUS SYSTEM DAMAGE. IARC
LISTS ETHYLBENZENE AS A POSSIBLE HUMAN CARCINOGEN (GROUP 2B). CONTAINS
CARBON BLACK. CHRONIC INFLAMMATION, LUNG FIBROSIS, AND LUNG TUMORS HAVE
BEEN OBSERVED IN SOME RATS EXPERIMENTALLY EXPOSED FOR LONG PERIODS OF TIME
TO EXCESSIVE CONCENTRATIONS OF CARBON BLACK AND SEVERAL INSOLUBLE FINE DUST
PARTICLES. TUMORS HAVE NOT BEEN OBSERVED IN OTHER ANIMAL SPECIES (I.E.,
MOUSE AND HAMSTER) UNDER SIMILAR CIRCUMSTANCES AND STUDY CONDITIONS.
EPIDEMIOLOGICAL STUDIES OF NORTH AMERICAN WORKERS SHOW NO EVIDENCE OF
CLINICALLY SIGNIFICANT ADVERSE HEALTH EFFECTS DUE TO OCCUPATIONAL EXPOSURE
TO CARBON BLACK.
CARBON BLACK IS LISTED AS A GROUP 2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY
IARC AND IS PROPOSED TO BE LISTED AS A4- "NOT CLASSIFIED AS A HUMAN
CARCINOGEN" BY THE AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS. SIGNIFICANT EXPOSURE IS NOT ANTICIPATED DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND
THE ACTUAL CONCENTRATION OF CARBON BLACK IN THE FORMULA. CONTAINS
TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP 2B-"POSSIBLY
CARCINOGENIC TO HUMANS" BY IARC. NO SIGNIFICANT EXPOSURE TO TITANIUM
DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS IN WHICH TITANIUM
DIOXIDE IS BOUND TO OTHER MATERIALS, SUCH AS IN PAINTS DURING BRUSH
APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND LEVEL
OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST AND THE
ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE FORMULA. (REF: IARC
MONOGRAPH, VOL. 93, 2010)OVEREXPOSURE TO METHYL ETHYL KETONE IN LABORATORY
ANIMALS HAS BEEN ASSOCIATED WITH LIVER ABNORMALITIES, KIDNEY AND LUNG
DAMAGE. FETOTOXIC/EMBRYOTOXIC EFFECTS FROM INHALATION HAVE BEEN SEEN IN
RATS EXPOSED TO >1000PPM DURING GESTATION. REPORTS HAVE ASSOCIATED REPEATED
AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN
AND NERVOUS SYSTEM DAMAGE. MAY CAUSE CENTRAL NERVOUS SYSTEM DISORDER (E.G.,
NARCOSIS INVOLVING A LOSS OF COORDINATION, WEAKNESS, FATIGUE, MENTAL
CONFUSION, AND BLURRED VISION) AND/OR DAMAGE. HIGH CONCENTRATIONS MAY LEAD
TO CENTRAL NERVOUS SYSTEM EFFECTS (DROWSINESS, DIZZINESS, NAUSEA,
HEADACHES, PARALYSIS, AND BLURRED VISION) AND/OR DAMAGE.
PRIMARY ROUTE(S) OF ENTRY: EYE CONTACT, INGESTION, INHALATION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
67-64-1 ACETONE 5800 >15700 MG/KG 50.1 MG/L RAT
MG/KG RAT RABBIT
123-86-4 N-BUTYL ACETATE 10768 >17600 MG/KG > 21 MG/L RAT
MG/KG RAT RABBIT
78-93-3 METHYL ETHYL KETONE 2483 5000 MG/KG N.E.
MG/KG RAT RABBIT
106-97-8 N-BUTANE N.E. N.E. 658 MG/L RAT
5131-66-8 PROPYLENE GLYCOL 1900 N.E. N.E.
MONOBUTYL ETHER MG/KG RAT
1330-20-7 XYLENES (O-, M-, P- 3500 >4350 MG/KG 29.08 MG/L
ISOMERS) MG/KG RAT RABBIT RAT
13463-67-7 TITANIUM DIOXIDE >10000 2500 MG/KG N.E.
MG/KG RAT
100-41-4 ETHYLBENZENE 3500 15400 MG/KG 17.4 MG/L RAT
MG/KG RAT RABBIT
96-29-7 METHYL ETHYL 930 MG/KG 1100 MG/KG >4.8 MG/L RAT
KETOXIME RAT RABBIT
64742-95-6 SOLVENT NAPHTHA, 8400 >2000 MG/KG N.E.
LIGHT AROMATIC MG/KG RAT RABBIT
1333-86-4 CARBON BLACK >15400 N.E. N.E.
MG/KG RAT
64742-48-9 NAPHTHA, >6000 >3160 MG/KG N.E.
HYDROTREATED HEAVY MG/KG RAT RABBIT
N.E. - NOT ESTABLISHED
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION:
PRODUCT IS A MIXTURE OF LISTED COMPONENTS. PRODUCT IS A MIXTURE OF LISTED
COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS. DO NOT INCINERATE CLOSED CONTAINERS. THIS PRODUCT
AS SUPPLIED IS A USEPA DEFINED IGNITABLE HAZARDOUS WASTE. DISPOSE OF
UNUSABLE PRODUCT AS A HAZARDOUS WASTE (D001) IN ACCORDANCE WITH LOCAL,
STATE, AND FEDERAL REGULATION.
| 14. TRANSPORT INFORMATION | |
DOMESTIC (USDOT) INTERNATIONAL (IMDG)
UN NUMBER N.A. 1950
PROPER SHIPPING NAME AEROSOLS AEROSOLS
HAZARD CLASS N.A. 2
PACKING GROUP N.A. N.A.
LIMITED QUANTITY YES YES
AIR (IATA) TDG (CANADA)
UN NUMBER 1950 N.A.
PROPER SHIPPING NAME AEROSOLS, FLAMMABLE AEROSOLS
HAZARD CLASS 2.1 N.A.
PACKING GROUP N.A. N.A.
LIMITED QUANTITY YES YES
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
GAS UNDER PRESSURE, CARCINOGENICITY, RESPIRATORY OR SKIN SENSITIZATION,
SERIOUS EYE DAMAGE OR EYE IRRITATION, SPECIFIC TARGET ORGAN TOXICITY
(SINGLE OR REPEATED EXPOSURE)
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
METHYL ETHYL KETONE 78-93-3
XYLENES (O-, M-, P- ISOMERS) 1330-20-7
ETHYLBENZENE 100-41-4
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
NO TSCA 12(B) COMPONENTS EXIST IN THIS PRODUCT.
U.S. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
WARNING: CANCER AND REPRODUCTIVE HARM - WWW.P65WARNINGS.CA.GOV.
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 2*
FLAMMABILITY 4
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 2
FLAMMABILITY 4
INSTABILITY 0
MAXIMUM INCREMENTAL REACTIVITY: 0.90
SDS REVISION DATE: 9/11/2018
REASON FOR REVISION:
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
01 - IDENTIFICATION
14 - TRANSPORT INFORMATION
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
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BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS OF
THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
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