| Common Name: | BRUSH ON ELECTRICAL TAPE BLACK 4 FL.OZ. |
| Manufacturer: | TECHNICAL CHEMICAL |
| SDS Revision Date: | 6/28/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 1MPX8 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
BLUEMAGIC(R*)
SINCE 1959
BRUSH ON ELECTRICAL TAPE BLACK 4 FL.OZ.
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY,
MARCH 26, 2012 / RULES AND REGULATIONS
REVISION DATE: 06/28/2016
SUPERSEDES: 10/08/2015
VERSION: 1.2
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
TRADE NAME: BRUSH ON ELECTRICAL TAPE BLACK 4 FL.OZ.
PRODUCT CODE: BOT55TRI
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES
ADVISED AGAINST:
USE OF THE SUBSTANCE/MIXTURE: BRUSH ON ELECTRICAL TAPE
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
TECHNICAL CHEMICAL COMPANY
P.O. BOX 139
CLEBURNE, TEXAS 76033
T: 817-645-6088
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC 24 HOUR: 1-800-424-9300, 1-703-527-3887 (INTERNATIONAL)
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
GHS-US CLASSIFICATION:
FLAM. LIQ. 2: H225
EYE IRRIT. 2A: H319
CARC. 2: H351
STOT SE 3: H336
FULL TEXT OF H STATEMENTS: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H319: CAUSES SERIOUS EYE IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H351: SUSPECTED OF CAUSING CANCER
PRECAUTIONARY STATEMENTS (GHS-US):
P201: OBTAIN SPECIAL INSTRUCTIONS
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P210: KEEP AWAY FROM HEAT,SPARKS,OPEN FLAMES,HOT SURFACES. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P261: AVOID BREATHING DUST,FUME,GAS,MIST,VAPOR SPRAY
P264: WASH AFFECTED AREAS THOROUGHLY AFTER HANDLING
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
P280:
WEAR PROTECTIVE GLOVES,PROTECTIVE CLOTHING,EYE PROTECTION,FACE PROTECTION
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION
P312: CALL A POISON CONTROL CENTER, DOCTOR, IF YOU FEEL UNWELL.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
P370+P378:
IN CASE OF FIRE: SEE SECTION 5.1 EXTINGUISHING MEDIA
P403+P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO APPROPRIATE WASTE DISPOSAL FACILITY,
IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL, INTERNATIONAL REGULATIONS.
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % GHS-US CLASSIFICATION
METHYL ACETATE (CAS NO) 79-20-9 30 - 40 FLAM. LIQ. 2, H225
STOT SE 3, H336
ACETONE (CAS NO) 67-64-1 25 - 35 FLAM. LIQ. 2, H225
EYE IRRIT. 2A, H319
STOT SE 3, H336
POLYMER OF VINYL (CAS NO) 28086-69-3 20 - 30 NOT CLASSIFIED
ACETATE AND VINYL
CHLORIDE
DIISONONYL (CAS NO) 28553-12-0 1 - 10 NOT CLASSIFIED
PHTHALATE
TALC (CAS NO) 14807-96-6 1 - 5 NOT CLASSIFIED
CARBON BLACK (CAS NO) 1333-86-4 1 - 5 CARC. 2, H351
METHANOL (CAS NO) 67-56-1 <0.1 FLAM. LIQ. 2, H225
ACUTE TOX. 3 (ORAL),
H301
ACUTE TOX. 3 (DERMAL),
H311
ACUTE TOX. 3
INHALATION:
DUST, MIST),
H331
STOT SE 1, H370
THE EXACT PERCENTAGE IS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE). SUSPECTED OF CAUSING
CANCER.
FIRST-AID MEASURES AFTER INHALATION:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE SKIN WITH WATER/SHOWER. REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED
CLOTHING.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES: IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE.
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
MAY CAUSE SLIGHT IRRITATION . ITCHING. RED SKIN. SKIN RASH/INFLAMMATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
INFLAMMATION/DAMAGE OF THE EYE TISSUE. IRRITATION OF THE EYE TISSUE.
REDNESS OF THE EYE TISSUE. CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS. MAY BE FATAL IF SWALLOWED
AND ENTERS AIRWAYS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE
CAUTION WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING
WATER FROM ENTERING ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO OPEN FLAMES. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: GLOVES. SAFETY GLASSES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING DUST, FUME, GAS,
MIST, VAPOR SPRAY.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. DAM UP THE
LIQUID SPILL. PLUG THE LEAK, CUT OFF THE SUPPLY.
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH
AS SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO OPEN FLAMES. NO SMOKING.
USE ONLY NON-SPARKING TOOLS. OBTAIN SPECIAL INSTRUCTIONS . DO NOT HANDLE
UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. AVOID BREATHING
DUST,FUME,GAS,MIST,VAPOR SPRAY. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA.
HYGIENE MEASURES:
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. CONTAMINATED WORK
CLOTHING SHOULD NOT BE ALLOWED OUT OF THE WORKPLACE. WASH CONTAMINATED
CLOTHING BEFORE REUSE. WASH AFFECTED AREAS THOROUGHLY AFTER HANDLING.
REMOVE CONTAMINATED CLOTHES. SEPARATE WORKING CLOTHES FROM TOWN CLOTHES.
LAUNDER SEPARATELY. WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND
WATER BEFORE EATING, DRINKING OR SMOKING AND WHEN LEAVING WORK.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM:
KEEP IN FIREPROOF PLACE. KEEP CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG BASES. STRONG ACIDS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
7.3. SPECIFIC END USE(S): FOLLOW LABEL DIRECTIONS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
METHANOL (67-56-1):
USA ACGIH ACGIH TWA (MG/M3) 262 MG/M3
USA ACGIH ACGIH TWA (PPM) 200 PPM (METHANOL; USA;
TIME-WEIGHTED AVERAGE EXPOSURE
LIMIT 8 H; TLV - ADOPTED VALUE)
USA ACGIH ACGIH STEL (MG/M3) 328 MG/M3
USA ACGIH ACGIH STEL (PPM) 250 PPM
USA OSHA OSHA PEL (TWA) (MG/M3) 260 MG/M3
USA OSHA OSHA PEL (TWA) (PPM) 200 PPM
BENZENE (71-43-2):
USA ACGIH ACGIH TWA (PPM) 1 PPM
USA ACGIH ACGIH STEL (PPM) 5 PPM
USA ACGIH ACGIH CEILING (PPM) 25 PPM
USA OSHA OSHA PEL (TWA) (PPM) 1 PPM
USA OSHA OSHA PEL (CEILING) (PPM) 5 PPM
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
LOCAL EXHAUST VENILATION, VENT HOODS . ENSURE GOOD VENTILATION OF THE WORK
STATION.
PERSONAL PROTECTIVE EQUIPMENT:
SAFETY GLASSES. GLOVES. AVOID ALL UNNECESSARY EXPOSURE.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
WHERE EXPOSURE THROUGH INHALATION MAY OCCUR FROM USE, RESPIRATORY
PROTECTION EQUIPMENT IS RECOMMENDED.
CONSUMER EXPOSURE CONTROLS: AVOID CONTACT DURING PREGNANCY/WHILE NURSING.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: LIQUID PASTE.
COLOR: BLACK.
ODOR: KETONES.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 56 - 58 DEG. C
FLASH POINT: -17.2 DEG. C
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: 216.2 MM Hg @ 25 DEG C
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: 0.88 - 0.92
SOLUBILITY: INSOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
EXPLOSION LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION:
VOC CONTENT: 15.008 G/L
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY:
HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
TOXIC FUME. . CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE GASES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
METHANOL (67-56-1):
LD50 ORAL RAT:
>=2528 MG/KG BODY WEIGHT APPLICATION AS 50% AQUEOUS SOLUTION
LD50 DERMAL RABBIT:
17100 MG/KG CORRESPONDING TO 20 ML/KG BW ACCORDING TO THE AUTHORS
LC50 INHALATION RAT (MG/L): 128.2 MG/L/4H AIR
BENZENE (71-43-2):
LD50 ORAL RAT:
>930 MG/KG (RAT; EQUIVALENT OR SIMILAR TO OECD 401; LITERATURE STUDY;
>2000 MG/KG BODYWEIGHT; RAT; EXPERIMENTAL VALUE)
LD50 DERMAL RABBIT:
>8240 MG/KG (RABBIT; EXPERIMENTAL VALUE; 21 CFR 191.10; >9.4; RABBIT)
LC50 INHALATION RAT (MG/L): 43.767 MG/L/4H (RAT; EXPERIMENTAL VALUE)
LC50 INHALATION RAT (PPM): 13700 PPM/4H (RAT; EXPERIMENTAL VALUE)
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY:
NOT CLASSIFIED BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA
ARE NOT MET
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
BENZENE (71-43-2):
IARC GROUP: 1
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/INJURIES AFTER INHALATION: MAY CAUSE DROWSINESS OR DIZZINESS.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
MAY CAUSE SLIGHT IRRITATION. ITCHING. RED SKIN. SKIN RASH/INFLAMMATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
INFLAMMATION/DAMAGE OF THE EYE TISSUE. IRRITATION OF THE EYE TISSUE.
REDNESS OF THE EYE TISSUE. CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS. MAY BE FATAL IF SWALLOWED
AND ENTERS AIRWAYS.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
METHANOL (67-56-1):
LC50 FISH 1:
15400 MG/L (LC50; EPA 660/3 - 75/009; 96 H; LEPOMIS MACROCHIRUS;
FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
EC50 DAPHNIA 1:
>10000 MG/L (EC50; DIN 38412-11; 48 H; DAPHNIA MAGNA; STATIC SYSTEM;
FRESH WATER; EXPERIMENTAL VALUE)
LC50 FISH 2: 10800 MG/L (LC50; 96 H; SALMO GAIRDNERI)
BENZENE (71-43-2):
LC50 FISH 1: 5.3 MG/L (LC50; 96 H; SALMO GAIRDNERI)
EC50 DAPHNIA 2:
10 MG/L (EC50; OECD 202: DAPHNIA SP. ACUTE IMMOBILISATION TEST; 48 H;
DAPHNIA MAGNA)
THRESHOLD LIMIT ALGAE 1:
100 MG/L (ERC50; OECD 201: ALGA, GROWTH INHIBITION TEST; 72 H;
PSEUDOKIRCHNERIELLA SUBCAPITATA; STATIC SYSTEM; FRESH WATER;
EXPERIMENTAL VALUE)
ACETONE (67-64-1):
EC50 DAPHNIA 2:
12600 MG/L (LC50; OTHER; 48 H; DAPHNIA MAGNA; STATIC SYSTEM; FRESH WATER;
EXPERIMENTAL VALUE)
12.2. PERSISTENCE AND DEGRADABILITY:
BRUSH ON ELECTRICAL TAPE BLACK 4 FL.OZ.:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
METHANOL (67-56-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. HIGHLY MOBILE
IN SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 0.6 - 1.12 G O2 /G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 1.42 G O2 /G SUBSTANCE
THOD: 1.5 G O2 /G SUBSTANCE
BOD (% OF THOD): 0.8 (LITERATURE STUDY)
BENZENE (71-43-2):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. OZONATION IN WATER. FORMING SEDIMENTS
IN WATER. BIODEGRADABLE IN THE SOIL. LOW POTENTIAL FOR ADSORPTION IN
SOIL. PHOTOLYSIS IN THE AIR.
BIOCHEMICAL OXYGEN DEMAND (BOD): 2.18 G O2 /G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.15 G O2 /G SUBSTANCE
THOD: 3.10 G O2 /G SUBSTANCE
BOD (% OF THOD): 0.70
ACETONE (67-64-1):
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
12.3. BIOACCUMULATIVE POTENTIAL:
BRUSH ON ELECTRICAL TAPE BLACK 4 FL.OZ.:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
METHANOL (67-56-1):
BCF FISH 1: < 10 (BCF; 72 H; LEUCISCUS IDUS)
LOG POW: -0.77 (EXPERIMENTAL VALUE; OTHER)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
BENZENE (71-43-2):
BCF FISH 1: 19 (BCF)
BCF FISH 2:
<10 (BCF; OECD 305: BIOCONCENTRATION: FLOW-THROUGH FISH TEST; 3 DAYS;
LEUCISCUS IDUS; FLOW-THROUGH SYSTEM; FRESH WATER; EXPERIMENTAL VALUE)
BCF OTHER AQUATIC ORGANISMS 1: 30 (BCF; 24 H; CHLORELLA SP.)
LOG POW: 2.13 (EXPERIMENTAL VALUE)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
ACETONE (67-64-1):
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
12.4. MOBILITY IN SOIL:
METHANOL (67-56-1):
SURFACE TENSION: 0.023 N/M (20 DEG. C)
LOG KOC: KOC,PCKOCWIN V1.66; 1; CALCULATED VALUE
BENZENE (71-43-2):
SURFACE TENSION: 0.029 N/M (20 DEG. C)
LOG KOC: KOC,134.1; QSAR
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO APPROPRIATE WASTE DISPOSAL FACILITY, IN
ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL, INTERNATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH ADR / RID / IMDG / IATA / ADN:
US DOT (GROUND): UN1866, RESIN SOLUTION, 3, II, LIMITED QUANTITY
ICAO/IATA (AIR): UN1866, RESIN SOLUTION, 3 , II, LIMITED QUANTITY
IMO/IMDG (WATER): UN1866, RESIN SOLUTION, 3 , II, LIMITED QUANTITY
SPECIAL PROVISIONS:
149:
WHEN TRANSPORTED AS A LIMITED QUANTITY OR A CONSUMER COMMODITY, THE
MAXIMUM NET CAPACITY SPECIFIED IN 173.150(B)(2) OF THIS SUBCHAPTER
FOR INNER PACKAGING MAY BE INCREASED TO 5 L (1.3 GALLONS)
B52:
NOTWITHSTANDING THE PROVISIONS OF 173.24B OF THIS SUBCHAPTER, NON-RECLOSING
PRESSURE RELIEF DEVICES ARE AUTHORIZED ON DOT 57 PORTABLE TANKS
IB2:
AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE
(31HZ1).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED
T4: 2.65 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1:
THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING:
DEGREE OF FILLING = 97 / 1 + A (TR - TF) WHERE:
TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS THE
TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING
TP8:
A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 1.5 BAR (150 KPA) MAY BE
USED WHEN THE FLASH POINT OF THE HAZARDOUS MATERIAL TRANSPORTED IS GREATER
THAN 0 C (32 F)
14.2. UN PROPER SHIPPING NAME:
PROPER SHIPPING NAME (DOT):
RESIN SOLUTION
FLAMMABLE
CLASS (DOT): 3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
PACKING GROUP (DOT): II - MEDIUM DANGER
DOT SPECIAL PROVISIONS (49 CFR 172.102):
149:
WHEN TRANSPORTED AS A LIMITED QUANTITY OR A CONSUMER COMMODITY, THE MAXIMUM
NET CAPACITY SPECIFIED IN 173.150(B)(2) OF THIS SUBCHAPTER FOR INNER
PACKAGING MAY BE INCREASED TO 5 L (1.3 GALLONS)
B52:
NOTWITHSTANDING THE PROVISIONS OF 173.24B OF THIS SUBCHAPTER, NON-RECLOSING
PRESSURE RELIEF DEVICES ARE AUTHORIZED ON DOT 57 PORTABLE TANKS
IB2:
AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE
(31HZ1).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED
T4: 2.65 178.274(D)(2) NORMAL............. 178.275(D)(3)
TP1:
THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING:
DEGREE OF FILLING = 97 / 1 + A (TR - TF) WHERE:
TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS THE
TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING
TP8:
A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 1.5 BAR (150 KPA) MAY BE
USED WHEN THE FLASH POINT OF THE HAZARDOUS MATERIAL TRANSPORTED IS GREATER
THAN 0 C (32 F)
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 150
DOT PACKAGING NON BULK (49 CFR 173.XXX): 173
DOT PACKAGING BULK (49 CFR 173.XXX): 242
14.3. ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
OVERLAND TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
TRANSPORT BY SEA:
DOT VESSEL STOWAGE LOCATION:
B:
(I) THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL CARRYING A NUMBER OF PASSENGERS LIMITED TO NOT
MORE THAN THE LARGER OF 25 PASSENGERS, OR ONE PASSENGER PER EACH 3 M OF
OVERALL VESSEL LENGTH; AND (II) "ON DECK ONLY" ON PASSENGER VESSELS IN
WHICH THE NUMBER OF PASSENGERS SPECIFIED IN PARAGRAPH (K)(2)(I) OF THIS
SECTION IS EXCEEDED
AIR TRANSPORT:
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
BRUSH ON ELECTRICAL TAPE BLACK 4 FL.OZ.:
SARA SECTION 311/312 HAZARD CLASSES:
DELAYED (CHRONIC) HEALTH HAZARD
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
METHANOL (67-56-1):
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
LISTED ON THE UNITED STATES SARA SECTION 302
LISTED ON THE UNITED STATES SARA SECTION 355
SARA SECTION 311/312 HAZARD CLASSES:
IMMEDIATE (ACUTE) HEALTH HAZARD
DELAYED (CHRONIC) HEALTH HAZARD
FIRE HAZARD
BENZENE (71-43-2):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
SUBJECT TO REPORTING REQUIREMENTS OF UNITED STATES SARA SECTION 313
15.2. INTERNATIONAL REGULATIONS:
CANADA:
BRUSH ON ELECTRICAL TAPE BLACK 4 FL.OZ.:
WHMIS CLASSIFICATION: CLASS B DIVISION 2 - FLAMMABLE LIQUID
METHANOL (67-56-1):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST):
WHMIS CLASSIFICATION:
CLASS B DIVISION 2 - FLAMMABLE LIQUID
CLASS D DIVISION 1 SUBDIVISION B - TOXIC MATERIAL CAUSING IMMEDIATE
AND SERIOUS TOXIC EFFECTS
CLASS D DIVISION 2 SUBDIVISION A - VERY TOXIC MATERIAL CAUSING OTHER
TOXIC EFFECTS
CLASS D DIVISION 2 SUBDIVISION B - TOXIC MATERIAL CAUSING OTHER TOXIC
EFFECTS
BENZENE (71-43-2):
LISTED ON THE CANADIAN DSL (DOMESTIC SUBSTANCES LIST)
EU-REGULATIONS:
METHANOL (67-56-1):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
BENZENE (71-43-2):
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC [DSD] OR 1999/45/EC [DPD]:
F+; R12
XI; R36
R66
R67
FULL TEXT OF R-PHRASES: SEE SECTION 16
15.2.2. NATIONAL REGULATIONS:
METHANOL (67-56-1):
LISTED ON THE CANADIAN IDL (INGREDIENT DISCLOSURE LIST)
BENZENE (71-43-2):
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON KECI (KOREAN EXISTING CHEMICALS INVENTORY)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
15.3. US STATE REGULATIONS:
BRUSH ON ELECTRICAL TAPE BLACK 4 FL.OZ.:
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
STATE OR LOCAL REGULATIONS:
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL)
METHANOL (67-56-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NON-SIGNIFICANT RISK LEVEL (NSRL):
BENZENE (71-43-2):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: YES
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: YES
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: YES
NON-SIGNIFICANT RISK LEVEL (NSRL):
ACETONE (67-64-1):
U.S. - CALIFORNIA - PROPOSITION 65 - CARCINOGENS LIST: NO
U.S. - CALIFORNIA - PROPOSITION 65 - DEVELOPMENTAL TOXICITY: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - FEMALE: NO
U.S. - CALIFORNIA - PROPOSITION 65 - REPRODUCTIVE TOXICITY - MALE: NO
NON-SIGNIFICANT RISK LEVEL (NSRL):
METHANOL (67-56-1):
STATE OR LOCAL REGULATIONS:
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL)
NEW JERSEY RIGHT-TO-KNOW
FLORIDA RIGHT TO KNOW
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
BENZENE (71-43-2):
STATE OR LOCAL REGULATIONS:
U.S. - CALIFORNIA - PROPOSITION 65 - MAXIMUM ALLOWABLE DOSE LEVELS (MADL)
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
NEW JERSEY RIGHT-TO-KNOW
| SECTION 16: OTHER INFORMATION | |
INDICATION OF CHANGES:
REVISION - SEE: *.
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H301: TOXIC IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H319: CAUSES SERIOUS EYE IRRITATION
H331: TOXIC IF INHALED
H336: MAY CAUSE DROWSINESS OR DIZZINESS
H351: SUSPECTED OF CAUSING CANCER
H370: CAUSES DAMAGE TO ORGANS
NFPA HEALTH HAZARD 2 - INTENSE OR CONTINUED EXPOSURE COULD CAUSE TEMPORARY
INCAPACITATION OR POSSIBLE RESIDUAL INJURY UNLESS
PROMPT MEDICAL ATTENTION IS GIVEN.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT CONDITIONS.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
HMIS III RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 3 SERIOUS HAZARD
PHYSICAL 0 MINIMAL HAZARD
PERSONAL PROTECTION B
SDS US (GHS HAZCOM 2012) - TCC
THE SUPPLIER IDENTIFIED IN SECTION 1 OF THIS MSDS HAS EVALUATED THIS
PRODUCT AND CERTIFIES IT TO BE LABELED AND PACKAGED IN COMPLIANCE WITH THE
APPLICABLE PROVISIONS OF THE FEDERAL HAZARDOUS SUBSTANCE ACT AS STATED IN
16 CFR 1500 AND ENFORCED BY THE CONSUMER PRODUCT SAFETY COMMISSION, AND
WHERE APPLICABLE THE PRODUCTS THAT REQUIRE CHILD RESISTANT CLOSURES ARE
PACKAGED IN ACCORDANCE WITH THE POISON PREVENTION PACKAGING ACT AS STATED
IN 16 CFR 1700 AND ENFORCED BY THE CONSUMER PRODUCT SAFETY COMMISSION. ALL
CLOSURES HAVE BEEN TESTED IN ACCORDANCE WITH THE LATEST PROTOCOLS. NO OTHER
TESTING IS REQUIRED TO CERTIFY COMPLIANCE WITH THE ABOVE. THE DATE OF
MANUFACTURE IS STAMPED ON THE PRODUCT
DISCLAIMER:
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON TESTS
BELIEVED TO BE RELIABLE. HOWEVER, THE MANUFACTURER/DISTRIBUTOR OF THIS
PRODUCT DOES NOT GUARANTEE THEIR ACCURACY OR COMPLETENESS NOR SHALL ANY OF
THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS
TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE
FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. ADJUSTMENT TO CONFORM TO
ACTUAL CONDITIONS OF USAGE MAY BE REQUIRED. THE MANUFACTURER/DISTRIBUTOR
ASSUMES NO RESPONSIBILITY FOR RESULTS OBTAINED OR FOR INCIDENTAL OR
CONSEQUENTIAL DAMAGES, INCLUDING LOST PROFITS, ARISING FROM THE USE OF
THESE DATA. NO WARRANTY AGAINST INFRINGEMENT OF ANY PATENT, COPYRIGHT OR
TRADEMARK IS MADE OR IMPLIED.
EN (ENGLISH US)