| Common Name: | MARINE ADHESIVE SEALANT FAST CURE 4000 UV, WHITE |
| Manufacturer: | 3M |
| SDS Revision Date: | 3/12/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 1RWH8, 1RWH9 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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3M(TM) MARINE ADHESIVE SEALANT FAST CURE 4000 UV, WHITE
03/12/19
3M
SAFETY DATA SHEET
COPYRIGHT, 2019, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 28-8279-3
VERSION NUMBER: 2.07
ISSUE DATE: 03/12/19
SUPERCEDES DATE: 03/05/19
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER:
3M(TM) MARINE ADHESIVE SEALANT FAST CURE 4000 UV, WHITE
PRODUCT IDENTIFICATION NUMBERS:
ID NUMBER UPC
62-5563-1632-1
62-5563-5232-6
7000121531
7000046623
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE: ADHESIVE
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: INDUSTRIAL ADHESIVES AND TAPES DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SKIN SENSITIZER: CATEGORY 1.
REPRODUCTIVE TOXICITY: CATEGORY 1B.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS:
EXCLAMATION MARK
HEALTH HAZARD
PICTOGRAMS:
EXCLAMATION MARK
HEALTH HAZARD
HAZARD STATEMENTS:
MAY CAUSE AN ALLERGIC SKIN REACTION.
MAY DAMAGE FERTILITY OR THE UNBORN CHILD.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
WEAR PROTECTIVE GLOVES.
CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ADVICE/ATTENTION. WASH CONTAMINATED CLOTHING BEFORE REUSE.
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
STORAGE: STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH APPLICABLE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
SUPPLEMENTAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO AMINES MAY DEVELOP A CROSS-SENSITIZATION
REACTION TO CERTAIN OTHER AMINES. PERSONS PREVIOUSLY SENSITIZED TO AMINES
MAY DEVELOP A CROSS-SENSITIZATION REACTION TO CERTAIN OTHER AMINES.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
CALCIUM CARBONATE 471-34-1 30 - 60 TRADE SECRET *
POLYETHER (NJTS REG. NO. TRADE SECRET* 15 - 40 TRADE SECRET *
04499600-6434)
DIISODECYL PHTHALATE 68515-49-1 10 - 20 TRADE SECRET *
TITANIUM DIOXIDE 13463-67-7 5 - 10 TRADE SECRET *
1,2-ETHANEDIAMINE, N1-[3- 1760-24-3 <1 TRADE SECRET *
(TRIMETHOXYSILYL)PROPYL]-
TIN, DIOCTYLBIS(2,4- 54068-28-9 <0.5 TRADE SECRET *
PENTANEDIONATO-O,O')-
NJTS OR NJTSRN: NEW JERSEY TRADE SECRET REGISTRY NUMBER.
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
FLUSH WITH LARGE AMOUNTS OF WATER. REMOVE CONTACT LENSES IF EASY TO DO.
CONTINUE RINSING. IF SIGNS/SYMPTOMS PERSIST, GET MEDICAL ATTENTION.
IF SWALLOWED: RINSE MOUTH. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER USE A FIRE FIGHTING AGENT SUITABLE FOR THE SURROUNDING
FIRE.
IN CASE OF FIRE:
USE A CARBON DIOXIDE OR DRY CHEMICAL EXTINGUISHER TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
IRRITANT VAPORS OR GASES DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER WITH BENTONITE,
VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT MATERIAL. MIX IN
SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER, ADDING AN ABSORBENT
MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR ENVIRONMENTAL HAZARD.
COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE. PLACE IN A CLOSED
CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE AUTHORITIES. SEAL THE
CONTAINER. DISPOSE OF COLLECTED MATERIAL AS SOON AS POSSIBLE IN ACCORDANCE
WITH APPLICABLE LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
KEEP OUT OF REACH OF CHILDREN. DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS
HAVE BEEN READ AND UNDERSTOOD. DO NOT BREATHE
DUST/FUME/GAS/MIST/VAPORS/SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT. WASH
THOROUGHLY AFTER HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED
OUT OF THE WORKPLACE. AVOID RELEASE TO THE ENVIRONMENT. WASH CONTAMINATED
CLOTHING BEFORE REUSE. USE PERSONAL PROTECTIVE EQUIPMENT (GLOVES,
RESPIRATORS, ETC.) AS REQUIRED.
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED TO PREVENT CONTAMINATION WITH WATER OR AIR.
IF CONTAMINATION IS SUSPECTED, DO NOT RESEAL CONTAINER. STORE AWAY FROM
HEAT. STORE AWAY FROM AMINES.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL
COMMENTS
TITANIUM DIOXIDE 13463-67-7 OSHA TWA(AS TOTAL DUST):
15 MG/M3
TITANIUM DIOXIDE 13463-67-7 ACGIH TWA: 10 MG/M3 A4:
NOT CLASS. AS
HUMAN CARCIN
LIMESTONE 471-34-1 OSHA TWA(AS TOTAL DUST):
15 MG/M3;
TWA(RESPIRABLE
FRACTION): 5 MG/M3
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
USE GENERAL DILUTION VENTILATION AND/OR LOCAL EXHAUST VENTILATION TO
CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT EXPOSURE LIMITS AND/OR
CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY. IF VENTILATION IS NOT ADEQUATE,
USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
SAFETY GLASSES WITH SIDE SHIELDS
SKIN/HAND PROTECTION:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
NOTE:
NITRILE GLOVES MAY BE WORN OVER POLYMER LAMINATE GLOVES TO IMPROVE
DEXTERITY.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
POLYMER LAMINATE
IF THIS PRODUCT IS USED IN A MANNER THAT PRESENTS A HIGHER POTENTIAL FOR
EXPOSURE (EG. SPRAYING, HIGH SPLASH POTENTIAL ETC.), THEN USE OF PROTECTIVE
COVERALLS MAY BE NECESSARY. SELECT AND USE BODY PROTECTION TO PREVENT
CONTACT BASED ON THE RESULTS OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING PROTECTIVE CLOTHING MATERIAL(S) ARE RECOMMENDED:
APRON - POLYMER LAMINATE
RESPIRATORY PROTECTION:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
ORGANIC VAPORS AND PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
SPECIFIC PHYSICAL FORM: PASTE
ODOR, COLOR, GRADE: WHITE VISCOUS LIQUID WITH SLIGHT ODOR.
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NO DATA AVAILABLE
MELTING POINT: NOT APPLICABLE
BOILING POINT: NOT APPLICABLE
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: NOT APPLICABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS(LEL): NOT APPLICABLE
FLAMMABLE LIMITS(UEL): NOT APPLICABLE
VAPOR PRESSURE: NOT APPLICABLE
VAPOR DENSITY: NOT APPLICABLE
DENSITY: 1.3 - 1.5 G/ML
SPECIFIC GRAVITY: 1.3 - 1.5 [REF STD:WATER=1]
SOLUBILITY IN WATER: NO DATA AVAILABLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
HAZARDOUS AIR POLLUTANTS: 0.011% WEIGHT
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS:
16 G/L [TEST METHOD: TESTED PER EPA METHOD 24]
PERCENT VOLATILE: 0.93% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS:
16 G/L [TEST METHOD: TESTED PER EPA METHOD 24]
VOC LESS H2O & EXEMPT SOLVENTS:
0.93% [TEST METHOD: TESTED PER EPA METHOD 24]
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN CONDITIONS
- SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: HEAT
10.5. INCOMPATIBLE MATERIALS:
ALCOHOLS
AMINES
WATER
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
CONTACT WITH THE SKIN DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
ALLERGIC SKIN REACTION (NON-PHOTO INDUCED):
SIGNS/SYMPTOMS MAY INCLUDE REDNESS, SWELLING, BLISTERING, AND ITCHING.
EYE CONTACT:
CONTACT WITH THE EYES DURING PRODUCT USE IS NOT EXPECTED TO RESULT IN
SIGNIFICANT IRRITATION.
INGESTION:
GASTROINTESTINAL IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE ABDOMINAL PAIN, STOMACH UPSET, NAUSEA, VOMITING
AND DIARRHEA. MAY CAUSE ADDITIONAL HEALTH EFFECTS (SEE BELOW).
ADDITIONAL HEALTH EFFECTS:
REPRODUCTIVE/DEVELOPMENTAL TOXICITY:
CONTAINS A CHEMICAL OR CHEMICALS WHICH CAN CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
CARCINOGENICITY:
INGREDIENT CAS NO. CLASS DESCRIPTION REGULATION
TITANIUM DIOXIDE 13463-67-7 GRP. 2B: INTERNATIONAL AGENCY
POSSIBLE HUMAN CARC. FOR RESEARCH ON CANCER
ADDITIONAL INFORMATION:
PERSONS PREVIOUSLY SENSITIZED TO AMINES MAY DEVELOP A CROSS-SENSITIZATION
REACTION TO CERTAIN OTHER AMINES.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT DERMAL NO DATA AVAILABLE;
CALCULATED ATE: >5,000 MG/KG
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
VAPOR(4 HR) CALCULATED ATE: >50 MG/L
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE: >5,000 MG/KG
CALCIUM CARBONATE DERMAL RAT LD50: >2,000 MG/KG
CALCIUM CARBONATE INHALATION- RAT LC50: 3 MG/L
DUST/MIST
(4 HOURS)
CALCIUM CARBONATE INGESTION RAT LD50: 6,450 MG/KG
POLYETHER (NJTS DERMAL LD50:
REG. NO. ESTIMATED TO BE >5,000 MG/KG
04499600-6434)
POLYETHER (NJTS INGESTION RAT LD50: 5,000 MG/KG
REG. NO.
04499600-6434)
DIISODECYL DERMAL RABBIT LD50: >3,160 MG/KG
PHTHALATE
DIISODECYL INHALATION- RAT LC50: >12.5 MG/L
PHTHALATE DUST/MIST
(4 HOURS)
DIISODECYL INGESTION RAT LD50: >9,700 MG/KG
PHTHALATE
TITANIUM DIOXIDE DERMAL RABBIT LD50: >10,000 MG/KG
TITANIUM DIOXIDE INHALATION- RAT LC50: >6.82 MG/L
DUST/MIST
(4 HOURS)
TITANIUM DIOXIDE INGESTION RAT LD50: >10,000 MG/KG
1,2-ETHANEDIAMINE, DERMAL RABBIT LD50: >2,000 MG/KG
N1-[3-(TRIMETHOXY-
SILYL)PROPYL]-
1,2-ETHANEDIAMINE, INHALATION- RAT LC50: >1.49, <2.44 MG/L
N1-[3-(TRIMETHOXY- DUST/MIST
SILYL)PROPYL]- (4 HOURS)
1,2-ETHANEDIAMINE, INGESTION RAT LD50: 1,897 MG/KG
N1-[3-(TRIMETHOXY-
SILYL)PROPYL]-
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
CALCIUM CARBONATE RABBIT NO SIGNIFICANT IRRITATION
DIISODECYL PHTHALATE RABBIT MINIMAL IRRITATION
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
1,2-ETHANEDIAMINE, RABBIT MILD IRRITANT
N1-[3-(TRIMETHOXY-
SILYL)PROPYL]-
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
CALCIUM CARBONATE RABBIT NO SIGNIFICANT IRRITATION
DIISODECYL PHTHALATE RABBIT MILD IRRITANT
TITANIUM DIOXIDE RABBIT NO SIGNIFICANT IRRITATION
1,2-ETHANEDIAMINE, RABBIT CORROSIVE
N1-[3-(TRIMETHOXY-
SILYL)PROPYL]-
SKIN SENSITIZATION:
NAME SPECIES VALUE
DIISODECYL PHTHALATE GUINEA PIG NOT CLASSIFIED
TITANIUM DIOXIDE HUMAN AND ANIMAL NOT CLASSIFIED
1,2-ETHANEDIAMINE, MULTIPLE SENSITIZING
N1-[3-(TRIMETHOXY- ANIMAL
SILYL)PROPYL]- SPECIES
TIN, DIOCTYLBIS(2,4- MOUSE SENSITIZING
PENTANEDIONATO-O,O')-
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
DIISODECYL PHTHALATE IN VITRO NOT MUTAGENIC
DIISODECYL PHTHALATE IN VIVO NOT MUTAGENIC
TITANIUM DIOXIDE IN VITRO NOT MUTAGENIC
TITANIUM DIOXIDE IN VIVO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
TITANIUM DIOXIDE INGESTION MULTIPLE NOT CARCINOGENIC
ANIMAL
SPECIES
TITANIUM DIOXIDE INHALATION RAT CARCINOGENIC
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
CALCIUM CARBONATE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
DIISODECYL PHTHALATE INGESTION NOT CLASSIFIED FOR FEMALE REPRODUCTION
DIISODECYL PHTHALATE INGESTION NOT CLASSIFIED FOR MALE REPRODUCTION
DIISODECYL PHTHALATE INGESTION TOXIC TO DEVELOPMENT
TIN, DIOCTYLBIS(2,4- INGESTION TOXIC TO DEVELOPMENT
PENTANEDIONATO-O,O')-
NAME SPECIES TEST RESULT EXPOSURE DURATION
CALCIUM CARBONATE RAT NOAEL: 625 MG/KG/DAY PREMATING & DURING
GESTATION
DIISODECYL PHTHALATE RAT NOAEL: 927 MG/KG/DAY 2 GENERATION
DIISODECYL PHTHALATE RAT NOAEL: 929 MG/KG/DAY 2 GENERATION
DIISODECYL PHTHALATE RAT NOAEL: 38 MG/KG/DAY 2 GENERATION
TIN, DIOCTYLBIS(2,4- RAT NOAEL: 1.8 MG/KG/DAY PREMATING INTO
PENTANEDIONATO-O,O')- LACTATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
CALCIUM CARBONATE INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
NAME SPECIES TEST RESULT EXPOSURE DURATION
CALCIUM CARBONATE RAT NOAEL: 0.812 MG/L 90 MINUTES
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
CALCIUM CARBONATE INHALATION RESPIRATORY SYSTEM NOT CLASSIFIED
DIISODECYL PHTHALATE INHALATION RESPIRATORY SYSTEM | NOT CLASSIFIED
HEMATOPOIETIC
SYSTEM | LIVER
DIISODECYL PHTHALATE INHALATION KIDNEY AND/OR NOT CLASSIFIED
BLADDER
DIISODECYL PHTHALATE INGESTION ENDOCRINE SYSTEM NOT CLASSIFIED
DIISODECYL PHTHALATE INGESTION LIVER | KIDNEY NOT CLASSIFIED
AND/OR BLADDER |
HEART
DIISODECYL PHTHALATE INGESTION HEMATOPOIETIC SYSTEM NOT CLASSIFIED
TITANIUM DIOXIDE INHALATION RESPIRATORY SYSTEM SOME POSITIVE DATA
EXIST, BUT THE DATA
ARE NOT SUFFICIENT
FOR CLASSIFICATION
TITANIUM DIOXIDE INHALATION PULMONARY FIBROSIS NOT CLASSIFIED
1,2-ETHANEDIAMINE, INHALATION RESPIRATORY SYSTEM MAY CAUSE DAMAGE TO
N1-[3-(TRIMETHOXY- ORGANS THOUGH
SILYL)PROPYL]- PROLONGED OR
REPEATED EXPOSURE
NAME SPECIES TEST RESULT EXPOSURE DURATION
CALCIUM CARBONATE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
DIISODECYL PHTHALATE RAT NOAEL: 0.5 MG/L 2 WEEKS
DIISODECYL PHTHALATE RAT NOAEL: 0.5 MG/L 2 GENERATION
DIISODECYL PHTHALATE RAT NOAEL: 686 MG/KG/DAY 90 DAYS
DIISODECYL PHTHALATE RAT NOAEL: 500 MG/KG/DAY 90 DAYS
DIISODECYL PHTHALATE DOG NOAEL: 320 MG/KG/DAY 90 DAYS
TITANIUM DIOXIDE RAT LOAEL: 0.01 MG/L 2 YEARS
TITANIUM DIOXIDE HUMAN NOAEL: NOT AVAILABLE OCCUPATIONAL EXPOSURE
1,2-ETHANEDIAMINE, RAT NOAEL: 0.015 MG/L 90 DAYS
N1-[3-(TRIMETHOXY-
SILYL)PROPYL]-
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. AS A
DISPOSAL ALTERNATIVE, INCINERATE IN A PERMITTED WASTE INCINERATION
FACILITY. PROPER DESTRUCTION MAY REQUIRE THE USE OF ADDITIONAL FUEL DURING
INCINERATION PROCESSES. EMPTY DRUMS/BARRELS/CONTAINERS USED FOR
TRANSPORTING AND HANDLING HAZARDOUS CHEMICALS (CHEMICAL
SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS HAZARDOUS AS PER APPLICABLE
REGULATIONS) SHALL BE CONSIDERED, STORED, TREATED & DISPOSED OF AS
HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY APPLICABLE WASTE REGULATIONS.
CONSULT WITH THE RESPECTIVE REGULATING AUTHORITIES TO DETERMINE THE
AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
EPCRA 311/312 HAZARD CLASSIFICATIONS:
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
REPRODUCTIVE TOXICITY
RESPIRATORY OR SKIN SENSITIZATION
ADDITIONAL TSCA INFORMATION:
COMPONENTS CAS NO ADDITIONAL INFORMATION
TIN, DIOCTYLBIS(2,4- 54068-28-9 ALLOWED USE(S): CATALYST.
PENTANEDIONATO-O,O')-
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
CALIFORNIA PROPOSITION 65:
INGREDIENT C.A.S. NO. LISTING
CADMIUM NONE MALE REPRODUCTIVE TOXIN
CADMIUM AND CADMIUM COMPOUNDS NONE CARCINOGEN
CADMIUM NONE DEVELOPMENTAL TOXIN
LEAD NONE FEMALE REPRODUCTIVE TOXIN
LEAD NONE MALE REPRODUCTIVE TOXIN
LEAD NONE CARCINOGEN
LEAD NONE DEVELOPMENTAL TOXIN
MERCURY AND MERCURY COMPOUNDS NONE DEVELOPMENTAL TOXIN
NICKEL (METALLIC) NONE CARCINOGEN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE FEMALE REPRODUCTIVE TOXIN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE MALE REPRODUCTIVE TOXIN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE CARCINOGEN
CHROMIUM (HEXAVALENT COMPOUNDS) NONE DEVELOPMENTAL TOXIN
15.3. CHEMICAL INVENTORIES
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA. ONE OR MORE OF THE COMPONENTS IN THIS
MATERIAL IS NOT LISTED ON THE TSCA INVENTORY, BUT IS APPROVED FOR SPECIFIC
COMMERCIAL USE(S) UNDER A US EPA LOW VOLUME EXEMPTION.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 2
FLAMMABILITY 1
INSTABILITY 0
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
DOCUMENT GROUP: 28-8279-3
VERSION NUMBER: 2.07
ISSUE DATE: 03/12/19
SUPERCEDES DATE: 03/05/19
DISCLAIMER:
THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) IS BELIEVED TO BE CORRECT
AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. USER IS RESPONSIBLE FOR DETERMINING WHETHER THE 3M PRODUCT IS FIT
FOR A PARTICULAR PURPOSE AND SUITABLE FOR USER'S METHOD OF USE OR
APPLICATION. GIVEN THE VARIETY OF FACTORS THAT CAN AFFECT THE USE AND
APPLICATION OF A 3M PRODUCT, SOME OF WHICH ARE UNIQUELY WITHIN THE USER'S
KNOWLEDGE AND CONTROL, IT IS ESSENTIAL THAT THE USER EVALUATE THE 3M
PRODUCT TO DETERMINE WHETHER IT IS FIT FOR A PARTICULAR PURPOSE AND
SUITABLE FOR USER'S METHOD OF USE OR APPLICATION.
3M PROVIDES INFORMATION IN ELECTRONIC FORM AS A SERVICE TO ITS CUSTOMERS.
DUE TO THE REMOTE POSSIBILITY THAT ELECTRONIC TRANSFER MAY HAVE RESULTED IN
ERRORS, OMISSIONS OR ALTERATIONS IN THIS INFORMATION, 3M MAKES NO
REPRESENTATIONS AS TO ITS COMPLETENESS OR ACCURACY. IN ADDITION,
INFORMATION OBTAINED FROM A DATABASE MAY NOT BE AS CURRENT AS THE
INFORMATION IN THE SDS AVAILABLE DIRECTLY FROM 3M
3M USA SDSS ARE AVAILABLE AT WWW.3M.COM