| Common Name: | ANNOVI CRANKCASE OIL |
| Manufacturer: | A.R. NORTH AMERICA |
| SDS Revision Date: | 4/3/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 1MDJ8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SAFETY DATA SHEET
ANNOVI CRANKCASE OIL
REVISION DATE: 4/3/17
PREPARED ACCORDING TO GLOBAL HARMONIZED SYSTEM (GHS) STANDARDS
| SECTION 1 CHEMICAL PRODUCT IDENTIFICATION |  |
A.R. NORTH AMERICA, INC.
140 81ST AVENUE NORTHEAST
FRIDLEY, MN 55432-1770
TEL: 763-398-2008
PRODUCT TRADE NAME: ANNOVI CRANKCASE OIL
CAS NUMBER: MIXTURE
SYNONYMS/OTHER: N/A
PART NUMBER(S): AR64516
RECOMMENDED USE: LUBRICANT
RESTRICTIONS ON USE: NOT DETERMINED
CREATED DATE: 4/3/2017
PREPARATION/REVISION DATE: 4/3/2017
EMERGENCY PHONE NUMBER: 1-800-424-9300 (CHEMTREC)
SDS CODE: 0199
| SECTION 2 HAZARD IDENTIFICATION | |
APPEARANCE: CLEAR BLUE FLUID
ODOR: MILD, OILY ODOR
CLASSIFICATION:
THIS MATERIAL IS NOT CONSIDERED TO BE HAZARDOUS ACCORDING TO THE GLOBALLY
HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING CHEMICALS (GHS), THIRD
REVISED EDITION
TARGET ORGANS: NOT APPLICABLE
PICTOGRAM(S): NONE REQUIRED
SIGNAL WORD: NONE REQUIRED
HAZARD STATEMENT: NOT REQUIRED
OTHER HAZARDS: NOT DETERMINED
PREVENTION: NONE REQUIRED
RESPONSE: NONE REQUIRED
STORAGE PROCEDURES: NONE REQUIRED
DISPOSAL: NONE REQUIRED
OTHER: SEE SECTION 11 FOR COMPLETE HEALTH HAZARD INFORMATION
| SECTION 3 COMPOSITION OF INGREDIENTS | |
COMPONENT CAS NUMBER PERCENTAGE (BY WEIGHT)
NO HAZARDOUS SUBSTANCE(S) OR COMPLEX SUBSTANCE(S) REQUIRED FOR DISCLOSURE
| SECTION 4 FIRST AID MEASURES | |
EYE CONTACT:
IF IRRITATION OCCURS, CAUTIOUSLY RINSE EYES WITH LUKEWARM, GENTLY FLOWING
WATER FOR 5 MINUTES, WHILE HOLDING THE EYELIDS OPEN. IF EYE IRRITATION
PERSISTS: GET MEDICAL ADVICE/ATTENTION.
SKIN CONTACT: CALL A DOCTOR IF YOU FEEL UNWELL
INHALATION:
GET MEDICAL ADVICE OR ATTENTION IF YOU FEEL UNWELL OR ARE CONCERNED.
INGESTION:
IF YOU FEEL UNWELL OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. RINSE MOUTH.
DO NOT INDUCE VOMITING. IF VOMITING OCCURS NATURALLY, LIE ON YOUR SIDE, IN
THE RECOVERY POSITION.
OTHER: NO ADDITIONAL INFORMATION
| SECTION 5 FIRE FIGHTING MEASURES | |
FLASH POINT: 198 DEG. C (388 DEG. F) BY CLEVELAND OPEN CUP TESTER
FLAMMABLE LIMITS: NOT DETERMINED
EXTINGUISHING MEDIA:
USE DRY CHEMICAL, ALCOHOL FOAM, ALL PURPOSE AFFF OR CARBON DIOXIDE TO
EXTINGUISH FIRE.
SPECIAL FIREFIGHTING PROCEDURES:
DO NOT DIRECT A SOLID STREAM OF WATER OR FOAM INTO HOT, BURNING POOLS OF
LIQUID SINCE THIS MAY CAUSE FROTHING AND INCREASE FIRE INTENSITY. FROTHING
CAN BE VIOLENT AND POSSIBLY ENDANGER ANY FIREFIGHTER STANDING TOO CLOSE TO
THE BURNING LIQUID. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS AND
STRUCTURES UNTIL FIRE IS OUT IF IT CAN BE DONE WITH MINIMAL RISK. AVOID
SPREADING BURNING MATERIAL WITH WATER USED FOR COOLING PURPOSES. WEAR FULL
FIREFIGHTING TURN-OUT GEAR (FULL BUNKER GEAR), AND RESPIRATORY PROTECTION
(SCBA)
UNUSUAL FIRE & EXPLOSION HAZARDS:
DENSE SMOKE MAY BE GENERATED WHILE BURNING. TOXIC FUMES, GASES OR VAPORS
MAY EVOLVE ON BURNING. HIGH TEMPERATURES MAY CREATE HEAVY FLAMMABLE VAPORS
THAT MAY SETTLE ALONG GROUND LEVEL AND LOW SPOTS TO CREATE AN INVISIBLE
FIRE HAZARD.
BYPRODUCTS OF COMBUSTION:
FIRES INVOLVING THIS PRODUCT MAY RELEASE OXIDES OF CARBON, PHOSPHORUS,
NITROGEN AND SULFUR; REACTIVE HYDROCARBONS AND IRRITATING VAPORS.
AUTO IGNITION TEMPERATURE: NOT DETERMINED
EXPLOSION DATA:
NOT DETERMINED. CARE SHOULD ALWAYS BE EXERCISED IN DUST/MIST AREAS.
OTHER:
DISPOSE OF FIRE DEBRIS AND CONTAMINATED EXTINGUISHING WATER IN ACCORDANCE
WITH OFFICIAL REGULATIONS.
| SECTION 6 ACCIDENTAL RELEASE MEASURES | |
SPILL CONTROL PROCEDURES (LAND):
IMMEDIATELY TURN OFF OR ISOLATE ANY SOURCE OF IGNITION (PILOT LIGHTS,
ELECTRICAL EQUIPMENT, FLAMES, HEATERS, ETC.). EVACUATE AREA AND VENTILATE.
PERSONNEL WEARING PROPER PROTECTIVE EQUIPMENT SHOULD CONTAIN SPILL
IMMEDIATELY WITH INERT MATERIALS (SAND, EARTH, CHEMICAL SPILL PADS OF
COTTON) BY FORMING DIKES. DIKES SHOULD BE PLACED TO CONTAIN SPILL IN A
MANNER THAT WILL PREVENT MATERIAL FROM ENTERING SEWERS AND WATERWAYS. LARGE
SPILL, ONCE CONTAINED, MAY BE PICKED UP USING EXPLOSION PROOF, NON-SPARKING
VACUUM PUMPS, SHOVELS, OR BUCKETS, AND DISPOSED OF IN SUITABLE CONTAINERS
FOR DISPOSAL. IF A LARGE SPILL OCCURS NOTIFY APPROPRIATE AUTHORITIES. IN
CASE OF ROAD SPILL OR ACCIDENT CONTACT CHEM-TREC (800-424-9300).
SPILL CONTROL PROCEDURES (WATER):
TRY TO CONTAIN LARGE SPILLS WITH FLOATING BOOMS TO PREVENT SPILL FROM
SPREADING. REMOVE FROM SURFACE BY SKIMMING OR WITH SUITABLE ABSORBENTS. IF
A LARGE SPILL OCCURS NOTIFY APPROPRIATE AUTHORITIES (NORMALLY THE NATIONAL
RESPONSE CENTER OR COAST GUARD AT 800-424-8802).
WASTE DISPOSAL METHOD:
DO NOT EMPTY INTO DRAINS. ALL DISPOSALS MUST COMPLY WITH FEDERAL, STATE,
AND LOCAL REGULATIONS. THE MATERIAL, IF SPILLED OR DISCARDED MAY BE A
REGULATED WASTE. REFER TO STATE AND LOCAL REGULATIONS. DEPARTMENT OF
TRANSPORTATION (DOT) REGULATIONS MAY APPLY FOR TRANSPORTING THIS MATERIAL
WHEN SPILLED. SEE SECTION 14.
OTHER:
CAUTION - IF SPILLED MATERIAL IS CLEANED UP USING A REGULATED SOLVENT, THE
RESULTING WASTE MIXTURE WILL BE REGULATED.
| SECTION 7 HANDLING AND STORAGE | |
HANDLING PROCEDURES:
KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO NOT TRANSFER TO UNMARKED
CONTAINERS. EMPTY CONTAINERS RETAIN PRODUCT RESIDUE WHICH MAY EXHIBIT
HAZARDS OF MATERIAL, THEREFORE DO NOT PRESSURIZE, CUT, GLAZE, WELD,
OR USE FOR ANY OTHER PURPOSES. RETURN DRUMS TO RECLAMATION CENTERS
FOR PROPER CLEANING AND REUSE.
HANDLING TEMPERATURES SHOULD NOT EXCEED 60 DEG. C (140 DEG. F) TO MINIMIZE
DANGER OF BURNS. OPEN CONTAINERS CAREFULLY IN A WELL VENTILATED AREA OR
USED APPROPRIATE RESPIRATORY PROTECTION. WASH THOROUGHLY AFTER HANDLING.
STORAGE PROCEDURES:
STORE CONTAINERS AWAY FROM HEAT, SPARKS, OPEN FLAME, OR OXIDIZING
MATERIALS. EXTENDED STORAGE AT EXCESSIVE TEMPERATURES MAY PRODUCE
ODOROUS AND TOXIC FUMES FROM PRODUCT DECOMPOSITION.
ADDITIONAL INFORMATION: NO ADDITIONAL INFORMATION
| SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EXPOSURE LIMITS/STANDARDS FOR MATERIALS THAT CAN BE FORMED WHEN HANDLING
THIS PRODUCT:
WHEN MISTS/AEROSOLS CAN OCCUR THE FOLLOWING ARE RECOMMENDED 5 MG/M3
ACGIH TLV (INHALABLE FRACTION), 5 MG/M3 - OSHAPEL
NOTE:
LIMITS/STANDARDS SHOWN FOR GUIDANCE ONLY. FOLLOW APPLICABLE REGULATIONS.
NO BIOLOGICAL LIMITS ALLOCATED.
PERSONAL PROTECTION:
APPLICABLE MAINLY TO PERSONS IN REPEATED CONTACT SITUATIONS SUCH AS
PACKAGING OF PRODUCT, SERVICE/MAINTENANCE, AND CLEANUP/SPILL CONTROL
PERSONNEL.
RESPIRATORY PROTECTION:
NONE REQUIRED IF VENTILATION IS ADEQUATE. OTHERWISE A RESPIRATORY
PROTECTION PROGRAM MEETING OSHA 1910.134 AND ANSI 88.2 REQUIREMENTS
MUST BE FOLLOWED. WHERE MISTING MAY OCCUR, WEAR AN MSHA/NIOSH APPROVED
(OR EQUIVALENT).
EYE PROTECTION:
EYE PROTECTION IS STRONGLY RECOMMENDED. WEAR SAFELY GLASSES WITH SIDE
SHIELDS OR VENTED/SPLASH PROOF GOGGLES (ANSI Z87.1 OR APPROVED EQUIVALENT).
HAND PROTECTION:
IMPERVIOUS, CHEMICALLY RESISTANT GLOVES SUCH AS NEOPRENE OR NITRILE RUBBER
TO AVOID SKIN SENSITIZATION AND ABSORPTION.
OTHER PROTECTION:
USE OF AN APRON AND OVER BOOTS OF CHEMICALLY IMPERVIOUS MATERIALS SUCH AS
NEOPRENE OR NITRILE RUBBER IS RECOMMENDED BASED ON LEVEL OF ACTIVITY AND
EXPOSURE. IF HANDLING HOT MATERIAL USE INSULATED PROTECTIVE EQUIPMENT.
LAUNDER SOILED CLOTHES. PROPERTY DISPOSE OF CONTAMINATED LEATHER ARTICLES
AND OTHER MATERIALS WHICH CANNOT BE DECONTAMINATED.
LOCAL CONTROL MEASURES:
USE ADEQUATE VENTILATION WHEN WORKING WITH MATERIAL IN AN ENCLOSED AREA.
MECHANICAL METHODS SUCH AS FUME HOODS OR AREA FANS MAY BE USED TO REDUCE
LOCALIZED VAPOR/MIST AREAS. IF VAPOR OR MIST IS GENERATED WHEN THE MATERIAL
HANDLED, ADEQUATE VENTILATION IN ACCORDANCE WITH GOOD ENGINEERING PRACTICE
MUST BE PROVIDED TO MAINTAIN CONCENTRATIONS BELOW THE SPECIFIED EXPOSURE.
EYEWASH STATIONS AND SHOWERS SHOULD BE AVAILABLE IN AREAS WHERE THIS
MATERIAL IS USED AND STORED.
OTHER:
CONSUMPTION OF FOOD AND DRINK SHOULD BE AVOIDED IN WORK AREAS WHERE PRODUCT
IS PRESENT. ALWAYS WASH HANDS AND FACE WITH SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING.
| SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR BLUE FLUID
ODOR: MILD, OILY ODOR
ODOR THRESHOLD: NOT DETERMINED
PH: NOT APPLICABLE
MELTING/FREEZING POINT: NOT DETERMINED
INITIAL BOILING POINT: NOT DETERMINED
BOILING RANGE: NOT DETERMINED
FLASH POINT: 198 DEG. C (388 DEG. F)
EVAPORATION RATE: NOT DETERMINED
FLAMMABILITY: NOT DETERMINED
UPPER FLAMMABLE LIMIT: NOT DETERMINED
LOWER FLAMMABLE LIMIT: NOT DETERMINED
VAPOR DENSITY: NOT DETERMINED
RELATIVE DENSITY: 0.88 AT 60 DEG. F
SOLUBILITY: NEGLIGIBLE IN WATER, MISCIBLE IN MOST PETROLEUM SOLVENTS.
PARTITION COEFFICIENT: NOT DETERMINED
AUTO-IGNITION TEMPERATURE: NOT DETERMINED
DECOMPOSITION TEMPERATURE: NOT DETERMINED
VISCOSITY: 55 CST AT 40 DEG. C (104 DEG. F)
OTHER: NOT APPLICABLE
| SECTION 10 STABILITY AND REACTIVITY | |
REACTIVITY:
CHEMICAL STABILITY:
MATERIAL IS CHEMICALLY STABLE AT ROOM TEMPERATURES AND PRESSURE.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
CONDITIONS TO AVOID: AVOID HIGH TEMPERATURES AND PRODUCT CONTAMINATION.
INCOMPATIBILITY WITH OTHER MATERIALS:
AVOID CONTACT WITH ACIDS AND STRONG OXIDIZING MATERIALS.
DECOMPOSITION PRODUCTS:
SMOKE, CARBON MONOXIDE, CARBON DIOXIDE, AND OTHER ALDEHYDES OF INCOMPLETE
COMBUSTION. OXIDES OF CARBON, NITROGEN, AND SULFUR, REACTIVE HYDROCARBONS
AND IRRITATING VAPORS.
OTHER: NOT APPLICABLE
| SECTION 11 TOXICOLOGICAL INFORMATION | |
ACUTE TOXICITY (LD50): *SEE NOTE AT THE BOTTOM OF THE SECTION
ORAL: >5000 MG/KG
DERMAL: >5000 MG/KG
INHALATION: >20.0 MG/L
SKIN IRRITATION: NON-IRRITANT
EYE IRRITATION: NON-IRRITANT
DERMAL SENSITIZATION: NOT EXPECTED TO HAVE A SENSITIZING EFFECT
RESPIRATORY SENSITIZATION: NOT EXPECTED TO HAVE A SENSITIZING EFFECT
ASPIRATION HAZARD: NOT APPLICABLE
CHRONIC TOXICITY:
MUTAGENICITY: NOT SUSPECTED OF CAUSING GENETIC DEFECTS
CARCINOGENICITY: NOT SUSPECTED OF CAUSING CANCER
REPRODUCTIVE TOXICITY: NOT EXPECTED TO HAVE ADVERSE EFFECTS ON REPRODUCTION
STOT - SINGLE EXPOSURE: NOT EXPECTED TO HAVE ADVERSE EFFECTS.
STOT - REPEATED EXPOSURE: NOT EXPECTED TO HAVE LONG TERM ADVERSE EFFECTS.
OTHER:
*ALL DATA IN THIS SECTION IS BASED OFF CALCULATIONS FROM PART 3 OF THE
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS) UTILIZING INFORMATION FROM THE CONSTITUENT COMPONENTS.
| SECTION 12 ECOLOGICAL INFORMATION | |
ENVIRONMENTAL TOXICITY:
FISH: >100 MG/L
INVERTEBRATES: >100 MG/L
AQUATIC PLANTS: >100 MG/L
MICROORGANISM: >100 MG/L
PERSISTENCE/DEGRADABILITY:
THIS PRODUCT IS NOT EXPECTED TO BE READILY BIODEGRADABLE.
BIOACCUMULATION: NOT DETERMINED
MOBILITY IN SOIL: NOT DETERMINED
OTHER:
ALL CLASSIFICATIONS ARE BASED ON CALCULATIONS IN PART 4 OF THE GLOBALLY
HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS (GHS)
UTILIZING INFORMATION FROM THE CONSTITUENT COMPONENTS.
| SECTION 13 DISPOSAL CONSIDERATIONS | |
WASTE DISPOSAL:
THIS PRODUCT UNADULTERATED BY OTHER MATERIALS CAN BE CLASSIFIED AS A
NONHAZARDOUS WASTE. DEPENDING ON USE, USED PRODUCT MAY BE REGULATED.
DISPOSE OF IN A LICENSED FACILITY. DO NOT DISCHARGE PRODUCT IN THE SEWER
SYSTEM. DISPOSE OF CONTAINERS BY CRUSHING OR PUNCTURING, SO AS TO PREVENT
UNAUTHORIZED USE OF USED CONTAINERS. WASTE MANAGEMENT SHOULD BE IN FULL
COMPLIANCE WITH FEDERAL, STATE, AND LOCAL LAWS.
OTHER:
THE TRANSPORTATION, STORAGE, TREATMENT AND DISPOSAL OF RCRA WASTE MATERIAL
MUST BE CONDUCTED IN COMPLIANCE WITH 40 CFR 262, 263, 264, 268 AND 270.
CHEMICAL ADDITIONS, PROCESSING OR OTHERWISE ALTERING THIS MATERIAL MAY
MAKE THE WASTE MANAGEMENT INFORMATION PRESENTED IN THIS SDS INCOMPLETE,
INACCURATE OR OTHERWISE INAPPROPRIATE.
| SECTION 14 TRANSPORT INFORMATION | |
LAND TRANSPORT (DOT): NOT REGULATED FOR LAND TRANSPORT
PROPER SHIPPING NAME: NOT APPLICABLE
LAND TRANSPORT (TDG): NOT REGULATED FOR LAND TRANSPORT
PROPER SHIPPING NAME: NOT APPLICABLE
SEA TRANSPORT (MDG): NOT REGULATED FOR SEA TRANSPORT
PROPER SHIPPING NAME: NOT APPLICABLE
AIR TRANSPORT (IATA): NOT REGULATED FOR AIR TRANSPORT
PROPER SHIPPING NAME: NOT APPLICABLE
OTHER: NOT APPLICABLE
| SECTION 15 REGULATORY INFORMATION | |
FEDERAL REGULATION:
CLEAN WATER ACT/OIL:
UNDER SECTION 311 OF THE CLEAN WATER ACT (40 CFR 110) AND THE OIL POLLUTION
CONTROL ACT OF 1990, THIS MATERIAL IS CONSIDERED AN OIL. ANY SPILL OR
DISCHARGES THAT PRODUCE A VISIBLE SHEEN OR FILM ON SURFACE OF WATER, OR IN
WATERWAYS, DITCHES, OR SEWERS LEADING TO SURFACE WATER MUST BE REPORTED.
CONTACT THE NATIONAL RESPONSE CENTER AT 800-424-8802.
TSCA:
ALL COMPONENTS OF THIS MATERIAL ARE LISTED IN THE U.S. TSCA INVENTORY.
OTHER TSCA: NOT APPLICABLE
SARA TITLE III:
SECTION 302/304 EXTREMELY HAZARDOUS SUBSTANCES: NONE
SECTION 311, 312 HAZARD CATEGORIZATION:
ACUTE (IMMEDIATE HEALTH EFFECTS): NO
CHRONIC (DELAYED HEALTH EFFECTS): NO
FIRE (HAZARD): NO
REACTIVITY (HAZARD): NO
PRESSURE (SUDDEN RELEASE HAZARD): NO
SECTION 313 TOXIC CHEMICALS:
NO COMPONENTS PRESENT ARE AT OR GREATER THAN THE DE MINIMIS (MINIMUM
REPORTABLE) CONCENTRATION REQUIREMENTS FOR REPORTING.
CERCLA:
FOR STATIONARY/MOVING SOURCES - REPORTABLE QUANTITY (DUE TO). NOT HAZARDOUS
DUE TO THE PETROLEUM EXCLUSION.
STATE REGULATIONS:
RIGHT-TO-KNOW: NOT DETERMINED
OTHER:
A RELEASE OF THIS PRODUCT, AS SUPPLIED, IS EXEMPT FROM REPORTING UNDER THE
COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND LIABILITY ACT
(CERCLA). HOWEVER, RELEASES MAY BE REPORTABLE TO THE NATIONAL RESPONSE
CENTER UNDER THE CLEAN WATER ACT. 33 U.S.C. 1321(B)(3) AND (5) - SEE HEAD
OF SECTION 15. FAILURE TO REPORT MAY RESULT IN SUBSTANTIAL CIVIL AND
CRIMINAL PENALTIES.
RECOMMEND CONTACTING THE LOCAL AUTHORITIES IN THE EVENT OF ANY TYPE OF
SPILL TO DETERMINE LOCAL REPORTING REQUIREMENTS AND ALSO TO AID IN THE
CLEANUP.
| SECTION 16 OTHER INFORMATION | |
NFPA 704 NPCA-HMIS
HEALTH 1 1
FIRE 1 1
REACTIVITY 0 0
SPECIFIC HAZARD NONE N/A
PROTECTION INDEX N/A B
KEY:
0 = MINIMAL
1 = SLIGHT
2 = MODERATE
3 = SERIOUS
4 = SEVERE
VERSION: 1
INFORMATION PROVIDED IN THIS SDS IS CONSIDERED ACCURATE AND RELIABLE BASED
ON INFORMATION ISSUED FROM INTERNAL AND OUTSIDE SOURCES TO THE BEST OF THE
AUTHORS' KNOWLEDGE. HOWEVER, THE AUTHOR'S MAKE NO REPRESENTATIONS,
GUARANTEES, OR WARRANTIES, EXPRESSED OR IMPLIED. OF MERCHANTABILITY OR
FITNESS FOR THE PARTICULAR PURPOSE, REGARDING THE ACCURACY OF SUCH
INFORMATION OR THE RESULT TO BE OBTAINED FROM THE USE THEREOF, OR AS TO
THE SUFFICIENCY OF THE INFORMATION HEREIN PRESENTED. THE AUTHORS ASSUME
NO RESPONSIBILITY FOR INJURY TO RECIPIENT OR TO THIRD PERSONS OR FOR ANY
DAMAGE TO ANY PROPERTY AND RECIPIENT ASSUMES ALL SUCH RISKS.
REVISIONS / COMMENTS: NONE