| Common Name: | SIE S37 1-GL METALMAX SGLS SAFETY YELLOW, 210477 |
| Manufacturer: | RUST-OLEUM |
| SDS Revision Date: | 5/10/2016 |
| SDS Format: | GHS-US |
| Item Number(s): | 1TBF2 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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DATE PRINTED: 5/10/2016
SAFETY DATA SHEET
RUST-OLEUM CORPORATION
TRUSTED QUALITY SINCE 1921
WWW.RUSTOLEUM.COM
| 1. IDENTIFICATION |  |
PRODUCT NAME: SIE S37 1-GL METALMAX SGLS SAFETY YELLOW
PRODUCT IDENTIFIER: 210477
PRODUCT USE/CLASS: TOPCOAT/SIERRA S-37
REVISION DATE: 5/10/2016
SUPERCEDES DATE: 9/2/2014
SUPPLIER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
MANUFACTURER:
RUST-OLEUM CORPORATION
11 HAWTHORN PARKWAY
VERNON HILLS, IL 60061
USA
PREPARER: REGULATORY DEPARTMENT
EMERGENCY TELEPHONE:
24 HOUR HOTLINE: 847-367-7700
| 2. HAZARD IDENTIFICATION | |
CLASSIFICATION:
SYMBOL(S) OF PRODUCT: EXCLAMATION MARK
SIGNAL WORD: WARNING
GHS HAZARD STATEMENTS:
SKIN SENSITIZER, CATEGORY 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
GHS LABEL PRECAUTIONARY STATEMENTS:
P261: AVOID BREATHING DUST, FUMES, GASES, MISTS, VAPORS, OR SPRAY.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P302+P352:
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
GHS SDS PRECAUTIONARY STATEMENTS:
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
HAZARDOUS SUBSTANCES:
CHEMICAL NAME CAS-NO. WT.% GHS SYMBOLS GHS STATEMENTS
RANGE
TITANIUM DIOXIDE 13463-67-7 2.5-10 NOT AVAILABLE NOT AVAILABLE
KAOLIN CLAY 1332-58-7 1.0-2.5 NOT AVAILABLE NOT AVAILABLE
ZINC PHOSPHATE 7779-90-0 1.0-2.5 NOT AVAILABLE NOT AVAILABLE
BIS(1,2,2,6,6- 41556-26-7 0.1-1.0 GHS07 H317
PENTAMETHYL-4-
PIPERIDINYL)
SEBACATE
5-CHLORO-2-METHYL- 55965-84-9 <0.1 GHS05-GHS06 H301-311-314-
4-ISOTHIAZOLIN- 317-331
3-ONE MIXTURE
WITH 2-METHYL-4-
ISOTHIAZOLIN-3-ONE
| 4. FIRST-AID MEASURES | |
FIRST AID - EYE CONTACT:
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. DO NOT ALLOW RUBBING OF EYES OR
KEEPING EYES CLOSED.
FIRST AID - SKIN CONTACT:
WASH SKIN WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS OR PERSISTS.
FIRST AID - INHALATION:
REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL ATTENTION. DO
NOT USE MOUTH-TO-MOUTH RESUSCITATION. IF YOU EXPERIENCE DIFFICULTY IN
BREATHING, LEAVE THE AREA TO OBTAIN FRESH AIR. IF CONTINUED DIFFICULTY IS
EXPERIENCED, GET MEDICAL ASSISTANCE IMMEDIATELY.
FIRST AID - INGESTION:
IF SWALLOWED, RINSE MOUTH WITH WATER. IF FEELING UNWELL, GET MEDICAL
ATTENTION. SWALLOWING LESS THAN AN OUNCE WILL NOT CAUSE SIGNIFICANT HARM.
FOR LARGER AMOUNTS, DO NOT INDUCE VOMITING, BUT GIVE ONE OR TWO GLASSES OF
WATER TO DRINK AND GET MEDICAL ATTENTION.
| 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
ALCOHOL FILM FORMING FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG
UNUSUAL FIRE AND EXPLOSION HAZARDS:
KEEP CONTAINERS TIGHTLY CLOSED. FLASH POINT IS TESTED TO BE GREATER THAN
200 DEGREES F. NO UNUSUAL FIRE OR EXPLOSION HAZARDS NOTED.
SPECIAL FIREFIGHTING PROCEDURES:
WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT BUILDUP OF STEAM.
IF WATER IS USED, FOG NOZZLES ARE PREFERRED.
| 6. ACCIDENTAL RELEASE MEASURES | |
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
IF SPILLED, CONTAIN SPILLED MATERIAL AND REMOVE WITH INERT ABSORBENT.
DISPOSE OF CONTAMINATED ABSORBENT, CONTAINER, AND UNUSED CONTENTS IN
ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. DO NOT INCINERATE
CLOSED CONTAINERS DISPOSE OF ACCORDING TO LOCAL, STATE (PROVINCIAL) AND
FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
| 7. HANDLING AND STORAGE | |
HANDLING:
WASH THOROUGHLY AFTER HANDLING. WASH HANDS BEFORE EATING. REMOVE
CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE. USE ONLY WITH ADEQUATE
VENTILATION. FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS
EMPTIED BECAUSE IT MAY RETAIN PRODUCT RESIDUES. AVOID BREATHING FUMES,
VAPORS, OR MIST. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID
CONTACT WITH EYES.
STORAGE:
STORE IN A DRY, WELL VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED WHEN
NOT IN USE. KEEP FROM FREEZING. KEEP CONTAINER CLOSED WHEN NOT IN USE.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CHEMICAL NAME CAS-NO. WEIGHT % LESS THAN
TITANIUM DIOXIDE 13463-67-7 10.0
KAOLIN CLAY 1332-58-7 5.0
ZINC PHOSPHATE 7779-90-0 5.0
BIS(1,2,2,6,6-PENTAMETHYL-4- 41556-26-7 1.0
PIPERIDINYL) SEBACATE
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN- 55965-84-9 0.1
3-ONE MIXTURE WITH 2-METHYL-4-
ISOTHIAZOLIN-3-ONE
CHEMICAL NAME ACGIH ACGIH OSHA OSHA
TLV-TWA TLV-STEL PEL-TWA PEL-CEILING
TITANIUM DIOXIDE 10 MG/M3 N.E. 15 MG/M3 N.E.
KAOLIN CLAY 2 MG/M3 N.E. 15 MG/M3 N.E.
ZINC PHOSPHATE N.E. N.E. N.E. N.E.
BIS(1,2,2,6,6- N.E. N.E. N.E. N.E.
PENTAMETHYL-4-
PIPERIDINYL) SEBACATE
5-CHLORO-2-METHYL-4- N.E. N.E. N.E. N.E.
ISOTHIAZOLIN-3-ONE
MIXTURE WITH 2-METHYL-
4-ISOTHIAZOLIN-3-ONE
PERSONAL PROTECTION:
ENGINEERING CONTROLS:
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS.
PREVENT BUILD-UP OF VAPORS BY OPENING ALL DOORS AND WINDOWS TO ACHIEVE
CROSS-VENTILATION.
RESPIRATORY PROTECTION:
A RESPIRATORY PROTECTION PROGRAM THAT MEETS OSHA 1910.134 AND ANSI Z88.2
REQUIREMENTS MUST BE FOLLOWED WHENEVER WORKPLACE CONDITIONS WARRANT A
RESPIRATOR'S USE. A NIOSH/MSHA APPROVED AIR PURIFYING RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCENTRATIONS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS.
SKIN PROTECTION:
USE GLOVES TO PREVENT PROLONGED SKIN CONTACT. NITRILE OR NEOPRENE GLOVES
MAY AFFORD ADEQUATE SKIN PROTECTION.
EYE PROTECTION:
USE SAFETY EYEWEAR DESIGNED TO PROTECT AGAINST SPLASH OF LIQUIDS. USE ANSI
Z87.1 APPROVED SAFETY EYEWEAR.
OTHER PROTECTIVE EQUIPMENT:
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER GUIDANCE
REGARDING TYPES OF PERSONAL PROTECTIVE EQUIPMENT AND THEIR APPLICATIONS.
REFER TO SAFETY SUPERVISOR OR INDUSTRIAL HYGIENIST FOR FURTHER INFORMATION
REGARDING PERSONAL PROTECTIVE EQUIPMENT AND ITS APPLICATION.
HYGIENIC PRACTICES:
WASH THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING OR SMOKING.
REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND LAUNDER BEFORE REUSE.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: LIQUID
PHYSICAL STATE: LIQUID
ODOR: SOLVENT LIKE
ODOR THRESHOLD: N.E.
RELATIVE DENSITY: 1.152
PH: N.D.
FREEZE POINT, DEG. C: N.D.
VISCOSITY: N.D.
SOLUBILITY IN WATER: SOLUABLE
PARTITION COEFFICIENT, N-OCTANOL/WATER: N.D.
DECOMPOSITION TEMP., DEG. C: N.D.
BOILING RANGE, DEG. C: 100 - 537
EXPLOSIVE LIMITS, VOL%: N.A. - N.A.
FLAMMABILITY: DOES NOT SUPPORT COMBUSTION
FLASH POINT, DEG. C: 94
EVAPORATION RATE: SLOWER THAN ETHER
AUTO-IGNITION TEMP., DEG. C: N.D.
VAPOR DENSITY: HEAVIER THAN AIR
VAPOR PRESSURE: N.D.
(SEE "OTHER INFORMATION" SECTION FOR ABBREVIATION LEGEND)
| 10. STABILITY AND REACTIVITY | |
CONDITIONS TO AVOID: AVOID CONTACT WITH STRONG ACID AND STRONG BASES.
INCOMPATIBILITY:
INCOMPATIBLE WITH STRONG OXIDIZING AGENTS, STRONG ACIDS AND STRONG
ALKALIES.
HAZARDOUS DECOMPOSITION:
BY OPEN FLAME, CARBON MONOXIDE AND CARBON DIOXIDE. WHEN HEATED TO
DECOMPOSITION, IT EMITS ACRID SMOKE AND IRRITATING FUMES.
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
STABILITY: THIS PRODUCT IS STABLE UNDER NORMAL STORAGE CONDITIONS.
| 11. TOXICOLOGICAL INFORMATION | |
EFFECTS OF OVEREXPOSURE - EYE CONTACT:
CAUSES EYE IRRITATION. IRRITATING, AND MAY INJURE EYE TISSUE IF NOT REMOVED
PROMPTLY.
EFFECTS OF OVEREXPOSURE - SKIN CONTACT:
SUBSTANCE MAY CAUSE SLIGHT SKIN IRRITATION. MAY CAUSE SKIN SENSITIZATION,
AN ALLERGIC REACTION, WHICH BECOMES EVIDENT UPON RE-EXPOSURE TO THIS
MATERIAL. LOW HAZARD FOR USUAL INDUSTRIAL HANDLING OR COMMERCIAL HANDLING
BY TRAINED PERSONNEL.
EFFECTS OF OVEREXPOSURE - INHALATION:
ROUTINE HANDLING AND APPLICATION DOES NOT REQUIRE USE OF RESPIRATORY
PROTECTION; HOWEVER, IF AIR MONITORING DEMONSTRATES VAPOR, MIST, OR DUST
LEVELS ABOVE APPLICABLE LIMITS, WEAR AN APPROPRIATE, PROPERLY FITTED
RESPIRATOR (NIOSH/MSHA APPROVED) DURING HANDLING AND APPLICATION. FOLLOW
RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE. HIGH GAS, VAPOR,
MIST OR DUST CONCENTRATIONS MAY BE HARMFUL IF INHALED. AVOID BREATHING
FUMES, SPRAY, VAPORS, OR MIST. LOW HAZARD FOR USUAL INDUSTRIAL HANDLING OR
COMMERCIAL HANDLING BY TRAINED PERSONNEL.
EFFECTS OF OVEREXPOSURE - INGESTION: SUBSTANCE MAY BE HARMFUL IF SWALLOWED.
EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS:
CONTAINS TITANIUM DIOXIDE. TITANIUM DIOXIDE IS LISTED AS A GROUP
2B-"POSSIBLY CARCINOGENIC TO HUMANS" BY IARC. NO SIGNIFICANT EXPOSURE TO
TITANIUM DIOXIDE IS THOUGHT TO OCCUR DURING THE USE OF PRODUCTS IN WHICH
TITANIUM DIOXIDE IS BOUND TO OTHER MATERIALS, SUCH AS IN PAINTS DURING
BRUSH APPLICATION OR DRYING. RISK OF OVEREXPOSURE DEPENDS ON DURATION AND
LEVEL OF EXPOSURE TO DUST FROM REPEATED SANDING OF SURFACES OR SPRAY MIST
AND THE ACTUAL CONCENTRATION OF TITANIUM DIOXIDE IN THE FORMULA. (REF: IARC
MONOGRAPH, VOL. 93, 2010)
PRIMARY ROUTE(S) OF ENTRY:
EYE CONTACT, INGESTION, INHALATION, SKIN ABSORPTION, SKIN CONTACT
ACUTE TOXICITY VALUES:
THE ACUTE EFFECTS OF THIS PRODUCT HAVE NOT BEEN TESTED. DATA ON INDIVIDUAL
COMPONENTS ARE TABULATED BELOW:
CAS-NO. CHEMICAL NAME ORAL LD50 DERMAL LD50 VAPOR LC50
13463-67-7 TITANIUM DIOXIDE >10000 MG/KG 2500 MG/KG N.I.
RAT
1332-58-7 KAOLIN CLAY 5500 MG/KG N.I. 25
7779-90-0 ZINC PHOSPHATE >5000 MG/KG N.I. N.I.
RAT
41556-26-7 BIS(1,2,2,6,6- 2615 MG/KG N.I. N.I.
PENTAMETHYL-4- RAT
PIPERIDINYL)
SEBACATE
55965-84-9 5-CHLORO-2-METHYL- 53 MG/KG RAT N.I. N.I.
4-ISOTHIAZOLIN-3-
ONE MIXTURE WITH
2-METHYL-4-
ISOTHIAZOLIN-3-ONE
N.I. - NO INFORMATION
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: PRODUCT IS A MIXTURE OF LISTED COMPONENTS.
| 13. DISPOSAL INFORMATION | |
DISPOSAL INFORMATION:
DISPOSE OF MATERIAL IN ACCORDANCE TO LOCAL, STATE, AND FEDERAL REGULATIONS
AND ORDINANCES. DO NOT ALLOW TO ENTER WATERWAYS, WASTEWATER, SOIL, STORM
DRAINS OR SEWER SYSTEMS.
| 14. TRANSPORT INFORMATION | |
DOMESTIC INTERNATIONAL AIR (IATA) TDG (CANADA)
(USDOT) (IMDG)
UN NUMBER N.A. N.A. N.A. N.A.
PROPER SHIPPING NOT NOT NOT NOT
NAME REGULATED REGULATED REGULATED REGULATED
HAZARD CLASS N.A. N.A. N.A. N.A.
PACKING GROUP N.A. N.A. N.A. N.A.
LIMITED QUANTITY NO NO NO NO
| 15. REGULATORY INFORMATION | |
U.S. FEDERAL REGULATIONS:
CERCLA - SARA HAZARD CATEGORY:
THIS PRODUCT HAS BEEN REVIEWED ACCORDING TO THE EPA 'HAZARD CATEGORIES'
PROMULGATED UNDER SECTIONS 311 AND 312 OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES:
ACUTE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313:
THIS PRODUCT CONTAINS THE FOLLOWING SUBSTANCES SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENT AND
REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:
CHEMICAL NAME CAS-NO.
ZINC PHOSPHATE 7779-90-0
TOXIC SUBSTANCES CONTROL ACT:
THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL SUBSTANCES SUBJECT TO THE
REPORTING REQUIREMENTS OF TSCA 12(B) IF EXPORTED FROM THE UNITED STATES:
CHEMICAL NAME CAS-NO.
SODIUM NITRITE 7632-00-0
2-METHYL-4-ISOTHIAZOLIN-3-ONE 2682-20-4
5-CHLORO-2-METHYL-4-ISOTHIAZOLIN-3-ONE 26172-55-4
ACETALDEHYDE 75-07-0
| 16. OTHER INFORMATION | |
HMIS RATINGS:
HEALTH 1*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA RATINGS:
HEALTH 1
FLAMMABILITY 1
INSTABILITY 0
VOLATILE ORGANIC COMPOUNDS, G/L: 4
SDS REVISION DATE: 5/10/2016
REASON FOR REVISION:
PRODUCT COMPOSITION CHANGED
SUBSTANCE AND/OR PRODUCT PROPERTIES CHANGED IN SECTION(S):
01 - IDENTIFICATION
02 - HAZARD IDENTIFICATION
05 - FIRE-FIGHTING MEASURES
09 - PHYSICAL & CHEMICAL PROPERTIES
15 - REGULATORY INFORMATION
16 - OTHER INFORMATION
STATEMENT(S) CHANGED
LEGEND:
N.A. - NOT APPLICABLE
N.E. - NOT ESTABLISHED
N.D. - NOT DETERMINED
RUST-OLEUM CORPORATION BELIEVES, TO THE BEST OF ITS KNOWLEDGE, INFORMATION
AND BELIEF, THE INFORMATION CONTAINED HEREIN TO BE ACCURATE AND RELIABLE AS
OF THE DATE OF THIS SAFETY DATA SHEET. HOWEVER, BECAUSE THE CONDITIONS OF
HANDLING, USE, AND STORAGE OF THESE MATERIALS ARE BEYOND OUR CONTROL, WE
ASSUME NO RESPONSIBILITY OR LIABILITY FOR PERSONAL INJURY OR PROPERTY
DAMAGE INCURRED BY THE USE OF THESE MATERIALS. RUST-OLEUM CORPORATION MAKES
NO WARRANTY, EXPRESSED OR IMPLIED, REGARDING THE ACCURACY OR RELIABILITY OF
THE DATA OR RESULTS OBTAINED FROM THEIR USE. ALL MATERIALS MAY PRESENT
UNKNOWN HAZARDS AND SHOULD BE USED WITH CAUTION. THE INFORMATION AND
RECOMMENDATIONS IN THIS MATERIAL SAFETY DATA SHEET ARE OFFERED FOR THE
USERS' CONSIDERATION AND EXAMINATION. IT IS THE RESPONSIBILITY OF THE USER
TO DETERMINE THE FINAL SUITABILITY OF THIS INFORMATION AND TO COMPLY WITH
ALL APPLICABLE INTERNATIONAL, FEDERAL, STATE, AND LOCAL LAWS AND
REGULATIONS.