| Common Name: | PYROIL BRAKE PARTS CLEANER |
| Manufacturer: | NITEO PRODUCTS |
| SDS Revision Date: | 7/31/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 1PKT6 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NITEO(TM) PRODUCTS
SAFETY DATA SHEET
PYROIL(TM) BRAKE PARTS CLEANER
PYBPC20
REVISION DATE: 07/31/2015
PRINT DATE: 9/25/2015
SDS NUMBER: R0339974
VERSION: 1.1
29 CFR 1910.1200 (OSHA HAZCOM 2012)
| SECTION 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: PYROIL(TM) BRAKE PARTS CLEANER
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
NITEO PRODUCTS, LLC
P.O. BOX 191629
DALLAS, TX 75219
UNITED STATES OF AMERICA
EMERGENCY TELEPHONE NUMBER:
CHEMTREC DIRECT: 1-800-424-9300
PRODUCT INFORMATION: 1-844-696-4836
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
ACUTE TOXICITY (INHALATION): CATEGORY 4
SKIN IRRITATION: CATEGORY 2
EYE IRRITATION: CATEGORY 2A
SKIN SENSITIZATION: CATEGORY 1
CARCINOGENICITY: CATEGORY 2
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - SINGLE EXPOSURE:
CATEGORY 3 (CENTRAL NERVOUS SYSTEM)
GHS LABEL ELEMENT:
HAZARD PICTOGRAMS:
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: WARNING
HAZARD STATEMENTS:
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HARMFUL IF INHALED.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF CAUSING CANCER.
PRECAUTIONARY STATEMENTS:
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WASH SKIN THOROUGHLY AFTER HANDLING.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
CALL A POISON CENTER OR DOCTOR/PHYSICIAN IF YOU FEEL UNWELL.
IF IN EYES: RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES.
REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
STORAGE:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
SUBSTANCE / MIXTURE: MIXTURE
HAZARDOUS COMPONENTS:
CHEMICAL NAME CAS-NO. CLASSIFICATION CONCENTRATION (%)
TETRACHLOROETHYLENE 127-18-4 ACUTE TOX. 4; H332 91.78
SKIN IRRIT. 2; H315
EYE IRRIT. 2A; H319
SKIN SENS. 1; H317
CARC. 2; H351
STOT SE 3; H336
CARBON DIOXIDE 124-38-9 PRESS. GAS LIQUEFIED 8.12
GAS; H280
| SECTION 4. FIRST AID MEASURES | |
GENERAL ADVICE:
MOVE OUT OF DANGEROUS AREA.
CALL A POISON CENTRE OR DOCTOR/PHYSICIAN IF EXPOSED OR YOU FEEL UNWELL.
SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
DO NOT LEAVE THE VICTIM UNATTENDED.
IF INHALED:
MOVE TO FRESH AIR.
KEEP PATIENT WARM AND AT REST.
IF UNCONSCIOUS PLACE IN RECOVERY POSITION AND SEEK MEDICAL ADVICE.
CONSULT A PHYSICIAN AFTER SIGNIFICANT EXPOSURE.
IN CASE OF SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. IF IRRITATION DEVELOPS, GET MEDICAL
ATTENTION.
IF ON SKIN, RINSE WELL WITH WATER.
WASH CONTAMINATED CLOTHING BEFORE RE-USE.
IN CASE OF EYE CONTACT:
IMMEDIATELY FLUSH EYE(S) WITH PLENTY OF WATER.
REMOVE CONTACT LENSES.
PROTECT UNHARMED EYE.
IF SWALLOWED:
OBTAIN MEDICAL ATTENTION.
DO NOT GIVE MILK OR ALCOHOLIC BEVERAGES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
IF SYMPTOMS PERSIST, CALL A PHYSICIAN.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
INHALATION OF HIGH CONCENTRATIONS OF THIS MATERIAL, AS COULD OCCUR IN
ENCLOSED SPACES OR DURING DELIBERATE ABUSE, MAY BE ASSOCIATED WITH CARDIAC
ARRHYTHMIAS. SYMPATHOMIMETIC DRUGS MAY INITIATE CARDIAC ARRHYTHMIAS IN
PERSONS EXPOSED TO THIS MATERIAL.
SIGNS AND SYMPTOMS OF EXPOSURE TO THIS MATERIAL THROUGH BREATHING,
SWALLOWING, AND/OR PASSAGE OF THE MATERIAL THROUGH THE SKIN MAY INCLUDE:
REDNESS OF THE SKIN
STOMACH OR INTESTINAL UPSET (NAUSEA, VOMITING, DIARRHEA)
IRRITATION (NOSE, THROAT, AIRWAYS)
TEMPORARY CHANGES IN MOOD AND BEHAVIOR
CONFUSION
IRREGULAR HEARTBEAT
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE IRRITATION.
HARMFUL IF INHALED.
MAY CAUSE DROWSINESS OR DIZZINESS.
SUSPECTED OF CAUSING CANCER.
NOTES TO PHYSICIAN: NO HAZARDS WHICH REQUIRE SPECIAL FIRST AID MEASURES.
| SECTION 5. FIREFIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
WATER SPRAY
FOAM
UNSUITABLE EXTINGUISHING MEDIA: HIGH VOLUME WATER JET
SPECIFIC HAZARDS DURING FIREFIGHTING:
DO NOT ALLOW RUN-OFF FROM FIRE FIGHTING TO ENTER DRAINS OR WATER COURSES.
HAZARDOUS COMBUSTION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE
CHLORINE
HYDROGEN CHLORIDE
PHOSGENE
SPECIFIC EXTINGUISHING METHODS:
PRODUCT IS COMPATIBLE WITH STANDARD FIRE-FIGHTING AGENTS.
FURTHER INFORMATION:
FIRE RESIDUES AND CONTAMINATED FIRE EXTINGUISHING WATER MUST BE DISPOSED OF
IN ACCORDANCE WITH LOCAL REGULATIONS.
SPECIAL PROTECTIVE EQUIPMENT FOR FIREFIGHTERS:
IN THE EVENT OF FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE PERSONAL PROTECTIVE EQUIPMENT.
ENSURE ADEQUATE VENTILATION.
AVOID BREATHING DUST.
PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUDED FROM AREA OF
SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED.
ENVIRONMENTAL PRECAUTIONS:
PREVENT PRODUCT FROM ENTERING DRAINS.
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
IF THE PRODUCT CONTAMINATES RIVERS AND LAKES OR DRAINS INFORM RESPECTIVE
AUTHORITIES.
OTHER INFORMATION:
COMPLY WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
| SECTION 7. HANDLING AND STORAGE | |
ADVICE ON SAFE HANDLING:
PROVIDE SUFFICIENT AIR EXCHANGE AND/OR EXHAUST IN WORK ROOMS.
DO NOT BREATHE VAPOURS/DUST.
DO NOT SMOKE.
PERSONS SUSCEPTIBLE TO SKIN SENSITISATION PROBLEMS OR ASTHMA, ALLERGIES,
CHRONIC OR RECURRENT RESPIRATORY DISEASE SHOULD NOT BE EMPLOYED IN ANY
PROCESS IN WHICH THIS MIXTURE IS BEING USED.
CONTAINER HAZARDOUS WHEN EMPTY.
AVOID EXPOSURE - OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
AVOID CONTACT WITH SKIN AND EYES.
SMOKING, EATING AND DRINKING SHOULD BE PROHIBITED IN THE APPLICATION AREA.
FOR PERSONAL PROTECTION SEE SECTION 8.
DISPOSE OF RINSE WATER IN ACCORDANCE WITH LOCAL AND NATIONAL REGULATIONS.
CONDITIONS FOR SAFE STORAGE:
BEWARE:
AEROSOL IS PRESSURIZED. KEEP AWAY FROM DIRECT SUN EXPOSURE AND TEMPERATURES
OVER 50 DEG. C. DO NOT OPEN BY FORCE OR THROW INTO FIRE EVEN AFTER USE. DO
NOT SPRAY ON FLAMES OR RED-HOT OBJECTS.
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE.
CONTAINERS WHICH ARE OPENED MUST BE CAREFULLY RESEALED AND KEPT UPRIGHT TO
PREVENT LEAKAGE.
OBSERVE LABEL PRECAUTIONS.
ELECTRICAL INSTALLATIONS / WORKING MATERIALS MUST COMPLY WITH THE
TECHNOLOGICAL SAFETY STANDARDS.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
COMPONENTS WITH WORKPLACE CONTROL PARAMETERS:
COMPONENTS CAS-NO. VALUE TYPE CONTROL BASIS
(FORM OF PARAMETERS /
EXPOSURE) PERMISSIBLE
CONCENTRATION
TETRACHLORO- 127-18-4 TWA 25 PPM ACGIH
ETHYLENE
STEL 100 PPM ACGIH
TWA 100 PPM OSHA/Z2
CEILING 200 PPM OSHA/Z2
MAX. CONC 300 PPM OSHA/Z2
TWA 25 PPM TN OEL
170 MG/M3
CARBON DIOXIDE 124-38-9 TWA 5,000 PPM ACGIH
STEL 30,000 PPM ACGIH
REL 5,000 PPM NIOSH/GUIDE
9,000 MG/M3
STEL 30,000 PPM NIOSH/GUIDE
54,000 MG/M3
PEL 5,000 PPM OSHA_TRANS
9,000 MG/M3
BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS:
COMPONENTS CAS-NO. CONTROL BIOLOGICAL SAMPLING PERMISSIBLE BASIS
PARAMETERS SPECIMEN TIME CONCEN-
TRATION
TETRA- 127-18-4 TETRA- BLOOD SAMPLING 0.5 MG/L
CHLORO- CHLORO- TIME:
ETHYLENE ETHYLENE PRIOR
TO
SHIFT.
TETRA- END- SAMPLING 3 PPM
CHLORO- EXHALED TIME:
ETHYLENE AIR PRIOR
TO
SHIFT.
ENGINEERING MEASURES:
PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO
MAINTAIN EXPOSURE BELOW EXPOSURE GUIDELINES (IF APPLICABLE) OR BELOW LEVELS
THAT CAUSE KNOWN, SUSPECTED OR APPARENT ADVERSE EFFECTS.
PERSONAL PROTECTIVE EQUIPMENT:
RESPIRATORY PROTECTION:
IN THE CASE OF VAPOUR FORMATION USE A RESPIRATOR WITH AN APPROVED FILTER.
IN THE CASE OF DUST OR AEROSOL FORMATION USE RESPIRATOR WITH AN APPROVED
FILTER.
A NIOSH-APPROVED AIR-PURIFYING RESPIRATOR WITH AN APPROPRIATE CARTRIDGE
AND/OR FILTER MAY BE PERMISSIBLE UNDER CERTAIN CIRCUMSTANCES WHERE AIRBORNE
CONCENTRATIONS ARE EXPECTED TO EXCEED EXPOSURE LIMITS (IF APPLICABLE) OR IF
OVEREXPOSURE HAS OTHERWISE BEEN DETERMINED. PROTECTION PROVIDED BY
AIR-PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRESSURE, AIR-SUPPLIED
RESPIRATOR IF THERE IS ANY POTENTIAL FOR UNCONTROLLED RELEASE, EXPOSURE
LEVELS ARE NOT KNOWN OR ANY OTHER CIRCUMSTANCES WHERE AN AIR-PURIFYING
RESPIRATOR MAY NOT PROVIDE ADEQUATE PROTECTION.
HAND PROTECTION:
REMARKS:
THE SUITABILITY FOR A SPECIFIC WORKPLACE SHOULD BE DISCUSSED WITH THE
PRODUCERS OF THE PROTECTIVE GLOVES.
EYE PROTECTION:
WEAR CHEMICAL SPLASH GOGGLES WHEN THERE IS THE POTENTIAL FOR EXPOSURE OF
THE EYES TO LIQUID, VAPOR OR MIST.
SKIN AND BODY PROTECTION:
WEAR AS APPROPRIATE:
IMPERVIOUS CLOTHING
SAFETY SHOES
CHOOSE BODY PROTECTION ACCORDING TO THE AMOUNT AND CONCENTRATION OF THE
DANGEROUS SUBSTANCE AT THE WORK PLACE. DISCARD GLOVES THAT SHOW TEARS,
PINHOLES, OR SIGNS OF WEAR. WEAR RESISTANT GLOVES (CONSULT YOUR SAFETY
EQUIPMENT SUPPLIER).
HYGIENE MEASURES:
WASH HANDS BEFORE BREAKS AND AT THE END OF WORKDAY.
WHEN USING DO NOT EAT OR DRINK.
WHEN USING DO NOT SMOKE.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: AEROSOL
PHYSICAL STATE: AEROSOL
ODOUR: NO DATA AVAILABLE
ODOUR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT/FREEZING POINT: NO DATA AVAILABLE
BOILING POINT/BOILING RANGE:
250.3 DEG. F / 121.3 DEG. C
CALCULATED PHASE TRANSITION LIQUID/GAS
FLASH POINT: DOES NOT FLASH
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NO DATA AVAILABLE
UPPER EXPLOSION LIMIT: NO DATA AVAILABLE
LOWER EXPLOSION LIMIT: NO DATA AVAILABLE
VAPOUR PRESSURE: 24.6642 HPA (25 DEG. C) CALCULATED VAPOR PRESSURE
RELATIVE VAPOUR DENSITY: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
DENSITY: NO DATA AVAILABLE
SOLUBILITY(IES):
WATER SOLUBILITY: NO DATA AVAILABLE
SOLUBILITY IN OTHER SOLVENTS: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
THERMAL DECOMPOSITION: NO DATA AVAILABLE
VISCOSITY:
VISCOSITY, DYNAMIC: NO DATA AVAILABLE
VISCOSITY, KINEMATIC: NO DATA AVAILABLE
OXIDIZING PROPERTIES: NO DATA AVAILABLE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: NO DECOMPOSITION IF STORED AND APPLIED AS DIRECTED.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
PRODUCT WILL NOT UNDERGO HAZARDOUS POLYMERIZATION.
CONDITIONS TO AVOID:
AVOID HEAT, OPEN FLAME, AND PROLONGED STORAGE AT ELEVATED TEMPERATURES.
UV LIGHT.
EXPOSURE TO SUNLIGHT.
INCOMPATIBLE MATERIALS:
ALKALI METALS
ALUMINUM
AMINES
BARIUM
STRONG ACIDS
STRONG BASES
STRONG OXIDIZING AGENTS
ZINC
HAZARDOUS DECOMPOSITION PRODUCTS:
CARBON DIOXIDE AND CARBON MONOXIDE
CHLORINE
HYDROGEN CHLORIDE
PHOSGENE
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INHALATION
SKIN CONTACT
EYE CONTACT
INGESTION
ACUTE TOXICITY: HARMFUL IF INHALED.
COMPONENTS:
TETRACHLOROETHYLENE:
ACUTE ORAL TOXICITY:
LD50 (RAT, MALE): 3,835 MG/KG
LD50 (RAT, FEMALE): 3,005 MG/KG
ACUTE INHALATION TOXICITY:
ASSESSMENT:
THE COMPONENT/MIXTURE IS CLASSIFIED AS ACUTE INHALATION TOXICITY,
CATEGORY 4.
ACUTE DERMAL TOXICITY:
LD50 (RABBIT): >3,228 MG/KG
ASSESSMENT:
NO ADVERSE EFFECT HAS BEEN OBSERVED IN ACUTE DERMAL TOXICITY TESTS.
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
PRODUCT:
REMARKS: MAY CAUSE SKIN IRRITATION AND/OR DERMATITIS.
COMPONENTS:
TETRACHLOROETHYLENE:
RESULT: IRRITATING TO SKIN
CARBON DIOXIDE:
RESULT: NOT IRRITATING TO SKIN
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
PRODUCT:
REMARKS:
VAPOURS MAY CAUSE IRRITATION TO THE EYES, RESPIRATORY SYSTEM AND THE SKIN.,
CAUSES SERIOUS EYE IRRITATION.
COMPONENTS:
TETRACHLOROETHYLENE:
RESULT: IRRITATING TO EYES
CARBON DIOXIDE:
RESULT: NOT IRRITATING TO EYES
RESPIRATORY OR SKIN SENSITISATION:
SKIN SENSITISATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
RESPIRATORY SENSITISATION: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
TETRACHLOROETHYLENE:
TEST TYPE: LOCAL LYMPH NODE ASSAY
EXPOSURE ROUTES: DERMAL
SPECIES: MOUSE
ASSESSMENT: MAY CAUSE SENSITISATION BY SKIN CONTACT.
METHOD: OECD TEST GUIDELINE 429
GLP: YES
GERM CELL MUTAGENICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
COMPONENTS:
TETRACHLOROETHYLENE:
GENOTOXICITY IN VITRO:
TEST TYPE: CHROMOSOME ABERRATION TEST IN VITRO
TEST SPECIES: CHINESE HAMSTER OVARY CELLS
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 473
RESULT: NEGATIVE
GLP: YES
TEST TYPE: AMES TEST
TEST SPECIES: SALMONELLA TYPHIMURIUM
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 471
RESULT: NEGATIVE
GLP: YES
TEST TYPE: IN VITRO MAMMALIAN CELL GENE MUTATION TEST
TEST SPECIES: MOUSE LYMPHOMA CELLS
METABOLIC ACTIVATION: WITH AND WITHOUT METABOLIC ACTIVATION
METHOD: OECD TEST GUIDELINE 476
RESULT: NEGATIVE
GLP: YES
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
COMPONENTS:
TETRACHLOROETHYLENE:
CARCINOGENICITY - ASSESSMENT:
LIMITED EVIDENCE OF CARCINOGENICITY IN ANIMAL STUDIES
REPRODUCTIVE TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
STOT - SINGLE EXPOSURE: MAY CAUSE DROWSINESS OR DIZZINESS.
COMPONENTS:
TETRACHLOROETHYLENE:
EXPOSURE ROUTES: INHALATION (VAPOUR)
TARGET ORGANS: CENTRAL NERVOUS SYSTEM
ASSESSMENT: MAY CAUSE DROWSINESS OR DIZZINESS.
STOT - REPEATED EXPOSURE: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
ASPIRATION TOXICITY: NOT CLASSIFIED BASED ON AVAILABLE INFORMATION.
FURTHER INFORMATION:
PRODUCT:
REMARKS:
SYMPTOMS OF OVEREXPOSURE MAY BE HEADACHE, DIZZINESS, TIREDNESS, NAUSEA AND
VOMITING., CONCENTRATIONS SUBSTANTIALLY ABOVE THE TLV VALUE MAY CAUSE
NARCOTIC EFFECTS., SOLVENTS MAY DEGREASE THE SKIN.
COMPONENTS:
TETRACHLOROETHYLENE:
REMARKS: CENTRAL NERVOUS SYSTEM
CARCINOGENICITY:
IARC:
GROUP 2A: PROBABLY CARCINOGENIC TO HUMANS
TETRACHLOROETHYLENE 127-18-4
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP: REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN
TETRACHLOROETHYLENE 127-18-4
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY:
COMPONENTS:
TETRACHLOROETHYLENE:
TOXICITY TO FISH:
LC50 (RAINBOW TROUT, DONALDSON TROUT (ONCORHYNCHUS MYKISS)):
4.73 - 5.27 MG/L
EXPOSURE TIME: 96 H
TEST TYPE: FLOW-THROUGH TEST
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 (WATER FLEA (DAPHNIA MAGNA)): 7 - 11 MG/L
EXPOSURE TIME: 48 H
TEST TYPE: STATIC TEST
TOXICITY TO ALGAE:
EC50 (GREEN ALGAE): 3.64 MG/L
END POINT: GROWTH INHIBITION
EXPOSURE TIME: 72 H
TOXICITY TO FISH (CHRONIC TOXICITY):
NOEC (JORDANELLA FLORIDAE (FLAGFISH)): 2.34 MG/L
EXPOSURE TIME: 28 D
TEST TYPE: FLOW-THROUGH TEST
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES (CHRONIC TOXICITY):
NOEC (DAPHNIA MAGNA (WATER FLEA)): 0.51 MG/L
EXPOSURE TIME: 28 D
END POINT: REPRODUCTION TEST
TEST TYPE: SEMI-STATIC TEST
TOXICITY TO BACTERIA:
IC50 (BACTERIA): 112 MG/L
EXPOSURE TIME: 24 H
PERSISTENCE AND DEGRADABILITY:
COMPONENTS:
TETRACHLOROETHYLENE:
BIODEGRADABILITY:
REMARKS: NOT READILY BIODEGRADABLE.
BIOACCUMULATIVE POTENTIAL:
COMPONENTS:
TETRACHLOROETHYLENE:
BIOACCUMULATION:
SPECIES: BLUEGILL (LEPOMIS MACROCHIRUS)
BIOCONCENTRATION FACTOR (BCF): 49
EXPOSURE TIME: 21 D
CONCENTRATION: 0.00343 MG/L
METHOD: FLOW THROUGH
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: 2.53 (23 DEG. C)
MOBILITY IN SOIL:
COMPONENTS: NO DATA AVAILABLE
OTHER ADVERSE EFFECTS: NO DATA AVAILABLE
PRODUCT:
ADDITIONAL ECOLOGICAL INFORMATION:
AN ENVIRONMENTAL HAZARD CANNOT BE EXCLUDED IN THE EVENT OF UNPROFESSIONAL
HANDLING OR DISPOSAL., TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
COMPONENTS:
| SECTION 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
GENERAL ADVICE:
THE PRODUCT SHOULD NOT BE ALLOWED TO ENTER DRAINS, WATER COURSES OR THE
SOIL.
DO NOT CONTAMINATE PONDS, WATERWAYS OR DITCHES WITH CHEMICAL OR USED
CONTAINER.
SEND TO A LICENSED WASTE MANAGEMENT COMPANY.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
CONTAMINATED PACKAGING:
EMPTY REMAINING CONTENTS.
EMPTY CONTAINERS SHOULD BE TAKEN TO AN APPROVED WASTE HANDLING SITE FOR
RECYCLING OR DISPOSAL.
DO NOT RE-USE EMPTY CONTAINERS.
DO NOT BURN, OR USE A CUTTING TORCH ON, THE EMPTY DRUM.
| SECTION 14. TRANSPORT INFORMATION | |
INTERNATIONAL TRANSPORT REGULATIONS:
REGULATION:
ID NUMBER PROPER *HAZARD SUBSIDIARY PACKING MARINE
SHIPPING CLASS HAZARDS GROUP POLLUTANT /
NAME LTD. QTY.
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND
WASTES:
UN 1950 AEROSOLS 2 MARINE POLLUTANT:
(TETRACHLOR
OETHYLENE) LIMITED
QUANTITY
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER:
UN 1950 AEROSOLS 2.2 MARINE POLLUTANT:
(TETRACHLOR
OETHYLENE) LIMITED
QUANTITY
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO:
UN 1950 AEROSOLS 2.2 MARINE POLLUTANT:
(TETRACHLOR
OETHYLENE) LIMITED
QUANTITY
INTERNATIONAL MARITIME DANGEROUS GOODS:
UN 1950 AEROSOLS 2.2 LIMITED QUANTITY
TRANSPORT CANADA - INLAND WATERWAYS:
UN 1950 AEROSOLS 2.2 LIMITED QUANTITY
TRANSPORT CANADA - RAIL:
UN 1950 AEROSOLS 2.2 MARINE POLLUTANT:
(TETRACHLOR
OETHYLENE) LIMITED
QUANTITY
TRANSPORT CANADA - ROAD:
UN 1950 AEROSOLS 2.2 MARINE POLLUTANT:
(TETRACHLOR
OETHYLENE) LIMITED
QUANTITY
U.S. DOT - INLAND WATERWAYS:
UN 1950 AEROSOLS, 2.2
NON-
FLAMMABLE
U.S. DOT - RAIL:
UN 1950 AEROSOLS, 2.2
NON-
FLAMMABLE
U.S. DOT - ROAD:
UN 1950 AEROSOLES 2.2
*ORM = ORM-D
CBL = COMBUSTIBLE LIQUID
MARINE POLLUTANT: YES
DANGEROUS GOODS DESCRIPTIONS (IF INDICATED ABOVE) MAY NOT REFLECT QUANTITY,
END-USE OR REGION-SPECIFIC EXCEPTIONS THAT CAN BE APPLIED. CONSULT SHIPPING
DOCUMENTS FOR DESCRIPTIONS THAT ARE SPECIFIC TO THE SHIPMENT.
| SECTION 15. REGULATORY INFORMATION | |
EPCRA - EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT:
CERCLA REPORTABLE QUANTITY:
COMPONENTS CAS-NO. COMPONENT RQ CALCULATED PRODUCT RQ
(LBS) (LBS)
TETRACHLOROETHYLENE 127-18-4 100 108.947534
SARA 311/312 HAZARDS:
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SARA 313 COMPONENT(S):
TETRACHLOROETHYLENE 127-18-4 91.78%
PENNSYLVANIA RIGHT TO KNOW:
TETRACHLOROETHYLENE 127-18-4 90.00 - 100.00%
CARBON DIOXIDE 124-38-9 5.00 - 10.00%
NEW JERSEY RIGHT TO KNOW:
TETRACHLOROETHYLENE 127-18-4 90.00 - 100.00%
CARBON DIOXIDE 124-38-9 5.00 - 10.00%
CALIFORNIA PROP 65:
WARNING!
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER.
TETRACHLOROETHYLENE 127-18-4
THE COMPONENTS OF THIS PRODUCT ARE REPORTED IN THE FOLLOWING INVENTORIES:
TSCA: ON TSCA INVENTORY
DSL: ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL.
AICS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
NZIOC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
ENCS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
KECI: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
PICCS: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
IECSC: ON THE INVENTORY, OR IN COMPLIANCE WITH THE INVENTORY
INVENTORIES:
AICS (AUSTRALIA), DSL (CANADA), IECSC (CHINA), REACH (EUROPEAN UNION),
ENCS (JAPAN), ISHL (JAPAN), KECI (KOREA), NZIOC (NEW ZEALAND), PICCS
(PHILIPPINES), TSCA (USA)
| SECTION 16. OTHER INFORMATION | |
FURTHER INFORMATION:
REVISION DATE: 07/31/2015
NFPA:
HEALTH 2
FLAMMABILITY 0
INSTABILITY 0
SPECIAL HAZARD.
HMIS III:
HEALTH 2*
FLAMMABILITY 0
PHYSICAL HAZARD 0
0 = NOT SIGNIFICANT
1 = SLIGHT
2 = MODERATE
3 = HIGH
4 = EXTREME
* = CHRONIC
NFPA FLAMMABLE AND COMBUSTIBLE LIQUIDS CLASSIFICATION: NOT APPLICABLE
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3:
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
H303: MAY BE HARMFUL IF SWALLOWED.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H319: CAUSES SERIOUS EYE IRRITATION.
H332: HARMFUL IF INHALED.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
SOURCES OF KEY DATA USED TO COMPILE THE SAFETY DATA SHEET
INTERNAL DATA INCLUDING OWN AND SPONSORED TEST REPORTS
THE UNECE ADMINISTERS REGIONAL AGREEMENTS IMPLEMENTING HARMONISED
CLASSIFICATION FOR LABELLING (GHS) AND TRANSPORT.
CEFIC, THE EUROPEAN CHEMICAL INDUSTRY COUNCIL.
ESIS EUROPEAN CHEMICAL SUBSTANCES INFORMATION SYSTEM
THE INFORMATION ACCUMULATED HEREIN IS BELIEVED TO BE ACCURATE BUT IS NOT
WARRANTED TO BE WHETHER ORIGINATING WITH THE COMPANY OR NOT. RECIPIENTS
ARE ADVISED TO CONFIRM IN ADVANCE OF NEED THAT THE INFORMATION IS CURRENT,
APPLICABLE, AND SUITABLE TO THEIR CIRCUMSTANCES. THIS SDS HAS BEEN PREPARED
BY NITEO'S ENVIRONMENTAL HEALTH AND SAFETY DEPARTMENT (1-844-696-4836).
LIST OF ABBREVIATIONS AND ACRONYMS THAT COULD BE, BUT NOT NECESSARILY ARE,
USED IN THIS SAFETY DATA SHEET:
ACGIH: AMERICAN CONFERENCE OF INDUSTRIAL HYGIENISTS
BEI: BIOLOGICAL EXPOSURE INDEX
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY).
CMR: CARCINOGENIC, MUTAGENIC OR TOXIC FOR REPRODUCTION
FG: FOOD GRADE
GHS:
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS.
H-STATEMENT: HAZARD STATEMENT
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION.
IATA-DGR:
DANGEROUS GOODS REGULATION BY THE "INTERNATIONAL AIR TRANSPORT ASSOCIATION"
(IATA).
ICAO: INTERNATIONAL CIVIL AVIATION ORGANIZATION
ICAO-TI (ICAO):
TECHNICAL INSTRUCTIONS BY THE "INTERNATIONAL CIVIL AVIATION ORGANIZATION"
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
ISO: INTERNATIONAL ORGANIZATION FOR STANDARDIZATION
LOGPOW: OCTANOL-WATER PARTITION COEFFICIENT
LCXX: LETHAL CONCENTRATION, FOR XX PERCENT OF TEST POPULATION
LDXX: LETHAL DOSE, FOR XX PERCENT OF TEST POPULATION.
ICXX: INHIBITORY CONCENTRATION FOR XX OF A SUBSTANCE
ECXX: EFFECTIVE CONCENTRATION OF XX
N.O.S.: NOT OTHERWISE SPECIFIED
OECD: ORGANIZATION FOR ECONOMIC CO-OPERATION AND DEVELOPMENT
OEL: OCCUPATIONAL EXPOSURE LIMIT
P-STATEMENT: PRECAUTIONARY STATEMENT
PBT: PERSISTENT, BIOACCUMULATIVE AND TOXIC
PPE: PERSONAL PROTECTIVE EQUIPMENT
STEL: SHORT-TERM EXPOSURE LIMIT
STOT: SPECIFIC TARGET ORGAN TOXICITY
TLV: THRESHOLD LIMIT VALUE
TWA: TIME-WEIGHTED AVERAGE
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
WEL: WORKPLACE EXPOSURE LEVEL
CERCLA:
COMPREHENSIVE ENVIRONMENTAL RESPONSE, COMPENSATION, AND LIABILITY ACT
DOT: DEPARTMENT OF TRANSPORTATION
FIFRA: FEDERAL INSECTICIDE, FUNGICIDE, AND RODENTICIDE ACT
HMIRC: HAZARDOUS MATERIALS INFORMATION REVIEW COMMISSION
HMIS: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
NFPA: NATIONAL FIRE PROTECTION ASSOCIATION
NIOSH: NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY AND HEALTH
OSHA: OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION
PMRA: HEALTH CANADA PEST MANAGEMENT REGULATORY AGENCY
RTK: RIGHT TO KNOW
WHMIS: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM