| Common Name: | SLIP PLATE NO 3 |
| Manufacturer: | ASBURY CARBONS |
| SDS Revision Date: | 4/10/2019 |
| SDS Format: | GHS-US |
| Item Number(s): | 1WVL5 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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ASBURY CARBONS
SAFETY DATA SHEET
ACCORDING TO OSHA HCS (29CFR 1910.1200) AND WHMIS 2015 REGULATIONS
REVISION: APRIL 10, 2019
| 1 IDENTIFICATION |  |
PRODUCT IDENTIFIER:
TRADE NAME: SLIP PLATE NO 3
OTHER MEANS OF IDENTIFICATION: NO OTHER IDENTIFIERS
RECOMMENDED USE AND RESTRICTION ON USE:
RECOMMENDED USE: LUBRICANT
RESTRICTIONS ON USE: NO RELEVANT INFORMATION AVAILABLE.
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
MANUFACTURER/SUPPLIER:
ASBURY CARBONS, INC.
PO BOX 144
405 OLD MAIN STREET
ASBURY, NJ 08802
USA
+1 908-537-2155
EMERGENCY TELEPHONE NUMBER:
CHEMTEL INC.
(800)255-3924 (NORTH AMERICA)
+1 (813)248-0585 (INTERNATIONAL)
1-300-954-583 (AUSTRALIA)
0-800-591-6042 (BRAZIL)
400-120-0751 (CHINA)
000-800-100-4086 (INDIA)
01-800-099-0731 (MEXICO)
| 2 HAZARD(S) IDENTIFICATION | |
CLASSIFICATION OF THE SUBSTANCE OR MIXTURE:
FLAM. LIQ. 2:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
SKIN IRRIT. 2:
H315: CAUSES SKIN IRRITATION.
SKIN SENS. 1:
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
CARC. 2:
H351: SUSPECTED OF CAUSING CANCER.
REPR. 2:
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT SE 3:
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
STOT RE 2:
H373:
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM AND THE PERIPHERAL
NERVOUS SYSTEM THROUGH PROLONGED OR REPEATED EXPOSURE.
ASP. TOX. 1:
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
LABEL ELEMENTS:
GHS LABEL ELEMENTS:
THE PRODUCT IS CLASSIFIED AND LABELED ACCORDING TO THE GLOBALLY HARMONIZED
SYSTEM (GHS).
HAZARD PICTOGRAMS:
GHS02: FLAME
GHS07: EXCLAMATION MARK
GHS08: HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H315: CAUSES SKIN IRRITATION.
H317: MAY CAUSE AN ALLERGIC SKIN REACTION.
H351: SUSPECTED OF CAUSING CANCER.
H361: SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
H336: MAY CAUSE DROWSINESS OR DIZZINESS.
H373:
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM AND THE PERIPHERAL NERVOUS
SYSTEM THROUGH PROLONGED OR REPEATED EXPOSURE.
H304: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
PRECAUTIONARY STATEMENTS:
P201: OBTAIN SPECIAL INSTRUCTIONS BEFORE USE.
P202:
DO NOT HANDLE UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD.
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P241: USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
P242: USE ONLY NON-SPARKING TOOLS.
P243: TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
P260: DO NOT BREATHE MIST/VAPORS/SPRAY.
P264: WASH THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P272: CONTAMINATED WORK CLOTHING MUST NOT BE ALLOWED OUT OF THE WORKPLACE.
P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION.
P301+P310:
IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P331: DO NOT INDUCE VOMITING.
P303+P361+P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304+P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P308+P313:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION.
P312: CALL A POISON CENTER/DOCTOR IF YOU FEEL UNWELL.
P333+P313:
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P370+P378:
IN CASE OF FIRE: USE FOAM, POWDER, OR CARBON DIOXIDE FOR EXTINCTION.
P403+P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
P405: STORE LOCKED UP.
P501:
DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
OTHER HAZARDS:
THERE ARE NO OTHER HAZARDS NOT OTHERWISE CLASSIFIED THAT HAVE BEEN
IDENTIFIED.
| 3 COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL CHARACTERIZATION: MIXTURES
COMPONENTS:
64742-89-8 SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. <40%
FLAM. LIQ. 2, H225
REPR. 2, H361; STOT RE 2, H373; ASP. TOX. 1, H304
SKIN IRRIT. 2, H315; STOT SE 3, H336
7782-42-5 GRAPHITE <25%
8032-32-4 LIGROINE 10-20%
FLAM. LIQ. 2, H225
ASP. TOX. 1, H304
142-82-5 HEPTANE <10%
FLAM. LIQ. 2, H225
ASP. TOX. 1, H304
SKIN IRRIT. 2, H315; STOT SE 3, H336
111-65-9 OCTANE <5%
FLAM. LIQ. 2, H225
ASP. TOX. 1, H304
SKIN IRRIT. 2, H315; STOT SE 3, H336
108-88-3 TOLUENE <1%
FLAM. LIQ. 2, H225
REPR. 2, H361; STOT RE 2, H373; ASP. TOX. 1, H304
SKIN IRRIT. 2, H315; STOT SE 3, H336
1330-20-7 XYLENE <1%
FLAM. LIQ. 3, H226
ASP. TOX. 1, H304
ACUTE TOX. 4, H312; ACUTE TOX. 4, H332; SKIN IRRIT. 2,
H315; EYE IRRIT. 2A, H319; STOT SE 3, H335
67-56-1 METHANOL <1%
FLAM. LIQ. 2, H225
ACUTE TOX. 3, H301; ACUTE TOX. 3, H311; ACUTE TOX. 3,
H331
STOT SE 1, H370
EYE IRRIT. 2B, H320
96-29-7 2-BUTANONE OXIME <1%
CARC. 2, H351
EYE DAM. 1, H318
ACUTE TOX. 4, H312; ACUTE TOX. 4, H332; SKIN SENS. 1,
H317 FLAM. LIQ. 4, H227
102-06-7 1,3-DIPHENYLGUANIDINE <1%
ACUTE TOX. 3, H301
REPR. 2, H361
EYE DAM. 1, H318
SKIN IRRIT. 2, H315; STOT SE 3, H335
14808-60-7 QUARTZ <1%
61789-51-3 NAPHTHENIC ACIDS, COBALT SALTS <1%
CARC. 2, H351; REPR. 2, H361
SKIN SENS. 1, H317
ADDITIONAL INFORMATION:
FOR THE WORDING OF THE LISTED HAZARD STATEMENTS, REFER TO SECTION 16.
| 4 FIRST-AID MEASURES | |
DESCRIPTION OF FIRST AID MEASURES:
AFTER INHALATION:
SUPPLY FRESH AIR; CONSULT DOCTOR IN CASE OF COMPLAINTS.
PROVIDE OXYGEN TREATMENT IF AFFECTED PERSON HAS DIFFICULTY BREATHING.
IN CASE OF UNCONSCIOUSNESS PLACE PATIENT STABLY IN SIDE POSITION FOR
TRANSPORTATION.
AFTER SKIN CONTACT:
IMMEDIATELY REMOVE ANY CLOTHING SOILED BY THE PRODUCT.
IMMEDIATELY WASH WITH WATER AND SOAP AND RINSE THOROUGHLY.
IF SKIN IRRITATION OR RASH OCCURS: GET MEDICAL ADVICE/ATTENTION.
AFTER EYE CONTACT:
REMOVE CONTACT LENSES IF WORN.
RINSE OPENED EYE FOR SEVERAL MINUTES UNDER RUNNING WATER. IF SYMPTOMS
PERSIST, CONSULT A DOCTOR.
AFTER SWALLOWING:
RINSE OUT MOUTH AND THEN DRINK PLENTY OF WATER.
DO NOT INDUCE VOMITING; IMMEDIATELY CALL FOR MEDICAL HELP.
A PERSON VOMITING WHILE LYING ON THEIR BACK SHOULD BE TURNED ONTO THEIR
SIDE.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
ALLERGIC REACTIONS
CAUSES SKIN IRRITATION.
COUGHING
BREATHING DIFFICULTY
NAUSEA IN CASE OF INGESTION.
MAY CAUSE GASTRO-INTESTINAL IRRITATION IF INGESTED.
DIZZINESS
DANGER:
MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
DANGER OF IMPAIRED BREATHING.
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
SUSPECTED OF CAUSING CANCER.
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM AND THE PERIPHERAL NERVOUS
SYSTEM THROUGH PROLONGED OR REPEATED EXPOSURE.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
CONTAINS 2-BUTANONE OXIME, NAPHTHENIC ACIDS, COBALT SALTS. MAY PRODUCE AN
ALLERGIC REACTION.
TREAT SKIN AND MUCOUS MEMBRANE WITH ANTIHISTAMINE AND CORTICOID
PREPARATIONS.
| 5 FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING AGENTS:
FOAM
GASEOUS EXTINGUISHING AGENTS
CARBON DIOXIDE
FIRE-EXTINGUISHING POWDER
FOR SAFETY REASONS UNSUITABLE EXTINGUISHING AGENTS: WATER
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
FORMATION OF TOXIC GASES IS POSSIBLE DURING HEATING OR IN CASE OF FIRE.
ADVICE FOR FIREFIGHTERS:
PROTECTIVE EQUIPMENT:
WEAR SELF-CONTAINED RESPIRATORY PROTECTIVE DEVICE.
WEAR FULLY PROTECTIVE SUIT.
ADDITIONAL INFORMATION: ELIMINATE ALL IGNITION SOURCES IF SAFE TO DO SO.
| 6 ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
USE RESPIRATORY PROTECTIVE DEVICE AGAINST THE EFFECTS OF
FUMES/DUST/AEROSOL.
WEAR PROTECTIVE EQUIPMENT. KEEP UNPROTECTED PERSONS AWAY.
ENSURE ADEQUATE VENTILATION.
KEEP AWAY FROM IGNITION SOURCES.
PROTECT FROM HEAT.
ENVIRONMENTAL PRECAUTIONS:
DO NOT ALLOW TO ENTER SEWERS/ SURFACE OR GROUND WATER.
PREVENT FROM SPREADING (E.G. BY DAMMING-IN OR OIL BARRIERS).
INFORM RESPECTIVE AUTHORITIES IN CASE OF SEEPAGE INTO WATER COURSE OR
SEWAGE SYSTEM.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
ABSORB WITH NON-COMBUSTIBLE LIQUID-BINDING MATERIAL (SAND, DIATOMITE, ACID
BINDERS, UNIVERSAL BINDERS).
SEND FOR RECOVERY OR DISPOSAL IN SUITABLE RECEPTACLES.
REFERENCE TO OTHER SECTIONS:
SEE SECTION 7 FOR INFORMATION ON SAFE HANDLING.
SEE SECTION 8 FOR INFORMATION ON PERSONAL PROTECTION EQUIPMENT.
SEE SECTION 13 FOR DISPOSAL INFORMATION.
| 7 HANDLING AND STORAGE | |
HANDLING:
PRECAUTIONS FOR SAFE HANDLING:
AVOID SPLASHES OR SPRAY IN ENCLOSED AREAS.
USE ONLY IN WELL VENTILATED AREAS.
AVOID CONTACT WITH THE EYES AND SKIN.
OPEN AND HANDLE RECEPTACLE WITH CARE.
KEEP OUT OF REACH OF CHILDREN.
INFORMATION ABOUT PROTECTION AGAINST EXPLOSIONS AND FIRES:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
KEEP IGNITION SOURCES AWAY - DO NOT SMOKE.
PROTECT AGAINST ELECTROSTATIC CHARGES.
FLAMMABLE GAS-AIR MIXTURES MAY BE FORMED IN EMPTY CONTAINERS/RECEPTACLES.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS TO BE MET BY STOREROOMS AND RECEPTACLES:
STORE IN COOL, DRY CONDITIONS IN WELL SEALED RECEPTACLES.
AVOID STORAGE NEAR EXTREME HEAT, IGNITION SOURCES OR OPEN FLAME.
INFORMATION ABOUT STORAGE IN ONE COMMON STORAGE FACILITY:
STORE AWAY FROM FOODSTUFFS.
STORE AWAY FROM OXIDIZING AGENTS.
SPECIFIC END USE(S): NO RELEVANT INFORMATION AVAILABLE.
| 8 EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
COMPONENTS WITH LIMIT VALUES THAT REQUIRE MONITORING AT THE WORKPLACE:
7782-42-5 GRAPHITE:
PEL (USA):
LONG-TERM VALUE:
15 MPPCF* MG/M3
*IMPINGER SAMPLES COUNTED BY LIGHT FIELD TECHN.
REL (USA):
LONG-TERM VALUE:
2.5* MG/M3
*RESPIRABLE DUST
TLV (USA):
LONG-TERM VALUE:
2* MG/M3
ALL FORMS EXCEPT GRAPHITE FIBERS; *RESP. FRACTION
EL (CANADA):
LONG-TERM VALUE:
2 MG/M3
RESPIRABLE
EV (CANADA):
LONG-TERM VALUE:
2 MG/M3
RESPIRABLE
LMPE (MEXICO):
LONG-TERM VALUE:
2* MG/M3
*FRACCION RESPIRABLE
8032-32-4 LIGROINE:
REL (USA):
LONG-TERM VALUE: 350 MG/M3
CEILING LIMIT VALUE:
1800* MG/M3
*15-MIN
TLV (USA): TLV WITHDRAWN - REFER TO APPENDIX H
EL (CANADA): RECIPROCAL CALCULATION METHOD - SEE OHS G5.48-12
LMPE (MEXICO):
SHORT-TERM VALUE: 1800 MG/M3, 400 PPM
LONG-TERM VALUE:
1350 MG/M3, 300 PPM
A3
142-82-5 HEPTANE:
PEL (USA):
LONG-TERM VALUE: 2000 MG/M3, 500 PPM
REL (USA):
LONG-TERM VALUE: 350 MG/M3, 85 PPM
CEILING LIMIT VALUE:
1800* MG/M3, 440* PPM
*15-MIN
TLV (USA):
SHORT-TERM VALUE: 2050 MG/M3, 500 PPM
LONG-TERM VALUE: 1640 MG/M3, 400 PPM
EL (CANADA):
SHORT-TERM VALUE: 500 PPM
LONG-TERM VALUE: 400 PPM
EV (CANADA):
SHORT-TERM VALUE: 2045 MG/M3, 500 PPM
LONG-TERM VALUE: 1635 MG/M3, 400 PPM
LMPE (MEXICO):
SHORT-TERM VALUE: 500 PPM
LONG-TERM VALUE: 400 PPM
111-65-9 OCTANE:
PEL (USA):
LONG-TERM VALUE:
2350 MG/M3, 500 PPM
N-OCTANE ONLY
REL (USA):
LONG-TERM VALUE: 350 MG/M3, 75 PPM
CEILING LIMIT VALUE:
1800* MG/M3, 385* PPM
*15 MIN
TLV (USA):
LONG-TERM VALUE: 1401 MG/M3, 300 PPM
EL (CANADA):
LONG-TERM VALUE: 300 PPM
EV (CANADA):
SHORT-TERM VALUE: 1,750 MG/M3, 375 PPM
LONG-TERM VALUE: 1,400 MG/M3, 300 PPM
LMPE (MEXICO):
LONG-TERM VALUE: 300 PPM
108-88-3 TOLUENE:
PEL (USA):
LONG-TERM VALUE: 200 PPM
CEILING LIMIT VALUE:
300; 500* PPM
*10-MIN PEAK PER 8-HR SHIFT
REL (USA):
SHORT-TERM VALUE: 560 MG/M3, 150 PPM
LONG-TERM VALUE: 375 MG/M3, 100 PPM
TLV (USA):
LONG-TERM VALUE:
75 MG/M3, 20 PPM
BEI
EL (CANADA):
LONG-TERM VALUE:
20 PPM
R
EV (CANADA):
LONG-TERM VALUE: 20 PPM
LMPE (MEXICO):
LONG-TERM VALUE:
20 PPM
A4, IBE
1330-20-7 XYLENE:
PEL (USA):
LONG-TERM VALUE: 435 MG/M3, 100 PPM
REL (USA):
SHORT-TERM VALUE: 655 MG/M3, 150 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
TLV (USA):
SHORT-TERM VALUE: 651 MG/M3, 150 PPM
LONG-TERM VALUE:
434 MG/M3, 100 PPM
BEI
EL (CANADA):
SHORT-TERM VALUE: 150 PPM
LONG-TERM VALUE: 100 PPM
EV (CANADA):
SHORT-TERM VALUE: 650 MG/M3, 150 PPM
LONG-TERM VALUE: 435 MG/M3, 100 PPM
LMPE (MEXICO):
SHORT-TERM VALUE: 150 PPM
LONG-TERM VALUE:
100 PPM
A4, IBE
67-56-1 METHANOL:
PEL (USA):
LONG-TERM VALUE: 260 MG/M3, 200 PPM
REL (USA):
SHORT-TERM VALUE: 325 MG/M3, 250 PPM
LONG-TERM VALUE:
260 MG/M3, 200 PPM
SKIN
TLV (USA):
SHORT-TERM VALUE: 328 MG/M3, 250 PPM
LONG-TERM VALUE:
262 MG/M3, 200 PPM
SKIN; BEI
EL (CANADA):
SHORT-TERM VALUE: 250 PPM
LONG-TERM VALUE:
200 PPM
SKIN
EV (CANADA):
SHORT-TERM VALUE: 325 MG/M3, 250 PPM
LONG-TERM VALUE:
260 MG/M3, 200 PPM
SKIN
LMPE (MEXICO):
SHORT-TERM VALUE: 250 PPM
LONG-TERM VALUE:
200 PPM
PIEL, IBE
96-29-7 2-BUTANONE OXIME:
WEEL (USA):
LONG-TERM VALUE:
10 PPM
DSEN
14808-60-7 QUARTZ:
PEL (USA):
LONG-TERM VALUE:
0.05* MG/M3
*RESP. DUST; 30MG/M3/%SiO2+2
REL (USA):
LONG-TERM VALUE:
0.05* MG/M3
*RESPIRABLE DUST; SEE POCKET GUIDE APP. A
TLV (USA):
LONG-TERM VALUE:
0.025* MG/M3
*AS RESPIRABLE FRACTION
EL (CANADA):
LONG-TERM VALUE: 0.025 MG/M3
ACGIH A2; IARC 1
EV (CANADA):
LONG-TERM VALUE:
0.10* MG/M3
*RESPIRABLE FRACTION
LMPE (MEXICO):
LONG-TERM VALUE:
0.025* MG/M3
A2, *FRACCION RESPIRABLE
INGREDIENTS WITH BIOLOGICAL LIMIT VALUES:
108-88-3 TOLUENE:
BEI (USA):
0.02 MG/L:
MEDIUM: BLOOD
TIME: PRIOR TO LAST SHIFT OF WORKWEEK
PARAMETER: TOLUENE
0.03 MG/L:
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: TOLUENE
0.3 MG/G CREATININE:
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: O-CRESOL WITH HYDROLYSIS (BACKGROUND)
1330-20-7 XYLENE:
BEI (USA):
1.5 G/G CREATININE:
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: METHYLHIPPURIC ACIDS
67-56-1 METHANOL:
BEI (USA):
15 MG/L:
MEDIUM: URINE
TIME: END OF SHIFT
PARAMETER: METHANOL (BACKGROUND, NONSPECIFIC)
EXPOSURE CONTROLS:
GENERAL PROTECTIVE AND HYGIENIC MEASURES:
THE USUAL PRECAUTIONARY MEASURES FOR HANDLING CHEMICALS SHOULD BE FOLLOWED.
KEEP AWAY FROM FOODSTUFFS, BEVERAGES AND FEED.
IMMEDIATELY REMOVE ALL SOILED AND CONTAMINATED CLOTHING.
WASH HANDS BEFORE BREAKS AND AT THE END OF WORK.
DO NOT INHALE GASES / FUMES / AEROSOLS.
AVOID CONTACT WITH THE EYES AND SKIN.
ENGINEERING CONTROLS:
TAKE PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
USE EXPLOSION-PROOF ELECTRICAL/VENTILATING/LIGHTING/EQUIPMENT.
USE ONLY NON-SPARKING TOOLS.
BREATHING EQUIPMENT:
WEAR APPROPRIATE NIOSH RESPIRATOR WHEN VENTILATION IS INADEQUATE AND
OCCUPATIONAL EXPOSURE LIMITS ARE EXCEEDED.
NIOSH OR EN APPROVED ORGANIC VAPOR RESPIRATOR EQUIPPED WITH A DUST/MIST
PREFILTER SHOULD BE USED.
PROTECTION OF HANDS: PROTECTIVE GLOVES
THE GLOVE MATERIAL HAS TO BE IMPERMEABLE AND RESISTANT TO THE PRODUCT/ THE
SUBSTANCE/ THE PREPARATION.
EYE PROTECTION: SAFETY GLASSES
BODY PROTECTION: PROTECTIVE WORK CLOTHING
LIMITATION AND SUPERVISION OF EXPOSURE INTO THE ENVIRONMENT:
NO RELEVANT INFORMATION AVAILABLE.
RISK MANAGEMENT MEASURES: NO RELEVANT INFORMATION AVAILABLE.
| 9 PHYSICAL AND CHEMICAL PROPERTIES | |
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
APPEARANCE:
FORM: LIQUID
COLOR: DARK GRAY
ODOR: PETROLEUM-LIKE
ODOR THRESHOLD: NOT DETERMINED.
PH-VALUE: NOT DETERMINED.
MELTING POINT/MELTING RANGE: NOT DETERMINED.
BOILING POINT/BOILING RANGE: 100-149 DEG. C (212-300.2 DEG. F)
FLASH POINT: -7.8 DEG. C (18 DEG. F)
FLAMMABILITY (SOLID, GASEOUS): NOT APPLICABLE.
AUTO-IGNITION TEMPERATURE: NOT DETERMINED.
DECOMPOSITION TEMPERATURE: NOT DETERMINED.
DANGER OF EXPLOSION:
PRODUCT IS NOT EXPLOSIVE. HOWEVER, FORMATION OF EXPLOSIVE AIR/
VAPOR MIXTURES ARE POSSIBLE.
EXPLOSION LIMITS:
LOWER: 0.9 VOL %
UPPER: 7 VOL %
OXIDIZING PROPERTIES: NON-OXIDIZING.
VAPOR PRESSURE AT 20 DEG. C (68 DEG. F): 18 MMHg
DENSITY:
RELATIVE DENSITY: 0.93
VAPOR DENSITY: 4.1 (AIR = 1)
EVAPORATION RATE: NOT DETERMINED.
SOLUBILITY IN / MISCIBILITY WITH WATER: SLIGHTLY SOLUBLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT DETERMINED.
VISCOSITY:
DYNAMIC: NOT DETERMINED.
KINEMATIC AT 40 DEG. C (104 DEG. F): <20.5 MM2/S
OTHER INFORMATION: NO RELEVANT INFORMATION AVAILABLE.
| 10 STABILITY AND REACTIVITY | |
REACTIVITY: NO RELEVANT INFORMATION AVAILABLE.
CHEMICAL STABILITY:
THERMAL DECOMPOSITION / CONDITIONS TO BE AVOIDED:
NO DECOMPOSITION IF USED AND STORED ACCORDING TO SPECIFICATIONS.
POSSIBILITY OF HAZARDOUS REACTIONS:
HIGHLY FLAMMABLE LIQUID AND VAPOR.
REACTS VIOLENTLY WITH OXIDIZING AGENTS.
TOXIC FUMES MAY BE RELEASED IF HEATED ABOVE THE DECOMPOSITION POINT.
USED EMPTY CONTAINERS MAY CONTAIN PRODUCT GASES WHICH FORM EXPLOSIVE
MIXTURES WITH AIR.
CAN FORM EXPLOSIVE MIXTURES IN AIR IF HEATED ABOVE FLASH POINT AND/OR
WHEN SPRAYED OR ATOMIZED.
CONDITIONS TO AVOID: EXCESSIVE HEAT.
INCOMPATIBLE MATERIALS: OXIDIZERS
HAZARDOUS DECOMPOSITION PRODUCTS:
UNDER FIRE CONDITIONS ONLY:
CARBON MONOXIDE AND CARBON DIOXIDE
| 11 TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
LD/LC50 VALUES THAT ARE RELEVANT FOR CLASSIFICATION:
142-82-5 HEPTANE:
ORAL:
LD50: >5000 MG/KG (RAT)
102-06-7 1,3-DIPHENYLGUANIDINE:
ORAL:
LD50: 107-111 MG/KG (RAT)
PRIMARY IRRITANT EFFECT:
ON THE SKIN: IRRITANT TO SKIN AND MUCOUS MEMBRANES.
ON THE EYE:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
SENSITIZATION:
CONTAINS 2-BUTANONE OXIME, NAPHTHENIC ACIDS, COBALT SALTS. MAY PRODUCE
AN ALLERGIC REACTION.
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
14808-60-7 QUARTZ 1
27253-31-2 COBALT CARBOXYLATE 2B
61789-36-4 NAPHTHENIC ACIDS, CALCIUM SALTS 2B
NTP (NATIONAL TOXICOLOGY PROGRAM):
14808-60-7 QUARTZ K
OSHA-CA (OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION):
NONE OF THE INGREDIENTS ARE LISTED.
PROBABLE ROUTE(S) OF EXPOSURE:
INGESTION.
INHALATION.
EYE CONTACT.
SKIN CONTACT.
GERM CELL MUTAGENICITY:
BASED ON AVAILABLE DATA, THE CLASSIFICATION CRITERIA ARE NOT MET.
CARCINOGENICITY: SUSPECTED OF CAUSING CANCER.
REPRODUCTIVE TOXICITY:
SUSPECTED OF DAMAGING FERTILITY OR THE UNBORN CHILD.
STOT-SINGLE EXPOSURE: MAY CAUSE DROWSINESS OR DIZZINESS.
STOT-REPEATED EXPOSURE:
MAY CAUSE DAMAGE TO THE CENTRAL NERVOUS SYSTEM AND THE PERIPHERAL NERVOUS
SYSTEM THROUGH PROLONGED OR REPEATED EXPOSURE.
ASPIRATION HAZARD: MAY BE FATAL IF SWALLOWED AND ENTERS AIRWAYS.
| 12 ECOLOGICAL INFORMATION | |
TOXICITY:
AQUATIC TOXICITY:
TOXIC TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
102-06-7 1,3-DIPHENYLGUANIDINE:
LC50:
9.6 MG/L (LEPOMIS MACROCHIRUS)
4.2 MG/L (PIMEPHALES PROMELAS)
EC50:
1.4-1.7 MG/L (PSEUDOKIRCHNERIELLA SUBCAPITATA)
17 MG/L (DAPHNIA)
7.5 MG/L (DESMODESMUS SUBSPICATUS)
PERSISTENCE AND DEGRADABILITY:
THE PRODUCT IS PARTIALLY BIODEGRADABLE. SIGNIFICANT RESIDUALS REMAIN.
BIOACCUMULATIVE POTENTIAL: NO RELEVANT INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO RELEVANT INFORMATION AVAILABLE.
RESULTS OF PBT AND VPVB ASSESSMENT:
PBT: NOT APPLICABLE.
VPVB: NOT APPLICABLE.
OTHER ADVERSE EFFECTS: NO RELEVANT INFORMATION AVAILABLE.
| 13 DISPOSAL CONSIDERATIONS | |
WASTE TREATMENT METHODS:
RECOMMENDATION:
CONTACT WASTE PROCESSORS FOR RECYCLING INFORMATION.
THE USER OF THIS MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED
MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL,
STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND
DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES.
UNCLEANED PACKAGINGS:
RECOMMENDATION: DISPOSAL MUST BE MADE ACCORDING TO OFFICIAL REGULATIONS.
| 14 TRANSPORT INFORMATION | |
UN-NUMBER:
DOT, ADR/RID/ADN, IMDG, IATA: UN1268
UN PROPER SHIPPING NAME:
DOT, ADR/RID/ADN, IMDG, IATA: PETROLEUM PRODUCTS, N.O.S.
TRANSPORT HAZARD CLASS(ES):
DOT: FLAMMABLE LIQUID, CLASS/DIVISION 3.1, 3.2, 3.3
CLASS: 3
LABEL: 3
ADR/RID/ADN: CLASS 3, FLAMMABLE LIQUIDS
CLASS: 3 (F1)
LABEL: 3
IMDG, IATA: CLASS 3 - FLAMMABLE LIQUIDS
CLASS: 3
LABEL: 3
PACKING GROUP:
DOT, ADR/RID/ADN, IMDG, IATA: II
ENVIRONMENTAL HAZARDS:
PRODUC T CONTAINS ENVIR ONM ENTALLY HAZAR DOUS SUBSTANCES:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH., HEPTANE
MARINE POLLUTANT:
ENVIRONMENT
YES
SPECIAL PRECAUTIONS FOR USER:
WARNING: FLAMMABLE LIQUIDS
DANGER CODE (KEMLER): 33
EMS NUMBER: F-E, S-E
TRANSPORT IN BULK ACCORDING TO ANNEX II OF MARPOL73/78 AND THE IBC CODE:
NOT APPLICABLE.
TRANSPORT/ADDITIONAL INFORMATION:
DOT:
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 1 L EACH.
LABELING AS A MARINE POLLUTANT IS ONLY REQUIRED FOR BULK SINGLE PACKAGE
SHIPMENTS. BULK PACKAGING CONSISTS OF A MAXIMUM CAPACITY OF GREATER THAN
450 L (119 GALLONS) FOR A LIQUID AND A MAXIMUM NET MASS GREATER THAN
400 KG (882 POUNDS) FOR A SOLID. (SEE 171.4(C))
ADR/RID/ADN:
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 1 L EACH.
MARINE POLLUTANTS PACKAGED IN SINGLE OR COMBINATION PACKAGINGS CONTAINING
A NET QUANTITY PER SINGLE OR INNER PACKAGING OF 5 L OR LESS FOR LIQUIDS
OR HAVING A NET MASS PER SINGLE OR INNER PACKAGING OF 5 KG OR LESS FOR
SOLIDS ARE NOT SUBJECT TO PROVISIONS RELEVANT TO MARINE POLLUTANTS.
(SEE 5.2.1.8.1)
IMDG:
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 1 L EACH.
MARINE POLLUTANTS PACKAGED IN SINGLE OR COMBINATION PACKAGINGS CONTAINING
A NET QUANTITY PER SINGLE OR INNER PACKAGING OF 5 L OR LESS FOR LIQUIDS OR
HAVING A NET MASS PER SINGLE OR INNER PACKAGING OF 5 KG OR LESS FOR SOLIDS
ARE NOT SUBJECT TO PROVISIONS RELEVANT TO MARINE POLLUTANTS. (SEE 2.10.2.7)
IATA:
LIMITED QUANTITY FOR PACKAGES LESS THAN 30 KG GROSS AND INNER PACKAGINGS
LESS THAN 0.5 L EACH / 1 L NET.
| 15 REGULATORY INFORMATION | |
SAFETY, HEALTH AND ENVIRONMENTAL REGULATIONS/LEGISLATION SPECIFIC FOR THE
SUBSTANCE OR MIXTURE:
UNITED STATES (USA):
SARA:
SECTION 302 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 355 (EXTREMELY HAZARDOUS SUBSTANCES):
NONE OF THE INGREDIENTS ARE LISTED.
SECTION 313 (SPECIFIC TOXIC CHEMICAL LISTINGS):
NONE OF THE INGREDIENTS ARE LISTED.
TSCA (TOXIC SUBSTANCES CONTROL ACT): ALL INGREDIENTS ARE LISTED OR EXEMPT.
PROPOSITION 65 (CALIFORNIA):
CHEMICALS KNOWN TO CAUSE CANCER:
REFERENCE TO CRYSTALLINE SILICA AND/OR QUARTZ IS BASED ON UNBOUND
RESPIRABLE PARTICLES AND IS NOT GENERALLY APPLICABLE TO PRODUCT AS
SUPPLIED.
14808-60-7 QUARTZ
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY FOR FEMALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY FOR MALES:
NONE OF THE INGREDIENTS ARE LISTED.
CHEMICALS KNOWN TO CAUSE DEVELOPMENTAL TOXICITY:
108-88-3 TOLUENE
67-56-1 METHANOL
EPA (ENVIRONMENTAL PROTECTION AGENCY):
142-82-5 HEPTANE D
108-88-3 TOLUENE II
1330-20-7 XYLENE I
IARC (INTERNATIONAL AGENCY FOR RESEARCH ON CANCER):
14808-60-7 QUARTZ 1
61789-51-3 NAPHTHENIC ACIDS, COBALT SALTS 2B
27253-31-2 COBALT CARBOXYLATE 2B
CANADIAN DOMESTIC SUBSTANCES LIST (DSL): (SUBSTANCES NOT LISTED.)
ALL INGREDIENTS ARE LISTED OR EXEMPT.
| 16 OTHER INFORMATION | |
THIS INFORMATION IS BASED ON OUR PRESENT KNOWLEDGE. HOWEVER, THIS SHALL
NOT CONSTITUTE A GUARANTEE FOR ANY SPECIFIC PRODUCT FEATURES AND SHALL
NOT ESTABLISH A LEGALLY VALID CONTRACTUAL RELATIONSHIP.
ABBREVIATIONS AND ACRONYMS:
ADR:
EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS
GOODS BY ROAD
IMDG: INTERNATIONAL MARITIME CODE FOR DANGEROUS GOODS
DOT: US DEPARTMENT OF TRANSPORTATION
IATA: INTERNATIONAL AIR TRANSPORT ASSOCIATION
CAS:
CHEMICAL ABSTRACTS SERVICE (DIVISION OF THE AMERICAN CHEMICAL SOCIETY)
LC50: LETHAL CONCENTRATION, 50 PERCENT
LD50: LETHAL DOSE, 50 PERCENT
PBT: PERSISTANT, BIO-ACCUMULABLE, TOXIC
VPVB: VERY PERSISTENT AND VERY BIOACCUMULATIVE
OSHA: OCCUPATIONAL SAFETY & HEALTH ADMINISTRATION
FLAM. LIQ. 2: FLAMMABLE LIQUIDS - CATEGORY 2
FLAM. LIQ. 3: FLAMMABLE LIQUIDS - CATEGORY 3
FLAM. LIQ. 4: FLAMMABLE LIQUIDS - CATEGORY 4
ACUTE TOX. 3: ACUTE TOXICITY - CATEGORY 3
ACUTE TOX. 4: ACUTE TOXICITY - CATEGORY 4
SKIN IRRIT. 2: SKIN CORROSION/IRRITATION - CATEGORY 2
EYE DAM. 1: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 1
EYE IRRIT. 2A: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2A
EYE IRRIT. 2B: SERIOUS EYE DAMAGE/EYE IRRITATION - CATEGORY 2B
SKIN SENS. 1: SKIN SENSITISATION - CATEGORY 1
CARC. 2: CARCINOGENICITY - CATEGORY 2
REPR. 2: REPRODUCTIVE TOXICITY - CATEGORY 2
STOT SE 1: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 1
STOT SE 3: SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) - CATEGORY 3
STOT RE 2: SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - CATEGORY 2
ASP. TOX. 1: ASPIRATION HAZARD - CATEGORY 1
SOURCES:
WEBSITE, EUROPEAN CHEMICALS AGENCY (ECHA.EUROPA.EU)
WEBSITE, US EPA SUBSTANCE REGISTRY SERVICES (OFMPUB.EPA.GOV/SOR INTERNET/
REGISTRY/SUBSTREG/HOME/OVERVIEW/HOME.DO)
WEBSITE, CHEMICAL ABSTRACTS REGISTRY, AMERICAN CHEMICAL SOCIETY
(WWW.CAS.ORG)
PATTY'S INDUSTRIAL HYGIENE, 6TH ED., ROSE, VERNON, ED. ISBN:
978-0-470-07488-6
CASARETT AND DOULL'S TOXICOLOGY:
THE BASIC SCIENCE OF POISONS, 8TH ED., KLAASEN, CURTIS D., ED., ISBN:
978-0-07-176923-5.
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