| Common Name: | ISOBUTYLENE (0.0005% - 1.34%), OXYGEN (19.5 - 23.5%) IN BALANCE NITROGEN, 50054 |
| Manufacturer: | CALGAZ |
| SDS Revision Date: | 3/24/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 1TAW7, 498Z26, 499A22, 55PT94 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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CALGAZ(TM)
ISOBUTYLENE (0.0005% - 1.34%), OXYGEN (19.5 - 23.5%) IN BALANCE NITROGEN
SAFETY DATA SHEET
50054
ACCORDING TO FEDERAL REGISTER / VOL. 77, NO. 58 / MONDAY,
MARCH 26, 2012 / RULES AND REGULATIONS
DATE OF ISSUE: 03/24/2015
VERSION: 1.0
| SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE |  |
AND OF THE COMPANY/UNDERTAKING
1.1. PRODUCT IDENTIFIER:
PRODUCT FORM: MIXTURE
PRODUCT NAME:
ISOBUTYLENE (0.0005% - 1.34%), OXYGEN (19.5 - 23.5%) IN BALANCE NITROGEN
1.2. RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
USE OF THE SUBSTANCE/MIXTURE: TEST GAS/CALIBRATION GAS.
1.3. DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
CALGAZ, DIVISION OF AIR LIQUIDE
821 CHESAPEAKE DRIVE
CAMBRIDGE, 21613
USA
T: 1-410-228-6400
F: 1-410-228-4251
INFO@CALGAZ.COM
WWW.CALGAZ.COM
1.4. EMERGENCY TELEPHONE NUMBER:
EMERGENCY NUMBER:
CHEMTREC: 1-800-424-9300
INTERNATIONALLY: 1-703-527-3887
| SECTION 2: HAZARDS IDENTIFICATION | |
2.1. CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
CLASSIFICATION (GHS-US):
COMPRESSED GAS: H280
FULL TEXT OF H-PHRASES: SEE SECTION 16
2.2. LABEL ELEMENTS:
GHS-US LABELING:
HAZARD PICTOGRAMS (GHS-US):
GHS04: GAS CYLINDER
SIGNAL WORD (GHS-US): WARNING
HAZARD STATEMENTS (GHS-US):
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
PRECAUTIONARY STATEMENTS (GHS-US):
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA
P403: STORE IN A WELL-VENTILATED PLACE
CGA-PG02:
PROTECT FROM SUNLIGHT WHEN AMBIENT TEMPERATURE EXCEEDS
52 DEG. C (125 DEG. F)
CGA-PG05: USE A BACK FLOW PREVENTIVE DEVICE IN THE PIPING
CGA-PG06: CLOSE VALVE AFTER EACH USE AND WHEN EMPTY
CGA-PG10: USE ONLY WITH EQUIPMENT RATED FOR CYLINDER PRESSURE
CGA-PG14: APPROACH SUSPECTED LEAK AREA WITH CAUTION
CGA-PG21: OPEN VALVE SLOWLY
2.3. OTHER HAZARDS: NO ADDITIONAL INFORMATION AVAILABLE
2.4. UNKNOWN ACUTE TOXICITY (GHS-US): NOT APPLICABLE
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
3.1. SUBSTANCE: NOT APPLICABLE
3.2. MIXTURE:
NAME PRODUCT IDENTIFIER % CLASSIFICATION
(GHS-US)
NITROGEN (CAS NO) 7727-37-9 75.16 - 80.4995 COMPRESSED GAS, H280
OXYGEN (CAS NO) 7782-44-7 19.5 - 23.5 OX. GAS 1, H270
ISOBUTYLENE (CAS NO) 115-11-7 0.0005 - 1.34 FLAM. GAS 1, H220
LIQUEFIED GAS, H280
FULL TEXT OF H-PHRASES: SEE SECTION 16
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
FIRST-AID MEASURES GENERAL:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE).
FIRST-AID MEASURES AFTER INHALATION:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
FIRST-AID MEASURES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
FIRST-AID MEASURES AFTER EYE CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
FIRST-AID MEASURES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SYMPTOMS/INJURIES AFTER INHALATION:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
SYMPTOMS/INJURIES UPON INTRAVENOUS ADMINISTRATION: NOT KNOWN.
CHRONIC SYMPTOMS: ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
NEEDED:
IF YOU FEEL UNWELL, SEEK MEDICAL ADVICE. IF BREATHING IS DIFFICULT,
GIVE OXYGEN.
| SECTION 5: FIREFIGHTING MEASURES | |
5.1. EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE.
UNSUITABLE EXTINGUISHING MEDIA:
DO NOT USE WATER JET TO EXTINGUISH.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FIRE HAZARD: THE PRODUCT IS NOT FLAMMABLE.
EXPLOSION HAZARD:
PRODUCT IS NOT EXPLOSIVE. HEAT MAY BUILD PRESSURE, RUPTURING CLOSED
CONTAINERS, SPREADING FIRE AND INCREASING RISK OF BURNS AND INJURIES.
REACTIVITY: NONE KNOWN.
5.3. ADVICE FOR FIREFIGHTERS:
FIREFIGHTING INSTRUCTIONS:
IN CASE OF FIRE: EVACUATE AREA. FIGHT FIRE REMOTELY DUE TO THE RISK OF
EXPLOSION. USE WATER SPRAY OR FOG FOR COOLING EXPOSED CONTAINERS. EXERCISE
CAUTION WHEN FIGHTING ANY CHEMICAL FIRE.
PROTECTION DURING FIREFIGHTING:
STANDARD PROTECTIVE CLOTHING AND EQUIPMENT (E.G., SELF CONTAINED BREATHING
APPARATUS) FOR FIRE FIGHTERS. DO NOT ENTER FIRE AREA WITHOUT PROPER
PROTECTIVE EQUIPMENT, INCLUDING RESPIRATORY PROTECTION.
SPECIFIC METHODS:
EXPOSURE TO FIRE MAY CAUSE CONTAINERS TO RUPTURE/EXPLODE. CONTINUE WATER
SPRAY FROM PROTECTED POSITION UNTIL CONTAINER STAYS COOL. MOVE CONTAINERS
AWAY FROM THE FIRE AREA IF THIS CAN BE DONE WITHOUT RISK.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
GENERAL MEASURES: ENSURE ADEQUATE VENTILATION.
6.1.1. FOR NON-EMERGENCY PERSONNEL:
PROTECTIVE EQUIPMENT:
WEAR PROTECTIVE EQUIPMENT CONSISTENT WITH THE SITE EMERGENCY PLAN.
EMERGENCY PROCEDURES:
ESCAPE THE DANGER AREA BY THE CLOSEST SAFE ROUTE. CLOSE DOORS AND WINDOWS
OF ADJACENT PREMISES. KEEP CONTAINERS CLOSED. MARK THE DANGER AREA. SEAL
OFF LOW-LYING AREAS. KEEP UPWIND.
6.1.2. FOR EMERGENCY RESPONDERS:
PROTECTIVE EQUIPMENT:
STANDARD PROTECTIVE CLOTHING AND EQUIPMENT (E.G., SELF CONTAINED BREATHING
APPARATUS) FOR FIRE FIGHTERS. EQUIP CLEANUP CREW WITH PROPER PROTECTION.
EMERGENCY PROCEDURES: EVACUATE AND LIMIT ACCESS. VENTILATE AREA.
6.2. ENVIRONMENTAL PRECAUTIONS: TRY TO STOP RELEASE IF SAFE TO DO SO.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
FOR CONTAINMENT: TRY TO STOP RELEASE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
DISPOSE OF THIS MATERIAL AND ITS CONTAINER IN ACCORDANCE WITH LOCAL
REGULATIONS.
6.4. REFERENCE TO OTHER SECTIONS: SEE ALSO SECTIONS 8 AND 13.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
ADDITIONAL HAZARDS WHEN PROCESSED:
PRESSURIZED CONTAINER:
DO NOT PIERCE OR BURN, EVEN AFTER USE. USE EQUIPMENT RATED FOR CYLINDER
PRESSURE.
PRECAUTIONS FOR SAFE HANDLING:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
SAFE HANDLING OF THE GAS RECEPTACLE:
PROTECT CYLINDERS FROM PHYSICAL DAMAGE; DO NOT DRAG, ROLL, SLIDE OR
DROP. DO NOT REMOVE OR DEFACE LABELS PROVIDED BY THE SUPPLIER FOR THE
IDENTIFICATION OF THE CYLINDER CONTENTS.
SAFE USE OF THE PRODUCT:
THE SUBSTANCE MUST BE HANDLED IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE
AND SAFETY PROCEDURES. ONLY EXPERIENCED AND PROPERLY INSTRUCTED PERSONS
SHOULD HANDLE GASES UNDER PRESSURE. CONSIDER PRESSURE RELIEF DEVICE(S)
IN GAS INSTALLATIONS. ENSURE THE COMPLETE GAS SYSTEM WAS (OR IS REGULARILY)
CHECKED FOR LEAKS BEFORE USE. DO NOT REMOVE OR DEFACE LABELS PROVIDED BY
THE SUPPLIER FOR THE IDENTIFICATION OF THE CYLINDER CONTENTS. USE ONLY
PROPERLY SPECIFIED EQUIPMENT WHICH IS SUITABLE FOR THIS PRODUCT, ITS
SUPPLY PRESSURE AND TEMPERATURE. CONTACT YOUR GAS SUPPLIER IF IN DOUBT.
HYGIENE MEASURES: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
7.2. CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
TECHNICAL MEASURES: NONE KNOWN.
STORAGE CONDITIONS:
DO NOT EXPOSE TO TEMPERATURES EXCEEDING 52 DEG. C (125 DEG. F). KEEP
CONTAINER CLOSED WHEN NOT IN USE. PROTECT CYLINDER FROM PHYSICAL DAMAGE.
STORE IN WELL VENTILATED AREA.
INCOMPATIBLE PRODUCTS: NONE KNOWN.
INCOMPATIBLE MATERIALS: FLAMMABLE MATERIALS.
STORAGE AREA: STORE AWAY FROM HEAT. STORE IN A WELL-VENTILATED PLACE.
7.3. SPECIFIC END USE(S): SEE SECTION 1.2.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
ISOBUTYLENE (0.0005% - 1.34%), OXYGEN (19.5 - 23.5%) IN BALANCE NITROGEN:
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
ISOBUTYLENE (115-11-7):
ACGIH:
ACGIH TWA (PPM): 250 PPM
OSHA: NOT APPLICABLE
OXYGEN (7782-44-7):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
NITROGEN (7727-37-9):
ACGIH: NOT APPLICABLE
OSHA: NOT APPLICABLE
8.2. EXPOSURE CONTROLS:
APPROPRIATE ENGINEERING CONTROLS:
PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION. SYSTEMS UNDER
PRESSURE SHOULD BE REGULARLY CHECKED FOR LEAKAGES. CONSIDER WORK PERMIT
SYSTEM E.G. FOR MAINTENANCE ACTIVITIES. ENSURE EXPOSURE IS BELOW
OCCUPATIONAL EXPOSURE LIMITS.
HAND PROTECTION:
WEAR WORKING GLOVES WHEN HANDLING GAS CONTAINERS. 29 CFR 1910.138:
HAND PROTECTION.
EYE PROTECTION:
WEAR SAFETY GLASSES WITH SIDE SHIELDS. 29 CFR 1910.133:
EYE AND FACE PROTECTION.
SKIN AND BODY PROTECTION:
WEAR SUITABLE PROTECTIVE CLOTHING, E.G. - LAB COATS, COVERALLS OR
FLAME RESISTANT CLOTHING.
RESPIRATORY PROTECTION:
NONE NECESSARY DURING NORMAL AND ROUTINE OPERATIONS. SEE
SECTIONS 5 & 6.
THERMAL HAZARD PROTECTION:
NONE NECESSARY DURING NORMAL AND ROUTINE OPERATIONS.
ENVIRONMENTAL EXPOSURE CONTROLS:
REFER TO LOCAL REGULATIONS FOR RESTRICTION OF EMISSIONS TO THE
ATMOSPHERE. SEE SECTION 13 FOR SPECIFIC METHODS FOR WASTE GAS
TREATMENT.
OTHER INFORMATION:
WEAR SAFETY SHOES WHILE HANDLING CONTAINERS. 29 CFR 1910.136:
FOOT PROTECTION.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: GAS
APPEARANCE: CLEAR, COLORLESS GAS.
MOLECULAR MASS: NOT APPLICABLE FOR GAS-MIXTURES.
COLOR: COLORLESS
ODOR: COAL GAS;ODORLESS
ODOR THRESHOLD: NO DATA AVAILABLE
PH: NOT APPLICABLE FOR GAS-MIXTURES.
RELATIVE EVAPORATION RATE (BUTYL ACETATE=1): NO DATA AVAILABLE
RELATIVE EVAPORATION RATE (ETHER=1): NOT APPLICABLE FOR GAS-MIXTURES.
MELTING POINT: NO DATA AVAILABLE
FREEZING POINT: NO DATA AVAILABLE
BOILING POINT: NO DATA AVAILABLE
FLASH POINT: NO DATA AVAILABLE
AUTO-IGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): SEE SECT. 2.1 & 2.2
VAPOR PRESSURE: NOT APPLICABLE.
RELATIVE VAPOR DENSITY AT 20 DEG. C: NO DATA AVAILABLE
RELATIVE DENSITY: NO DATA AVAILABLE
RELATIVE GAS DENSITY: LIGHTER OR SIMILAR TO AIR.
SOLUBILITY:
WATER:
SOLUBILITY IN WATER OF COMPONENT(S) OF THE MIXTURE:
INSOLUBLE
39 MG/L
20 MG/L
LOG POW: NOT APPLICABLE FOR GAS-MIXTURES.
LOG KOW: NOT APPLICABLE FOR GAS-MIXTURES.
VISCOSITY, KINEMATIC: NOT APPLICABLE.
VISCOSITY, DYNAMIC: NOT APPLICABLE.
EXPLOSIVE PROPERTIES: NOT APPLICABLE - NOT FLAMMABLE.
OXIDIZING PROPERTIES:
SUPPORTS COMBUSTION. NOT COMBUSTIBLE BUT ENHANCES COMBUSTION OF OTHER
SUBSTANCES.
EXPLOSIVE LIMITS: NOT APPLICABLE - NOT FLAMMABLE
9.2. OTHER INFORMATION:
ADDITIONAL INFORMATION: NONE.
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY: NONE KNOWN.
10.2. CHEMICAL STABILITY: STABLE UNDER NORMAL CONDITIONS.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
CAN FORM EXPLOSIVE MIXTURES WITH FLAMMABLE MATERIALS.
10.4. CONDITIONS TO AVOID:
NONE UNDER RECOMMENDED STORAGE AND HANDLING CONDITIONS (SEE SECTION 7).
10.5. INCOMPATIBLE MATERIALS: FLAMMABLE MATERIALS.
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER NORMAL CONDITIONS OF STORAGE AND USE HAZARDOUS DECOMPOSITION PRODUCTS
SHOULD NOT BE PRODUCED.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NOT CLASSIFIED
ISOBUTYLENE (115-11-7):
LC50 INHALATION RAT (MG/L): 620 MG/L/4H
LC50 INHALATION RAT (PPM): 239620.46 PPM/4H
ATE US (GASES): 271823.000 PPMV/4H
ATE US (VAPORS): 620.000 MG/L/4H
ATE US (DUST, MIST): 620.000 MG/L/4H
OXYGEN (7782-44-7):
LC50 INHALATION RAT (PPM): 800000 PPM/4H
NITROGEN (7727-37-9):
LC50 INHALATION RAT (PPM): 820000 PPM/4H
SKIN CORROSION/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE FOR GAS-MIXTURES.
SERIOUS EYE DAMAGE/IRRITATION: NOT CLASSIFIED
PH: NOT APPLICABLE FOR GAS-MIXTURES.
RESPIRATORY OR SKIN SENSITIZATION: NOT CLASSIFIED
GERM CELL MUTAGENICITY: NOT CLASSIFIED
CARCINOGENICITY: NOT CLASSIFIED
ISOBUTYLENE (115-11-7):
NATIONAL TOXICOLOGY PROGRAM (NTP) STATUS: 1 - EVIDENCE OF CARCINOGENICITY
REPRODUCTIVE TOXICITY: NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): NOT CLASSIFIED
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): NOT CLASSIFIED
ASPIRATION HAZARD: NOT CLASSIFIED
SYMPTOMS/INJURIES AFTER INHALATION:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER SKIN CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER EYE CONTACT:
ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
SYMPTOMS/INJURIES AFTER INGESTION:
INGESTION IS NOT CONSIDERED A POTENTIAL ROUTE OF EXPOSURE.
SYMPTOMS/INJURIES UPON INTRAVENOUS ADMINISTRATION: NOT KNOWN.
CHRONIC SYMPTOMS: ADVERSE EFFECTS NOT EXPECTED FROM THIS PRODUCT.
| SECTION 12: ECOLOGICAL INFORMATION | |
12.1. TOXICITY:
ECOLOGY - GENERAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.2. PERSISTENCE AND DEGRADABILITY:
ISOBUTYLENE (0.0005% - 1.34%), OXYGEN (19.5 - 23.5%) IN BALANCE NITROGEN:
PERSISTENCE AND DEGRADABILITY: NO DATA AVAILABLE.
ISOBUTYLENE (115-11-7):
PERSISTENCE AND DEGRADABILITY:
THE SUBSTANCE IS BIODEGRADABLE. UNLIKELY TO PERSIST.
OXYGEN (7782-44-7):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
PERSISTENCE AND DEGRADABILITY: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.3. BIOACCUMULATIVE POTENTIAL:
ISOBUTYLENE (0.0005% - 1.34%), OXYGEN (19.5 - 23.5%) IN BALANCE NITROGEN:
LOG POW: NOT APPLICABLE FOR GAS-MIXTURES.
LOG KOW: NOT APPLICABLE FOR GAS-MIXTURES.
BIOACCUMULATIVE POTENTIAL: NO DATA AVAILABLE.
ISOBUTYLENE (115-11-7):
LOG POW: 2.35
BIOACCUMULATIVE POTENTIAL:
NOT EXPECTED TO BIOACCUMULATE DUE TO THE LOW LOG KOW (LOG KOW < 4).
REFER TO SECTION 9.
OXYGEN (7782-44-7):
LOG POW: NOT APPLICABLE FOR INORGANIC GASES.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
LOG POW: NOT APPLICABLE FOR INORGANIC GASES.
BIOACCUMULATIVE POTENTIAL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.4. MOBILITY IN SOIL:
ISOBUTYLENE (0.0005% - 1.34%), OXYGEN (19.5 - 23.5%) IN BALANCE NITROGEN:
MOBILITY IN SOIL: NO DATA AVAILABLE.
ISOBUTYLENE (115-11-7):
ECOLOGY - SOIL:
BECAUSE OF ITS HIGH VOLATILITY, THE PRODUCT IS UNLIKELY TO CAUSE GROUND
OR WATER POLLUTION.
OXYGEN (7782-44-7):
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
NITROGEN (7727-37-9):
ECOLOGY - SOIL: NO ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
12.5. OTHER ADVERSE EFFECTS:
EFFECT ON OZONE LAYER: NONE.
EFFECT ON THE GLOBAL WARMING:
NO KNOWN ECOLOGICAL DAMAGE CAUSED BY THIS PRODUCT.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. WASTE TREATMENT METHODS:
WASTE TREATMENT METHODS:
CONTACT SUPPLIER IF GUIDANCE IS REQUIRED. DO NOT DISCHARGE INTO ANY
PLACE WHERE ITS ACCUMULATION COULD BE DANGEROUS. ENSURE THAT THE
EMISSION LEVELS FROM LOCAL REGULATIONS OR OPERATING PERMITS ARE NOT
EXCEEDED.
WASTE DISPOSAL RECOMMENDATIONS:
REFER TO THE CGA PAMPHLET P-63 "DISPOSAL OF GASES" AVAILABLE AT
WWW.CGANET.COM FOR MORE GUIDANCE ON SUITABLE DISPOSAL METHODS.
| SECTION 14: TRANSPORT INFORMATION | |
IN ACCORDANCE WITH DOT:
TRANSPORT DOCUMENT DESCRIPTION:
UN1956 COMPRESSED GAS, N.O.S. (OXYGEN, NITROGEN)
UN-NO.(DOT): UN1956
PROPER SHIPPING NAME (DOT): COMPRESSED GAS, N.O.S.
HAZARD LABELS (DOT): 2.2 - NON-FLAMMABLE GAS
DOT SYMBOLS: G - IDENTIFIES PSN REQUIRING A TECHNICAL NAME
DOT PACKAGING EXCEPTIONS (49 CFR 173.XXX): 306;307
DOT PACKAGING NON BULK (49 CFR 173.XXX): 302;305
DOT PACKAGING BULK (49 CFR 173.XXX): 314;315
DOT QUANTITY LIMITATIONS PASSENGER AIRCRAFT/RAIL (49 CFR 173.27): 75 KG
DOT QUANTITY LIMITATIONS CARGO AIRCRAFT ONLY (49 CFR 175.75): 150 KG
DOT VESSEL STOWAGE LOCATION:
A - THE MATERIAL MAY BE STOWED "ON DECK" OR "UNDER DECK" ON A CARGO VESSEL
AND ON A PASSENGER VESSEL.
ADDITIONAL INFORMATION:
OTHER INFORMATION: NO SUPPLEMENTARY INFORMATION AVAILABLE.
SPECIAL TRANSPORT PRECAUTIONS:
AVOID TRANSPORT ON VEHICLES WHERE THE LOAD SPACE IS NOT SEPARATED FROM
THE DRIVER'S COMPARTMENT. ENSURE VEHICLE DRIVER IS AWARE OF THE POTENTIAL
HAZARDS OF THE LOAD AND KNOWS WHAT TO DO IN THE EVENT OF AN ACCIDENT OR AN
EMERGENCY. BEFORE TRANSPORTING PRODUCT CONTAINERS:
ENSURE THERE IS ADEQUATE VENTILATION.
ENSURE THAT CONTAINERS ARE FIRMLY SECURED.
ENSURE CYLINDER VALVE IS CLOSED AND NOT LEAKING.
ENSURE VALVE OUTLET CAP NUT OR PLUG (WHERE PROVIDED) IS CORRECTLY FITTED.
ENSURE VALVE PROTECTION DEVICE (WHERE PROVIDED) IS CORRECTLY FITTED.
ADR:
TRANSPORT DOCUMENT DESCRIPTION: UN 1956 COMPRESSED GAS, N.O.S., 2.2
CLASS (ADR): 2 - GASES
HAZARD LABELS (ADR): 2.2 - NON-FLAMMABLE COMPRESSED GAS
TRANSPORT BY SEA:
UN-NO. (IMDG): 1956
PROPER SHIPPING NAME (IMDG): COMPRESSED GAS, N.O.S.
CLASS (IMDG): 2.2 - NON-FLAMMABLE, NON-TOXIC GASES
AIR TRANSPORT:
UN-NO.(IATA): 1956
PROPER SHIPPING NAME (IATA): COMPRESSED GAS, N.O.S.
CLASS (IATA): 2
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS:
ISOBUTYLENE (115-11-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
OXYGEN (7782-44-7):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
NITROGEN (7727-37-9):
LISTED ON THE UNITED STATES TSCA (TOXIC SUBSTANCES CONTROL ACT) INVENTORY
15.2. INTERNATIONAL REGULATIONS:
CANADA:
ISOBUTYLENE (115-11-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST)
OXYGEN (7782-44-7):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST)
WHMIS CLASSIFICATION:
CLASS A - COMPRESSED GAS
CLASS C - OXIDIZING MATERIAL
NITROGEN (7727-37-9):
LISTED ON THE CANADIAN DSL (DOMESTIC SUSTANCES LIST)
WHMIS CLASSIFICATION: CLASS A - COMPRESSED GAS
EU-REGULATIONS:
ISOBUTYLENE (115-11-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
OXYGEN (7782-44-7):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
NITROGEN (7727-37-9):
LISTED ON THE EEC INVENTORY EINECS (EUROPEAN INVENTORY OF EXISTING
COMMERCIAL CHEMICAL SUBSTANCES)
CLASSIFICATION ACCORDING TO REGULATION (EC) NO. 1272/2008 [CLP]:
NOT CLASSIFIED
CLASSIFICATION ACCORDING TO DIRECTIVE 67/548/EEC [DSD] OR 1999/45/EC [DPD]:
15.2.2. NATIONAL REGULATIONS:
ISOBUTYLENE (115-11-7):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE JAPANESE ENCS (EXISTING & NEW CHEMICAL SUBSTANCES) INVENTORY
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
OXYGEN (7782-44-7):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED OR
IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
NITROGEN (7727-37-9):
LISTED ON THE AICS (AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES)
LISTED ON IECSC (INVENTORY OF EXISTING CHEMICAL SUBSTANCES PRODUCED
OR IMPORTED IN CHINA)
LISTED ON THE KOREAN ECL (EXISTING CHEMICALS LIST)
LISTED ON NZIOC (NEW ZEALAND INVENTORY OF CHEMICALS)
LISTED ON PICCS (PHILIPPINES INVENTORY OF CHEMICALS AND CHEMICAL
SUBSTANCES)
15.3. US STATE REGULATIONS:
ISOBUTYLENE (115-11-7):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
OXYGEN (7782-44-7):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
NITROGEN (7727-37-9):
U.S. - MASSACHUSETTS - RIGHT TO KNOW LIST
U.S. - NEW JERSEY - RIGHT TO KNOW HAZARDOUS SUBSTANCE LIST
U.S. - PENNSYLVANIA - RTK (RIGHT TO KNOW) LIST
| SECTION 16: OTHER INFORMATION | |
INDICATION OF CHANGES:
REVISED SAFETY DATA SHEET IN ACCORDANCE WITH OSHA FINAL RULE ON GHS
IMPLEMENTATION PROMULGATED MARCH 26, 2012.
OTHER INFORMATION:
THIS SAFETY DATA SHEET IS OFFERED PURSUANT TO OSHA'S HAZARD
COMMUNICATION STANDARD, 29 CFR, 1910.1200. OTHER GOVERNMENT
REGULATIONS MUST BE REVIEWED FOR APPLICABILITY TO THIS PRODUCT.
FULL TEXT OF H-PHRASES:
COMPRESSED GAS: GASES UNDER PRESSURE COMPRESSED GAS
FLAM. GAS 1: FLAMMABLE GASES CATEGORY 1
LIQUEFIED GAS: GASES UNDER PRESSURE LIQUEFIED GAS
OX. GAS 1: OXIDIZING GASES CATEGORY 1
H220: EXTREMELY FLAMMABLE GAS
H270: MAY CAUSE OR INTENSIFY FIRE; OXIDIZER
H280: CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED
SDS US (GHS HAZCOM 2012)
THIS SAFETY DATA SHEET IS OFFERED PURSUANT TO OSHA'S HAZARD COMMUNICATION
STANDARD, 29 CFR, 1910.1200. OTHER GOVERNMENT REGULATIONS MUST BE REVIEWED
FOR APPLICABILITY TO THIS GAS MIXTURE. TO THE BEST OF CALGAZ'S KNOWLEDGE,
THE INFORMATION CONTAINED HEREIN IS RELIABLE AND ACCURATE AS OF THIS DATE;
HOWEVER, ACCRUACY, SUITABILITY OR COMPLETENESS ARE NOT GUARANTEED AND NO
WARRANTIES OF ANY TYPE, EITHER EXPRESS OR IMPLIED, ARE PROVIDED. THE
INFORMATION CONTAINED HEREIN RELATES ONLY TO THIS SPECIFIC PRODUCT. IF
THIS GAS MIXTURE IS COMBINED WITH OTHER MATERIALS, ALL COMPONENT
PROPERTIES MUST BE CONSIDERED. DATA MAY BE CHANGED FROM TIME TO TIME. BE
SURE TO CONSULT THE LATEST EDITION.
EN (ENGLISH US)
SDS ID: 50054