| Common Name: | R-Y1 ROLMARK YELLOW STENCIL INK |
| Manufacturer: | MARSH SHIPPING SUPPLY |
| SDS Revision Date: | 10/7/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 1F153 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ACC. TO OSHA HCS
PRINTING DATE: 10/07/2015
REVIEWED ON: 10/07/2015
| 1 IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: R-Y1 ROLMARK YELLOW STENCIL INK
ARTICLE NUMBER:
PRODUCT CODES: 20900, 20926, 1F153, 33567
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NO FURTHER RELEVANT INFORMATION AVAILABLE.
APPLICATION OF THE SUBSTANCE / THE MIXTURE: PRINTING INKS
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
MARSH SHIPPING SUPPLY CO., LLC
926 MCDONOUGH LAKE ROAD - UNIT E
COLLINSVILLE, IL 62234
USA
INFORMATION DEPARTMENT: CUSTOMERSERVICE@MSSCLLC.COM
EMERGENCY TELEPHONE NUMBER:
INFOTRAC: 1-800-535-5053
INTERNATIONAL: 352-323-3500 (CALL COLLECT)
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS02: FLAME
FLAM. LIQ. 3:
H226: FLAMMABLE LIQUID AND VAPOUR.
GHS08: HEALTH HAZARD
CARC. 2:
H351: SUSPECTED OF CAUSING CANCER.
GHS07: EXCLAMATION MARK
EYE IRRIT. 2A:
H319: CAUSES SERIOUS EYE IRRITATION.
ADDITIONAL INFORMATION:
THE PIGMENT TITANIUM DIOXIDE CAS# 13463-67-7 IS SUSPECTED OF CAUSING CANCER
WHEN INHALED AS A DUST FORM. THIS PIGMENT IS BOUND IN THE INK, AND UNDER
NORMAL CONDITIONS OF USE THE EXPOSURE TO THE DUST FORM IS NOT LIKELY.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS: GHS02, GHS07, GHS08
SIGNAL WORD: WARNING
HAZARD-DETERMINING COMPONENTS OF LABELING: TITANIUM DIOXIDE
HAZARD STATEMENTS:
FLAMMABLE LIQUID AND VAPOUR.
CAUSES SERIOUS EYE IRRITATION.
SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
WEAR EYE PROTECTION / FACE PROTECTION.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
KEEP CONTAINER TIGHTLY CLOSED.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
WASH THOROUGHLY AFTER HANDLING.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE:
USE FOR EXTINCTION: CO2, POWDER OR WATER SPRAY.
STORE LOCKED UP.
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
INFORMATION PERTAINING TO PARTICULAR DANGERS FOR MAN AND ENVIRONMENT:
POTENTIAL CHRONIC HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE OF VAPORS, SPRAY, OR MATERIAL MAY CAUSE
DISEASES OF THE LUNGS. REPORTS HAVE ASSOCIATED REPEATED OVEREXPOSURE TO
SOLVENTS WITH BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE OF THIS
PRODUCT MAY BE HARMFUL OR FATAL.
TARGET ORGANS:
OVEREXPOSURE TO THIS MATERIAL OR ITS COMPONENTS HAS BEEN SUGGESTED AS A
CAUSE OF THE FOLLOWING EFFECTS IN LABORATORY ANIMALS AND/OR HUMANS, AND
MAY AGGRAVATE PREEXISTING DISORDERS OF THESE ORGANS IN HUMANS:
ANEMIA, BLOOD DISORDERS, BRAIN DAMAGE, CARDIAC FUNCTION, EYE, LIVER, LUNG,
MENSTRUAL AND FERTILITY, SKIN, RESPIRATORY, CENTRAL NERVOUS SYSTEM
CLASSIFICATION SYSTEM:
NFPA RATINGS (SCALE 0 - 4):
HEALTH 1
FIRE 2
REACTIVITY 0
HMIS-RATINGS (SCALE 0 - 4):
HEALTH 1
FIRE 2
REACTIVITY 0
OTHER HAZARDS:
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
DESCRIPTION:
MIXTURE OF THE SUBSTANCES LISTED BELOW WITH NONHAZARDOUS ADDITIONS.
HAZARDOUS COMPONENTS:
123-42-2 4-HYDROXY-4-METHYLPENTAN-2-ONE 65.74%
FLAM. LIQ. 3, H226; EYE IRRIT. 2, H319
5468-75-7 YELLOW AAOT PIGMENT 14 11.0%
MODIFIED ROSIN ESTER NJ TSRN 80100080-509 7P 3.97%
EINECS POLYMER EXEMPT - ALL COMPONENTS LISTED
112945-52-5 AMORPHOUS FUMED SILICA, SILICON DIOXIDE, 0.22%
CRYSTALLINE FREE
13463-67-7 TITANIUM DIOXIDE 16.488%
CARC. 2, H351
7631-86-9 SILICON DIOXIDE, CHEMICALLY PREPARED 1.099%
ACRYLIC COPOLYMER - EU POLYMER EXEMPTED - 0.66%
NOT REGULATED
6448-95-9 NAPHTHANIL RED PIGMENT C.I. 22 0.09%
ADDITIONAL INFORMATION:
THIS PRODUCT CONTAINS PIGMENTS WHICH MAY BECOME A DUST NUISANCE WHEN
REMOVED BY ABRASIVE BLASTING OR SANDING. AIRBORNE NUISANCE PARTICULATES
HAVE AN ACGIH TLV FOR TOTAL DUST OF 10 MG/M3
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
GENERAL INFORMATION:
TAKE AFFECTED PERSONS OUT INTO THE FRESH AIR.
INVOLVE DOCTOR IMMEDIATELY.
AFTER INHALATION: SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
AFTER SKIN CONTACT:
IMMEDIATELY RINSE WITH WATER FOR 15 MINUTES. IF IRRITATION EXISTS CALL
PHYSICIAN.
AFTER EYE CONTACT:
RINSE OPENED EYE FOR FIFTEEN MINUTES UNDER RUNNING WATER. IF IRRITATION
PERSISTS, CONSULT A DOCTOR.
AFTER SWALLOWING:
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
BREATHING DIFFICULTY
HEADACHE
DIZZINESS
THIRST
CRAMP
GASTRIC OR INTESTINAL DISORDERS
COUGHING
ALLERGIC REACTIONS
NAUSEA
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
CO2, EXTINGUISHING POWDER OR WATER SPRAY. FIGHT LARGER FIRES WITH WATER
SPRAY OR ALCOHOL RESISTANT FOAM.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NITROGEN OXIDES (NOX)
CARBON MONOXIDE (CO)
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION:
DISPOSE OF FIRE DEBRIS AND CONTAMINATED FIRE FIGHTING WATER IN ACCORDANCE
WITH OFFICIAL REGULATIONS. COLLECT CONTAMINATED FIRE FIGHTING WATER
SEPARATELY. IT MUST NOT ENTER THE SEWAGE SYSTEM.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION
WEAR PROTECTIVE CLOTHING.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO REACH SEWAGE SYSTEM OR ANY WATER COURSE.
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
PREVENT FROM SPREADING (E.G. BY DAMMING-IN OR OIL BARRIERS).
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ABSORB WITH LIQUID-BINDING MATERIAL (SAND, DIATOMITE, ACID BINDERS,
UNIVERSAL BINDERS, SAWDUST).
DISPOSE CONTAMINATED MATERIAL AS WASTE ACCORDING TO ITEM 13.
ENSURE ADEQUATE VENTILATION.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
STORE IN COOL, DRY PLACE IN TIGHTLY CLOSED RECEPTACLES.
KEEP AWAY FROM HEAT AND DIRECT SUNLIGHT.
ENSURE GOOD VENTILATION/EXHAUSTION AT THE WORKPLACE.
PREVENT FORMATION OF AEROSOLS.
HANDLE WITH CARE. AVOID JOLTING, FRICTION AND IMPACT.
HYDROCARBON SOLVENTS ARE BASICALLY NON-CONDUCTORS OF ELECTRICITY AND CAN
BECOME ELECTROSTATICALLY CHARGED DURING MIXING OR MOVING, OBSERVE
GROUNDING/GROUNDING OF CONTAINERS AND OTHER EQUIPMENT WHEN HANDLING.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
NO SPECIAL MEASURES REQUIRED.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE ONLY IN THE ORIGINAL RECEPTACLE.
PREVENT ANY SEEPAGE INTO THE GROUND.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
DO NOT STORE TOGETHER WITH OXIDIZING AND ACIDIC MATERIALS AS WELL AS
HEAVY-METAL COMPOUNDS.
STORE AWAY FROM FOODSTUFFS.
FURTHER INFORMATION ABOUT STORAGE CONDITIONS:
KEEP RECEPTACLE TIGHTLY SEALED.
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
PROTECT FROM HUMIDITY AND WATER.
PROTECT FROM EXPOSURE TO THE LIGHT.
SPECIFIC END USE(S): NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
123-42-2 4-HYDROXY-4-METHYLPENTAN-2-ONE:
PEL:
LONG-TERM VALUE: 240 MG/M3, 50 PPM
REL:
LONG-TERM VALUE: 240 MG/M3, 50 PPM
TLV:
LONG-TERM VALUE: 238 MG/M3, 50 PPM
5468-75-7 YELLOW AA OT PIGMENT 14:
TLV:
SHORT-TERM VALUE: 10 AS NUISANCE MG/M3
MODIFIED ROSIN ESTER NJ TSRN 80100080-5097P:
EINECS POLYMER EXEMPT - ALL COMPONENTS LISTED
PEL:
LONG-TERM VALUE: 5*15** MG/M3, 15*50** PPM
*RESPIRABLE FRACTION
**TOTAL DUST
112945-52-5 AMORPHOUS FUMED SILICA, SILICON DIOXIDE, CRYSTALLINE FREE:
TLV:
LONG-TERM VALUE: 3.5 MG/M3
ADDITIONAL INFORMATION:
THE LISTS THAT WERE VALID DURING THE CREATION WERE USED AS BASIS.
EXPOSURE CONTROLS:
PERSONAL PROTECTIVE EQUIPMENT:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES FOR HANDLING CHEMICALS SHOULD BE FOLLOWED.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE EYES AND SKIN.
PREGNANT WOMEN SHOULD STRICTLY AVOID INHALATION OR SKIN CONTACT.
DO NOT EAT, DRINK, SMOKE OR SNIFF WHILE WORKING.
BREATHING EQUIPMENT:
USE SUITABLE RESPIRATORY PROTECTIVE DEVICE IN CASE OF INSUFFICIENT
VENTILATION.
DO NOT BREATH VAPORS, SPRAY MISTS, OR SANDING DUSTS. USE AIR PURIFYING
RESPIRATORS FITTED WITH ORGANIC VAPOR/HEPA CARTRIDGES ONLY IF AIR
MONITORING DEMONSTRATES SOLVENT/PARTICULATE LEVELS DO NOT EXCEED THE
RESPIRATOR MAXIMUM USE CONCENTRATION. USE PROPERLY FITTED NIOSH APPROVED
RESPIRATORS. LOCAL AND GENERAL EXHAUST SHOULD MINIMIZE ANY EXPOSURE.
PROTECTION OF HANDS: PROTECTIVE GLOVES
MATERIAL OF GLOVES:
NITRILE OR NATURAL RUBBER GLOVES ARE TYPICALLY USED TO PROTECT FROM MINOR
CONTACT. BUTYL TYPE ARE BEST FOR PROLONGED CONTACT.
NITRILE RUBBER, NBR
EYE PROTECTION: VAPOR PROOF SAFETY GOGGLES OR FULL FACE RESPIRATOR
BODY PROTECTION:
SOLVENT RESISTANT PROTECTIVE CLOTHING
IMPERVIOUS PROTECTIVE CLOTHING
TYVEK(R) COVERALLS TO PROTECT FROM LIGHT OVERSPRAY PROTECTION OR SARANEX
23-P(R) FOR MODERATE EXPOSURE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL INFORMATION:
APPEARANCE:
FORM: FLUID
COLOR: YELLOW
ODOR: ALCOHOL-LIKE
ODOUR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
CHANGE IN CONDITION:
MELTING POINT/MELTING RANGE: UNDETERMINED.
BOILING POINT/BOILING RANGE: 150 DEG. C (302 DEG. F)
FLASH POINT: 58 DEG. C (136 DEG. F)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
IGNITION TEMPERATURE: 620 DEG. C (1148 DEG. F)
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
AUTO IGNITING: PRODUCT IS NOT SELFIGNITING.
DANGER OF EXPLOSION: NOT DETERMINED.
EXPLOSION LIMITS:
LOWER: 1.4 VOL %
UPPER: 8.1 VOL %
VAPOR PRESSURE AT 20 DEG. C (68 DEG. F): 1.1 HPA (1 MMHg)
DENSITY AT 20 DEG. C (68 DEG. F): 1.13614 G/CM3 (9.481 LBS/GAL)
RELATIVE DENSITY: NOT DETERMINED.
VAPOUR DENSITY: NOT DETERMINED.
EVAPORATION RATE: NOT DETERMINED.
SOLUBILITY IN / MISCIBILITY WITH WATER: NOT MISCIBLE OR DIFFICULT TO MIX.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC: NOT DETERMINED.
SOLVENT CONTENT:
ORGANIC SOLVENTS: 65.7%
VOC CONTENT:
65.7%
746.9 G/L / 6.23 LB/GL
SOLIDS CONTENT: 34.3%
OTHER INFORMATION: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY:
CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED ACCORDING TO SPECIFICATIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
REACTS WITH ACIDS, ALKALIS AND OXIDIZING AGENTS.
CONDITIONS TO AVOID: NO FURTHER RELEVANT INFORMATION AVAILABLE.
INCOMPATIBLE MATERIALS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
HAZARDOUS DECOMPOSITION PRODUCTS:
NITROGEN OXIDES
CARBON MONOXIDE AND CARBON DIOXIDE
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
123-42-2 4-HYDROXY-4-METHYLPENTAN-2-ONE:
ORAL:
LD50: 4000 MG/KG (RAT)
DERMAL:
LD50: 13630 MG/KG (RAB)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE: IRRITATING EFFECT.
SENSITIZATION:
SENSITIZING EFFECT THROUGH INHALATION IS POSSIBLE WITH PROLONGED EXPOSURE.
SENSITIZING EFFECT BY SKIN CONTACT IS POSSIBLE WITH PROLONGED EXPOSURE.
ADDITIONAL TOXICOLOGICAL INFORMATION:
THE PRODUCT SHOWS THE FOLLOWING DANGERS ACCORDING TO INTERNALLY APPROVED
CALCULATION METHODS FOR PREPARATIONS:
IRRITANT
DANGER THROUGH SKIN ABSORPTION.
CARCINOGENIC CATEGORIES:
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
13463-67-7 TITANIUM DIOXIDE 2B 16.488%
7631-86-9 SILICON DIOXIDE, CHEMICALLY PREPARED 3 1.099%
NTP (NATIONAL TOXICOLOGY PROGRAM): NONE OF THE INGREDIENTS IS LISTED.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO FURTHER RELEVANT INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO FURTHER RELEVANT INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
GENERAL NOTES:
WATER HAZARD CLASS 1 (SELF-ASSESSMENT): SLIGHTLY HAZARDOUS FOR WATER
THIS STATEMENT WAS DEDUCED FROM THE PROPERTIES OF THE SINGLE COMPONENTS.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO FURTHER RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
MUST NOT BE DISPOSED OF TOGETHER WITH HOUSEHOLD GARBAGE. DO NOT ALLOW
PRODUCT TO REACH SEWAGE SYSTEM.
HAND OVER TO HAZARDOUS WASTE DISPOSERS.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER:
DOT, ADR, IMDG, IATA: UN1210
UN PROPER SHIPPING NAME:
DOT: PRINTING INK
ADR: 1210 PRINTING INK
IMDG, IATA: PRINTING INK
TRANSPORT HAZARD CLASS(ES):
DOT: FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
CLASS: 3 FLAMMABLE LIQUIDS
LABEL: 3
ADR, IMDG, IATA: CLASS 3, FLAMMABLE LIQUIDS
CLASS: 3 FLAMMABLE LIQUIDS
LABEL: 3
PACKING GROUP:
DOT, ADR, IMDG, IATA: III
ENVIRONMENTAL HAZARDS:
MARINE POLLUTANT: NO
SPECIAL PRECAUTIONS FOR USER:
WARNING: FLAMMABLE LIQUIDS
DANGER CODE (KEMLER): 30
EMS NUMBER: F-E, S-D
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
ADR:
EXCEPTED QUANTITIES (EQ) CODE: E1
MAXIMUM NET QUANTITY PER INNER PACKAGING: 30 ML
MAXIMUM NET QUANTITY PER OUTER PACKAGING: 1000 ML
IMDG:
LIMITED QUANTITIES (LQ): 5L
EXCEPTED QUANTITIES (EQ):
CODE: E1
MAXIMUM NET QUANTITY PER INNER PACKAGING: 30 ML
MAXIMUM NET QUANTITY PER OUTER PACKAGING: 1000 ML
UN "MODEL REGULATION": UN1210, PRINTING INK, 3, III
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
SARA:
SARA TITLE III SECTION 311/312 - HAZARD COMMUNICATION STANDARD (40 CFR
370):
13463-67-7 TITANIUM DIOXIDE 16.488%
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED OR EXEMPT.
123-42-2 4-HYDROXY-4-METHYLPENTAN-2-ONE
13463-67-7 TITANIUM DIOXIDE
5468-75-7 YELLOW AAOT PIGMENT 14
MODIFIED ROSIN ESTER NJ TSRN 80100080-5097P
EINECS POLYMER EXEMPT - ALL COMPONENTS LISTED
7631-86-9 SILICON DIOXIDE, CHEMICALLY PREPARED
21645-51-2 ALUMINIUM HYDROXIDE
ACRYLIC COPOLYMER - EU POLYMER EXEMPTED -
NOT REGULATED
112945-52-5 AMORPHOUS FUMED SILICA, SILICON DIOXIDE,
CRYSTALLINE FREE
6448-95-9 NAPHTHANIL RED PIGMENT C.I. 22
PROPOSITION 65/CHEMICALS KNOWN TO CAUSE CANCER:
13463-67-7 TITANIUM DIOXIDE 16.488%
ACGIH CARCINOGEN:
13463-67-7 TITANIUM DIOXIDE A4 16.488%
CANCEROGENITY CATEGORIES:
TLV (THRESHOLD LIMIT VALUE ESTABLISHED BY ACGIH):
13463-67-7 TITANIUM DIOXIDE A4 16.488%
NIOSH (NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH):
123-42-2 4-HYDROXY-4-METHYLPENTAN- GUIDELINES 89-104 65.74%
2-ONE
13463-67-7 TITANIUM DIOXIDE * 16.488%
STATE REGULATIONS:
NEW JERSEY RIGHT-TO-KNOW:
MODIFIED ROSIN ESTER NJ TSRN TSRN 80100080-5097P 3.97%
80100080-5097P
EINECS POLYMER EXEMPT - ALL COMPONENTS LISTED
MASSACHUSSETTS RIGHT-TO-KNOW / HAZARDOUS SUBSTANCE CODES:
123-42-2 4-HYDROXY-4-METHYLPENTAN- 2, 4 65.74%
2-ONE
13463-67-7 TITANIUM DIOXIDE 4 16.488%
7631-86-9 SILICON DIOXIDE, CHEMICALLY 2, 4, 5 F5 1.099%
PREPARED
FLORIDA HAZARDOUS / TOXIC SUBSTANCE LISTS:
123-42-2 4-HYDROXY-4-METHYLPENTAN-2-ONE TOXIC 65.74%
7631-86-9 SILICON DIOXIDE, CHEMICALLY TOXIC 1.099%
PREPARED
PENNSYLVANIA HAZARDOUS SUBSTANCES:
123-42-2 4-HYDROXY-4-METHYLPENTAN-2-ONE 65.74%
13463-67-7 TITANIUM DIOXIDE LISTED 16.488%
7631-86-9 SILICON DIOXIDE, CHEMICALLY LISTED 1.099%
PREPARED
MINNESOTA RIGHT TO KNOW / HAZARDOUS SUBSTANCES:
123-42-2 4-HYDROXY-4-METHYLPENTAN-2-ONE ANO 65.74%
13463-67-7 TITANIUM DIOXIDE A 16.488%
7631-86-9 SILICON DIOXIDE, CHEMICALLY CODES ANOR, 1.099%
PREPARED CARCINOGEN
ILLINOIS RIGHT TO KNOW: NONE OF THE INGREDIENTS IS LISTED.
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS: GHS02, GHS07, GHS08
SIGNAL WORD: WARNING
HAZARD-DETERMINING COMPONENTS OF LABELING: TITANIUM DIOXIDE
HAZARD STATEMENTS:
FLAMMABLE LIQUID AND VAPOUR.
CAUSES SERIOUS EYE IRRITATION.
SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
WEAR PROTECTIVE GLOVES / EYE PROTECTION / FACE PROTECTION.
WEAR EYE PROTECTION / FACE PROTECTION.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
KEEP CONTAINER TIGHTLY CLOSED.
USE ONLY NON-SPARKING TOOLS.
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
WASH THOROUGHLY AFTER HANDLING.
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
IF ON SKIN (OR HAIR):
REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
IN CASE OF FIRE:
USE FOR EXTINCTION: CO2, POWDER OR WATER SPRAY.
STORE LOCKED UP.
STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH LOCAL/REGIONAL/NATIONAL/
INTERNATIONAL REGULATIONS.
NATIONAL REGULATIONS:
OCCUPATIONAL SAFETY AND HEALTH ACT (OSHA):
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
WATER HAZARD CLASS:
WATER HAZARD CLASS 1 (SELF-ASSESSMENT): SLIGHTLY HAZARDOUS FOR WATER.
CHEMICAL SAFETY ASSESSMENT:
A CHEMICAL SAFETY ASSESSMENT HAS NOT BEEN CARRIED OUT.
| 16 OTHER INFORMATION | |
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE NAMED SUPPLIER NOR ANY OF ITS SUBSIDIARIES
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN. FINAL DETERMINATION OF SUITABILITY OF ANY
MATERIAL IS THE SOLE RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS
ARE DESCRIBED HEREIN, WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS
THAT EXIST.
RELEVANT PHRASES:
H226: FLAMMABLE LIQUID AND VAPOUR.
H319: CAUSES SERIOUS EYE IRRITATION.
H351: SUSPECTED OF CAUSING CANCER.
CONTACT: COMPLIANCE DEPARTMENT
DATE OF PREPARATION / LAST REVISION: 10/07/2015 / -
ABBREVIATIONS AND ACRONYMS:
RID:
REGLEMENT INTERNATIONAL CONCERNANT LE TRANSPORT DES MARCHANDISES
DANGEREUSES PAR CHEMIN DE FER (REGULATIONS CONCERNING THE INTERNATIONAL
TRANSPORT OF DANGEROUS GOODS BY RAIL)
ICAO: INTERNATIONAL CIVIL AVIATION ORGANISATION
ADR:
ACCORD EUROPEEN SUR LE TRANSPORT DES MARCHANDISES DANGEREUSES PAR ROUTE
(EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD)
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
EINECS: EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
ELINCS: EUROPEAN LIST OF NOTIFIED CHEMICAL SUBSTANCES
CAS: CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION (USA)
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM (USA)
VOC: VOLATILE ORGANIC COMPOUNDS (USA, EU)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
FLAM. LIQ. 3: FLAMMABLE LIQUIDS, HAZARD CATEGORY 3
EYE IRRIT. 2: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION, HAZARD CATEGORY 2A
CARC. 2: CARCINOGENICITY, HAZARD CATEGORY 2
USA