| Common Name: | LOCTITE SI 5019 BL AE KNOWN AS RTV BLUE 190 ML AE, 40482 |
| Manufacturer: | HENKEL |
| SDS Revision Date: | 3/22/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 1TDX4 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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HENKEL
SAFETY DATA SHEET
REVISION NUMBER: 006.0
ISSUE DATE: 03/22/2017
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT NAME: LOCTITE SI 5019 BL AE KNOWN AS RTV BLUE 190 ML AE
PRODUCT TYPE: SILICONE
RESTRICTION OF USE: NONE IDENTIFIED
IDH NUMBER: 743916
ITEM NUMBER: 40482
REGION: UNITED STATES
COMPANY ADDRESS:
HENKEL CORPORATION
ONE HENKEL WAY
ROCKY HILL, CONNECTICUT 06067
CONTACT INFORMATION:
TELEPHONE: +1 (860) 571-5100
MEDICAL EMERGENCY PHONE:
POISON CONTROL CENTER: 1-877-671-4608 (TOLL FREE) OR 1-303-592-1711
TRANSPORT EMERGENCY PHONE:
CHEMTREC: 1-800-424-9300 (TOLL FREE) OR 1-703-527-3887
INTERNET: WWW.HENKELNA.COM
| 2. HAZARDS IDENTIFICATION | |
EMERGENCY OVERVIEW:
DANGER:
CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED.
CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.
HAZARD CLASS HAZARD CATEGORY
GASES UNDER PRESSURE COMPR. GAS
SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1
PICTOGRAM(S):
GAS CYLINDER
CORROSION
EXCLAMATION MARK
PRECAUTIONARY STATEMENTS:
PREVENTION:
AVOID BREATHING VAPORS, MIST, OR SPRAY. WASH AFFECTED AREA THOROUGHLY AFTER
HANDLING. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT OF THE
WORKPLACE. WEAR PROTECTIVE GLOVES, EYE PROTECTION, AND FACE PROTECTION.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING.
STORAGE: PROTECT FROM SUNLIGHT. STORE IN A WELL-VENTILATED PLACE.
DISPOSAL:
DISPOSE OF CONTENTS AND/OR CONTAINER ACCORDING TO FEDERAL, STATE/PROVINCIAL
AND LOCAL GOVERNMENTAL REGULATIONS.
CLASSIFICATION COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200) AND IS CONSISTENT WITH THE PROVISIONS OF THE UNITED NATIONS
GLOBALLY HARMONIZED SYSTEM OF CLASSIFICATION AND LABELING OF CHEMICALS
(GHS).
SEE SECTION 11 FOR ADDITIONAL TOXICOLOGICAL INFORMATION.
| 3. COMPOSITION / INFORMATION ON INGREDIENTS | |
HAZARDOUS COMPONENT(S) CAS NUMBER PERCENTAGE*
DISTILLATES (PETROLEUM), HYDROTREATED MIDDLE 64742-46-7 5 - 10
SILICON DIOXIDE 7631-86-9 5 - 10
NORFLURANE 811-97-2 5 - 10
SILOXANES AND SILICONES, DI-ME 63148-62-9 1 - 5
METHYLSILANETRIYL TRIACETATE 4253-34-3 1 - 5
TRIACETOXYETHYLSILANE 17689-77-9 1 - 5
ACETIC ACID 64-19-7 0.1 - 1
GAMMA-GLYCIDOXYPROPYL TRIMETHOXYSILANE 2530-83-8 0.1 - 1
* EXACT PERCENTAGES MAY VARY OR ARE TRADE SECRET. CONCENTRATION RANGE IS
PROVIDED TO ASSIST USERS IN PROVIDING APPROPRIATE PROTECTIONS.
| 4. FIRST AID MEASURES | |
INHALATION:
MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF SYMPTOMS DEVELOP AND PERSIST,
GET MEDICAL ATTENTION.
SKIN CONTACT:
WIPE OFF PASTE WITH PAPER TOWEL OR CLOTH. WASH WITH SOAP AND WATER. IF SKIN
IRRITATION PERSISTS, CALL A PHYSICIAN.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. IF EYE IRRITATION PERSISTS, CONSULT A SPECIALIST.
INGESTION:
DO NOT INDUCE VOMITING. IF A PERSON FEELS UNWELL OR SYMPTOMS OF SKIN
IRRITATION APPEAR, CONSULT A PHYSICIAN.
SYMPTOMS: SEE SECTION 11.
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
SPECIAL FIREFIGHTING PROCEDURES: WEAR FULL PROTECTIVE CLOTHING.
UNUSUAL FIRE OR EXPLOSION HAZARDS:
COOL AEROSOL CONTAINERS WITH JET OF WATER. CONTAINERS MAY EXPLODE.
HAZARDOUS COMBUSTION PRODUCTS:
OXIDES OF SILICON. FORMALDEHYDE. OXIDES OF CARBON. TOXIC AND IRRITATING
VAPORS.
| 6. ACCIDENTAL RELEASE MEASURES | |
USE PERSONAL PROTECTION RECOMMENDED IN SECTION 8, ISOLATE THE HAZARD AREA
AND DENY ENTRY TO UNNECESSARY AND UNPROTECTED PERSONNEL.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW PRODUCT TO ENTER SEWER OR WATERWAYS.
CLEAN-UP METHODS:
STORE IN A PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL. SPILLED MATERIAL
WILL SOLIDIFY. SCRAPE UP AS MUCH MATERIAL AS POSSIBLE. MAINTAIN GOOD
VENTILATION FOR LARGE SPILLS.
| 7. HANDLING AND STORAGE | |
HANDLING:
AVOID CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT HANDLE CONTACT LENSES
UNTIL ALL SEALANT HAS BEEN REMOVED FROM HANDS. RESIDUAL SEALANT MAY
TRANSFER TO LENSES AND CAUSE EYE IRRITATION.
STORAGE:
FOR SAFE STORAGE, STORE BETWEEN 0 DEG. C (32 DEG. F) AND 60 DEG. C (140
DEG. F) KEEP CONTAINER CLOSED.
FOR INFORMATION ON PRODUCT SHELF LIFE, PLEASE REVIEW LABELS ON CONTAINER OR
CHECK THE TECHNICAL DATA SHEET.
| 8. EXPOSURE CONTROLS / PERSONAL PROTECTION | |
EMPLOYERS SHOULD COMPLETE AN ASSESSMENT OF ALL WORKPLACES TO DETERMINE THE
NEED FOR, AND SELECTION OF, PROPER EXPOSURE CONTROLS AND PROTECTIVE
EQUIPMENT FOR EACH TASK PERFORMED.
HAZARDOUS COMPONENT(S) ACGIH TLV OSHA PEL AIHA WEEL OTHER
DISTILLATES (PETROLEUM), 5 MG/M3 TWA 5 MG/M3 PEL NONE NONE
HYDROTREATED MIDDLE INHALABLE MIST.
FRACTION. 100 PPM
(400 MG/M3)
PEL
SILICON DIOXIDE 6 MG/M3 TWA 20 MPPCF TWA NONE 3 MG/M3
0.8 MG/M3 TWA
TWA RESPIRABLE
FRACTION.
NORFLURANE NONE NONE 1,000 PPM NONE
(4,240
MG/M3) TWA
SILOXANES AND SILICONES, NONE NONE NONE NONE
DI-ME
METHYLSILANETRIYL NONE NONE NONE NONE
TRIACETATE
TRIACETOXYETHYLSILANE NONE NONE NONE NONE
ACETIC ACID 15 PPM STEL 10 PPM NONE NONE
10 PPM TWA (25 MG/M3)
PEL
GAMMA-GLYCIDOXYPROPYL NONE NONE NONE NONE
TRIMETHOXYSILANE
ENGINEERING CONTROLS:
ENSURE ADEQUATE VENTILATION, ESPECIALLY IN CONFINED AREAS. USE LOCAL
VENTILATION IF GENERAL VENTILATION IS INSUFFICIENT TO MAINTAIN VAPOR
CONCENTRATION BELOW ESTABLISHED EXPOSURE LIMITS.
RESPIRATORY PROTECTION:
USE NIOSH APPROVED RESPIRATOR IF THERE IS POTENTIAL TO EXCEED EXPOSURE
LIMIT(S).
EYE/FACE PROTECTION: SAFETY GOGGLES OR SAFETY GLASSES WITH SIDE SHIELDS.
SKIN PROTECTION:
CHEMICAL RESISTANT, IMPERMEABLE GLOVES. NITRILE GLOVES. BUTYL RUBBER
GLOVES.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: AEROSOL, LIQUID OR PASTE
COLOR: BLUE
ODOR: ACETIC ACID
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
VAPOR PRESSURE: <10 MMHg (20 DEG. C (68 DEG. F))
BOILING POINT/RANGE: NOT AVAILABLE.
MELTING POINT/RANGE: NOT AVAILABLE.
SPECIFIC GRAVITY: 1.03 AT 20 DEG. C (68 DEG. F)
VAPOR DENSITY: HEAVIER THAN AIR.
FLASH POINT: >93.0 DEG. C (>199.4 DEG. F)
FLAMMABLE/EXPLOSIVE LIMITS - LOWER: 4% (ACETIC ACID)
FLAMMABLE/EXPLOSIVE LIMITS - UPPER: 19.9% (ACETIC ACID)
AUTOIGNITION TEMPERATURE: NOT AVAILABLE.
FLAMMABILITY: NOT APPLICABLE
EVAPORATION RATE: NOT AVAILABLE.
SOLUBILITY IN WATER: NOT SOLUBLE. POLYMERIZES IN PRESENCE OF WATER.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
VOC CONTENT: 3.9%; 39.4 G/L (CALCULATED)
VISCOSITY: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
| 10. STABILITY AND REACTIVITY | |
STABILITY: STABLE UNDER NORMAL CONDITIONS OF STORAGE AND USE.
HAZARDOUS REACTIONS: WILL NOT OCCUR.
HAZARDOUS DECOMPOSITION PRODUCTS:
OXIDES OF CARBON. OXIDES OF SILICON. FORMALDEHYDE. ACETIC ACID IS LIBERATED
SLOWLY UPON CONTACT WITH MOISTURE. IRRITATING ORGANIC VAPOURS.
INCOMPATIBLE MATERIALS: WATER. BASES. OXIDIZING AGENTS. ACIDS.
REACTIVITY: NOT AVAILABLE.
CONDITIONS TO AVOID:
PROLONGED HEATING AT TEMPERATURES ABOVE 150 DEG. C. EXPOSURE TO MOISTURE.
| 11. TOXICOLOGICAL INFORMATION | |
RELEVANT ROUTES OF EXPOSURE:
SKIN, INHALATION, EYES, INGESTION
POTENTIAL HEALTH EFFECTS/SYMPTOMS:
INHALATION:
ACETIC ACID PRODUCED DURING CURE MAY IRRITATE EYES, NOSE AND THROAT. WHEN
HEATED TO TEMPERATURES EXCEEDING 300 DEG. F (150 DEG. C) IN THE PRESENCE OF
AIR, SILICONES MAY FORM FORMALDEHYDE VAPORS. FORMALDEHYDE IS A POTENTIAL
CANCER HAZARD AND A KNOWN SKIN AND RESPIRATORY SENSITIZER. VAPORS IRRITATE
THE EYES, NOSE AND THROAT. SAFE HANDLING CONDITIONS MAY BE MAINTAINED BY
KEEPING FORMALDEHYDE VAPOR CONCENTRATIONS BELOW THE OSHA PERMISSIBLE LIMIT.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE DAMAGE.
INGESTION:
NOT EXPECTED UNDER NORMAL CONDITIONS OF USE. MAY CAUSE GASTROINTESTINAL
TRACT IRRITATION IF SWALLOWED.
HAZARDOUS COMPONENT(S) LD50S AND LC50S IMMEDIATE AND DELAYED HEALTH
EFFECTS
DISTILLATES (PETROLEUM), NONE IRRITANT
HYDROTREATED MIDDLE
SILICON DIOXIDE ORAL LD50 (RAT): NUISANCE DUST
>22,500 MG/KG
ORAL LD50 (MOUSE):
>15,000 MG/KG
NORFLURANE NONE CARDIAC, CENTRAL NERVOUS
SYSTEM, IRRITANT,
RESPIRATORY, SKIN
SILOXANES AND SILICONES, NONE IRRITANT
DI-ME
METHYLSILANETRIYL NONE IRRITANT, ALLERGEN
TRIACETATE
TRIACETOXYETHYLSILANE NONE NO TARGET ORGANS
ACETIC ACID ORAL LD50 (RABBIT): ALLERGEN, CORROSIVE, EYES,
1,200 MG/KG GASTROINTESTINAL, IMMUNE
ORAL LD50 (MOUSE): SYSTEM, IRRITANT, KIDNEY
4,960 MG/KG
ORAL LD50 (RAT):
3.53 G/KG
ORAL LD50 (RAT):
3.31 G/KG
DERMAL LD50
(RABBIT):
1,060 MG/KG
INHALATION LC50
(RAT, 4 H):
11.4 MG/L
GAMMA-GLYCIDOXYPROPYL NONE ALLERGEN, IRRITANT
TRIMETHOXYSILANE
HAZARDOUS COMPONENT(S) NTP CARCINOGEN IARC CARCINOGEN OSHA CARCINOGEN
(SPECIFICALLY
REGULATED)
DISTILLATES (PETROLEUM), NO NO NO
HYDROTREATED MIDDLE
SILICON DIOXIDE NO NO NO
NORFLURANE NO NO NO
SILOXANES AND SILICONES, NO NO NO
DI-ME
METHYLSILANETRIYL NO NO NO
TRIACETATE
TRIACETOXYETHYLSILANE NO NO NO
ACETIC ACID NO NO NO
GAMMA-GLYCIDOXYPROPYL NO NO NO
TRIMETHOXYSILANE
| 12. ECOLOGICAL INFORMATION | |
ECOLOGICAL INFORMATION: NOT AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
INFORMATION PROVIDED IS FOR UNUSED PRODUCT ONLY.
RECOMMENDED METHOD OF DISPOSAL:
FOLLOW ALL LOCAL, STATE, FEDERAL AND PROVINCIAL REGULATIONS FOR DISPOSAL.
CURED RUBBER CAN BE INCINERATED OR LANDFILLED FOLLOWING EPA AND LOCAL
REGULATIONS.
HAZARDOUS WASTE NUMBER: NOT A RCRA HAZARDOUS WASTE.
| 14. TRANSPORT INFORMATION | |
THE TRANSPORT INFORMATION PROVIDED IN THIS SECTION ONLY APPLIES TO THE
MATERIAL/FORMULATION ITSELF, AND IS NOT SPECIFIC TO ANY
PACKAGE/CONFIGURATION.
U.S. DEPARTMENT OF TRANSPORTATION GROUND (49 CFR):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.2
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
INTERNATIONAL AIR TRANSPORTATION (ICAO/IATA):
PROPER SHIPPING NAME: AEROSOLS, NON-FLAMMABLE
HAZARD CLASS OR DIVISION: 2.2
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
WATER TRANSPORTATION (IMO/IMDG):
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS OR DIVISION: 2.2
IDENTIFICATION NUMBER: UN 1950
PACKING GROUP: NONE
| 15. REGULATORY INFORMATION | |
UNITED STATES REGULATORY INFORMATION:
TSCA 8 (B) INVENTORY STATUS:
ALL COMPONENTS ARE LISTED OR ARE EXEMPT FROM LISTING ON THE TOXIC
SUBSTANCES CONTROL ACT INVENTORY.
TSCA 12 (B) EXPORT NOTIFICATION: NONE ABOVE REPORTING DE MINIMIS
CERCLA/SARA SECTION 302 EHS: NONE ABOVE REPORTING DE MINIMIS.
CERCLA/SARA SECTION 311/312: IMMEDIATE HEALTH
CERCLA/SARA SECTION 313: NONE ABOVE REPORTING DE MINIMIS.
CALIFORNIA PROPOSITION 65:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
CANADA REGULATORY INFORMATION:
CEPA DSL/NDSL STATUS:
ALL COMPONENTS ARE LISTED ON OR ARE EXEMPT FROM LISTING ON THE CANADIAN
DOMESTIC SUBSTANCES LIST.
| 16. OTHER INFORMATION | |
THIS SAFETY DATA SHEET CONTAINS CHANGES FROM THE PREVIOUS VERSION IN
SECTIONS: NEW SAFETY DATA SHEET FORMAT.
PREPARED BY: REGULATORY AFFAIRS
ISSUE DATE: 03/22/2017
DISCLAIMER:
THE DATA CONTAINED HEREIN ARE FURNISHED FOR INFORMATION ONLY AND ARE
BELIEVED TO BE RELIABLE. HOWEVER, HENKEL CORPORATION AND ITS AFFILIATES
("HENKEL") DOES NOT ASSUME RESPONSIBILITY FOR ANY RESULTS OBTAINED BY
PERSONS OVER WHOSE METHODS HENKEL HAS NO CONTROL. IT IS THE USER'S
RESPONSIBILITY TO DETERMINE THE SUITABILITY OF HENKEL'S PRODUCTS OR ANY
PRODUCTION METHODS MENTIONED HEREIN FOR A PARTICULAR PURPOSE, AND TO ADOPT
SUCH PRECAUTIONS AS MAY BE ADVISABLE FOR THE PROTECTION OF PROPERTY AND
PERSONS AGAINST ANY HAZARDS THAT MAY BE INVOLVED IN THE HANDLING AND USE OF
ANY HENKEL'S PRODUCTS. IN LIGHT OF THE FOREGOING, HENKEL SPECIFICALLY
DISCLAIMS ALL WARRANTIES, EXPRESS OR IMPLIED, INCLUDING WARRANTIES OF
MERCHANTABILITY AND FITNESS FOR A PARTICULAR PURPOSE, ARISING FROM SALE OR
USE OF HENKEL'S PRODUCTS. HENKEL FURTHER DISCLAIMS ANY LIABILITY FOR
CONSEQUENTIAL OR INCIDENTAL DAMAGES OF ANY KIND, INCLUDING LOST PROFITS.