| Common Name: | GREENCHOICE SUBFLOOR ADHESIVE, 4122 |
| Manufacturer: | FRANKLIN INTERNATIONAL |
| SDS Revision Date: | 6/2/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 1FCB7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
FRANKLIN INTERNATIONAL
SAFETY DATA SHEET
GREENCHOICE SUBFLOOR ADHESIVE
| SECTION 1. IDENTIFICATION |  |
GHS PRODUCT IDENTIFIER: GREENCHOICE SUBFLOOR ADHESIVE
PRODUCT TYPE: LIQUID.
CAS #: MIXTURE
ADDRESS:
FRANKLIN INTERNATIONAL
2020 BRUCK STREET
COLUMBUS OH 43207
CONTACT PERSON: FRANKLIN TECHNICAL SERVICES
TELEPHONE: (800) 877-4583
IN CASE OF EMERGENCY:
FRANKLIN SECURITY: (614) 445-1300
REFERENCE NUMBER: 3635
PRODUCT CODE: 4122
DATE OF REVISION: 6/2/2015.
PRINT DATE: 6/3/2015.
CHEMTREC (24 HOUR): (800) 424-9300
CHEMTREC INTERNATIONAL: (703) 527-3887
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST: NOT APPLICABLE.
| SECTION 2. HAZARDS IDENTIFICATION | |
OSHA/HCS STATUS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) (KIDNEYS) (ORAL):
CATEGORY 2
GHS LABEL ELEMENTS:
HAZARD PICTOGRAMS: HEALTH HAZARD
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
MAY CAUSE DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE IF
SWALLOWED. (KIDNEYS)
PRECAUTIONARY STATEMENTS:
GENERAL:
READ LABEL BEFORE USE. KEEP OUT OF REACH OF CHILDREN. IF MEDICAL ADVICE IS
NEEDED, HAVE PRODUCT CONTAINER OR LABEL AT HAND.
PREVENTION: DO NOT BREATHE VAPOR.
RESPONSE: GET MEDICAL ATTENTION IF YOU FEEL UNWELL.
DISPOSAL:
DISPOSE OF CONTENTS AND CONTAINER IN ACCORDANCE WITH ALL LOCAL, REGIONAL,
NATIONAL AND INTERNATIONAL REGULATIONS.
HAZARDS NOT OTHERWISE CLASSIFIED: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS INGREDIENTS:
UNITED STATES:
NAME CAS NUMBER %
GLYCEROL 56-81-5 1 - 5
ETHANEDIOL 107-21-1 1 - 5
CANADA:
NAME CAS NUMBER %
OXYDIPROPYL DIBENZOATE 27138-31-4 5 - 10
GLYCEROL 56-81-5 1 - 5
ETHANEDIOL 107-21-1 1 - 5
MEXICO:
NAME CAS NUMBER UN NUMBER % IDLH CLASSIFICATION
H F R SPECIAL
GLYCEROL 56-81-5 NOT 1 - 5 1 1 0
AVAILABLE.
ETHANEDIOL 107-21-1 NOT 1 - 5 2 1 0
AVAILABLE.
OXYDIPROPYL 27138-31-4 NOT 5 - 10 2 0 0
DIBENZOATE AVAILABLE.
ANY CONCENTRATION SHOWN AS A RANGE IS TO PROTECT CONFIDENTIALITY OR IS DUE
TO BATCH VARIATION.
THERE ARE NO ADDITIONAL INGREDIENTS PRESENT WHICH, WITHIN THE CURRENT
KNOWLEDGE OF THE SUPPLIER AND IN THE CONCENTRATIONS APPLICABLE, ARE
CLASSIFIED AS HAZARDOUS TO HEALTH OR THE ENVIRONMENT AND HENCE REQUIRE
REPORTING IN THIS SECTION.
OCCUPATIONAL EXPOSURE LIMITS, IF AVAILABLE, ARE LISTED IN SECTION 8.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF NECESSARY FIRST AID MEASURES:
EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER, OCCASIONALLY LIFTING THE UPPER
AND LOWER EYELIDS. CHECK FOR AND REMOVE ANY CONTACT LENSES. CONTINUE TO
RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION FOLLOWING EXPOSURE OR
IF FEELING UNWELL.
INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. IF NOT BREATHING, IF BREATHING IS IRREGULAR OR IF RESPIRATORY
ARREST OCCURS, PROVIDE ARTIFICIAL RESPIRATION OR OXYGEN BY TRAINED
PERSONNEL. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION. GET MEDICAL ATTENTION FOLLOWING EXPOSURE
OR IF FEELING UNWELL. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
SKIN CONTACT:
FLUSH CONTAMINATED SKIN WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING
AND SHOES. CONTINUE TO RINSE FOR AT LEAST 10 MINUTES. GET MEDICAL ATTENTION
FOLLOWING EXPOSURE OR IF FEELING UNWELL. WASH CLOTHING BEFORE REUSE. CLEAN
SHOES THOROUGHLY BEFORE REUSE.
INGESTION:
WASH OUT MOUTH WITH WATER. REMOVE DENTURES IF ANY. REMOVE VICTIM TO FRESH
AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR BREATHING. IF MATERIAL
HAS BEEN SWALLOWED AND THE EXPOSED PERSON IS CONSCIOUS, GIVE SMALL
QUANTITIES OF WATER TO DRINK. STOP IF THE EXPOSED PERSON FEELS SICK AS
VOMITING MAY BE DANGEROUS. DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO
BY MEDICAL PERSONNEL. IF VOMITING OCCURS, THE HEAD SHOULD BE KEPT LOW SO
THAT VOMIT DOES NOT ENTER THE LUNGS. GET MEDICAL ATTENTION FOLLOWING
EXPOSURE OR IF FEELING UNWELL. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. IF UNCONSCIOUS, PLACE IN RECOVERY POSITION AND GET
MEDICAL ATTENTION IMMEDIATELY. MAINTAIN AN OPEN AIRWAY. LOOSEN TIGHT
CLOTHING SUCH AS A COLLAR, TIE, BELT OR WAISTBAND.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
OVER-EXPOSURE SIGNS/SYMPTOMS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED, IF
NECESSARY:
NOTES TO PHYSICIAN:
TREAT SYMPTOMATICALLY. CONTACT POISON TREATMENT SPECIALIST IMMEDIATELY IF
LARGE QUANTITIES HAVE BEEN INGESTED OR INHALED.
SPECIFIC TREATMENTS: NO SPECIFIC TREATMENT.
PROTECTION OF FIRST-AIDERS:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. IT MAY BE DANGEROUS TO THE PERSON PROVIDING AID TO GIVE
MOUTH-TO-MOUTH RESUSCITATION.
SEE TOXICOLOGICAL INFORMATION (SECTION 11)
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE AN EXTINGUISHING AGENT SUITABLE FOR THE SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA: NONE KNOWN.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
IN A FIRE OR IF HEATED, A PRESSURE INCREASE WILL OCCUR AND THE CONTAINER
MAY BURST.
HAZARDOUS THERMAL DECOMPOSITION PRODUCTS:
DECOMPOSITION PRODUCTS MAY INCLUDE THE FOLLOWING MATERIALS:
CARBON DIOXIDE
CARBON MONOXIDE
SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
PROMPTLY ISOLATE THE SCENE BY REMOVING ALL PERSONS FROM THE VICINITY OF
THE INCIDENT IF THERE IS A FIRE. NO ACTION SHALL BE TAKEN INVOLVING ANY
PERSONAL RISK OR WITHOUT SUITABLE TRAINING.
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
FIRE-FIGHTERS SHOULD WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND
SELF-CONTAINED BREATHING APPARATUS (SCBA) WITH A FULL FACE-PIECE OPERATED
IN POSITIVE PRESSURE MODE.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
FOR NON-EMERGENCY PERSONNEL:
NO ACTION SHALL BE TAKEN INVOLVING ANY PERSONAL RISK OR WITHOUT SUITABLE
TRAINING. EVACUATE SURROUNDING AREAS. KEEP UNNECESSARY AND UNPROTECTED
PERSONNEL FROM ENTERING. DO NOT TOUCH OR WALK THROUGH SPILLED MATERIAL.
AVOID BREATHING VAPOR OR MIST. PROVIDE ADEQUATE VENTILATION. WEAR
APPROPRIATE RESPIRATOR WHEN VENTILATION IS INADEQUATE. PUT ON APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT.
FOR EMERGENCY RESPONDERS:
IF SPECIALISED CLOTHING IS REQUIRED TO DEAL WITH THE SPILLAGE, TAKE NOTE OF
ANY INFORMATION IN SECTION 8 ON SUITABLE AND UNSUITABLE MATERIALS. SEE ALSO
THE INFORMATION IN "FOR NON-EMERGENCY PERSONNEL".
ENVIRONMENTAL PRECAUTIONS:
AVOID DISPERSAL OF SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL,
WATERWAYS, DRAINS AND SEWERS. INFORM THE RELEVANT AUTHORITIES IF THE
PRODUCT HAS CAUSED ENVIRONMENTAL POLLUTION (SEWERS, WATERWAYS, SOIL OR
AIR).
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
SMALL SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. DILUTE WITH
WATER AND MOP UP IF WATER-SOLUBLE. ALTERNATIVELY, OR IF WATER-INSOLUBLE,
ABSORB WITH AN INERT DRY MATERIAL AND PLACE IN AN APPROPRIATE WASTE
DISPOSAL CONTAINER. DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR.
LARGE SPILL:
STOP LEAK IF WITHOUT RISK. MOVE CONTAINERS FROM SPILL AREA. APPROACH
RELEASE FROM UPWIND. PREVENT ENTRY INTO SEWERS, WATER COURSES, BASEMENTS OR
CONFINED AREAS. WASH SPILLAGES INTO AN EFFLUENT TREATMENT PLANT OR PROCEED
AS FOLLOWS. CONTAIN AND COLLECT SPILLAGE WITH NON-COMBUSTIBLE, ABSORBENT
MATERIAL E.G. SAND, EARTH, VERMICULITE OR DIATOMACEOUS EARTH AND PLACE IN
CONTAINER FOR DISPOSAL ACCORDING TO LOCAL REGULATIONS (SEE SECTION 13).
DISPOSE OF VIA A LICENSED WASTE DISPOSAL CONTRACTOR. CONTAMINATED ABSORBENT
MATERIAL MAY POSE THE SAME HAZARD AS THE SPILLED PRODUCT.
NOTE:
SEE SECTION 1 FOR EMERGENCY CONTACT INFORMATION AND SECTION 13 FOR WASTE
DISPOSAL.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
PROTECTIVE MEASURES:
PUT ON APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT (SEE SECTION 8). DO NOT
BREATHE VAPOR OR MIST. DO NOT INGEST. AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. KEEP IN THE ORIGINAL CONTAINER OR AN APPROVED ALTERNATIVE MADE
FROM A COMPATIBLE MATERIAL, KEPT TIGHTLY CLOSED WHEN NOT IN USE. EMPTY
CONTAINERS RETAIN PRODUCT RESIDUE AND CAN BE HAZARDOUS. DO NOT REUSE
CONTAINER.
ADVICE ON GENERAL OCCUPATIONAL HYGIENE:
EATING, DRINKING AND SMOKING SHOULD BE PROHIBITED IN AREAS WHERE THIS
MATERIAL IS HANDLED, STORED AND PROCESSED. WORKERS SHOULD WASH HANDS AND
FACE BEFORE EATING, DRINKING AND SMOKING. REMOVE CONTAMINATED CLOTHING AND
PROTECTIVE EQUIPMENT BEFORE ENTERING EATING AREAS. SEE ALSO SECTION 8 FOR
ADDITIONAL INFORMATION ON HYGIENE MEASURES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE BETWEEN THE FOLLOWING TEMPERATURES:
10 TO 32.222 DEG. C (50 TO 90 DEG. F).
STORE IN ACCORDANCE WITH LOCAL REGULATIONS. STORE IN ORIGINAL CONTAINER
PROTECTED FROM DIRECT SUNLIGHT IN A DRY, COOL AND WELL-VENTILATED AREA,
AWAY FROM INCOMPATIBLE MATERIALS (SEE SECTION 10) AND FOOD AND DRINK.
KEEP CONTAINER TIGHTLY CLOSED AND SEALED UNTIL READY FOR USE. CONTAINERS
THAT HAVE BEEN OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE. DO NOT STORE IN UNLABELED CONTAINERS. USE APPROPRIATE
CONTAINMENT TO AVOID ENVIRONMENTAL CONTAMINATION.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
UNITED STATES:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT NAME EXPOSURE LIMITS
GLYCEROL OSHA PEL 1989 (UNITED STATES, 3/1989).
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 10 MG/M3 8 HOURS.
FORM: TOTAL DUST
OSHA PEL (UNITED STATES, 2/2013).
TWA: 5 MG/M3 8 HOURS.
FORM: RESPIRABLE FRACTION
TWA: 15 MG/M3 8 HOURS.
FORM: TOTAL DUST
ETHANEDIOL OSHA PEL 1989 (UNITED STATES, 3/1989).
CEIL: 50 PPM
CEIL: 125 MG/M3
ACGIH TLV (UNITED STATES, 4/2014).
C: 100 MG/M3
FORM: AEROSOL
CANADA:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT LIST NAME TWA (8 HOURS) STEL (15 MINS)
PPM MG/M3 OTHER PPM MG/M3 OTHER
ETHANEDIOL US ACGIH 4/2014
AB 4/2009
BC 4/2014
10 20
ON 1/2013
QC 1/2014 50 127
GLYCEROL AB 4/2009 10
BC 4/2014 10
3
ON 1/2013 10
QC 1/2014 10
INGREDIENT LIST NAME CEILING NOTATIONS
PPM MG/M3 OTHER
ETHANEDIOL US ACGIH 4/2014 100 [A]
AB 4/2009 100 [3] [B]
BC 4/2014 100 [A]
[C]
50 [D]
ON 1/2013 100 [B]
QC 1/2014 [E]
GLYCEROL AB 4/2009 [3] [F]
BC 4/2014 [F]
[G]
ON 1/2013 [H]
QC 1/2014 [I]
[3] SKIN SENSITIZATION
FORM:
[A] AEROSOL
[B] AEROSOL
[C] PARTICULATE
[D] VAPOUR
[E] VAPOUR AND MIST
[F] MIST
[G] RESPIRABLE MIST
[H] INHALABLE FRACTION
[I] MIST
MEXICO:
OCCUPATIONAL EXPOSURE LIMITS:
INGREDIENT EXPOSURE LIMITS
GLYCEROL NOM-010-STPS (MEXICO, 9/2000).
LMPE-PPT: 10 MG/M3 8 HOURS.
FORM: MIST
ETHANEDIOL NOM-010-STPS (MEXICO, 9/2000).
LMPE-PICO: 100 MG/M3
CONSULT LOCAL AUTHORITIES FOR ACCEPTABLE EXPOSURE LIMITS.:
APPROPRIATE ENGINEERING CONTROLS:
IF USER OPERATIONS GENERATE DUST, FUMES, GAS, VAPOR OR MIST, USE PROCESS
ENCLOSURES, LOCAL EXHAUST VENTILATION OR OTHER ENGINEERING CONTROLS TO KEEP
WORKER EXPOSURE TO AIRBORNE CONTAMINANTS BELOW ANY RECOMMENDED OR STATUTORY
LIMITS.
ENVIRONMENTAL EXPOSURE CONTROLS:
EMISSIONS FROM VENTILATION OR WORK PROCESS EQUIPMENT SHOULD BE CHECKED TO
ENSURE THEY COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION
LEGISLATION. IN SOME CASES, FUME SCRUBBERS, FILTERS OR ENGINEERING
MODIFICATIONS TO THE PROCESS EQUIPMENT WILL BE NECESSARY TO REDUCE
EMISSIONS TO ACCEPTABLE LEVELS.
INDIVIDUAL PROTECTION MEASURES:
HYGIENE MEASURES:
WASH HANDS, FOREARMS AND FACE THOROUGHLY AFTER HANDLING CHEMICAL PRODUCTS,
BEFORE EATING, SMOKING AND USING THE LAVATORY AND AT THE END OF THE WORKING
PERIOD. APPROPRIATE TECHNIQUES SHOULD BE USED TO REMOVE POTENTIALLY
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE REUSING. ENSURE
THAT EYEWASH STATIONS AND SAFETY SHOWERS ARE CLOSE TO THE WORKSTATION
LOCATION.
EYE/FACE PROTECTION:
SAFETY EYEWEAR COMPLYING WITH AN APPROVED STANDARD SHOULD BE USED WHEN A
RISK ASSESSMENT INDICATES THIS IS NECESSARY TO AVOID EXPOSURE TO LIQUID
SPLASHES, MISTS, GASES OR DUSTS. IF CONTACT IS POSSIBLE, THE FOLLOWING
PROTECTION SHOULD BE WORN, UNLESS THE ASSESSMENT INDICATES A HIGHER DEGREE
OF PROTECTION: SAFETY GLASSES WITH SIDE-SHIELDS.
SKIN PROTECTION:
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY. CONSIDERING THE PARAMETERS
SPECIFIED BY THE GLOVE MANUFACTURER, CHECK DURING USE THAT THE GLOVES ARE
STILL RETAINING THEIR PROTECTIVE PROPERTIES. IT SHOULD BE NOTED THAT THE
TIME TO BREAKTHROUGH FOR ANY GLOVE MATERIAL MAY BE DIFFERENT FOR DIFFERENT
GLOVE MANUFACTURERS. IN THE CASE OF MIXTURES, CONSISTING OF SEVERAL
SUBSTANCES, THE PROTECTION TIME OF THE GLOVES CANNOT BE ACCURATELY
ESTIMATED.
BODY PROTECTION:
PERSONAL PROTECTIVE EQUIPMENT FOR THE BODY SHOULD BE SELECTED BASED ON THE
TASK BEING PERFORMED AND THE RISKS INVOLVED AND SHOULD BE APPROVED BY A
SPECIALIST BEFORE HANDLING THIS PRODUCT.
OTHER SKIN PROTECTION:
APPROPRIATE FOOTWEAR AND ANY ADDITIONAL SKIN PROTECTION MEASURES SHOULD BE
SELECTED BASED ON THE TASK BEING PERFORMED AND THE RISKS INVOLVED AND
SHOULD BE APPROVED BY A SPECIALIST BEFORE HANDLING THIS PRODUCT.
RESPIRATORY PROTECTION:
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE:
PHYSICAL STATE: LIQUID. [PASTE.]
COLOR: OFF-WHITE.
ODOR: CHARACTERISTIC.
ODOR THRESHOLD: NOT AVAILABLE.
PH: 6.5 TO 8.5
MELTING POINT: NOT AVAILABLE.
BOILING POINT: 100 DEG. C (212 DEG. F)
FLASH POINT:
CLOSED CUP: >93.333 DEG. C (>200 DEG. F) [SETAFLASH.]
EVAPORATION RATE: <1 (BUTYL ACETATE = 1)
VOC (LESS WATER, LESS EXEMPT SOLVENTS): 33 G/L
RELATIVE DENSITY: 1.22
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY:
NO SPECIFIC TEST DATA RELATED TO REACTIVITY AVAILABLE FOR THIS PRODUCT OR
ITS INGREDIENTS.
CHEMICAL STABILITY: THE PRODUCT IS STABLE.
POSSIBILITY OF HAZARDOUS REACTIONS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS REACTIONS WILL NOT
OCCUR.
CONDITIONS TO AVOID: NO SPECIFIC DATA.
INCOMPATIBLE MATERIALS: NO SPECIFIC DATA.
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE, HAZARDOUS DECOMPOSITION
PRODUCTS SHOULD NOT BE PRODUCED.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES DOSE EXPOSURE
NAME
GLYCEROL LD50 DERMAL RABBIT >18700 MG/KG
LD50 ORAL RAT 12600 MG/KG
ETHANEDIOL LC50 INHALATION RAT 10.92 MG/L 4 HOURS
VAPOR
LD50 ORAL RAT 4700 MG/KG
CONCLUSION/SUMMARY: NOT AVAILABLE.
IRRITATION/CORROSION:
PRODUCT/ RESULT SPECIES SCORE EXPOSURE OBSERVATION
INGREDIENT
NAME
GLYCEROL EYES: RABBIT 24 HOURS
MILD 500 MILLIGRAMS
IRRITANT
SKIN: SKIN: RABBIT 24 HOURS
MILD MILD 500 MILLIGRAMS
IRRITANT IRRITANT
ETHANEDIOL EYES: RABBIT 24 HOURS
MILD 500 MILLIGRAMS
IRRITANT
EYES: EYES: RABBIT 1 HOURS
MILD MILD 100 MILLIGRAMS
IRRITANT IRRITANT
EYES: EYES: RABBIT 6 HOURS
MODERATE MODERATE 1440 MILLIGRAMS
IRRITANT IRRITANT
SKIN: SKIN: RABBIT 555 MILLIGRAMS
MILD MILD
IRRITANT IRRITANT
CONCLUSION/SUMMARY:
SKIN:
PROLONGED OR REPEATED CONTACT CAN DEFAT THE SKIN AND LEAD TO IRRITATION,
CRACKING AND/OR DERMATITIS.
EYES: THIS PRODUCT MAY IRRITATE EYES UPON CONTACT.
RESPIRATORY:
INHALATION OF OIL MIST OR VAPORS AT ELEVATED TEMPERATURES MAY CAUSE
RESPIRATORY IRRITATION.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
NAME CATEGORY ROUTE OF EXPOSURE TARGET ORGANS
ETHANEDIOL CATEGORY 2 ORAL KIDNEYS
CATEGORY 3 NOT APPLICABLE. NARCOTIC EFFECTS
INFORMATION ON THE LIKELY ROUTES OF EXPOSURE:
ROUTES OF ENTRY ANTICIPATED: ORAL, DERMAL, INHALATION.
POTENTIAL ACUTE HEALTH EFFECTS:
EYE CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INHALATION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SKIN CONTACT: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
INGESTION: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
EYE CONTACT: NO SPECIFIC DATA.
INHALATION: NO SPECIFIC DATA.
SKIN CONTACT: NO SPECIFIC DATA.
INGESTION: NO SPECIFIC DATA.
DELAYED AND IMMEDIATE EFFECTS AND ALSO CHRONIC EFFECTS FROM SHORT AND LONG
TERM EXPOSURE:
SHORT TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
LONG TERM EXPOSURE:
POTENTIAL IMMEDIATE EFFECTS: NOT AVAILABLE.
POTENTIAL DELAYED EFFECTS: NOT AVAILABLE.
| SECTION 12. ECOLOGICAL INFORMATION | |
TOXICITY:
PRODUCT/INGREDIENT RESULT SPECIES EXPOSURE
NAME
GLYCEROL ACUTE EC50: ALGAE 96 HOURS
77712 MG/L
ACUTE EC50: CRUSTACEANS 48 HOURS
1851 MG/L
ACUTE LC50: FISH - RAINBOW TROUT 96 HOURS
51 MG/L
ETHANEDIOL ACUTE EC50: ALGAE - SELENASTRUM 96 HOURS
10940 MG/L CAPRIOCORNUTUM
ACUTE LC50: CRUSTACEANS - 48 HOURS
13140000 CERIODAPHNIA DUBIA
(MICRO)G/L
FRESH WATER
ACUTE LC50: DAPHNIA - DAPHNIA 48 HOURS
41000000 MAGNA - NEONATE
(MICRO)G/L
FRESH WATER
ACUTE LC50: FISH - PIMEPHALES 96 HOURS
8050000 PROMELAS
(MICRO)G/L
FRESH WATER
CHRONIC NOEC: ALGAE - SELENASTRUM 96 HOURS
10000 MG/L CAPRIOCORNUTUM
CONCLUSION/SUMMARY: NOT AVAILABLE.
PERSISTENCE AND DEGRADABILITY:
PRODUCT/INGREDIENT NAME AQUATIC HALF-LIFE PHOTOLYSIS BIODEGRADABILITY
GLYCEROL READILY
ETHANEDIOL READILY
BIOACCUMULATIVE POTENTIAL:
PRODUCT/INGREDIENT NAME LOGPOW BCF POTENTIAL
GLYCEROL -1.76 3.162 LOW
ETHANEDIOL -1.36 10 LOW
OTHER ADVERSE EFFECTS: NO KNOWN SIGNIFICANT EFFECTS OR CRITICAL HAZARDS.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
THE GENERATION OF WASTE SHOULD BE AVOIDED OR MINIMIZED WHEREVER POSSIBLE.
DISPOSAL OF THIS PRODUCT, SOLUTIONS AND ANY BY-PRODUCTS SHOULD AT ALL TIMES
COMPLY WITH THE REQUIREMENTS OF ENVIRONMENTAL PROTECTION AND WASTE DISPOSAL
LEGISLATION AND ANY REGIONAL LOCAL AUTHORITY REQUIREMENTS. DISPOSE OF
SURPLUS AND NON-RECYCLABLE PRODUCTS VIA A LICENSED WASTE DISPOSAL
CONTRACTOR. WASTE SHOULD NOT BE DISPOSED OF UNTREATED TO THE SEWER UNLESS
FULLY COMPLIANT WITH THE REQUIREMENTS OF ALL AUTHORITIES WITH JURISDICTION.
WASTE PACKAGING SHOULD BE RECYCLED. INCINERATION OR LANDFILL SHOULD ONLY BE
CONSIDERED WHEN RECYCLING IS NOT FEASIBLE. THIS MATERIAL AND ITS CONTAINER
MUST BE DISPOSED OF IN A SAFE WAY. CARE SHOULD BE TAKEN WHEN HANDLING
EMPTIED CONTAINERS THAT HAVE NOT BEEN CLEANED OR RINSED OUT. EMPTY
CONTAINERS OR LINERS MAY RETAIN SOME PRODUCT RESIDUES. AVOID DISPERSAL OF
SPILLED MATERIAL AND RUNOFF AND CONTACT WITH SOIL, WATERWAYS, DRAINS AND
SEWERS.
| SECTION 14. TRANSPORT INFORMATION | |
DOT TDG MEXICO
CLASSIFICATION CLASSIFICATION CLASSIFICATION
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER SHIPPING NAME
TRANSPORT HAZARD
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO. NO.
ADDITIONAL INFORMATION
ADR/RID IMDG IATA
UN NUMBER NOT REGULATED. NOT REGULATED. NOT REGULATED.
UN PROPER SHIPPING NAME
TRANSPORT HAZARD
CLASS(ES)
PACKING GROUP
ENVIRONMENTAL HAZARDS NO. NO. NO.
ADDITIONAL INFORMATION
SPECIAL PRECAUTIONS FOR USER:
TRANSPORT WITHIN USER'S PREMISES:
ALWAYS TRANSPORT IN CLOSED CONTAINERS THAT ARE UPRIGHT AND SECURE. ENSURE
THAT PERSONS TRANSPORTING THE PRODUCT KNOW WHAT TO DO IN THE EVENT OF AN
ACCIDENT OR SPILLAGE.
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL 73/78 AND THE IBC CODE:
NOT AVAILABLE.
| SECTION 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
TSCA 8(A) PAIR: NONYLPHENOL, BRANCHED, ETHOXYLATED
TSCA 8(A) CDR EXEMPT/PARTIAL EXEMPTION: NOT DETERMINED
UNITED STATES INVENTORY (TSCA 8B): ALL COMPONENTS ARE LISTED OR EXEMPTED.
COMMERCE CONTROL LIST PRECURSOR: 2-DIETHYLAMINOETHANOL
CLEAN AIR ACT SECTION 112 (B) HAZARDOUS AIR POLLUTANTS (HAPS): LISTED
CLEAN AIR ACT SECTION 602 CLASS I SUBSTANCES: NOT LISTED
CLEAN AIR ACT SECTION 602 CLASS II SUBSTANCES: NOT LISTED
SARA 302/304:
COMPOSITION/INFORMATION ON INGREDIENTS: NO PRODUCTS WERE FOUND.
SARA 304 RQ: NOT APPLICABLE.
SARA 311/312:
CLASSIFICATION: DELAYED (CHRONIC) HEALTH HAZARD
COMPOSITION/INFORMATION ON INGREDIENTS:
NAME % FIRE SUDDEN REACTIVE IMMEDIATE DELAYED
HAZARD RELEASE OF (ACUTE) (CHRONIC)
PRESSURE HEALTH HEALTH
HAZARD HAZARD
GLYCEROL 1 - 5 NO. NO. NO. YES. NO.
ETHANEDIOL 1 - 5 NO. NO. NO. YES. YES.
SARA 313:
PRODUCT NAME CAS NUMBER %
FORM R - REPORTING REQUIREMENTS:
ETHANEDIOL 107-21-1 1 - 5
SUPPLIER NOTIFICATION:
ETHANEDIOL 107-21-1 1 - 5
SARA 313 NOTIFICATIONS MUST NOT BE DETACHED FROM THE SDS AND ANY COPYING
AND REDISTRIBUTION OF THE SDS SHALL INCLUDE COPYING AND REDISTRIBUTION OF
THE NOTICE ATTACHED TO COPIES OF THE SDS SUBSEQUENTLY REDISTRIBUTED.
STATE REGULATIONS:
MASSACHUSETTS:
THE FOLLOWING COMPONENTS ARE LISTED: GLYCERINE MIST; ETHYLENE GLYCOL
NEW YORK:
THE FOLLOWING COMPONENTS ARE LISTED: ETHYLENE GLYCOL
NEW JERSEY:
THE FOLLOWING COMPONENTS ARE LISTED:
GLYCERIN; 1,2,3-PROPANETRIOL; ETHYLENE GLYCOL; 1,2-ETHANEDIOL
PENNSYLVANIA:
THE FOLLOWING COMPONENTS ARE LISTED: 1,2,3-PROPANETRIOL; 1,2-ETHANEDIOL
CALIFORNIA PROP. 65: NOT AVAILABLE.
INGREDIENT CANCER REPRODUCTIVE NO SIGNIFICANT MAXIMUM ACCEPTABLE
NAME RISK LEVEL DOSAGE LEVEL
NOT APPLICABLE.
CANADA:
CANADIAN LISTS:
CANADIAN NPRI:
THE FOLLOWING COMPONENTS ARE LISTED: ETHYLENE GLYCOL
CEPA TOXIC SUBSTANCES: NONE OF THE COMPONENTS ARE LISTED.
CANADA INVENTORY: NOT DETERMINED.
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CONTROLLED PRODUCTS REGULATIONS AND THE MSDS CONTAINS ALL THE
INFORMATION REQUIRED BY THE CONTROLLED PRODUCTS REGULATIONS.
MEXICO:
CLASSIFICATION:
HEALTH 1
FLAMMABILITY 1
REACTIVITY 0
SPECIAL
INTERNATIONAL REGULATIONS:
INTERNATIONAL LISTS:
AUSTRALIA INVENTORY (AICS): NOT DETERMINED.
CHINA INVENTORY (IECSC): NOT DETERMINED.
JAPAN INVENTORY: NOT DETERMINED.
KOREA INVENTORY: NOT DETERMINED.
MALAYSIA INVENTORY (EHS REGISTER): NOT DETERMINED.
NEW ZEALAND INVENTORY OF CHEMICALS (NZIOC): NOT DETERMINED.
PHILIPPINES INVENTORY (PICCS): NOT DETERMINED.
TAIWAN INVENTORY (CSNN): NOT DETERMINED.
EUROPE: NOT DETERMINED.
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE I CHEMICALS: NOT LISTED
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE II CHEMICALS: NOT LISTED
CHEMICAL WEAPONS CONVENTION LIST SCHEDULE III CHEMICALS: NOT LISTED
| SECTION 16. OTHER INFORMATION | |
HAZARDOUS MATERIAL INFORMATION SYSTEM (U.S.A.):
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARDS 0
CAUTION:
HMIS(R*) RATINGS ARE BASED ON A 0-4 RATING SCALE, WITH 0 REPRESENTING
MINIMAL HAZARDS OR RISKS, AND 4 REPRESENTING SIGNIFICANT HAZARDS OR RISKS
ALTHOUGH HMIS(R*) RATINGS ARE NOT REQUIRED ON SDSS UNDER 29 CFR 1910.1200,
THE PREPARER MAY CHOOSE TO PROVIDE THEM. HMIS(R*) RATINGS ARE TO BE USED
WITH A FULLY IMPLEMENTED HMIS(R*) PROGRAM. HMIS(R*) IS A REGISTERED MARK OF
THE NATIONAL PAINT & COATINGS ASSOCIATION (NPCA). HMIS(R*) MATERIALS MAY BE
PURCHASED EXCLUSIVELY FROM J. J. KELLER (800) 327-6868.
THE CUSTOMER IS RESPONSIBLE FOR DETERMINING THE PPE CODE FOR THIS MATERIAL.
NATIONAL FIRE PROTECTION ASSOCIATION (U.S.A.):
HEALTH 1
FLAMMABILITY 1
INSTABILITY/REACTIVITY 0
SPECIAL
REPRINTED WITH PERMISSION FROM NFPA 704-2001, IDENTIFICATION OF THE HAZARDS
OF MATERIALS FOR EMERGENCY RESPONSE COPYRIGHT (C)1997, NATIONAL FIRE
PROTECTION ASSOCIATION, QUINCY, MA 02269. THIS REPRINTED MATERIAL IS NOT
THE COMPLETE AND OFFICIAL POSITION OF THE NATIONAL FIRE PROTECTION
ASSOCIATION, ON THE REFERENCED SUBJECT WHICH IS REPRESENTED ONLY BY THE
STANDARD IN ITS ENTIRETY.
COPYRIGHT (C)2001, NATIONAL FIRE PROTECTION ASSOCIATION, QUINCY, MA 02269.
THIS WARNING SYSTEM IS INTENDED TO BE INTERPRETED AND APPLIED ONLY BY
PROPERLY TRAINED INDIVIDUALS TO IDENTIFY FIRE, HEALTH AND REACTIVITY
HAZARDS OF CHEMICALS. THE USER IS REFERRED TO CERTAIN LIMITED NUMBER OF
CHEMICALS WITH RECOMMENDED CLASSIFICATIONS IN NFPA 49 AND NFPA 325, WHICH
WOULD BE USED AS A GUIDELINE ONLY. WHETHER THE CHEMICALS ARE CLASSIFIED BY
NFPA OR NOT, ANYONE USING THE 704 SYSTEMS TO CLASSIFY CHEMICALS DOES SO AT
THEIR OWN RISK.
HISTORY:
DATE OF PRINTING: 6/3/2015.
DATE OF ISSUE/DATE OF REVISION: 6/2/2015.
DATE OF PREVIOUS ISSUE: 5/22/2015.
VERSION: 4.1
KEY TO ABBREVIATIONS:
ATE: ACUTE TOXICITY ESTIMATE
BCF: BIOCONCENTRATION FACTOR
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELLING OF CHEMICALS
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
IBC: INTERMEDIATE BULK CONTAINER
IMDG: INTERNATIONAL MARITIME DANGEROUS GOODS
LOGPOW: LOGARITHM OF THE OCTANOL/WATER PARTITION COEFFICIENT
MARPOL 73/78:
INTERNATIONAL CONVENTION FOR THE PREVENTION OF POLLUTION FROM SHIPS, 1973
AS MODIFIED BY THE PROTOCOL OF 1978. ("MARPOL" = MARINE POLLUTION)
UN: UNITED NATIONS
REFERENCES: NOT AVAILABLE.
| INDICATES INFORMATION THAT HAS CHANGED FROM PREVIOUSLY ISSUED VERSION.
NOTICE TO READER:
TO THE BEST OF OUR KNOWLEDGE, THE INFORMATION CONTAINED HEREIN IS ACCURATE.
HOWEVER, NEITHER THE ABOVE-NAMED SUPPLIER, NOR ANY OF ITS SUBSIDIARIES,
ASSUMES ANY LIABILITY WHATSOEVER FOR THE ACCURACY OR COMPLETENESS OF THE
INFORMATION CONTAINED HEREIN.
FINAL DETERMINATION OF SUITABILITY OF ANY MATERIAL IS THE SOLE
RESPONSIBILITY OF THE USER. ALL MATERIALS MAY PRESENT UNKNOWN HAZARDS AND
SHOULD BE USED WITH CAUTION. ALTHOUGH CERTAIN HAZARDS ARE DESCRIBED HEREIN,
WE CANNOT GUARANTEE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.