| Common Name: | BEAD SEALER |
| Manufacturer: | PLEWS EDELMANN |
| SDS Revision Date: | 5/13/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 1EKX3 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET (SDS)
OSHA HAZCOM STANDARD 29 CFR 1910.1200(G), REV. 2012 AND GHS REV 03.
PRINTING DATE: 05/13/2015
REVIEWED ON: 05/13/2015
| 1 IDENTIFICATION |  |
|
PRODUCT IDENTIFIER: 12090TF
TRADE NAME: BEAD SEALER
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
PLEWS, INC.
1550 FRANKLIN GROVE RD.
DIXON, IL 61021
PHONE: 800-545-1689
EMERGENCY TELEPHONE NUMBER:
FOR CHEMICAL EMERGENCY SPILL, LEAK, FIRE, EXPOSURE, OR ACCIDENT
CALL CHEMTREC DAY OR NIGHT:
WITHIN USA AND CANADA: 1-800-424-9300 OR
OUTSIDE USA AND CANADA: +1 703-527-3887 (COLLECT CALLS ACCEPTED)
| 2 HAZARD(S) IDENTIFICATION | |
|
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS02: FLAME
FLAM. LIQ. 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
GHS08: HEALTH HAZARD
CARC. 2:
H351: SUSPECTED OF CAUSING CANCER.
ASP. TOX. 1:
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
GHS09: ENVIRONMENT
AQUATIC ACUTE 1:
H400: VERY TOXIC TO AQUATIC LIFE.
AQUATIC CHRONIC 1:
H410: VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
GHS07: EXCLAMATION MARK
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
STOT SE 3:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
GHS09: ENVIRONMENT
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELING: N-HEPTANE
HAZARD STATEMENTS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SKIN IRRITATION.
SUSPECTED OF CAUSING CANCER.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
VERY TOXIC TO AQUATIC LIFE.
VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
WEAR PROTECTIVE GLOVES.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
AVOID RELEASE TO THE ENVIRONMENT.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
WASH THOROUGHLY AFTER HANDLING.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
SPECIFIC TREATMENT (SEE ON THIS LABEL).
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
DO NOT INDUCE VOMITING.
IN CASE OF FIRE:
USE FOR EXTINCTION: CO2, POWDER OR WATER SPRAY.
COLLECT SPILLAGE.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
STORE LOCKED UP.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
CLASSIFICATION SYSTEM:
NFPA RATINGS (SCALE 0 - 4):
HEALTH 1
FIRE 3
REACTIVITY 0
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 1*
FIRE 3
REACTIVITY 0
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
DESCRIPTION:
MIXTURE: CONSISTING OF THE FOLLOWING COMPONENTS.
DANGEROUS COMPONENTS:
142-82-5 N-HEPTANE 80-90%
FLAM. LIQ. 2, H225; ASP. TOX. 1, H304;
AQUATIC ACUTE 1, H400; AQUATIC CHRONIC 1,
H410; SKIN IRRIT. 2, H315; STOT SE 3, H336
9006-04-6 NATURAL RUBBER LATEX 1-10%
1333-86-4 CARBON BLACK <1%
CARC. 2, H351; SKIN IRRIT. 2, H315;
EYE IRRIT. 2A, H319; STOT SE 3, H335
| 4 FIRST-AID MEASURES | |
|
DESCRIPTION OF FIRST AID MEASURES:
AFTER INHALATION:
SEEK IMMEDIATE MEDICAL ADVICE.
IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION OR GIVE OXYGEN BY TRAINED
PERSONNEL. GET IMMEDIATE MEDICAL ATTENTION.
SUPPLY FRESH AIR.
IN CASE OF UNCONSCIOUSNESS, PLACE PATIENT SECURELY ON SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
AFTER EYE CONTACT:
HOLD EYELIDS APART AND FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST
20 MINUTES.
SEEK MEDICAL TREATMENT.
AFTER SWALLOWING:
SEEK IMMEDIATE MEDICAL ADVICE.
DO NOT INDUCE VOMITING WITHOUT MEDICAL ADVICE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 5 FIRE-FIGHTING MEASURES | |
|
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, SAND, EXTINGUISHING POWDER. DO NOT USE WATER.
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: WATER WITH FULL JET
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
MAY PRODUCE INCOMPLETE COMBUSTION PRODUCTS (CO, CO2).
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND
(NIOSH APPROVED OR EQUIVALENT), AND FULL PROTECTIVE GEAR TO PREVENT
CONTACT WITH SKIN AND EYES.
| 6 ACCIDENTAL RELEASE MEASURES | |
|
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENVIRONMENTAL PRECAUTIONS:
INFORM RESPECTIVE AUTHORITIES IN CASE OF SEEPAGE INTO WATER COURSE OR
SEWAGE SYSTEM.
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
USE THE APPROPRIATE TOOLS TO COLLECT THE MATERIAL AND DISPOSE OF IT IN AN
APPROVED WASTE DIPOSAL CONTAINER.
ABSORB WITH LIQUID-BINDING MATERIAL (IE. SAND, DIATOMITE, ACID BINDERS,
UNIVERSAL BINDERS, SAWDUST).
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO SECTION 13.
ENSURE ADEQUATE VENTILATION.
DO NOT FLUSH WITH WATER OR AQUEOUS CLEANSING AGENTS
DISPOSE OF THE COLLECTED MATERIAL ACCORDING TO REGULATIONS.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
|
PRECAUTIONS FOR SAFE HANDLING:
ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE.
OPEN AND HANDLE RECEPTACLE WITH CARE.
PREVENT FORMATION OF AEROSOLS.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
PROTECT FROM HEAT.
PROTECT AGAINST ELECTROSTATIC CHARGES.
KEEP PROTECTIVE RESPIRATORY DEVICE AVAILABLE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN A COOL LOCATION.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY: NOT REQUIRED.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
KEEP RECEPTACLE TIGHTLY SEALED.
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
PROTECT FROM HEAT AND DIRECT SUNLIGHT.
SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
|
ADDITIONAL INFORMATION ABOUT DESIGN OF TECHNICAL SYSTEMS:
NO FURTHER DATA; SEE SECTION 7.
CONTROL PARAMETERS:
COMPONENTS WITH OCCUPATIONAL EXPOSURE LIMITS:
142-82-5 N-HEPTANE:
PEL:
LONG-TERM VALUE: 2000 MG/M3, 500 PPM
REL:
LONG-TERM VALUE: 350 MG/M3, 85 PPM
CEILING LIMIT VALUE: 1800* MG/M3, 440* PPM
*15-MIN
TLV:
SHORT-TERM VALUE: 2050 MG/M3, 500 PPM
LONG-TERM VALUE: 1640 MG/M3, 400 PPM
9006-04-6 NATURAL RUBBER LATEX:
TLV:
LONG-TERM VALUE: 0.0001* MG/M3
SKIN; DSEN, RSEN;* INH. FRACTION
1333-86-4 CARBON BLACK:
PEL:
LONG-TERM VALUE: 3.5 MG/M3
REL:
LONG-TERM VALUE: 3.5* MG/M3
*0.1 IN PRESENCE OF PAHS; SEE POCKET GUIDE APPS.A+C
TLV:
LONG-TERM VALUE: 3* MG/M3
*INHALABLE FRACTION
ADDITIONAL INFORMATION:
THE LISTS THAT WERE VALID DURING THE CREATION WERE USED AS BASIS.
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
STORE PROTECTIVE CLOTHING SEPARATELY.
AVOID CONTACT WITH THE SKIN.
AVOID CONTACT WITH THE EYES AND SKIN.
BREATHING EQUIPMENT: NOT REQUIRED.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE
SUBSTANCE/ THE PREPARATION.
DUE TO MISSING TESTS NO RECOMMENDATION TO THE GLOVE MATERIAL CAN BE GIVEN
FOR THE PRODUCT/ THE PREPARATION/ THE CHEMICAL MIXTURE.
SELECT GLOVE MATERIAL BASED ON PENETRATION TIMES, RATES OF DIFFUSION AND
DEGRADATION.
MATERIAL OF GLOVES:
THE SELECTION OF THE SUITABLE GLOVES DOES NOT ONLY DEPEND ON THE MATERIAL,
BUT ALSO ON FURTHER MARKS OF QUALITY AND VARIES FROM MANUFACTURER TO
MANUFACTURER. AS THE PRODUCT IS A PREPARATION OF SEVERAL SUBSTANCES, THE
RESISTANCE OF THE GLOVE MATERIAL CAN NOT BE CALCULATED IN ADVANCE AND HAS
THEREFORE TO BE CHECKED PRIOR TO THE APPLICATION.
PENETRATION TIME OF GLOVE MATERIAL:
THE EXACT BREAK-THROUGH TIME HAS TO BE DETERMINED AND OBSERVED BY THE
MANUFACTURER OF THE PROTECTIVE GLOVES.
EYE PROTECTION: TIGHTLY SEALED GOGGLES
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
|
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: PASTY
COLOR: BLACK
ODOR: GASOLINE-LIKE
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: 98 DEG. C (208 DEG. F)
FLASH POINT: -4 DEG. C (25 DEG. F)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
IGNITION TEMPERATURE: 215 DEG. C (419 DEG. F)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
AUTO IGNITING: PRODUCT IS NOT SELFIGNITING.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/VAPOR
MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: 1.1 VOL %
UPPER: 6.7 VOL %
VAPOR PRESSURE @ 20 DEG. C (68 DEG. F): 48 HPA (36 MM Hg)
DENSITY @ 20 DEG. C (68 DEG. F): 0.722 G/CM3 (6.025 LBS/GAL)
RELATIVE DENSITY: NOT DETERMINED.
VAPOUR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT DETERMINED.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
SOLVENT CONTENT:
ORGANIC SOLVENTS: 80-90 %
VOC CONTENT: 80-90 %
SOLIDS CONTENT: 1-10 %
OTHER INFORMATION NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
|
REACTIVITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
CARBON DIOXIDE AND CARBON MONOXIDE MAY FORM WHEN HEATED TO DECOMPOSITION
POSSIBILITY OF HAZARDOUS REACTIONS: NO DANGEROUS REACTIONS KNOWN.
CONDITIONS TO AVOID: NO FURTHER RELEVANT INFORMATION AVAILABLE.
INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS:
NO DANGEROUS DECOMPOSITION PRODUCTS KNOWN.
| 11 TOXICOLOGICAL INFORMATION | |
|
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
1333-86-4 CARBON BLACK:
ORAL LD50: 10000 MG/KG (RAT)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: NO IRRITATING EFFECT.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO INTERNALLY APPROVED
CALCULATION METHODS FOR PREPARATIONS:
IRRITANT
CARCINOGENIC.
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
GROUP 1 - CARCINOGENIC TO HUMANS
GROUP 2A - PROBABLY CARCINOGENIC TO HUMANS
GROUP 2B - POSSIBLY CARCINOGENIC TO HUMANS
GROUP 3 - NOT CLASSIFIABLE AS TO ITS CARCINOGENICITY TO HUMANS
GROUP 4 - PROBABLY NOT CARCINOGENIC TO HUMANS
STYROL-BUTADIEN-POLYMER 3
1333-86-4 CARBON BLACK 2B
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS ARE LISTED.
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS ARE LISTED.
| 12 ECOLOGICAL INFORMATION | |
|
TOXICITY:
AQUATIC TOXICITY:
AVOID RELEASE INTO THE ENVIRONMENT. RUNOFF FROM FIRE CONTROL OR DILUTION
WATER MAY CAUSE POLLUTION.
PERSISTENCE AND DEGRADABILITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ECOTOXICAL EFFECTS:
REMARK: VERY TOXIC FOR FISH
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER COURSE OR SEWAGE SYSTEM.
DANGER TO DRINKING WATER IF EVEN SMALL QUANTITIES LEAK INTO THE GROUND.
ALSO POISONOUS FOR FISH AND PLANKTON IN WATER BODIES.
VERY TOXIC FOR AQUATIC ORGANISMS
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
|
WASTE TREATMENT METHODS:
RECOMMENDATION:
OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS WHEN
DISPOSING OF THIS MATERIAL.
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
|
UN-NUMBER:
DOT, ADR, IMDG, IATA: UN2278
UN PROPER SHIPPING NAME:
DOT: N-HEPTENE
ADR: UN2278 N-HEPTENE , MIXTURE , ENVIRONMENTALLY HAZARDOUS
IMDG: N- HEPTENE, MIXTURE, MARINE POLLUTANT
IATA: N- HEPTENE, MIXTURE
TRANSPORT HAZARD CLASS(ES):
DOT: FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
CLASS: 3 FLAMMABLE LIQUIDS
LABEL: 3
ADR:
CLASS 3, FLAMMABLE LIQUIDS
ENVIRONMENT
CLASS: 3 (F1) FLAMMABLE LIQUIDS
LABEL: 3
IMDG:
CLASS 3 - FLAMMABLE LIQUIDS
ENVIRONMENT
CLASS: 3 FLAMMABLE LIQUIDS
LABEL: 3
IATA: CLASS 3, FLAMMABLE LIQUIDS
CLASS: 3 FLAMMABLE LIQUIDS
LABEL: 3
PACKING GROUP:
DOT, ADR, IMDG, IATA: II
ENVIRONMENTAL HAZARDS:
PRODUCT CONTAINS ENVIRONMENTALLY HAZARDOUS SUBSTANCES: N-HEPTANE
MARINE POLLUTANT:
YES
SYMBOL (FISH AND TREE)
SPECIAL MARKING (ADR): SYMBOL (FISH AND TREE)
SPECIAL PRECAUTIONS FOR USER:
WARNING: FLAMMABLE LIQUIDS
DANGER CODE (KEMLER): 33
EMS NUMBER: F-E,S-D
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
DOT:
QUANTITY LIMITATIONS:
ON PASSENGER AIRCRAFT/RAIL: 5 L
ON CARGO AIRCRAFT ONLY: 60 L
REMARKS:
ERG NUMBER: 128
ADR:
EXCEPTED QUANTITIES (EQ):
CODE: E2
MAXIMUM NET QUANTITY PER INNER PACKAGING: 30 ML
MAXIMUM NET QUANTITY PER OUTER PACKAGING: 500 ML
IMDG:
LIMITED QUANTITIES (LQ): 1L
EXCEPTED QUANTITIES (EQ):
CODE: E2
MAXIMUM NET QUANTITY PER INNER PACKAGING: 30 ML
MAXIMUM NET QUANTITY PER OUTER PACKAGING: 500 ML
UN "MODEL REGULATION":
UN2278 , N-HEPTENE , MIXTURE , ENVIRONMENTALLY HAZARDOUS, 3, II
| 15 REGULATORY INFORMATION | |
|
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA:
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
NONE OF THE INGREDIENTS ARE LISTED.
TSCA (TOXIC SUBSTANCES CONTROL ACT):
142-82-5 N-HEPTANE
STYROL-BUTADIEN-POLYMER
1333-86-4 CARBON BLACK
PROPOSITION 65:
CHEMICALS KNOWN TO CAUSE CANCER:
1333-86-4 CARBON BLACK
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE REPRODUCTIVE TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
NONE OF THE INGREDIENTS ARE LISTED.
CARCINOGENIC CATEGORIES:
EPA (ENVIRONMENTAL PROTECTION AGENCY):
142-82-5 N-HEPTANE D
TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH):
1333-86-4 CARBON BLACK A4
NIOSH-CA (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
1333-86-4 CARBON BLACK
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
GHS09: ENVIRONMENT
SIGNAL WORD: DANGER
HAZARD-DETERMINING COMPONENTS OF LABELING: N-HEPTANE
HAZARD STATEMENTS
HIGHLY FLAMMABLE LIQUID AND VAPOR.
CAUSES SKIN IRRITATION.
SUSPECTED OF CAUSING CANCER.
MAY CAUSE DROWSINESS OR DIZZINESS.
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
VERY TOXIC TO AQUATIC LIFE.
VERY TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
WEAR PROTECTIVE GLOVES.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
AVOID RELEASE TO THE ENVIRONMENT.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
WASH THOROUGHLY AFTER HANDLING.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
SPECIFIC TREATMENT (SEE ON THIS LABEL).
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
DO NOT INDUCE VOMITING.
IN CASE OF FIRE:
USE FOR EXTINCTION: CO2, POWDER OR WATER SPRAY.
COLLECT SPILLAGE.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
STORE LOCKED UP.
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
NATIONAL REGULATIONS:
THE PRODUCT IS SUBJECT TO BE LABELED ACCORDING WITH THE PREVAILING VERSION
OF THE REGULATIONS ON HAZARDOUS SUBSTANCES.
STATE RIGHT TO KNOW:
142-82-5 N-HEPTANE
FLAM. LIQ. 2, H225; ASP. TOX. 1, H304; AQUATIC ACUTE 1,
H400; AQUATIC CHRONIC 1, H410; SKIN IRRIT. 2, H315; STOT
SE 3, H336
STYROL-BUTADIEN-POLYMER
9006-04-6 NATURAL RUBBER LATEX
1333-86-4 CARBON BLACK
CARC. 2, H351; SKIN IRRIT. 2, H315; EYE IRRIT. 2A,
H319; STOT SE 3, H335
ALL INGREDIENTS ARE LISTED.
INFORMATION ABOUT LIMITATION OF USE:
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
THE INFORMATION AND RECOMMENDATIONS IN THIS SAFETY DATA SHEET ARE, TO
THE BEST OF OUR KNOWLEDGE, ACCURATE AS OF THE DATE OF ISSUE. NOTHING
HEREIN SHALL BE DEEMED TO CREATE WARRANTY, EXPRESSED OR IMPLIED AND
SHALL NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP. IT IS
THE RESPONSIBILITY OF THE USER TO DETERMINE APPLICABILITY OF THIS
INFORMATION AND THE SUITABILITY OF THE MATERIAL OR PRODUCT FOR ANY
PARTICULAR PURPOSE.
DATE OF PREPARATION / LAST REVISION: 05/13/2015 / 1
ABBREVIATIONS AND ACRONYMS:
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
ADN:
THE EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY INLAND WATERWAYS
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
VOC: VOLATILE ORGANIC COMPOUNDS (USA, EU)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
FLAM. LIQ. 2: FLAMMABLE LIQUIDS, HAZARD CATEGORY 2
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2A
CARC. 2: CARCINOGENICITY, HAZARD CATEGORY 2
STOT SE 3:
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE, HAZARD CATEGORY 3
ASP. TOX. 1: ASPIRATION HAZARD, HAZARD CATEGORY 1
AQUATIC ACUTE 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - ACUTEHAZARD, CATEGORY 1
AQUATIC CHRONIC 1:
HAZARDOUS TO THE AQUATIC ENVIRONMENT - CHRONIC HAZARD, CATEGORY 1
| DATA COMPARED TO THE PREVIOUS VERSION ALTERED.
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