| Common Name: | BRUSH ON ELECTRICAL TAPE RED 4 FL.OZ. |
| Manufacturer: | TECHNICAL CHEMICAL |
| SDS Revision Date: | 11/10/2014 |
| SDS Format: | GHS-US |
| Item Number(s): | 1MPY2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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JOHNSEN'S(R*)
BRUSH ON ELECTRICAL TAPE RED 4 FL.OZ.
SAFETY DATA SHEET
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY, MARCH 26, 2012 /
RULES AND REGULATIONS
REVISION DATE: 11/10/2014
VERSION:
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
TRADE NAME: BRUSH ON ELECTRICAL TAPE RED 4 FL.OZ.
PRODUCT CODE: BOT58TRI
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: BRUSH ON ELECTRICAL TAPE
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
TECHNICAL CHEMICAL COMPANY
P.O. BOX 139
CLEBURNE, TEXAS 76033
T: 817-645-6088
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC 24 HOUR: 1-800-424-9300, 1-703-527-3887 (INTERNATIONAL)
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
FLAM. LIQ. 2: H225
EYE IRRIT. 2A: H319
STOT SE 3: H335
STOT SE 3: H336
FULL TEXT OF H-PHRASES: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS02: FLAME
GHS07: EXCLAMATION MARK
SIGNAL WORD (GHS-US): DANGER
HAZARD STATEMENTS (GHS-US):
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H319: CAUSES SERIOUS EYE IRRITATION
H335: MAY CAUSE RESPIRATORY IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
PRECAUTIONARY STATEMENTS (GHS-US):
P210: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAMES, HOT SURFACES. - NO SMOKING
P233: KEEP CONTAINER TIGHTLY CLOSED
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT
P241: USE EXPLOSION-PROOF ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT
P242: USE ONLY NON-SPARKING TOOLS
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE
P261: AVOID BREATHING DUST, FUME, GAS, MIST, VAPOR SPRAY
P264: WASH AFFECTED AREAS THOROUGHLY AFTER HANDLING
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
P280:
WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION, FACE
PROTECTION
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING
P305+P351+P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING
P312: CALL A POISON CONTROL CENTER, DOCTOR, IF YOU FEEL UNWELL.
P337+P313:
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION
P370+P378:
IN CASE OF FIRE: SEE SECTION 5.1 EXTINGUISHING MEDIA
P403+P233: STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL
P405: STORE LOCKED UP
P501:
DISPOSE OF CONTENTS/CONTAINER TO APPROPRIATE WASTE DISPOSAL FACILITY, IN
ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL, INTERNATIONAL REGULATIONS.
2.3. OTHER HAZARDS:
OTHER HAZARDS NOT CONTRIBUTING TO THE CLASSIFICATION:
NONE UNDER NORMAL CONDITIONS.
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NO DATA AVAILABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % CLASSIFICATION (GHS-US)
METHYL ETHYL (CAS NO): 78-93-3 35 - 45 FLAM. LIQ. 2, H225
KETONE EYE IRRIT. 2A, H319
STOT SE 3, H336
METHYL ISOBUTYL (CAS NO): 108-10-1 25 - 35 FLAM. LIQ. 2, H225
KETONE ACUTE TOX. 3
(INHALATION: GAS), H331
EYE IRRIT. 2A, H319
STOT SE 3, H335
CYCLOHEXANONE (CAS NO): 108-94-1 2 - 6 FLAM. LIQ. 3, H226
ACUTE TOX. 4 (ORAL), H302
ACUTE TOX. 3 (DERMAL), H311
ACUTE TOX. 4 (INHALATION),
H332
CHROMIUM (III) (CAS NO): 1308-38-9 0 - 1 NOT CLASSIFIED
OXIDE
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
REMOVE TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING. CALL A POISON CENTER/DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
FIRST-AID MEASURES AFTER SKIN CONTACT:
RINSE SKIN WITH WATER/SHOWER. REMOVE/TAKE OFF IMMEDIATELY ALL CONTAMINATED
CLOTHING.
FIRST-AID MEASURES AFTER EYE CONTACT:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
FIRST-AID MEASURES AFTER INGESTION:
RINSE MOUTH. DO NOT INDUCE VOMITING. OBTAIN EMERGENCY MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES: IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE.
SYMPTOMS/INJURIES AFTER INHALATION:
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
MAY CAUSE SLIGHT IRRITATION. ITCHING. RED SKIN. SKIN RASH/INFLAMMATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
IRRITATION OF THE EYE TISSUE. INFLAMMATION/DAMAGE OF THE EYE TISSUE.
REDNESS OF THE EYE TISSUE. CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS. MAY BE FATAL IF SWALLOWED
AND ENTERS AIRWAYS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
FOAM. DRY POWDER. CARBON DIOXIDE. WATER SPRAY. SAND.
UNSUITABLE EXTINGUISHING MEDIA: DO NOT USE A HEAVY WATER STREAM.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: HIGHLY FLAMMABLE LIQUID AND VAPOR.
EXPLOSION HAZARD: MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR MIXTURE.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE CAUTION
WHEN FIGHTING ANY CHEMICAL FIRE. PREVENT FIRE-FIGHTING WATER FROM ENTERING
ENVIRONMENT.
PROTECTION DURING FIREFIGHTING:
DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTIVE EQUIPMENT, INCLUDING
RESPIRATORY PROTECTION.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES:
REMOVE IGNITION SOURCES. USE SPECIAL CARE TO AVOID STATIC ELECTRIC CHARGES.
NO NAKED LIGHTS. NO SMOKING.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT: GLOVES. SAFETY GLASSES.
EMERGENCY PROCEDURES: EVACUATE UNNECESSARY PERSONNEL.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
EQUIP CLEANUP CREW WITH PROPER PROTECTION. AVOID BREATHING DUST, FUME, GAS,
MIST, VAPOR SPRAY.
EMERGENCY PROCEDURES: VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS:
PREVENT ENTRY TO SEWERS AND PUBLIC WATERS. NOTIFY AUTHORITIES IF LIQUID
ENTERS SEWERS OR PUBLIC WATERS.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT:
CONTAIN RELEASED SUBSTANCE, PUMP INTO SUITABLE CONTAINERS. PLUG THE LEAK,
CUT OFF THE SUPPLY. DAM UP THE LIQUID SPILL.
METHODS FOR CLEANING UP:
SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR DIATOMACEOUS EARTH AS
SOON AS POSSIBLE. COLLECT SPILLAGE. STORE AWAY FROM OTHER MATERIALS.
6.4. REFERENCE TO OTHER SECTIONS:
SEE HEADING 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
PRECAUTIONS FOR SAFE HANDLING:
WASH HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK. PROVIDE GOOD VENTILATION IN
PROCESS AREA TO PREVENT FORMATION OF VAPOR. NO NAKED LIGHTS. NO SMOKING.
USE ONLY NON-SPARKING TOOLS. AVOID BREATHING DUST, FUME, GAS, MIST, VAPOR
SPRAY. USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
HYGIENE MEASURES:
WASH AFFECTED AREAS THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR SMOKE
WHEN USING THIS PRODUCT. WASH CONTAMINATED CLOTHING BEFORE REUSE. WASH
HANDS AND OTHER EXPOSED AREAS WITH MILD SOAP AND WATER BEFORE EATING,
DRINKING OR SMOKING AND WHEN LEAVING WORK.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES:
PROPER GROUNDING PROCEDURES TO AVOID STATIC ELECTRICITY SHOULD BE FOLLOWED.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT. USE EXPLOSION-PROOF
ELECTRICAL, VENTILATING, LIGHTING EQUIPMENT.
STORAGE CONDITIONS:
KEEP ONLY IN THE ORIGINAL CONTAINER IN A COOL, WELL VENTILATED PLACE AWAY
FROM: KEEP IN FIREPROOF PLACE. KEEP CONTAINER TIGHTLY CLOSED.
INCOMPATIBLE PRODUCTS: STRONG BASES. STRONG ACIDS.
INCOMPATIBLE MATERIALS: SOURCES OF IGNITION. DIRECT SUNLIGHT. HEAT SOURCES.
7.3. SPECIFIC END USE(S): FOLLOW LABEL DIRECTIONS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
METHYL ETHYL KETONE (78-93-3):
USA ACGIH:
ACGIH TWA (PPM): 200 PPM
USA ACGIH:
ACGIH STEL (PPM): 200 PPM
METHYL ISOBUTYL KETONE (108-10-1):
USA ACGIH:
ACGIH TWA (PPM): 20 PPM
USA ACGIH:
ACGIH STEL (PPM): 20 PPM
CYCLOHEXANONE (108-94-1):
USA ACGIH:
ACGIH TWA (PPM): 20 PPM
USA ACGIH:
ACGIH STEL (PPM): 20 PPM
CHROMIUM (III) OXIDE (1308-38-9):
USA ACGIH:
ACGIH TWA (MG/M3): 0.5 MG/M3
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS: LOCAL EXHAUST VENTILATION, VENT HOODS.
PERSONAL PROTECTIVE EQUIPMENT:
AVOID ALL UNNECESSARY EXPOSURE. GLOVES. SAFETY GLASSES.
HAND PROTECTION: WEAR PROTECTIVE GLOVES.
EYE PROTECTION: CHEMICAL GOGGLES OR SAFETY GLASSES.
SKIN AND BODY PROTECTION: WEAR SUITABLE PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
WHERE EXPOSURE THROUGH INHALATION MAY OCCUR FROM USE, RESPIRATORY
PROTECTION EQUIPMENT IS RECOMMENDED.
OTHER INFORMATION: DO NOT EAT, DRINK OR SMOKE DURING USE.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: LIQUID PASTE.
COLOR: RED.
ODOR: KETONES.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: 80 DEG. C
FLASH POINT: -5 DEG. C
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
VAPOR PRESSURE: NO DATA AVAILABLE
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: 0.88 - 0.92
SOLUBILITY: INSOLUBLE IN WATER.
LOG POW: NO DATA AVAILABLE
LOG KOW: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
EXPLOSIVE PROPERTIES: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
EXPLOSIVE LIMITS: NO DATA AVAILABLE
9.2. OTHER INFORMATION: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NO ADDITIONAL INFORMATION AVAILABLE
10.2. CHEMICAL STABILITY:
HIGHLY FLAMMABLE LIQUID AND VAPOR. MAY FORM FLAMMABLE/EXPLOSIVE VAPOR-AIR
MIXTURE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS: NOT ESTABLISHED.
10.4. CONDITIONS TO AVOID:
DIRECT SUNLIGHT. EXTREMELY HIGH OR LOW TEMPERATURES. OPEN FLAME.
10.5. INCOMPATIBLE MATERIALS: STRONG ACIDS. STRONG BASES.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
TOXIC FUME. CARBON MONOXIDE. CARBON DIOXIDE. MAY RELEASE FLAMMABLE GASES.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
METHYL ETHYL KETONE (78-93-3):
LD50 ORAL RAT:
2737 MG/KG (RAT; EQUIVALENT OR SIMILAR TO OECD 423; READ-ACROSS;
2054 MG/KG; RAT; EQUIVALENT OR SIMILAR TO OECD 423; READ-ACROSS;
2328 MG/KG; RAT)
LD50 DERMAL RABBIT:
6480 MG/KG (RABBIT; EXPERIMENTAL VALUE; EQUIVALENT OR SIMILAR TO OECD 402;
>10; RABBIT)
LC50 INHALATION RAT (MG/L): 34 MG/L/4H (RAT; LITERATURE STUDY)
LC50 INHALATION RAT (PPM): 11300 PPM/4H (RAT; LITERATURE STUDY)
METHYL ISOBUTYL KETONE (108-10-1):
LD50 ORAL RAT:
2080 MG/KG (RAT; EQUIVALENT OR SIMILAR TO OECD 401; EXPERIMENTAL VALUE)
LD50 DERMAL RAT:
>=2000 MG/KG BODY WEIGHT (RAT; EXPERIMENTAL VALUE; OECD 402: ACUTE DERMAL
TOXICITY)
LD50 DERMAL RABBIT: >16000 MG/KG (RABBIT)
LC50 INHALATION RAT (MG/L): 8.2 - 16.4, RAT; EXPERIMENTAL VALUE
LC50 INHALATION RAT (PPM):
2000 PPM/4H (RAT; EXPERIMENTAL VALUE, RAT; EXPERIMENTAL VALUE)
CYCLOHEXANONE (108-94-1):
LD50 ORAL RAT:
1535 MG/KG (RAT; BASF TEST; EXPERIMENTAL VALUE; 2650 MG/KG BODYWEIGHT; RAT)
LD50 DERMAL RABBIT: 948 MG/KG (RABBIT)
LC50 INHALATION RAT (MG/L): 11 MG/L/4H (RAT)
LC50 INHALATION RAT (PPM): 2639 PPM/4H (RAT)
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
SERIOUS EYE DAMAGE/IRRITATION: CAUSES SERIOUS EYE IRRITATION.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
CYCLOHEXANONE (108-94-1):
IARC GROUP: 3
CHROMIUM (III) OXIDE (1308-38-9):
IARC GROUP: 3
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE):
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
POTENTIAL ADVERSE HUMAN HEALTH EFFECTS AND SYMPTOMS:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SYMPTOMS/INJURIES AFTER INHALATION:
MAY CAUSE RESPIRATORY IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
MAY CAUSE SLIGHT IRRITATION. ITCHING. RED SKIN. SKIN RASH/INFLAMMATION.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
IRRITATION OF THE EYE TISSUE. INFLAMMATION/DAMAGE OF THE EYE TISSUE.
REDNESS OF THE EYE TISSUE. CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS/INJURIES AFTER INGESTION:
MAY BE HARMFUL IF SWALLOWED AND ENTERS AIRWAYS. MAY BE FATAL IF SWALLOWED
AND ENTERS AIRWAYS.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
METHYL ETHYL KETONE (78-93-3):
LC50 FISH 1: 1690 MG/L (96 H; LEPOMIS MACROCHIRUS; LETHAL)
EC50 DAPHNIA 1: 308 MG/L (48 H; DAPHNIA MAGNA; LOCOMOTOR EFFECT)
LC50 FISH 2: 2990 MG/L (96 H; PIMEPHALES PROMELAS)
TLM FISH 1: 5600 MG/L (96 H; GAMBUSIA AFFINIS)
TLM FISH 2: 1690 MG/L (96 H; LEPOMIS MACROCHIRUS)
TLM OTHER AQUATIC ORGANISMS 1: >1000 PPM (96 H)
THRESHOLD LIMIT ALGAE 1: 110 MG/L (168 H; MICROCYSTIS AERUGINOSA)
THRESHOLD LIMIT ALGAE 2: 4300 MG/L (192 H; SCENEDESMUS QUADRICAUDA)
METHYL ISOBUTYL KETONE (108-10-1):
LC50 FISH 1: 505 MG/L (96 H; PIMEPHALES PROMELAS; GLP)
EC50 DAPHNIA 1: 170 MG/L (48 H; DAPHNIA MAGNA; STATIC SYSTEM)
EC50 OTHER AQUATIC ORGANISMS 1:
400 MG/L (96 H; SELENASTRUM CAPRICORNUTUM; GROWTH RATE)
LC50 FISH 2: 600 MG/L 96 H; SALMO GAIRDNERI (ONCORHYNCHUS MYKISS)
EC50 DAPHNIA 2: >1000 MG/L (48 H; DAPHNIA MAGNA; GLP)
THRESHOLD LIMIT ALGAE 1: 136 MG/L (MICROCYSTIS AERUGINOSA)
THRESHOLD LIMIT ALGAE 2:
725 MG/L (8 DAYS; SCENEDESMUS QUADRICAUDA; NOMINAL CONCENTRATION)
CYCLOHEXANONE (108-94-1):
LC50 FISH 1: 527 - 732 MG/L (96 H; PIMEPHALES PROMELAS)
LC50 OTHER AQUATIC ORGANISMS 1: 10 - 100 MG/L (96 H)
EC50 DAPHNIA 1: 820 MG/L (24 H; DAPHNIA MAGNA; GLP)
LC50 FISH 2: 536 MG/L (48 H; LEUCISCUS IDUS)
EC50 DAPHNIA 2: >100 MG/L (48 H; DAPHNIA MAGNA)
TLM FISH 1: 10 - 100,96 H; PISCES
TLM OTHER AQUATIC ORGANISMS 1: 10 - 100,96 H
THRESHOLD LIMIT OTHER AQUATIC ORGANISMS 1: 10 - 100,96 H
THRESHOLD LIMIT ALGAE 1: 52 MG/L (192 H; MICROCYSTIS AERUGINOSA)
THRESHOLD LIMIT ALGAE 2: 370 MG/L (192 H; SCENEDESMUS QUADRICAUDA)
CHROMIUM (III) OXIDE (1308-38-9):
LC50 FISH 1: >0.0029 MG/L (96 H; BRACHYDANIO RERIO; MEASURED CONCENTRATION)
LC50 FISH 2: >=10000 MG/L (96 H; BRACHYDANIO RERIO; NOMINAL CONCENTRATION)
TLM FISH 1: >1000 MG/L (LEUCISCUS IDUS; NOMINAL CONCENTRATION)
12.2. PERSISTENCE AND DEGRADABILITY:
BRUSH ON ELECTRICAL TAPE RED 4 FL.OZ.:
PERSISTENCE AND DEGRADABILITY: NOT ESTABLISHED.
METHYL ETHYL KETONE (78-93-3):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN
THE SOIL UNDER ANAEROBIC CONDITIONS.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.92 G O2 /G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.31 G O2 /G SUBSTANCE
THOD: 2.44 G O2/G SUBSTANCE
BOD (% OF THOD): >% THOD (5 DAY(S)) >0.5
METHYL ISOBUTYL KETONE (108-10-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. BIODEGRADABLE IN
THE SOIL UNDER ANAEROBIC CONDITIONS. LOW POTENTIAL FOR ADSORPTION IN SOIL.
PHOTOLYSIS IN THE AIR.
BIOCHEMICAL OXYGEN DEMAND (BOD): 2.06 G O2 /G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.16 G O2 /G SUBSTANCE
THOD: 2.72 G O2 /G SUBSTANCE
BOD (% OF THOD): 0.76 % THOD
CYCLOHEXANONE (108-94-1):
PERSISTENCE AND DEGRADABILITY:
READILY BIODEGRADABLE IN WATER. BIODEGRADABLE IN THE SOIL. HIGHLY MOBILE IN
SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): 1.232 G O2 /G SUBSTANCE
CHEMICAL OXYGEN DEMAND (COD): 2.605 G O2 /G SUBSTANCE
THOD: 2.605 G O2 /G SUBSTANCE
BOD (% OF THOD): 0.32 - 0.47% THOD
CHROMIUM (III) OXIDE (1308-38-9):
PERSISTENCE AND DEGRADABILITY:
BIODEGRADABILITY: NOT APPLICABLE. FORMING SEDIMENTS IN WATER.
BIODEGRADABILITY IN SOIL: NOT APPLICABLE. ADSORBS INTO THE SOIL.
BIOCHEMICAL OXYGEN DEMAND (BOD): NOT APPLICABLE
CHEMICAL OXYGEN DEMAND (COD): NOT APPLICABLE
THOD: NOT APPLICABLE
BOD (% OF THOD): NOT APPLICABLE
12.3. BIOACCUMULATIVE POTENTIAL:
BRUSH ON ELECTRICAL TAPE RED 4 FL.OZ.:
BIOACCUMULATIVE POTENTIAL: NOT ESTABLISHED.
METHYL ETHYL KETONE (78-93-3):
LOG POW:
0.3 (EXPERIMENTAL VALUE; OECD 117: PARTITION COEFFICIENT (N-OCTANOL/WATER),
HPLC METHOD; 40 DEG. C)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
METHYL ISOBUTYL KETONE (108-10-1):
BCF FISH 1: 2 - 5 (PISCES)
LOG POW:
1.9 (EXPERIMENTAL VALUE; OECD 117: PARTITION COEFFICIENT (N-OCTANOL/WATER),
HPLC METHOD)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (BCF <500).
CYCLOHEXANONE (108-94-1):
BCF OTHER AQUATIC ORGANISMS 1: 2.4
LOG POW:
0.86 (EXPERIMENTAL VALUE; OECD 107: PARTITION COEFFICIENT
(N-OCTANOL/WATER): SHAKE FLASK METHOD; 25 DEG. C)
BIOACCUMULATIVE POTENTIAL: LOW POTENTIAL FOR BIOACCUMULATION (LOG KOW <4).
CHROMIUM (III) OXIDE (1308-38-9):
BCF OTHER AQUATIC ORGANISMS 1: 116 (CRASSOSTREA SP.; CHROME)
BCF OTHER AQUATIC ORGANISMS 2: 86 (MYTILUS EDULIS; CHROME)
BIOACCUMULATIVE POTENTIAL: BIOACCUMABLE.
12.4. MOBILITY IN SOIL:
METHYL ETHYL KETONE (78-93-3):
SURFACE TENSION: 0.024 N/M (20 DEG. C)
ECOLOGY - SOIL: SLIGHTLY HARMFUL TO PLANTS.
METHYL ISOBUTYL KETONE (108-10-1):
SURFACE TENSION: 0.024 N/M (20 DEG. C)
CYCLOHEXANONE (108-94-1):
SURFACE TENSION: 0.034 N/M (20 DEG. C)
12.5. OTHER ADVERSE EFFECTS:
OTHER INFORMATION: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE DISPOSAL RECOMMENDATIONS:
DISPOSE IN A SAFE MANNER IN ACCORDANCE WITH LOCAL/NATIONAL REGULATIONS.
DISPOSE OF CONTENTS/CONTAINER TO APPROPRIATE WASTE DISPOSAL FACILITY, IN
ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL, INTERNATIONAL REGULATIONS.
ADDITIONAL INFORMATION:
HANDLE EMPTY CONTAINERS WITH CARE BECAUSE RESIDUAL VAPORS ARE FLAMMABLE.
ECOLOGY - WASTE MATERIALS: AVOID RELEASE TO THE ENVIRONMENT.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH ADR / RID / IMDG / IATA / ADN:
US DOT (GROUND):
UN1993, FLAMMABLE LIQUIDS, N.O.S. (METHYL ETHYL KETONE, METHYL ISOBUTYL
KETONE, CYCLOHEXANONE), 3, II, LIMITED QUANTITY
ICAO/IATA (AIR):
UN1993, FLAMMABLE LIQUIDS, N.O.S. (METHYL ETHYL KETONE, METHYL ISOBUTYL
KETONE, CYCLOHEXANONE), 3 , II, LIMITED QUANTITY
IMO/IMDG (WATER):
UN1993, FLAMMABLE LIQUIDS, N.O.S. (METHYL ETHYL KETONE, METHYL ISOBUTYL
KETONE, CYCLOHEXANONE), 3 , II, LIMITED QUANTITY
SPECIAL PROVISIONS:
IB2 - AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE
(31HZ1).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
T7: 4 178.274(D)(2) NORMAL...... 178.275(D)(3)
TP1:
THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING:
DEGREE OF FILLING = 97 / 1 + A (TR - TF) WHERE:
TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS THE
TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
TP8:
A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 1.5 BAR (150 KPA) MAY BE
USED WHEN THE FLASH POINT OF THE HAZARDOUS MATERIAL TRANSPORTED IS GREATER
THAN 0 C (32 F).
TP28:
A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 2.65 BAR (265 KPA) MAY BE
USED PROVIDED THE CALCULATED TEST PRESSURE IS 2.65 BAR OR LESS BASED ON THE
MAWP OF THE HAZARDOUS MATERIAL, AS DEFINED IN 178.275 OF THIS SUBCHAPTER,
WHERE THE TEST PRESSURE IS 1.5 TIMES THE MAWP.
14.2. UN PROPER SHIPPING NAME:
PROPER SHIPPING NAME (DOT):
FLAMMABLE LIQUIDS, N.O.S. (METHYL ETHYL KETONE, METHYL ISOBUTYL KETONE,
CYCLOHEXANONE)
DEPARTMENT OF TRANSPORTATION (DOT) HAZARD CLASSES:
3 - CLASS 3 - FLAMMABLE AND COMBUSTIBLE LIQUID 49 CFR 173.120
HAZARD LABELS (DOT): 3 - FLAMMABLE LIQUID
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
PACKING GROUP (DOT): II - MEDIUM DANGER
DOT SPECIAL PROVISIONS (49 CFR 172.102):
IB2 - AUTHORIZED IBCS:
METAL (31A, 31B AND 31N); RIGID PLASTICS (31H1 AND 31H2); COMPOSITE
(31HZ1).
ADDITIONAL REQUIREMENT:
ONLY LIQUIDS WITH A VAPOR PRESSURE LESS THAN OR EQUAL TO 110 KPA AT 50 C
(1.1 BAR AT 122 F), OR 130 KPA AT 55 C (1.3 BAR AT 131 F) ARE AUTHORIZED.
T7: 4 178.274(D)(2) NORMAL....... 178.275(D)(3)
TP1:
THE MAXIMUM DEGREE OF FILLING MUST NOT EXCEED THE DEGREE OF FILLING
DETERMINED BY THE FOLLOWING:
DEGREE OF FILLING = 97 / 1 + A (TR - TF) WHERE:
TR IS THE MAXIMUM MEAN BULK TEMPERATURE DURING TRANSPORT, AND TF IS THE
TEMPERATURE IN DEGREES CELSIUS OF THE LIQUID DURING FILLING.
TP8:
A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 1.5 BAR (150 KPA) MAY BE
USED WHEN THE FLASH POINT OF THE HAZARDOUS MATERIAL TRANSPORTED IS GREATER
THAN 0 C (32 F).
TP28:
A PORTABLE TANK HAVING A MINIMUM TEST PRESSURE OF 2.65 BAR (265 KPA) MAY BE
USED PROVIDED THE CALCULATED TEST PRESSURE IS 2.65 BAR OR LESS BASED ON THE
MAWP OF THE HAZARDOUS MATERIAL, AS DEFINED IN 178.275 OF THIS SUBCHAPTER,
WHERE THE TEST PRESSURE IS 1.5 TIMES THE MAWP.
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 150
DOT PACKAGING NON BULK (49 CFR 173.XXX): 202
DOT PACKAGING BULK (49 CFR 173.XXX): 242
14.3. ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
OVERLAND TRANSPORT: NO ADDITIONAL INFORMATION AVAILABLE
TRANSPORT BY SEA:
DOT VESSEL STOWAGE LOCATION:
B - (I) THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO
VESSEL AND ON A PASSENGER VESSEL CARRYING A NUMBER OF PASSENGERS LIMITED TO
NOT MORE THAN THE LARGER OF 25 PASSENGERS, OR ONE PASSENGER PER EACH 3 M OF
OVERALL VESSEL LENGTH; AND (II) "ON DECK ONLY" ON PASSENGER VESSELS IN
WHICH THE NUMBER OF PASSENGERS SPECIFIED IN PARAGRAPH (K)(2)(I) OF THIS
SECTION IS EXCEEDED.
AIR TRANSPORT:
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 5 L
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 60 L
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
BRUSH ON ELECTRICAL TAPE RED 4 FL.OZ.:
SARA SECTION 311/312 HAZARD CLASSES:
DELAYED (CHRONIC) HEALTH HAZARD
FIRE HAZARD
IMMEDIATE (ACUTE) HEALTH HAZARD
15.2. INTERNATIONAL REGULATIONS:
CANADA:
BRUSH ON ELECTRICAL TAPE RED 4 FL.OZ.:
WHMIS CLASSIFICATION: CLASS B DIVISION 2 - FLAMMABLE LIQUID
EU-REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC [DSD] OR 1999/45/EC [DPD]:
NOT CLASSIFIED
15.2.2. NATIONAL REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
15.3. US STATE REGULATIONS: NO ADDITIONAL INFORMATION AVAILABLE
| SECTION 16: OTHER INFORMATION | |
OTHER INFORMATION: NONE.
FULL TEXT OF H-PHRASES: SEE SECTION 16
ACUTE TOX. 3 (DERMAL): ACUTE TOXICITY (DERMAL) CATEGORY 3
ACUTE TOX. 3 (INHALATION: GAS):
ACUTE TOXICITY (INHALATION: GAS) CATEGORY 3
ACUTE TOX. 4 (INHALATION): ACUTE TOXICITY (INHALATION) CATEGORY 4
ACUTE TOX. 4 (ORAL): ACUTE TOXICITY (ORAL) CATEGORY 4
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION CATEGORY 2A
FLAM. LIQ. 2: FLAMMABLE LIQUIDS CATEGORY 2
FLAM. LIQ. 3: FLAMMABLE LIQUIDS CATEGORY 3
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) CATEGORY 3
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR
H226: FLAMMABLE LIQUID AND VAPOR
H302: HARMFUL IF SWALLOWED
H311: TOXIC IN CONTACT WITH SKIN
H319: CAUSES SERIOUS EYE IRRITATION
H331: TOXIC IF INHALED
H332: HARMFUL IF INHALED
H335: MAY CAUSE RESPIRATORY IRRITATION
H336: MAY CAUSE DROWSINESS OR DIZZINESS
NFPA HEALTH HAZARD 2 - INTENSE OR CONTINUED EXPOSURE COULD CAUSE TEMPORARY
INCAPACITATION OR POSSIBLE RESIDUAL INJURY UNLESS
PROMPT MEDICAL ATTENTION IS GIVEN.
NFPA FIRE HAZARD 3 - LIQUIDS AND SOLIDS THAT CAN BE IGNITED UNDER ALMOST
ALL AMBIENT CONDITIONS.
NFPA REACTIVITY 0 - NORMALLY STABLE, EVEN UNDER FIRE EXPOSURE
CONDITIONS, AND ARE NOT REACTIVE WITH WATER.
HMIS III RATING:
HEALTH 2 MODERATE HAZARD - TEMPORARY OR MINOR INJURY MAY OCCUR
FLAMMABILITY 3 SERIOUS HAZARD
PHYSICAL 0 MINIMAL HAZARD
PERSONAL PROTECTION B
SDS US (GHS HAZCOM 2012) - TCC
THE SUPPLIER IDENTIFIED IN SECTION 1 OF THIS MSDS HAS EVALUATED THIS
PRODUCT AND CERTIFIES IT TO BE LABELED AND PACKAGED IN COMPLIANCE WITH THE
APPLICABLE PROVISIONS OF THE FEDERAL HAZARDOUS SUBSTANCE ACT AS STATED IN
16 CFR 1500 AND ENFORCED BY THE CONSUMER PRODUCT SAFETY COMMISSION, AND
WHERE APPLICABLE THE PRODUCTS THAT REQUIRE CHILD RESISTANT CLOSURES ARE
PACKAGED IN ACCORDANCE WITH THE POISON PREVENTION PACKAGING ACT AS STATED
IN 16 CFR 1700 AND ENFORCED BY THE CONSUMER PRODUCT SAFETY COMMISSION. ALL
CLOSURES HAVE BEEN TESTED IN ACCORDANCE WITH THE LATEST PROTOCOLS. NO OTHER
TESTING IS REQUIRED TO CERTIFY COMPLIANCE WITH THE ABOVE. THE DATE OF
MANUFACTURE IS STAMPED ON THE PRODUCT
DISCLAIMER:
THE INFORMATION AND RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON TESTS
BELIEVED TO BE RELIABLE. HOWEVER, THE MANUFACTURER/DISTRIBUTOR OF THIS
PRODUCT DOES NOT GUARANTEE THEIR ACCURACY OR COMPLETENESS NOR SHALL ANY OF
THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR IMPLIED, AS TO
THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS
OF THE GOODS FOR A PARTICULAR PURPOSE. ADJUSTMENT TO CONFORM TO ACTUAL
CONDITIONS OF USAGE MAY BE REQUIRED. THE MANUFACTURER/DISTRIBUTOR ASSUMES
NO RESPONSIBILITY FOR RESULTS OBTAINED OR FOR INCIDENTAL OR CONSEQUENTIAL
DAMAGES, INCLUDING LOST PROFITS, ARISING FROM THE USE OF THESE DATA. NO
WARRANTY AGAINST INFRINGEMENT OF ANY PATENT, COPYRIGHT OR TRADEMARK IS MADE
OR IMPLIED.
10/11/2014
EN (ENGLISH US)