| Common Name: | MARINE ADHESIVE SEALANT FAST CURE 5200, WHITE; PN 06520, 05220, 06534, 06535 |
| Manufacturer: | 3M |
| SDS Revision Date: | 10/22/2018 |
| SDS Format: | GHS-US |
| Item Number(s): | 1RWH7, 205YN7 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) MARINE ADHESIVE SEALANT FAST CURE 5200, WHITE; PN 06520, 05220,
06534, 06535
10/22/18
3M
SAFETY DATA SHEET
COPYRIGHT, 2018, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 16-5850-9
VERSION NUMBER: 13.00
ISSUE DATE: 10/22/18
SUPERCEDES DATE: 04/06/18
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) MARINE ADHESIVE SEALANT FAST CURE 5200, WHITE; PN 06520, 05220,
06534, 06535
PRODUCT IDENTIFICATION NUMBERS:
ID NUMBER UPC
60-9800-4557-3 00051135065204
60-9800-4562-3
62-5239-5236-4
60-9800-4558-1 00051135052204
62-5239-0330-0
7000000629, 7000120490, 7000120491, 7010367674, 7010309906
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE SEALANT, SEALANT
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
RESPIRATORY SENSITIZER: CATEGORY 1.
SKIN SENSITIZER: CATEGORY 1.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): CATEGORY 1.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: HEALTH HAZARD
PICTOGRAMS: HEALTH HAZARD
HAZARD STATEMENTS:
MAY CAUSE ALLERGY OR ASTHMA SYMPTOMS OR BREATHING DIFFICULTIES IF INHALED.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES DAMAGE TO ORGANS THROUGH PROLONGED OR REPEATED EXPOSURE:
RESPIRATORY SYSTEM
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
DO NOT BREATHE DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IN CASE OF INADEQUATE VENTILATION WEAR RESPIRATORY PROTECTION.
WEAR PROTECTIVE GLOVES.
DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH THOROUGHLY AFTER HANDLING.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF INHALED:
IF BREATHING IS DIFFICULT, REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE
FOR BREATHING.
IF EXPERIENCING RESPIRATORY SYMPTOMS:
CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
WASH CONTAMINATED CLOTHING BEFORE REUSE.
GET MEDICAL ADVICE/ATTENTION IF YOU FEEL UNWELL.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
SUPPLEMENTAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
1% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE ORAL TOXICITY.
2% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
URETHANE POLYMER 51447-37-1 40 - 70 TRADE SECRET *
TITANIUM DIOXIDE 13463-67-7 10 - 30 TRADE SECRET *
FUMED SILICA 112945-52-5 1 - 5 TRADE SECRET *
P,P'-METHYLENEBIS 101-68-8 <2.4 TRADE SECRET *
(PHENYL ISOCYANATE)
ZINC OXIDE 1314-13-2 <2.3 TRADE SECRET *
ALKYL ISOCYANATE SILANE 85702-90-5 <2 TRADE SECRET *
CARBITOL ACETATE 112-15-2 <2.0 TRADE SECRET *
FUMED SILICA 7631-86-9 0.5 - 1.5 TRADE SECRET *
HEPTANE 142-82-5 <0.3 TRADE SECRET *
(GAMMA-MERCAPTOPROPYL) 4420-74-0 <0.2 TRADE SECRET *
TRIMETHOXYSILANE
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
MATERIAL WILL NOT BURN. USE A FIRE FIGHTING AGENT SUITABLE FOR THE
SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
ISOCYANATES DURING COMBUSTION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
HYDROGEN CYANIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
TOXIC VAPOR, GAS, PARTICULATE DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
POUR ISOCYANATE DECONTAMINANT SOLUTION (90% WATER, 8% CONCENTRATED AMMONIA,
2% DETERGENT) ON SPILL AND ALLOW TO REACT FOR 10 MINUTES. OR POUR WATER ON
SPILL AND ALLOW TO REACT FOR MORE THAN 30 MINUTES. COVER WITH ABSORBENT
MATERIAL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH
BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES, BUT DO NOT SEAL THE CONTAINER FOR 48 HOURS TO AVOID PRESSURE
BUILD-UP. CLEAN UP RESIDUE WITH AN APPROPRIATE SOLVENT SELECTED BY A
QUALIFIED AND AUTHORIZED PERSON. VENTILATE THE AREA WITH FRESH AIR. READ
AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT LABEL AND SDS. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED TO PREVENT CONTAMINATION WITH WATER OR AIR.
IF CONTAMINATION IS SUSPECTED, DO NOT RESEAL CONTAINER. STORE AWAY FROM
AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
P,P'-METHYLENEBIS 101-68-8 ACGIH TWA: 0.005 PPM
(PHENYL ISOCYANATE)
P,P'-METHYLENEBIS 101-68-8 OSHA CEIL:
(PHENYL ISOCYANATE) 0.2 MG/M3(0.02
PPM)
SILICA, AMORPHOUS 112945-52-5 OSHA TWA
CONCENTRATION:
0.8 MG/M3;
TWA:
20 MILLIONS OF
PARTICLES/CU.
FT.
ZINC OXIDE 1314-13-2 ACGIH TWA(RESPIRABLE
FRACTION):
2 MG/M3;
STEL(RESPIRABLE
FRACTION):
10 MG/M3
ZINC OXIDE 1314-13-2 OSHA TWA(AS FUME):
5 MG/M3;
TWA(AS TOTAL
DUST):
15 MG/M3;
TWA(RESPIRABLE
FRACTION):
5 MG/M3
TITANIUM DIOXIDE 13463-67-7 ACGIH TWA: 10 MG/M3 A4:
NOT CLASS. AS
HUMAN CARCIN
TITANIUM DIOXIDE 13463-67-7 OSHA TWA(AS TOTAL
DUST): 15 MG/M3
HEPTANE 142-82-5 ACGIH TWA: 400 PPM;
STEL: 500 PPM
HEPTANE 142-82-5 OSHA TWA:
2000 MG/M3(500
PPM)
SILICA, AMORPHOUS 7631-86-9 OSHA TWA
CONCENTRATION:
0.8 MG/M3;
TWA:
20 MILLIONS OF
PARTICLES/CU.
FT.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION: NONE REQUIRED.
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING. NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY. GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT. THE FOLLOWING
PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED: APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: WHITE THIXOTROPIC PASTE, SLIGHT ODOR
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NO DATA AVAILABLE
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.3 G/ML
SPECIFIC GRAVITY: 1.3 [REF STD: WATER=1]
SOLUBILITY IN WATER: NIL
SOLUBILITY- NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: 100,000 - 500,000 CENTIPOISE
HAZARDOUS AIR POLLUTANTS: 2.6% WEIGHT [TEST METHOD: CALCULATED]
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
38 G/L [TEST METHOD: TESTED PER EPA METHOD 24] [DETAILS: EU VOC CONTENT]
PERCENT VOLATILE: 2.83% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
38 G/L [TEST METHOD: TESTED PER EPA METHOD 24]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS:
AMINES
ALCOHOLS
WATER
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR
THE SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT
BELOW THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
ALLERGIC RESPIRATORY REACTION:
SIGNS/SYMPTOMS MAY INCLUDE DIFFICULTY BREATHING, WHEEZING, COUGH, AND
TIGHTNESS OF CHEST.
MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
SKIN CONTACT:
MILD SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, AND
DRYNESS.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CONTACT WITH THE EYES DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA.
ADDITIONAL HEALTH EFFECTS:
PROLONGED OR REPEATED EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
RESPIRATORY EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SHORTNESS OF BREATH, CHEST TIGHTNESS,
WHEEZING, INCREASED HEART RATE, BLUISH COLORED SKIN (CYANOSIS), SPUTUM
PRODUCTION, CHANGES IN LUNG FUNCTION TESTS, AND/OR RESPIRATORY FAILURE.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
TITANIUM DIOXIDE 13463-67-7 GRP. 2B: INTERNATIONAL AGENCY FOR
POSSIBLE HUMAN RESEARCH ON CANCER
CARC.
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO ISOCYANATES MAY DEVELOP A
CROSS-SENSITIZATION REACTION TO OTHER ISOCYANATES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE
NOT SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE; CALCULATED ATE:
VAPOR(4 HR) >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE; CALCULATED ATE:
>5,000 MG/KG
URETHANE POLYMER DERMAL LD50 ESTIMATED TO BE:
>5,000 MG/KG
URETHANE POLYMER INGESTION RAT LD50: >5,000 MG/KG
TITANIUM DIOXIDE DERMAL RABBIT LD50: >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50: >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50: >10,000 MG/KG
FUMED SILICA DERMAL RABBIT LD50: >5,000 MG/KG
FUMED SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
FUMED SILICA INGESTION RAT LD50: >5,110 MG/KG
P,P'-METHYLENEBIS DERMAL RABBIT LD50: >5,000 MG/KG
(PHENYL
ISOCYANATE)
P,P'-METHYLENEBIS INHALATION- RAT LC50: 0.368 MG/L
(PHENYL DUST/MIST
ISOCYANATE) (4 HOURS)
P,P'-METHYLENEBIS INGESTION RAT LD50: 31,600 MG/KG
(PHENYL
ISOCYANATE)
ZINC OXIDE DERMAL LD50 ESTIMATED TO BE: >5,000 MG/KG
ZINC OXIDE INHALATION- RAT LC50: >5.7 MG/L
DUST/MIST
(4 HOURS)
ZINC OXIDE INGESTION RAT LD50: >5,000 MG/KG
CARBITOL ACETATE DERMAL RABBIT LD50: 15,000 MG/KG
CARBITOL ACETATE INGESTION RAT LD50: 11,000 MG/KG
FUMED SILICA DERMAL RABBIT LD50: >5,000 MG/KG
FUMED SILICA INHALATION- RAT LC50: >0.691 MG/L
DUST/MIST
(4 HOURS)
FUMED SILICA INGESTION RAT LD50: >5,110 MG/KG
HEPTANE DERMAL RABBIT LD50: 3,000 MG/KG
HEPTANE INHALATION- RAT LC50: 103 MG/L
VAPOR (4
HOURS)
HEPTANE INGESTION RAT LD50: >15,000 MG/KG
(GAMMA- DERMAL RABBIT LD50: 2,270 MG/KG
MERCAPTOPROPYL)
TRIMETHOXYSILANE
(GAMMA- INGESTION RAT LD50: 770 MG/KG
MERCAPTOPROPYL)
TRIMETHOXYSILANE
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
FUMED SILICA RABBIT NO SIGNIFICANT IRRITATION
P,P'-METHYLENEBIS OFFICIAL CLASSIFICATION IRRITANT
(PHENYL ISOCYANATE)
ZINC OXIDE HUMAN AND ANIMAL NO SIGNIFICANT IRRITATION
CARBITOL ACETATE HUMAN AND ANIMAL MINIMAL IRRITATION
FUMED SILICA RABBIT NO SIGNIFICANT IRRITATION
HEPTANE HUMAN MILD IRRITANT
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT
IRRITATION
FUMED SILICA RABBIT NO SIGNIFICANT
IRRITATION
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) OFFICIAL SEVERE IRRITANT
CLASSIFICATION
ZINC OXIDE RABBIT MILD IRRITANT
CARBITOL ACETATE RABBIT SEVERE IRRITANT
FUMED SILICA RABBIT NO SIGNIFICANT
IRRITATION
HEPTANE PROFESSIONAL MODERATE IRRITANT
JUDGMENT
SKIN SENSITIZATION:
NAME SPECIES VALUE
TITANIUM DIOXIDE HUMAN AND ANIMAL NOT CLASSIFIED
FUMED SILICA HUMAN AND ANIMAL NOT CLASSIFIED
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) OFFICIAL SENSITIZING
CLASSIFICATION
ZINC OXIDE GUINEA PIG NOT CLASSIFIED
CARBITOL ACETATE HUMAN AND ANIMAL NOT CLASSIFIED
FUMED SILICA HUMAN AND ANIMAL NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
NAME SPECIES VALUE
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) HUMAN SENSITIZING
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
FUMED SILICA IN VITRO NOT MUTAGENIC
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ZINC OXIDE IN VITRO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
ZINC OXIDE IN VIVO SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
CARBITOL ACETATE IN VITRO NOT MUTAGENIC
FUMED SILICA IN VITRO NOT MUTAGENIC
HEPTANE IN VITRO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
FUMED SILICA NOT SPECIFIED MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
P,P'-METHYLENEBIS INHALATION RAT SOME POSITIVE DATA EXIST, BUT
(PHENYL ISOCYANATE) THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
FUMED SILICA NOT SPECIFIED MOUSE SOME POSITIVE DATA EXIST, BUT
THE DATA ARE NOT SUFFICIENT
FOR CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE SPECIES TEST RESULT EXPOSURE
DURATION
FUMED SILICA INGESTION NOT CLASSIFIED RAT NOAEL: 1
FOR FEMALE 509 GENERATION
REPRODUCTION MG/KG/DAY
FUMED SILICA INGESTION NOT CLASSIFIED RAT NOAEL: 1
FOR MALE 497 GENERATION
REPRODUCTION MG/KG/DAY
FUMED SILICA INGESTION NOT CLASSIFIED RAT NOAEL: DURING
FOR 1,350 ORGANOGEN-
DEVELOPMENT MG/KG/DAY ESIS
P,P'- INHALATION NOT CLASSIFIED RAT NOAEL: DURING
METHYLENEBIS FOR 0.004 MG/L ORGANOGEN-
(PHENYL DEVELOPMENT ESIS
ISOCYANATE)
ZINC OXIDE INGESTION NOT CLASSIFIED MULTIPLE NOAEL: PREMATING
FOR ANIMAL 125 & DURING
REPRODUCTION SPECIES MG/KG/DAY GESTATION
AND/OR
DEVELOPMENT
FUMED SILICA INGESTION NOT CLASSIFIED RAT NOAEL: 1
FOR FEMALE 509 GENERATION
REPRODUCTION MG/KG/DAY
FUMED SILICA INGESTION NOT CLASSIFIED RAT NOAEL: 1
FOR MALE 497 GENERATION
REPRODUCTION MG/KG/DAY
FUMED SILICA INGESTION NOT CLASSIFIED RAT NOAEL: DURING
FOR 1,350 ORGANOGEN-
DEVELOPMENT MG/KG/DAY ESIS
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
P,P'-METHYLENEBIS INHALATION RESPIRATORY IRRITATION MAY CAUSE
(PHENYL RESPIRATORY
ISOCYANATE) IRRITATION
CARBITOL ACETATE INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
CARBITOL ACETATE INGESTION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
HEPTANE INHALATION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
HEPTANE INHALATION RESPIRATORY IRRITATION SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
HEPTANE INGESTION CENTRAL NERVOUS MAY CAUSE
SYSTEM DEPRESSION DROWSINESS OR
DIZZINESS
NAME SPECIES TEST RESULT EXPOSURE
DURATION
P,P'-METHYLENEBIS OFFICIAL NOAEL: NOT AVAILABLE
(PHENYL CLASSIFICATION
ISOCYANATE)
CARBITOL ACETATE HUMAN AND ANIMAL NOAEL: NOT AVAILABLE NOT APPLICABLE
CARBITOL ACETATE MULTIPLE ANIMAL NOAEL: NOT AVAILABLE NOT APPLICABLE
SPECIES
HEPTANE HUMAN NOAEL: NOT AVAILABLE
HEPTANE HUMAN NOAEL: NOT AVAILABLE
HEPTANE HUMAN NOAEL: NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
TITANIUM DIOXIDE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA ARE
NOT SUFFICIENT FOR
CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY FIBROSIS NOT CLASSIFIED
FUMED SILICA INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
| SILICOSIS
P,P'-METHYLENEBIS INHALATION RESPIRATORY SYSTEM CAUSES DAMAGE TO ORGANS
(PHENYL THROUGH PROLONGED OR
ISOCYANATE) REPEATED EXPOSURE
ZINC OXIDE INGESTION NERVOUS SYSTEM NOT CLASSIFIED
ZINC OXIDE INGESTION ENDOCRINE SYSTEM | NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM | KIDNEY
AND/OR BLADDER
CARBITOL ACETATE INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
| LIVER | IMMUNE
SYSTEM | KIDNEY
AND/OR BLADDER
FUMED SILICA INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
| SILICOSIS
HEPTANE INHALATION LIVER | NERVOUS NOT CLASSIFIED
SYSTEM | KIDNEY
AND/OR BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
TITANIUM DIOXIDE RAT LOAEL: 0.01 MG/L 2 YEARS
TITANIUM DIOXIDE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
FUMED SILICA HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
P,P'-METHYLENEBIS RAT LOAEL: 0.004 MG/L 13 WEEKS
(PHENYL
ISOCYANATE)
ZINC OXIDE RAT NOAEL: 600 MG/KG/DAY 10 DAYS
ZINC OXIDE OTHER NOAEL: 500 MG/KG/DAY 6 MONTHS
CARBITOL ACETATE RAT NOAEL: 0.48 MG/L 2 WEEKS
FUMED SILICA HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
HEPTANE RAT NOAEL: 12 MG/L 26 WEEKS
ASPIRATION HAZARD:
NAME VALUE
HEPTANE ASPIRATION HAZARD
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
RESPIRATORY OR SKIN SENSITIZATION
SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATED EXPOSURE)
SECTION 313 TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF THAT
SECTION AND 40 CFR PART 372 (EPCRA):
INGREDIENT C.A.S. NO % BY WT
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 TRADE SECRET <2.4
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 <2.4
(BENZENE, 1,1'-METHYLENEBIS[4-
ISOCYANATO-)
P,P'-METHYLENEBIS(PHENYL ISOCYANATE) 101-68-8 <2.4
(DIISOCYANATES (CERTAIN CHEMICALS
ONLY))
ZINC OXIDE (ZINC COMPOUNDS) 1314-13-2 <2.3
CARBITOL ACETATE (GLYCOL ETHERS) 112-15-2 <2.0
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ALL REQUIRED COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE ACTIVE PORTION OF THE TSCA INVENTORY.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 16-5850-9
VERSION NUMBER: 13.00
ISSUE DATE: 10/22/18
SUPERCEDES DATE: 04/06/18
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED
IN ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
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