| Common Name: | QUICKSTIX 668 RETAINING COMPOUND-HIGH TEMP, 39148 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 4/26/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 1LLT5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 006.0
ISSUE DATE: 04/26/2016
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: QUICKSTIX(TM) 668(TM) RETAINING COMPOUND-HIGH TEMP
PRODUCT TYPE: ANAEROBIC ADHESIVE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 640470
ITEM NUMBER: 39148
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
FATAL IF INHALED.
HAZARD CLASS HAZARD CATEGORY
ACUTE TOXICITY INHALATION 2
SKIN IRRITATION 2
EYE IRRITATION 2A
SKIN SENSITIZATION 1
PICTOGRAM(S):
SKULLS AND CROSSBONES
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
DO NOT BREATHE DUST OR FUMES. WASH AFFECTED AREA THOROUGHLY AFTER HANDLING.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA. CONTAMINATED WORK CLOTHING
SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WEAR PROTECTIVE GLOVES, EYE
PROTECTION, AND FACE PROTECTION. [IN CASE OF INADEQUATE VENTILATION] WEAR
RESPIRATORY PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE
FOR BREATHING. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ATTENTION.
IF EYE IRRITATION PERSISTS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED. STORE
LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD
(29 CFR 1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED
NATIONS GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF
CHEMICALS (GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DIMETHACRYLATE ESTER PROPRIETARY 30 - 60
POLYGLYCOL DIMETHACRYLATE PROPRIETARY 10 - 30
RESIN PROPRIETARY 10 - 30
HYDROXYALKYL METHACRYLATE 27813-02-1 5 - 10
SILICA, AMORPHOUS, FUMED, CRYSTAL-FREE 112945-52-5 1 - 5
CUMENE HYDROPEROXIDE 80-15-9 1 - 5
1-ACETYL-2-PHENYLHYDRAZINE 114-83-0 0.1 - 1
CUMENE 98-82-8 0.1 - 1
METHACRYLIC ACID 79-41-4 0.1 - 1
* EXACT PERCENTAGE IS A TRADE SECRET. CONCENTRATION RANGE IS PROVIDED
TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER (USING SOAP, IF AVAILABLE).
REMOVE CONTAMINATED CLOTHING AND FOOTWEAR. WASH CLOTHING BEFORE REUSE.
GET MEDICAL ATTENTION.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGESTION:
DO NOT INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL
ATTENTION.
SYMPTOMS: SEE SECTION 11.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES:
WEAR SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING, SUCH
AS TURN-OUT GEAR. IN CASE OF FIRE, KEEP CONTAINERS COOL WITH WATER SPRAY.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
UNCONTROLLED POLYMERIZATION MAY OCCUR AT HIGH TEMPERATURES RESULTING IN
EXPLOSIONS OR RUPTURE OF STORAGE CONTAINERS.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF CARBON, OXIDES OF NITROGEN, IRRITATING ORGANIC VAPORS. OXIDES
OF SULFUR. TOXIC FUMES.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
REMOVE ALL SOURCES OF IGNITION. EVACUATE AND VENTILATE SPILL AREA; DIKE
SPILL TO PREVENT ENTRY INTO WATER SYSTEM; WEAR FULL PROTECTIVE EQUIPMENT
DURING CLEANUP. SOAK UP WITH INERT ABSORBENT MATERIAL (E.G. SAND, SILICA
GEL, ACID BINDER, UNIVERSAL BINDER, SAWDUST). SCRAPE UP AS MUCH MATERIAL
AS POSSIBLE. STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
REFER TO SECTION 8 "EXPOSURE CONTROLS / PERSONAL PROTECTION" PRIOR TO
CLEAN UP.
| 7. HANDLING AND STORAGE | |
HANDLING:
USE ONLY WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH EYES, SKIN AND
CLOTHING. DO NOT BREATHE VAPOR AND MIST. WASH THOROUGHLY AFTER HANDLING.
KEEP CONTAINER CLOSED. REFER TO SECTION 8.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 0 DEG. C (32 DEG. F) AND 38 DEG. C
(100.4 DEG. F)
KEEP IN A COOL, WELL VENTILATED AREA AWAY FROM HEAT, SPARKS AND OPEN FLAME.
KEEP CONTAINER TIGHTLY CLOSED UNTIL READY FOR USE.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE
THE NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL
DIMETHACRYLATE ESTER NONE NONE
POLYGLYCOL DIMETHACRYLATE NONE NONE
RESIN NONE NONE
HYDROXYALKYL METHACRYLATE NONE NONE
SILICA, AMORPHOUS, FUMED, 10 MG/M3 TWA 20 MPPCF TWA
CRYSTAL-FREE INHALABLE DUST. 0.8 MG/M3 TWA
3 MG/M3 TWA
RESPIRABLE FRACTION.
CUMENE HYDROPEROXIDE NONE NONE
1-ACETYL-2-PHENYLHYDRAZINE NONE NONE
CUMENE 50 PPM TWA 50 PPM
(245 MG/M3) PEL
(SKIN)
METHACRYLIC ACID 20 PPM TWA NONE
HAZARDOUS COMPONENT(S) AIHA WEEL OTHER
DIMETHACRYLATE ESTER NONE NONE
POLYGLYCOL DIMETHACRYLATE NONE NONE
RESIN NONE NONE
HYDROXYALKYL METHACRYLATE NONE 1 PPM TWA
3 PPM STEL
SILICA, AMORPHOUS, FUMED, NONE NONE
CRYSTAL-FREE
CUMENE HYDROPEROXIDE 1 PPM NONE
(6 MG/M3)
TWA
(SKIN)
1-ACETYL-2-PHENYLHYDRAZINE NONE NONE
CUMENE NONE NONE
METHACRYLIC ACID NONE NONE
ENGINEERING CONTROLS:
PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO MAINTAIN WORKER EXPOSURE
BELOW EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION:
SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS. FULL FACE PROTECTION
SHOULD BE USED IF THE POTENTIAL FOR SPLASHING OR SPRAYING OF PRODUCT
EXISTS. SAFETY SHOWERS AND EYE WASH STATIONS SHOULD BE AVAILABLE.
SKIN PROTECTION:
USE CHEMICAL RESISTANT, IMPERMEABLE CLOTHING INCLUDING GLOVES AND EITHER
AN APRON OR BODY SUIT TO PREVENT SKIN CONTACT. NEOPRENE GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: SEMI-SOLID
COLOR: GREEN
ODOR: MILD
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT APPLICABLE
VAPOR PRESSURE: <5 MMHg (80 DEG. F (26.7 DEG. C))
BOILING POINT/RANGE: >300 DEG. F (>148.9 DEG. C)
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.1228
VAPOR DENSITY: NOT AVAILABLE.
FLASH POINT: NOT APPLICABLEPRODUCT IS A SOLID.
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: NOT AVAILABLE.
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: NOT AVAILABLE.
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: SLIGHT
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 0.79%; 8.86 G/L
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS:
NONE UNDER NORMAL PROCESSING. POLYMERIZATION MAY OCCUR AT ELEVATED
TEMPERATURE OR IN THE PRESENCE OF INCOMPATIBLE MATERIALS.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF NITROGEN. TOXIC FUMES. IRRITATING ORGANIC
VAPOURS. OXIDES OF SULFUR.
INCOMPATIBLE MATERIALS:
ACIDS. REDUCING AGENTS. ALKALIS. AMINES. THIS CHEMICAL CONTAINS HEAVY
METALS. PEROXIDES. OXYGEN SCAVENGERS. FREE RADICAL INITIATORS. OTHER
POLYMERIZATION INITIATORS. STRONG OXIDIZING AGENTS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
ELEVATED TEMPERATURES. HEAT, FLAMES, SPARKS AND OTHER SOURCES OF IGNITION.
STORE AWAY FROM INCOMPATIBLE MATERIALS.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE: SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
THIS PRODUCT IS HARMFUL OR FATAL BY INHALATION. INHALATION OF VAPORS OR
MISTS OF THE PRODUCT MAY BE IRRITATING TO THE RESPIRATORY SYSTEM.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
INGESTION: MAY CAUSE GASTROINTESTINAL TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED
HEALTH EFFECTS
DIMETHACRYLATE ESTER NONE IRRITANT, ALLERGEN
POLYGLYCOL DIMETHACRYLATE NONE ALLERGEN, IRRITANT
RESIN NONE NO TARGET ORGANS
HYDROXYALKYL METHACRYLATE NONE IRRITANT, ALLERGEN
SILICA, AMORPHOUS, FUMED, NONE NUISANCE DUST
CRYSTAL-FREE
CUMENE HYDROPEROXIDE INHALATION LC50 ALLERGEN, CENTRAL
(MOUSE, 4 H): NERVOUS SYSTEM,
200 MG/L CORROSIVE, IRRITANT,
MUTAGEN
1-ACETYL-2-PHENYLHYDRAZINE ORAL LD50 (MOUSE): ALLERGEN, BLOOD,
270 MG/KG KIDNEY, MUTAGEN,
SOME EVIDENCE OF
CARCINOGENICITY
CUMENE ORAL LD50 (RAT): CENTRAL NERVOUS
2.91 G/KG SYSTEM, IRRITANT,
LUNG
ORAL LD50 (RAT):
1,400 MG/KG
INHALATION LC50
(RAT, 4 H): 8000 PPM
METHACRYLIC ACID ORAL LD50 (MOUSE): CORROSIVE, IRRITANT,
1,332 MG/KG ALLERGEN
ORAL LD50 (MOUSE):
1,600 MG/KG
ORAL LD50 (MOUSE):
1,250 MG/KG
ORAL LD50 (RABBIT):
1,200 MG/KG
ORAL LD50 (RAT):
1,060 MG/KG
ORAL LD50 (RAT):
2,224 MG/KG
DERMAL LD50 (RABBIT):
500 MG/KG
INHALATION LC50
(RAT, 4 H): 7.1 MG/L
HAZARDOUS COMPONENT(S) NTP IARC OSHA CARCINOGEN
CARCINOGEN CARCINOGEN (SPECIFICALLY
REGULATED)
DIMETHACRYLATE ESTER NO NO NO
POLYGLYCOL DIMETHACRYLATE NO NO NO
RESIN NO NO NO
HYDROXYALKYL METHACRYLATE NO NO NO
SILICA, AMORPHOUS, FUMED, NO NO NO
CRYSTAL-FREE
CUMENE HYDROPEROXIDE NO NO NO
1-ACETYL-2-PHENYLHYDRAZINE NO NO NO
CUMENE REASONABLY GROUP 2B NO
ANTICIPATED
TO BE A HUMAN
CARCINOGEN.
METHACRYLIC ACID NO NO NO
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: NOT REGULATED
HAZARD CLASS OR DIVISION: NONE
IDENTIFICATION NUMBER: NONE
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH, DELAYED HEALTH
CERCLA/SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND
COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372). CUMENE HYDROPEROXIDE
(CAS# 80-15-9).
CERCLA REPORTABLE QUANTITY:
CUMENE HYDROPEROXIDE (CAS# 80-15-9) 10 LBS. (4.54 KG)
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER. THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: 2
PREPARED BY: SHEILA GINES, REGULATORY AFFAIRS SPECIALIST
ISSUE DATE: 04/26/2016
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE
OF ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE
OR USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.