| Common Name: | SP702 ENGINE DEGREASER AEROSOL |
| Manufacturer: | SPRAYON PRODUCTS GROUP |
| SDS Revision Date: | 11/28/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 1D269 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
S00702000
| SECTION 1. IDENTIFICATION |  |
PRODUCT NAME: SP(TM)702 ENGINE DEGREASER AEROSOL
PRODUCT CODE: S00702000
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
PRODUCT TYPE: AEROSOL.
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: PAINT OR PAINT RELATED MATERIAL.
MANUFACTURER:
SPRAYON PRODUCTS GROUP
101 W. PROSPECT AVENUE
CLEVELAND, OHIO 44115
EMERGENCY TELEPHONE NUMBER OF THE COMPANY:
US / CANADA: (800) 424-9300
MEXICO:
SETIQ: 01-800-00-214-00 / (52) 55-5559-1588 24 HOURS / 365 DAYS A YEAR
PRODUCT INFORMATION TELEPHONE NUMBER:
US / CANADA: (800) 247-3266
MEXICO: NOT AVAILABLE
REGULATORY INFORMATION TELEPHONE NUMBER:
US / CANADA: (216) 566-2902
MEXICO: NOT AVAILABLE
TRANSPORTATION EMERGENCY TELEPHONE NUMBER:
US / CANADA: (800) 424-9300
MEXICO:
SETIQ: 01-800-00-214-00 / (52) 55-5559-1588 24 HOURS / 365 DAYS A YEAR
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: COMPRESSED GAS
SKIN CORROSION/IRRITATION: CATEGORY 1
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 1
SKIN SENSITIZATION: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 2
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ACUTE
ORAL TOXICITY: 1.6%
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ACUTE
DERMAL TOXICITY: 2.7%
PERCENTAGE OF THE MIXTURE CONSISTING OF INGREDIENT(S) OF UNKNOWN ACUTE
INHALATION TOXICITY: 5.7%
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS:
FLAME
GAS CYLINDER
CORROSION
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
EXTREMELY FLAMMABLE AEROSOL.
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE.
PRECAUTIONARY STATEMENTS:
PREVENTION:
WEAR PROTECTIVE GLOVES. WEAR EYE OR FACE PROTECTION. WEAR PROTECTIVE
CLOTHING. KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER
IGNITION SOURCES. NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER
IGNITION SOURCE. DO NOT BREATHE DUST OR MIST. WASH HANDS THOROUGHLY AFTER
HANDLING. CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE
WORKPLACE.
PRESSURIZED CONTAINER: DO NOT PIERCE OR BURN, EVEN AFTER USE.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. IMMEDIATELY
CALL A POISON CENTER OR PHYSICIAN.
IF SWALLOWED:
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. RINSE MOUTH. DO NOT INDUCE
VOMITING.
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH WATER OR
SHOWER. WASH CONTAMINATED CLOTHING BEFORE REUSE. IMMEDIATELY CALL A POISON
CENTER OR PHYSICIAN.
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING. IMMEDIATELY CALL A POISON
CENTER OR PHYSICIAN.
STORAGE:
STORE LOCKED UP. PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES
EXCEEDING 50 DEG. C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
SUPPLEMENTAL LABEL ELEMENTS:
DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. CONTAINS SOLVENTS WHICH CAN
CAUSE PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING THE CONTENTS CAN BE HARMFUL OR
FATAL. FOR INDUSTRIAL USE ONLY.
PLEASE REFER TO THE SDS FOR ADDITIONAL INFORMATION. KEEP OUT OF REACH OF
CHILDREN. KEEP UPRIGHT IN A COOL, DRY PLACE. DO NOT DISCARD EMPTY CAN IN
TRASH COMPACTOR.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE/MIXTURE: MIXTURE
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE.
CAS NUMBER/OTHER IDENTIFIERS:
INGREDIENT NAME % BY WEIGHT CAS NUMBER
| BUTANE </=5 106-97-8
D-LIMONENE </=5 5989-27-5
2-BUTOXYETHANOL </=3 111-76-2
PROPANE </=3 74-98-6
TETRASODIUM ETHYLENEDIAMINETETRAACETATE </=3 64-02-8
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS
DUE TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH AND HENCE REQUIRE REPORTING IN THIS
SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE
UPPER AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE
TO RINSE FOR AT LEAST 10 MINUTES. CHEMICAL BURNS MUST BE TREATED PROMPTLY
BY A PHYSICIAN.
INHALATION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN.
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS. IF
NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY ARREST OCCURS,
PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED PERSONNEL. IT MAY BE
DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH RESUSCITATION.
IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND. IN CASE OF INHALATION OF DECOMPOSITION
PRODUCTS IN A FIRE, SYMPTOMS MAY BE DELAYED. THE EXPOSED PERSON MAY NEED
TO BE KEPT UNDER MEDICAL SURVEILLANCE FOR 48 HOURS.
SKIN CONTACT:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
WITH PLENTY OF SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND SHOES.
WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE REMOVING IT, OR
WEAR GLOVES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. CHEMICAL BURNS
MUST BE TREATED PROMPTLY BY A PHYSICIAN. IN THE EVENT OF ANY COMPLAINTS
OR SYMPTOMS, AVOID FURTHER EXPOSURE. WASH CLOTHING BEFORE REUSE. CLEAN
SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
GET MEDICAL ATTENTION IMMEDIATELY. CALL A POISON CENTER OR PHYSICIAN. WASH
OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH AIR
AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL HAS
BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL QUANTITIES
OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS VOMITING MAY
BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL
PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO THAT VOMIT
DOES NOT ENTER THE LUNGS. CHEMICAL BURNS MUST BE TREATED PROMPTLY BY A
PHYSICIAN. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF
UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET MEDICAL ATTENTION
IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT CLOTHING SUCH AS A
COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: CAUSES SEVERE BURNS. MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: STOMACH PAINS
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED,
IF NECESSARY:
NOTES TO PHYSICIAN:
IN CASE OF INHALATION OF DECOMPOSITION PRODUCTS IN A FIRE, SYMPTOMS MAY
BE DELAYED. THE EXPOSED PERSON MAY NEED TO BE KEPT UNDER MEDICAL
SURVEILLANCE FOR 48 HOURS.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IF IT IS SUSPECTED THAT FUMES ARE STILL PRESENT, THE RESCUER
SHOULD WEAR AN APPROPRIATE MASK OR SELF-CONTAINED BREATHING APPARATUS.
IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE MOUTH-TO-MOUTH
RESUSCITATION. WASH CONTAMINATED CLOTHING THOROUGHLY WITH WATER BEFORE
REMOVING IT, OR WEAR GLOVES.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING:
EXTREMELY FLAMMABLE AEROSOL. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION
HAZARD. IN FROM THE CHEMICAL A FIRE OR IF HEATED, A PRESSURE INCREASE
WILL OCCUR AND THE CONTAINER MAY BURST, WITH THE RISK OF A SUBSEQUENT
EXPLOSION. GAS MAY ACCUMULATE IN LOW OR CONFINED AREAS OR TRAVEL A
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK, CAUSING FIRE
OR EXPLOSION. BURSTING AEROSOL CONTAINERS MAY BE PROPELLED FROM A FIRE AT
HIGH SPEED.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
NITROGEN OXIDES
METAL OXIDE/OXIDES
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING. MOVE CONTAINERS FROM FIRE AREA
IF THIS CAN BE DONE WITHOUT RISK. USE WATER SPRAY TO KEEP FIRE-EXPOSED
CONTAINERS COOL.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. IN THE CASE OF AEROSOLS BEING RUPTURED, CARE
SHOULD BE TAKEN DUE TO THE RAPID ESCAPE OF THE PRESSURIZED CONTENTS AND
PROPELLANT. IF A LARGE NUMBER OF CONTAINERS ARE RUPTURED, TREAT AS A BULK
MATERIAL SPILLAGE ACCORDING TO THE INSTRUCTIONS IN THE CLEAN-UP SECTION.
DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL. SHUT OFF ALL IGNITION
SOURCES. NO FLARES, SMOKING OR FLAMES IN HAZARD AREA. DO NOT BREATHE VAPOR
OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR APPROPRIATE RESPIRATOR WHEN
VENTILATION IS INADEQUATE. PUT ON APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALIZED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE
OF ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS.
SEE ALSO THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. DILUTE WITH WATER AND MOP UP IF
WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE, ABSORB WITH AN INERT
DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE DISPOSAL CONTAINER. DISPOSE
OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. USE SPARK-PROOF
TOOLS AND EXPLOSION-PROOF EQUIPMENT. APPROACH RELEASE FROM UPWIND. PREVENT
ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR CONFINED AREAS. WASH
SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED AS FOLLOWS. CONTAIN
AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT MATERIAL E.G. SAND,
EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN CONTAINER FOR
DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13). DISPOSE OF VIA
A LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT MATERIAL MAY
POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). PERSONS
WITH A HISTORY OF SKIN SENSITIZATION PROBLEMS SHOULD NOT BE EMPLOYED IN
ANY PROCESS IN WHICH THIS PRODUCT IS USED.
PRESSURIZED CONTAINER:
PROTECT FROM SUNLIGHT AND DO NOT EXPOSE TO TEMPERATURES EXCEEDING
50 DEG. C. DO NOT PIERCE OR BURN, EVEN AFTER USE. DO NOT GET IN EYES OR
ON SKIN OR CLOTHING. DO NOT BREATHE VAPOR OR MIST. DO NOT INGEST. AVOID
BREATHING GAS. USE ONLY WITH ADEQUATE VENTILATION. WEAR APPROPRIATE
RESPIRATOR WHEN VENTILATION IS INADEQUATE. STORE AND USE AWAY FROM HEAT,
SPARKS, OPEN FLAME OR ANY OTHER IGNITION SOURCE. USE EXPLOSION-PROOF
ELECTRICAL (VENTILATING, LIGHTING AND MATERIAL HANDLING) EQUIPMENT. USE
ONLY NON-SPARKING TOOLS. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE AND CAN
BE HAZARDOUS.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE AWAY FROM DIRECT
SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA, AWAY FROM INCOMPATIBLE
MATERIALS (SEE SECTION 10) AND FOOD AND DRINK. PROTECT FROM SUNLIGHT.
STORE LOCKED UP. ELIMINATE ALL IGNITION SOURCES. USE APPROPRIATE
CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION. SEE SECTION 10 FOR
INCOMPATIBLE MATERIALS BEFORE HANDLING OR USE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS (OSHA UNITED STATES):
INGREDIENT NAME CAS # EXPOSURE LIMITS
| BUTANE 106-97-8 NIOSH REL (UNITED STATES, 10/2016).
TWA: 800 PPM 10 HOURS.
TWA: 1900 MG/M3 10 HOURS.
ACGIH TLV (UNITED STATES, 3/2019).
EXPLOSIVE POTENTIAL.
STEL: 1000 PPM 15 MINUTES.
D-LIMONENE 5989-27-5 AIHA WEEL (UNITED STATES, 7/2018).
TWA: 30 PPM 8 HOURS.
2-BUTOXYETHANOL 111-76-2 ACGIH TLV (UNITED STATES, 3/2019).
TWA: 20 PPM 8 HOURS.
NIOSH REL (UNITED STATES, 10/2016).
ABSORBED THROUGH SKIN.
TWA: 5 PPM 10 HOURS.
TWA: 24 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 5/2018).
ABSORBED THROUGH SKIN.
TWA: 50 PPM 8 HOURS.
TWA: 240 MG/M3 8 HOURS.
PROPANE 74-98-6 NIOSH REL (UNITED STATES, 10/2016).
TWA: 1000 PPM 10 HOURS.
TWA: 1800 MG/M3 10 HOURS.
OSHA PEL (UNITED STATES, 5/2018).
TWA: 1000 PPM 8 HOURS.
TWA: 1800 MG/M3 8 HOURS.
ACGIH TLV (UNITED STATES, 3/2019).
OXYGEN DEPLETION [ASPHYXIANT].
EXPLOSIVE POTENTIAL.
TETRASODIUM 64-02-8 NONE.
ETHYLENEDIAMINE-
TETRAACETATE
OCCUPATIONAL EXPOSURE LIMITS (CANADA):
INGREDIENT NAME CAS # EXPOSURE LIMITS
| BUTANE 106-97-8 CA ALBERTA PROVINCIAL (CANADA, 6/2018).
8 HRS OEL: 1000 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 800 PPM 8 HOURS.
TWAEV: 1900 MG/M3 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 1/2018).
TWA: 800 PPM 8 HOURS.
CA SASKATCHEWAN PROVINCIAL
(CANADA, 7/2013).
STEL: 1250 PPM 15 MINUTES.
TWA: 1000 PPM 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL
(CANADA, 5/2019). EXPLOSIVE POTENTIAL.
STEL: 1000 PPM 15 MINUTES.
D-LIMONENE 5989-27-5 AIHA WEEL (UNITED STATES, 7/2018).
TWA: 30 PPM 8 HOURS.
ETHYLENE GLYCOL 111-76-2 CA ALBERTA PROVINCIAL (CANADA, 6/2018).
MONOBUTYL ETHER 8 HRS OEL: 97 MG/M3 8 HOURS.
8 HRS OEL: 20 PPM 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL
(CANADA, 5/2019).
TWA: 20 PPM 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 1/2018).
TWA: 20 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 20 PPM 8 HOURS.
TWAEV: 97 MG/M3 8 HOURS.
CA SASKATCHEWAN PROVINCIAL
(CANADA, 7/2013).
STEL: 30 PPM 15 MINUTES.
TWA: 20 PPM 8 HOURS.
NORMAL PROPANE 74-98-6 CA ALBERTA PROVINCIAL (CANADA, 6/2018).
8 HRS OEL: 1000 PPM 8 HOURS.
CA QUEBEC PROVINCIAL (CANADA, 1/2014).
TWAEV: 1000 PPM 8 HOURS.
TWAEV: 1800 MG/M3 8 HOURS.
CA ONTARIO PROVINCIAL (CANADA, 1/2018).
TWA: 1000 PPM 8 HOURS.
CA SASKATCHEWAN PROVINCIAL
(CANADA, 7/2013).
STEL: 1250 PPM 15 MINUTES.
TWA: 1000 PPM 8 HOURS.
CA BRITISH COLUMBIA PROVINCIAL
(CANADA, 5/2019).
OXYGEN DEPLETION [ASPHYXIANT].
EXPLOSIVE POTENTIAL.
OCCUPATIONAL EXPOSURE LIMITS (MEXICO):
CAS # EXPOSURE LIMITS
| BUTANE 106-97-8 NOM-010-STPS-2014 (MEXICO, 4/2016).
TWA: 1000 PPM 8 HOURS.
2-BUTOXYETHANOL 111-76-2 NOM-010-STPS-2014 (MEXICO, 4/2016).
ABSORBED THROUGH SKIN.
TWA: 20 PPM 8 HOURS.
PROPANE 74-98-6 NOM-010-STPS-2014 (MEXICO, 4/2016).
TWA: 1000 PPM 8 HOURS.
APPROPRIATE ENGINEERING CONTROLS:
USE ONLY WITH ADEQUATE VENTILATION. IF USER OPERATIONS GENERATE DUST,
FUMES, GAS, VAPOR OR MIST, USE PROCESS ENCLOSURES, LOCAL EXHAUST
VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP WORKER EXPOSURE TO
AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY LIMITS. THE
ENGINEERING CONTROLS ALSO NEED TO KEEP GAS, VAPOR OR DUST CONCENTRATIONS
BELOW ANY LOWER EXPLOSIVE LIMITS. USE EXPLOSION-PROOF VENTILATION
EQUIPMENT.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE
WORKING PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE THAT
EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION:
CHEMICAL SPLASH GOGGLES AND/OR FACE SHIELD. IF INHALATION HAZARDS EXIST,
A FULL-FACE RESPIRATOR MAY BE REQUIRED INSTEAD.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT. WHEN THERE IS A RISK OF IGNITION
FROM STATIC ELECTRICITY, WEAR ANTISTATIC PROTECTIVE CLOTHING. FOR THE
GREATEST PROTECTION FROM STATIC DISCHARGES, CLOTHING SHOULD INCLUDE
ANTI-STATIC OVERALLS, BOOTS AND GLOVES.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD
BE SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
BASED ON THE HAZARD AND POTENTIAL FOR EXPOSURE, SELECT A RESPIRATOR THAT
MEETS THE APPROPRIATE STANDARD OR CERTIFICATION. RESPIRATORS MUST BE USED
ACCORDING TO A RESPIRATORY PROTECTION PROGRAM TO ENSURE PROPER FITTING,
TRAINING, AND OTHER IMPORTANT ASPECTS OF USE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID.
COLOR: NOT AVAILABLE.
ODOR: NOT AVAILABLE.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 12.4
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
BOILING POINT/BOILING RANGE: NOT AVAILABLE.
FLASH POINT:
CLOSED CUP: -29 DEG. C (-20.2 DEG. F) [PENSKY-MARTENS CLOSED CUP]
EVAPORATION RATE: 0.09 (BUTYL ACETATE = 1)
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
LOWER AND UPPER EXPLOSIVE (FLAMMABLE) LIMITS:
LOWER: 0.7%
UPPER: 10.6%
VAPOR PRESSURE: 101.3 KPA (760 MMHg) [AT 20 DEG. C]
VAPOR DENSITY: 0.012 [AIR = 1]
RELATIVE DENSITY: 0.96
SOLUBILITY: NOT AVAILABLE.
PARTITION COEFFICIENT N-OCTANOL/WATER: NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY:
KINEMATIC (40 DEG. C (104 DEG. F)): >0.205 CM2/S (>20.5 CST)
MOLECULAR WEIGHT: NOT APPLICABLE.
AEROSOL PRODUCT:
TYPE OF AEROSOL: SPRAY
HEAT OF COMBUSTION: 5.325 KJ/G
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID:
AVOID ALL POSSIBLE SOURCES OF IGNITION (SPARK OR FLAME).
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
| BUTANE LC50 INHALATION VAPOR RAT 658000 MG/M3 4 HOURS
D-LIMONENE LD50 DERMAL RABBIT >5000 MG/KG
LD50 ORAL RAT 4400 MG/KG
2-BUTOXYETHANOL LCLO INHALATION VAPOR GUINEA >3.1 MG/L 1 HOURS
PIG
LD50 DERMAL GUINEA >2000 MG/KG
PIG
LD50 ORAL RAT 1300 MG/KG
TETRASODIUM LD50 ORAL RAT 10 G/KG
ETHYLENEDIAMINE-
TETRAACETATE
IRRITATION/CORROSION:
PRODUCT/INGREDIENT RESULT SPECIES SCORE EXPOSURE OBSERVATION
NAME
| D-LIMONENE SKIN: RABBIT 24 HOURS
MILD 10 %
IRRITANT
2-BUTOXYETHANOL EYES: RABBIT 24 HOURS
MODERATE 100 MG
IRRITANT
EYES: RABBIT 100 MG
SEVERE
IRRITANT
SKIN: RABBIT 500 MG
MILD
IRRITANT
TETRASODIUM EYES: RABBIT 24 HOURS
ETHYLENEDIAMINE- MODERATE 100 MG
TETRAACETATE IRRITANT
SKIN: RABBIT 24 HOURS
MODERATE 500 MG
IRRITANT
SENSITIZATION: NOT AVAILABLE.
MUTAGENICITY: NOT AVAILABLE.
CARCINOGENICITY: NOT AVAILABLE.
CLASSIFICATION:
PRODUCT/INGREDIENT NAME OSHA IARC NTP
| D-LIMONENE 3
2-BUTOXYETHANOL 3
REPRODUCTIVE TOXICITY: NOT AVAILABLE.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
BUTANE CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION
D-LIMONENE CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION
2-BUTOXYETHANOL CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION
PROPANE CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
CATEGORY 3 NOT APPLICABLE. RESPIRATORY TRACT
IRRITATION
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
BUTANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
D-LIMONENE CATEGORY 2 NOT DETERMINED NOT DETERMINED
2-BUTOXYETHANOL CATEGORY 2 NOT DETERMINED NOT DETERMINED
PROPANE CATEGORY 2 NOT DETERMINED NOT DETERMINED
ASPIRATION HAZARD:
NAME RESULT
BUTANE ASPIRATION HAZARD - CATEGORY 1
D-LIMONENE ASPIRATION HAZARD - CATEGORY 1
PROPANE ASPIRATION HAZARD - CATEGORY 1
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE: NOT AVAILABLE.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: CAUSES SEVERE BURNS. MAY CAUSE AN ALLERGIC SKIN REACTION.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN
WATERING
REDNESS
INHALATION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
RESPIRATORY TRACT IRRITATION
COUGHING
SKIN CONTACT:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING:
PAIN OR IRRITATION
REDNESS
BLISTERING MAY OCCUR
INGESTION:
ADVERSE SYMPTOMS MAY INCLUDE THE FOLLOWING: STOMACH PAINS
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND
LONG TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
POTENTIAL CHRONIC HEALTH EFFECTS: NOT AVAILABLE.
GENERAL:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE. ONCE
SENSITIZED, A SEVERE ALLERGIC REACTION MAY OCCUR WHEN SUBSEQUENTLY EXPOSED
TO VERY LOW LEVELS.
CARCINOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
MUTAGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
TERATOGENICITY: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
DEVELOPMENTAL EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
FERTILITY EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
NUMERICAL MEASURES OF TOXICITY:
ACUTE TOXICITY ESTIMATES:
ROUTE ATE VALUE
ORAL 21928.48 MG/KG
DERMAL 55000 MG/KG
INHALATION (VAPORS) 550 MG/L
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
| D-LIMONENE ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
421 (MICRO)G/L MAGNA
FRESH WATER
ACUTE EC50: FISH - PIMEPHALES 96 HOURS
688 (MICRO)G/L PROMELAS - JUVENILE
FRESH WATER (FLEDGLING,
HATCHLING, WEANLING)
2-BUTOXYETHANOL ACUTE EC50: DAPHNIA - DAPHNIA 48 HOURS
>1000 MG/L MAGNA
FRESH WATER
ACUTE LC50: CRUSTACEANS - CRANGON 48 HOURS
800000 (MICRO)G/L CRANGON
MARINE WATER
ACUTE LC50: FISH - MENIDIA 96 HOURS
1250000 (MICRO)G/L BERYLLINA
MARINE WATER
TETRASODIUM ACUTE LC50: FISH - LEPOMIS 96 HOURS
ETHYLENEDIAMINE- 486000 (MICRO)G/L MACROCHIRUS
TETRAACETATE FRESH WATER
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
2-BUTOXYETHANOL READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
| TETRASODIUM ETHYLENEDIAMINETETRAACETATE 1.8 LOW
MOBILITY IN SOIL:
SOIL/WATER PARTITION COEFFICIENT (KOC): NOT AVAILABLE.
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL
TIMES COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE
DISPOSAL LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS.
DISPOSE OF SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE
DISPOSAL CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE
SEWER UNLESS FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH
JURISDICTION. WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL
SHOULD ONLY BE CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL
AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY. EMPTY CONTAINERS OR
LINERS MAY RETAIN SOME PRODUCT RESIDUES. DO NOT PUNCTURE OR INCINERATE
CONTAINER.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER UN1950 UN1950 UN1950
UN PROPER AEROSOLS AEROSOLS AEROSOLS
SHIPPING NAME
TRANSPORT 2.1 2.1 2.1
HAZARD
CLASS(ES) FLAMMABLE GAS, CLASS 2.1, CLASS 2.1,
CLASS/DIVISION 2.1 FLAMMABLE GASES FLAMMABLE GASES
PACKING GROUP
ENVIRONMENTAL NO. NO. NO.
HAZARDS
ADDITIONAL PRODUCT CLASSIFIED
INFORMATION AS PER THE
FOLLOWING SECTIONS
OF THE
TRANSPORTATION OF
DANGEROUS GOODS
REGULATIONS:
2.13-2.17
(CLASS 2).
ERG NO.: 126 ERG NO.: 126 ERG NO.: 126
IATA IMDG
UN NUMBER UN1950 UN1950
UN PROPER SHIPPING NAME AEROSOLS, FLAMMABLE AEROSOLS
TRANSPORT HAZARD CLASS(ES) 2.1 2.1
CLASS 2.1, CLASS 2.1 - FLAMMABLE
FLAMMABLE GASES GASES
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO.
ADDITIONAL INFORMATION EMERGENCY SCHEDULES:
F-D, S-U
SPECIAL PRECAUTIONS FOR USER:
MULTI-MODAL SHIPPING DESCRIPTIONS ARE PROVIDED FOR INFORMATIONAL PURPOSES
AND DO NOT CONSIDER CONTAINER SIZES. THE PRESENCE OF A SHIPPING DESCRIPTION
FOR A PARTICULAR MODE OF TRANSPORT (SEA, AIR, ETC.), DOES NOT INDICATE THAT
THE PRODUCT IS PACKAGED SUITABLY FOR THAT MODE OF TRANSPORT. ALL PACKAGING
MUST BE REVIEWED FOR SUITABILITY PRIOR TO SHIPMENT, AND COMPLIANCE WITH
THE APPLICABLE REGULATIONS IS THE SOLE RESPONSIBILITY OF THE PERSON
OFFERING THE PRODUCT FOR TRANSPORT. PEOPLE LOADING AND UNLOADING DANGEROUS
GOODS MUST BE TRAINED ON ALL OF THE RISKS DERIVING FROM THE SUBSTANCES AND
ON ALL ACTIONS IN CASE OF EMERGENCY SITUATIONS.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL AND THE IBC CODE:
NOT AVAILABLE.
PROPER SHIPPING NAME: NOT AVAILABLE.
SHIP TYPE: NOT AVAILABLE.
POLLUTION CATEGORY: NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
SARA 313:
SARA 313 (40 CFR 372.45) SUPPLIER NOTIFICATION CAN BE FOUND ON THE
ENVIRONMENTAL DATA SHEET.
CALIFORNIA PROP. 65: NOT APPLICABLE.
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): NOT DETERMINED.
CHINA INVENTORY (IECSC): NOT DETERMINED.
JAPAN INVENTORY (ENCS): NOT DETERMINED.
JAPAN INVENTORY (ISHL): NOT DETERMINED.
KOREA INVENTORY (KECI): NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC): NOT DETERMINED.
PHILIPPINES INVENTORY (PICCS): NOT DETERMINED.
TAIWAN CHEMICAL SUBSTANCES INVENTORY (TCSI): NOT DETERMINED.
THAILAND INVENTORY: NOT DETERMINED.
TURKEY INVENTORY: NOT DETERMINED.
VIETNAM INVENTORY: NOT DETERMINED.
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 3*
FLAMMABILITY 2
PHYSICAL HAZARDS 3
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
FOR MORE INFORMATION ON HMIS(R*) PERSONAL PROTECTIVE EQUIPMENT (PPE) CODES,
CONSULT THE HMIS(R*) IMPLEMENTATION MANUAL.
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS.
ALTHOUGH HMIS(R*) RATINGS AND THE ASSOCIATED LABEL ARE NOT REQUIRED ON
SDSS OR PRODUCTS LEAVING A FACILITY UNDER 29 CFR 1910.1200, THE PREPARER
MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED WITH A FULLY
IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED TRADEMARK AND
SERVICE MARK OF THE AMERICAN COATINGS ASSOCIATION, INC.
PROCEDURE USED TO DERIVE THE CLASSIFICATION:
CLASSIFICATION JUSTIFICATION
FLAMMABLE AEROSOLS - CATEGORY 1 ON BASIS OF TEST DATA
GASES UNDER PRESSURE - COMPRESSED GAS CALCULATION METHOD
SKIN CORROSION/IRRITATION - CATEGORY 1 ON BASIS OF TEST DATA
SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1 ON BASIS OF TEST DATA
SKIN SENSITIZATION - CATEGORY 1 CALCULATION METHOD
SPECIFIC TARGET ORGAN TOXICITY CALCULATION METHOD
(REPEATED EXPOSURE) - CATEGORY 2
HISTORY:
DATE OF PRINTING: 11/28/2019
DATE OF ISSUE/DATE OF REVISION: 11/28/2019
DATE OF PREVIOUS ISSUE: 6/25/2019
VERSION: 9
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
N/A: NOT AVAILABLE
SGG: SEGREGATION GROUP
UN: UNITED NATIONS
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
IT IS RECOMMENDED THAT EACH CUSTOMER OR RECIPIENT OF THIS SAFETY DATA
SHEET (SDS) STUDY IT CAREFULLY AND CONSULT RESOURCES, AS NECESSARY OR
APPROPRIATE, TO BECOME AWARE OF AND UNDERSTAND THE DATA CONTAINED IN THIS
SDS AND ANY HAZARDS ASSOCIATED WITH THE PRODUCT. THIS INFORMATION IS
PROVIDED IN GOOD FAITH AND BELIEVED TO BE ACCURATE AS OF THE EFFECTIVE
DATE HEREIN. HOWEVER, NO WARRANTY, EXPRESS OR IMPLIED, IS GIVEN. THE
INFORMATION PRESENTED HERE APPLIES ONLY TO THE PRODUCT AS SHIPPED. THE
ADDITION OF ANY MATERIAL CAN CHANGE THE COMPOSITION, HAZARDS AND RISKS OF
THE PRODUCT. PRODUCTS SHALL NOT BE REPACKAGED, MODIFIED, OR TINTED EXCEPT
AS SPECIFICALLY INSTRUCTED BY THE MANUFACTURER, INCLUDING BUT NOT LIMITED
TO THE INCORPORATION OF PRODUCTS NOT SPECIFIED BY THE MANUFACTURER, OR
THE USE OR ADDITION OF PRODUCTS IN PROPORTIONS NOT SPECIFIED BY THE
MANUFACTURER. REGULATORY REQUIREMENTS ARE SUBJECT TO CHANGE AND MAY DIFFER
BETWEEN VARIOUS LOCATIONS AND JURISDICTIONS. THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO ENSURE THAT HIS ACTIVITIES COMPLY WITH ALL COUNTRY, FEDERAL,
STATE, PROVINCIAL OR LOCAL LAWS. THE CONDITIONS FOR USE OF THE PRODUCT ARE
NOT UNDER THE CONTROL OF THE MANUFACTURER; THE CUSTOMER/BUYER/USER IS
RESPONSIBLE TO DETERMINE THE CONDITIONS NECESSARY FOR THE SAFE USE OF THIS
PRODUCT. THE CUSTOMER/BUYER/USER SHOULD NOT USE THE PRODUCT FOR ANY PURPOSE
OTHER THAN THE PURPOSE SHOWN IN THE APPLICABLE SECTION OF THIS SDS WITHOUT
FIRST REFERRING TO THE SUPPLIER AND OBTAINING WRITTEN HANDLING
INSTRUCTIONS. DUE TO THE PROLIFERATION OF SOURCES FOR INFORMATION SUCH AS
MANUFACTURER-SPECIFIC SDS, THE MANUFACTURER CANNOT BE RESPONSIBLE FOR SDSS
OBTAINED FROM ANY OTHER SOURCE.
SHW-85-NA-GHS-US