| Common Name: | PEROXIDE CLEANER CONCENTRATE |
| Manufacturer: | 3M |
| SDS Revision Date: | 7/13/2017 |
| SDS Format: | GHS-US |
| Item Number(s): | 20AT47 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
3M(TM) PEROXIDE CLEANER CONCENTRATE
07/13/17
3M
SAFETY DATA SHEET
COPYRIGHT, 2017, 3M COMPANY.
ALL RIGHTS RESERVED. COPYING AND/OR DOWNLOADING OF THIS INFORMATION FOR
THE PURPOSE OF PROPERLY UTILIZING 3M PRODUCTS IS ALLOWED PROVIDED THAT:
(1) THE INFORMATION IS COPIED IN FULL WITH NO CHANGES UNLESS PRIOR WRITTEN
AGREEMENT IS OBTAINED FROM 3M, AND
(2) NEITHER THE COPY NOR THE ORIGINAL IS RESOLD OR OTHERWISE DISTRIBUTED
WITH THE INTENTION OF EARNING A PROFIT THEREON.
DOCUMENT GROUP: 31-9335-6
VERSION NUMBER: 4.00
ISSUE DATE: 07/13/17
SUPERCEDES DATE: 05/05/14
| SECTION 1: IDENTIFICATION |  |
1.1. PRODUCT IDENTIFIER: 3M(TM) PEROXIDE CLEANER CONCENTRATE
PRODUCT IDENTIFICATION NUMBERS: 70-0715-9580-8, 70-0716-6116-2
1.2. RECOMMENDED USE AND RESTRICTIONS ON USE:
RECOMMENDED USE:
PEROXIDE CLEANING SOLUTION, NO FRAGRANCE ADDED, HARD SURFACE CLEANER
1.3. SUPPLIER'S DETAILS:
MANUFACTURER: 3M
DIVISION: COMMERCIAL SOLUTIONS DIVISION
ADDRESS:
3M CENTER
ST. PAUL, MN 55144-1000
USA
TELEPHONE: 1-888-3M HELPS (1-888-364-3577)
1.4. EMERGENCY TELEPHONE NUMBER:
1-800-364-3577 OR (651) 737-6501 (24 HOURS)
| SECTION 2: HAZARD IDENTIFICATION | |
2.1. HAZARD CLASSIFICATION:
SERIOUS EYE DAMAGE/IRRITATION: CATEGORY 1.
SKIN CORROSION/IRRITATION: CATEGORY 2.
2.2. LABEL ELEMENTS:
SIGNAL WORD: DANGER
SYMBOLS: CORROSION
PICTOGRAMS: ORROSION
HAZARD STATEMENTS:
CAUSES SERIOUS EYE DAMAGE.
CAUSES SKIN IRRITATION.
PRECAUTIONARY STATEMENTS:
GENERAL: KEEP OUT OF REACH OF CHILDREN.
PREVENTION:
WEAR EYE/FACE PROTECTION.
WEAR PROTECTIVE GLOVES.
WASH THOROUGHLY AFTER HANDLING.
RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN
IF SKIN IRRITATION OCCURS: GET MEDICAL ADVICE/ATTENTION.
TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
2.3. HAZARDS NOT OTHERWISE CLASSIFIED:
10% OF THE MIXTURE CONSISTS OF INGREDIENTS OF UNKNOWN ACUTE INHALATION
TOXICITY.
| SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS | |
INGREDIENT C.A.S. NO. % BY WT
WATER 7732-18-5 60 - 90 TRADE SECRET*
ETHOXYLATED C9-11 ALCOHOLS 68439-46-3 7 - 13 TRADE SECRET*
HYDROGEN PEROXIDE 7722-84-1 3 - 7 TRADE SECRET*
1-HYDROXYETHANE-1,1- TRADE SECRET* <0.1 TRADE SECRET*
DIPHOSPHONIC ACID
SODIUM HYDROXIDE 11310-73-2 <0.1 TRADE SECRET*
*THE SPECIFIC CHEMICAL IDENTITY AND/OR EXACT PERCENTAGE (CONCENTRATION) OF
THIS COMPOSITION HAS BEEN WITHHELD AS A TRADE SECRET.
| SECTION 4: FIRST AID MEASURES | |
4.1. DESCRIPTION OF FIRST AID MEASURES:
INHALATION:
REMOVE PERSON TO FRESH AIR. IF YOU FEEL UNWELL, GET MEDICAL ATTENTION.
SKIN CONTACT:
IMMEDIATELY WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE. IF SIGNS/SYMPTOMS DEVELOP, GET MEDICAL ATTENTION.
EYE CONTACT:
IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
REMOVE CONTACT LENSES IF EASY TO DO. CONTINUE RINSING. IMMEDIATELY GET
MEDICAL ATTENTION.
IF SWALLOWED:
RINSE MOUTH. DO NOT INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
4.2. MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
SEE SECTION 11.1. INFORMATION ON TOXICOLOGICAL EFFECTS.
4.3. INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT
REQUIRED: NOT APPLICABLE
| SECTION 5: FIRE-FIGHTING MEASURES | |
5.1. SUITABLE EXTINGUISHING MEDIA:
MATERIAL WILL NOT BURN. USE A FIRE FIGHTING AGENT SUITABLE FOR THE
SURROUNDING FIRE. NON-COMBUSTIBLE. USE A FIRE FIGHTING AGENT SUITABLE
FOR SURROUNDING FIRE.
5.2. SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NONE INHERENT IN THIS PRODUCT.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS:
SUBSTANCE CONDITION
CARBON MONOXIDE DURING COMBUSTION
CARBON DIOXIDE DURING COMBUSTION
OXIDES OF NITROGEN DURING COMBUSTION
OXIDES OF PHOSPHORUS DURING COMBUSTION
5.3. SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS:
NO SPECIAL PROTECTIVE ACTIONS FOR FIRE-FIGHTERS ARE ANTICIPATED.
| SECTION 6: ACCIDENTAL RELEASE MEASURES | |
6.1. PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
EVACUATE AREA. VENTILATE THE AREA WITH FRESH AIR. FOR LARGE SPILL, OR
SPILLS IN CONFINED SPACES, PROVIDE MECHANICAL VENTILATION TO DISPERSE OR
EXHAUST VAPORS, IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE PRACTICE. REFER
TO OTHER SECTIONS OF THIS SDS FOR INFORMATION REGARDING PHYSICAL AND HEALTH
HAZARDS, RESPIRATORY PROTECTION, VENTILATION, AND PERSONAL PROTECTIVE
EQUIPMENT.
6.2. ENVIRONMENTAL PRECAUTIONS:
AVOID RELEASE TO THE ENVIRONMENT. FOR LARGER SPILLS, COVER DRAINS AND BUILD
DIKES TO PREVENT ENTRY INTO SEWER SYSTEMS OR BODIES OF WATER.
6.3. METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
CONTAIN SPILL. WORKING FROM AROUND THE EDGES OF THE SPILL INWARD, COVER
WITH BENTONITE, VERMICULITE, OR COMMERCIALLY AVAILABLE INORGANIC ABSORBENT
MATERIAL. MIX IN SUFFICIENT ABSORBENT UNTIL IT APPEARS DRY. REMEMBER,
ADDING AN ABSORBENT MATERIAL DOES NOT REMOVE A PHYSICAL, HEALTH, OR
ENVIRONMENTAL HAZARD. COLLECT AS MUCH OF THE SPILLED MATERIAL AS POSSIBLE.
PLACE IN A CLOSED CONTAINER APPROVED FOR TRANSPORTATION BY APPROPRIATE
AUTHORITIES. CLEAN UP RESIDUE WITH WATER. SEAL THE CONTAINER. DISPOSE OF
COLLECTED MATERIAL AS SOON AS POSSIBLE.
| SECTION 7: HANDLING AND STORAGE | |
7.1. PRECAUTIONS FOR SAFE HANDLING:
THIS PRODUCT IS NOT INTENDED TO BE USED WITHOUT PRIOR DILUTION AS SPECIFIED
ON THE PRODUCT LABEL. GROUNDING OR SAFETY SHOES WITH ELECTROSTATIC
DISSIPATING SOLES (ESD) ARE NOT REQUIRED WITH A CHEMICAL DISPENSING SYSTEM.
KEEP OUT OF REACH OF CHILDREN. AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/
SPRAY. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT EAT, DRINK OR
SMOKE WHEN USING THIS PRODUCT. WASH THOROUGHLY AFTER HANDLING. AVOID
RELEASE TO THE ENVIRONMENT. AVOID CONTACT WITH OXIDIZING AGENTS
(EG. CHLORINE, CHROMIC ACID ETC.)
7.2. CONDITIONS FOR SAFE STORAGE INCLUDING ANY INCOMPATIBILITIES:
STORE AWAY FROM OXIDIZING AGENTS.
| SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION | |
8.1. CONTROL PARAMETERS:
OCCUPATIONAL EXPOSURE LIMITS:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN THE TABLE
BELOW, AN OCCUPATIONAL EXPOSURE LIMIT IS NOT AVAILABLE FOR THE COMPONENT.
INGREDIENT C.A.S. NO. AGENCY LIMIT TYPE ADDITIONAL COMMENTS
SODIUM HYDROXIDE 1310-73-2 OSHA TWA: 2 MG/M3
SODIUM HYDROXIDE 1310-73-2 ACGIH CEIL: 2 MG/M3
HYDROGEN PEROXIDE 7722-84-1 OSHA TWA:
1.4 MG/M3
(1 PPM)
HYDROGEN PEROXIDE 7722-84-1 ACGIH TWA: A3: CONFIRMED ANIMAL
1 PPM
CARCIN.
ACGIH: AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS
AIHA: AMERICAN INDUSTRIAL HYGIENE ASSOCIATION
CMRG: CHEMICAL MANUFACTURER'S RECOMMENDED GUIDELINES
OSHA:
UNITED STATES DEPARTMENT OF LABOR - OCCUPATIONAL SAFETY AND HEALTH
ADMINISTRATION
TWA: TIME-WEIGHTED-AVERAGE
STEL: SHORT TERM EXPOSURE LIMIT
CEIL: CEILING
8.2. EXPOSURE CONTROLS:
8.2.1. ENGINEERING CONTROLS:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SPECIAL
VENTILATION IS NOT REQUIRED. USE GENERAL DILUTION VENTILATION AND/OR
LOCAL EXHAUST VENTILATION TO CONTROL AIRBORNE EXPOSURES TO BELOW RELEVANT
EXPOSURE LIMITS AND/OR CONTROL DUST/FUME/GAS/MIST/VAPORS/SPRAY.
IF VENTILATION IS NOT ADEQUATE, USE RESPIRATORY PROTECTION EQUIPMENT.
8.2.2. PERSONAL PROTECTIVE EQUIPMENT (PPE):
EYE/FACE PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, EYE CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR. IF THE PRODUCT IS NOT USED WITH
A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN ACCIDENTAL RELEASE, WEAR
PROTECTIVE EYE/FACE PROTECTION.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE:
SELECT AND USE EYE/FACE PROTECTION TO PREVENT CONTACT BASED ON THE RESULTS
OF AN EXPOSURE ASSESSMENT.
THE FOLLOWING EYE/FACE PROTECTION(S) ARE RECOMMENDED:
FULL FACE SHIELD
INDIRECT VENTED GOGGLES
SKIN/HAND PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, SKIN CONTACT WITH
THE CONCENTRATE IS NOT EXPECTED TO OCCUR. IF PRODUCT IS NOT USED WITH A
CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN ACCIDENTAL RELEASE:
SELECT AND USE GLOVES AND/OR PROTECTIVE CLOTHING APPROVED TO RELEVANT LOCAL
STANDARDS TO PREVENT SKIN CONTACT BASED ON THE RESULTS OF AN EXPOSURE
ASSESSMENT. SELECTION SHOULD BE BASED ON USE FACTORS SUCH AS EXPOSURE
LEVELS, CONCENTRATION OF THE SUBSTANCE OR MIXTURE, FREQUENCY AND DURATION,
PHYSICAL CHALLENGES SUCH AS TEMPERATURE EXTREMES, AND OTHER USE CONDITIONS.
CONSULT WITH YOUR GLOVE AND/OR PROTECTIVE CLOTHING MANUFACTURER FOR
SELECTION OF APPROPRIATE COMPATIBLE GLOVES/PROTECTIVE CLOTHING.
GLOVES MADE FROM THE FOLLOWING MATERIAL(S) ARE RECOMMENDED:
NEOPRENE
NITRILE RUBBER
POLYMER LAMINATE
RESPIRATORY PROTECTION:
NOTE:
WHEN USED WITH A CHEMICAL DISPENSING SYSTEM AS DIRECTED, RESPIRATORY
PROTECTION IS NOT REQUIRED.
IF PRODUCT IS NOT USED WITH A CHEMICAL DISPENSING SYSTEM OR IF THERE IS AN
ACCIDENTAL RELEASE:
AN EXPOSURE ASSESSMENT MAY BE NEEDED TO DECIDE IF A RESPIRATOR IS REQUIRED.
IF A RESPIRATOR IS NEEDED, USE RESPIRATORS AS PART OF A FULL RESPIRATORY
PROTECTION PROGRAM. BASED ON THE RESULTS OF THE EXPOSURE ASSESSMENT, SELECT
FROM THE FOLLOWING RESPIRATOR TYPE(S) TO REDUCE INHALATION EXPOSURE:
HALF FACEPIECE OR FULL FACEPIECE AIR-PURIFYING RESPIRATOR SUITABLE FOR
PARTICULATES
FOR QUESTIONS ABOUT SUITABILITY FOR A SPECIFIC APPLICATION, CONSULT WITH
YOUR RESPIRATOR MANUFACTURER.
| SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES | |
9.1. INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
GENERAL PHYSICAL FORM: LIQUID
ODOR, COLOR, GRADE: CLEAR ODORLESS LIQUID
ODOR THRESHOLD: NO DATA AVAILABLE
PH: 4 - 6
MELTING POINT: NOT APPLICABLE
BOILING POINT: 212 DEG. F
FLASH POINT: NO FLASH POINT
EVAPORATION RATE: NO DATA AVAILABLE
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): NOT APPLICABLE
FLAMMABLE LIMITS (LEL): NOT APPLICABLE
FLAMMABLE LIMITS (UEL): NOT APPLICABLE
FLAMMABLE LIMITS (UEL): NOT APPLICABLE
VAPOR PRESSURE: 17.5 MMHG [@ 20 DEG. C]
VAPOR DENSITY: NO DATA AVAILABLE
DENSITY: 1.02 - 1.03 G/ML
SPECIFIC GRAVITY: 1.02 - 1.03
[REF STD: WATER=1]
SOLUBILITY IN WATER: NO DATA AVAILABLE
SOLUBILITY-NON-WATER: NO DATA AVAILABLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO DATA AVAILABLE
AUTOIGNITION TEMPERATURE: NO DATA AVAILABLE
DECOMPOSITION TEMPERATURE: NO DATA AVAILABLE
VISCOSITY: NO DATA AVAILABLE
MOLECULAR WEIGHT: NO DATA AVAILABLE
VOLATILE ORGANIC COMPOUNDS: <0.1% WEIGHT
VOC LESS H2O & EXEMPT SOLVENTS: 610 - 625 G/L
| SECTION 10: STABILITY AND REACTIVITY | |
10.1. REACTIVITY:
THIS MATERIAL MAY BE REACTIVE WITH CERTAIN AGENTS UNDER CERTAIN
CONDITIONS - SEE THE REMAINING HEADINGS IN THIS SECTION.
10.2. CHEMICAL STABILITY: STABLE.
10.3. POSSIBILITY OF HAZARDOUS REACTIONS:
HAZARDOUS POLYMERIZATION WILL NOT OCCUR.
10.4. CONDITIONS TO AVOID: NONE KNOWN.
10.5. INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS
10.6. HAZARDOUS DECOMPOSITION PRODUCTS:
SUBSTANCE CONDITION
NONE KNOWN.
REFER TO SECTION 5.2 FOR HAZARDOUS DECOMPOSITION PRODUCTS DURING
COMBUSTION.
| SECTION 11: TOXICOLOGICAL INFORMATION | |
THE INFORMATION BELOW MAY NOT BE CONSISTENT WITH THE MATERIAL
CLASSIFICATION IN SECTION 2 IF SPECIFIC INGREDIENT CLASSIFICATIONS ARE
MANDATED BY A COMPETENT AUTHORITY. IN ADDITION, TOXICOLOGICAL DATA ON
INGREDIENTS MAY NOT BE REFLECTED IN THE MATERIAL CLASSIFICATION AND/OR THE
SIGNS AND SYMPTOMS OF EXPOSURE, BECAUSE AN INGREDIENT MAY BE PRESENT BELOW
THE THRESHOLD FOR LABELING, AN INGREDIENT MAY NOT BE AVAILABLE FOR
EXPOSURE, OR THE DATA MAY NOT BE RELEVANT TO THE MATERIAL AS A WHOLE.
11.1. INFORMATION ON TOXICOLOGICAL EFFECTS:
SIGNS AND SYMPTOMS OF EXPOSURE:
BASED ON TEST DATA AND/OR INFORMATION ON THE COMPONENTS, THIS MATERIAL MAY
PRODUCE THE FOLLOWING HEALTH EFFECTS:
INHALATION:
RESPIRATORY TRACT IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE COUGH, SNEEZING, NASAL DISCHARGE, HEADACHE,
HOARSENESS, AND NOSE AND THROAT PAIN.
SKIN CONTACT:
SKIN IRRITATION:
SIGNS/SYMPTOMS MAY INCLUDE LOCALIZED REDNESS, SWELLING, ITCHING, DRYNESS,
CRACKING, BLISTERING, AND PAIN.
EYE CONTACT:
CORROSIVE (EYE BURNS):
SIGNS/SYMPTOMS MAY INCLUDE CLOUDY APPEARANCE OF THE CORNEA, CHEMICAL BURNS,
SEVERE PAIN, TEARING, ULCERATIONS, SIGNIFICANTLY IMPAIRED VISION OR
COMPLETE LOSS OF VISION.
INGESTION:
GASTROINTESTINAL CORROSION:
SIGNS/SYMPTOMS MAY INCLUDE SEVERE MOUTH, THROAT AND ABDOMINAL PAIN; NAUSEA;
VOMITING; AND DIARRHEA; BLOOD IN THE FECES AND/OR VOMITUS MAY ALSO BE
SEEN.
ADDITIONAL HEALTH EFFECTS:
SINGLE EXPOSURE MAY CAUSE TARGET ORGAN EFFECTS:
DERMAL EFFECTS:
SIGNS/SYMPTOMS MAY INCLUDE CHANGES IN SKIN PIGMENTATION AND/OR COLORATION.
TOXICOLOGICAL DATA:
IF A COMPONENT IS DISCLOSED IN SECTION 3 BUT DOES NOT APPEAR IN A TABLE
BELOW, EITHER NO DATA ARE AVAILABLE FOR THAT ENDPOINT OR THE DATA ARE NOT
SUFFICIENT FOR CLASSIFICATION.
ACUTE TOXICITY:
NAME ROUTE SPECIES VALUE
OVERALL PRODUCT INHALATION- NO DATA AVAILABLE;
DUST/MIST CALCULATED ATE: >12.5 MG/L
(4 HR)
OVERALL PRODUCT INGESTION NO DATA AVAILABLE;
CALCULATED ATE: >5,000 MG/KG
ETHOXYLATED C9-11 DERMAL RABBIT LD50: >2,000 MG/KG
ALCOHOLS
ETHOXYLATED C9-11 INGESTION RAT LD50: 1,378 MG/KG
ALCOHOLS
HYDROGEN PEROXIDE DERMAL RABBIT LD50: >2,000 MG/KG
HYDROGEN PEROXIDE INHALATION- RAT LC50: 2 MG/L
DUST/MIST
(4 HOURS)
HYDROGEN PEROXIDE INGESTION RAT LD50: 1,193 MG/KG
ATE = ACUTE TOXICITY ESTIMATE
SKIN CORROSION/IRRITATION:
NAME SPECIES VALUE
ETHOXYLATED C9-11 ALCOHOLS RABBIT IRRITANT
HYDROGEN PEROXIDE RABBIT CORROSIVE
SODIUM HYDROXIDE RABBIT CORROSIVE
SERIOUS EYE DAMAGE/IRRITATION:
NAME SPECIES VALUE
OVERALL PRODUCT IN VITRO DATA CORROSIVE
ETHOXYLATED C9-11 ALCOHOLS PROFESSIONAL CORROSIVE
JUDGEMENT
HYDROGEN PEROXIDE RABBIT CORROSIVE
SODIUM HYDROXIDE RABBIT CORROSIVE
SKIN SENSITIZATION:
NAME SPECIES VALUE
ETHOXYLATED C9-11 ALCOHOLS GUINEA PIG NOT CLASSIFIED
HYDROGEN PEROXIDE GUINEA PIG NOT CLASSIFIED
SODIUM HYDROXIDE HUMAN NOT CLASSIFIED
RESPIRATORY SENSITIZATION:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR
THE DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
GERM CELL MUTAGENICITY:
NAME ROUTE VALUE
ETHOXYLATED C9-11 ALCOHOLS IN VITRO NOT MUTAGENIC
HYDROGEN PEROXIDE IN VIVO NOT MUTAGENIC
HYDROGEN PEROXIDE IN VITRO SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
SODIUM HYDROXIDE IN VITRO NOT MUTAGENIC
CARCINOGENICITY:
NAME ROUTE SPECIES VALUE
HYDROGEN PEROXIDE DERMAL MULTIPLE SOME POSITIVE DATA EXIST, BUT THE
ANIMAL DATA ARE NOT SUFFICIENT FOR
SPECIES CLASSIFICATION
HYDROGEN PEROXIDE INGESTION MOUSE SOME POSITIVE DATA EXIST, BUT THE
DATA ARE NOT SUFFICIENT FOR
CLASSIFICATION
REPRODUCTIVE TOXICITY:
REPRODUCTIVE AND/OR DEVELOPMENTAL EFFECTS:
NAME ROUTE VALUE
ETHOXYLATED C9-11 ALCOHOLS DERMAL NOT CLASSIFIED FOR FEMALE
REPRODUCTION
ETHOXYLATED C9-11 ALCOHOLS DERMAL NOT CLASSIFIED FOR DEVELOPMENT
ETHOXYLATED C9-11 ALCOHOLS DERMAL NOT CLASSIFIED FOR MALE
REPRODUCTION
HYDROGEN PEROXIDE INGESTION NOT CLASSIFIED FOR FEMALE
REPRODUCTION
HYDROGEN PEROXIDE INGESTION NOT CLASSIFIED FOR MALE
REPRODUCTION
HYDROGEN PEROXIDE INGESTION NOT CLASSIFIED FOR DEVELOPMENT
NAME SPECIES TEST RESULT EXPOSURE DURATION
ETHOXYLATED C9-11 ALCOHOLS RAT NOAEL: 2 GENERATION
250 MG/KG/DAY
ETHOXYLATED C9-11 ALCOHOLS RAT NOAEL: 2 GENERATION
250 MG/KG/DAY
ETHOXYLATED C9-11 ALCOHOLS RAT NOAEL: 2 GENERATION
100 MG/KG/DAY
HYDROGEN PEROXIDE RAT LOAEL: 6 MONTHS
5 MG/KG/DAY
HYDROGEN PEROXIDE RAT LOAEL: 6 MONTHS
5 MG/KG/DAY
HYDROGEN PEROXIDE RAT LOAEL: DURING
5 MG/KG/DAY GESTATION
TARGET ORGAN(S):
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ETHOXYLATED C9-11 INHALATION RESPIRATORY SOME POSITIVE DATA EXIST,
ALCOHOLS IRRITATION BUT THE DATA ARE NOT
SUFFICIENT FOR
CLASSIFICATION
HYDROGEN PEROXIDE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
HYDROGEN PEROXIDE INGESTION NERVOUS SYSTEM SOME POSITIVE DATA EXIST,
BUT THE DATA ARE NOT
SUFFICIENT
CLASSIFICATION
SODIUM HYDROXIDE INHALATION RESPIRATORY MAY CAUSE RESPIRATORY
IRRITATION IRRITATION
NAME SPECIES TEST RESULT EXPOSURE DURATION
ETHOXYLATED C9-11 NOT AVAILABLE NOAEL: NOT AVAILABLE NOT AVAILABLE
ALCOHOLS
HYDROGEN PEROXIDE HUMAN NOAEL: NOT AVAILABLE
HYDROGEN PEROXIDE HUMAN LOAEL: NOT AVAILABLE POISONING AND/OR
ABUSE
SODIUM HYDROXIDE HUMAN NOAEL: NOT AVAILABLE
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE:
NAME ROUTE TARGET ORGAN(S) VALUE
ETHOXYLATED C9-11 ALCOHOLS DERMAL KIDNEY AND/OR NOT CLASSIFIED
BLADDER
HEMATOPOIETIC
SYSTEM
HYDROGEN PEROXIDE INGESTION HEMATOPOIETIC NOT CLASSIFIED
SYSTEM
HYDROGEN PEROXIDE INGESTION LIVER NOT CLASSIFIED
KIDNEY AND/OR
BLADDER
NAME SPECIES TEST RESULT EXPOSURE DURATION
ETHOXYLATED C9-11 ALCOHOLS RAT NOAEL: 13 WEEKS
125 MG/KG/DAY
HYDROGEN PEROXIDE RAT NOEL: 6 MONTHS
0.005 MG/KG/DAY
HYDROGEN PEROXIDE MOUSE NOAEL: 35 WEEKS
NOT AVAILABLE
ASPIRATION HAZARD:
FOR THE COMPONENT/COMPONENTS, EITHER NO DATA ARE CURRENTLY AVAILABLE OR THE
DATA ARE NOT SUFFICIENT FOR CLASSIFICATION.
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL TOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 12: ECOLOGICAL INFORMATION | |
ECOTOXICOLOGICAL INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL ECOTOXICOLOGICAL INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
CHEMICAL FATE INFORMATION:
PLEASE CONTACT THE ADDRESS OR PHONE NUMBER LISTED IN SECTION 1 OF THIS
SDS FOR ADDITIONAL CHEMICAL FATE INFORMATION ON THIS MATERIAL AND/OR
ITS COMPONENTS.
| SECTION 13: DISPOSAL CONSIDERATIONS | |
13.1. DISPOSAL METHODS:
DISPOSE OF CONTENTS/ CONTAINER IN ACCORDANCE WITH THE
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
DISPOSE OF WASTE PRODUCT IN A PERMITTED INDUSTRIAL WASTE FACILITY. EMPTY
DRUMS/BARRELS/CONTAINERS USED FOR TRANSPORTING AND HANDLING HAZARDOUS
CHEMICALS (CHEMICAL SUBSTANCES/MIXTURES/PREPARATIONS CLASSIFIED AS
HAZARDOUS AS PER APPLICABLE REGULATIONS) SHALL BE CONSIDERED, STORED,
TREATED & DISPOSED OF AS HAZARDOUS WASTES UNLESS OTHERWISE DEFINED BY
APPLICABLE WASTE REGULATIONS. CONSULT WITH THE RESPECTIVE REGULATING
AUTHORITIES TO DETERMINE THE AVAILABLE TREATMENT AND DISPOSAL FACILITIES.
EPA HAZARDOUS WASTE NUMBER (RCRA): NOT REGULATED
| SECTION 14: TRANSPORT INFORMATION | |
FOR TRANSPORT INFORMATION, PLEASE VISIT:
HTTP://3M.COM/TRANSPORTINFO OR CALL 1-800-364-3577 OR 651-737-6501.
| SECTION 15: REGULATORY INFORMATION | |
15.1. US FEDERAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
311/312 HAZARD CATEGORIES:
FIRE HAZARD: NO
PRESSURE HAZARD: NO
REACTIVITY HAZARD: YES
IMMEDIATE HAZARD: YES
DELAYED HAZARD: NO
EPCRA 311/312 HAZARD CLASSIFICATIONS (EFFECTIVE JANUARY 1, 2018):
PHYSICAL HAZARDS: NOT APPLICABLE
HEALTH HAZARDS:
HAZARD NOT OTHERWISE CLASSIFIED (HNOC)
SERIOUS EYE DAMAGE OR EYE IRRITATION
SKIN CORROSION OR IRRITATION
15.2. STATE REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
15.3. CHEMICAL INVENTORIES:
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
AUSTRALIA NATIONAL INDUSTRIAL CHEMICAL NOTIFICATION AND ASSESSMENT SCHEME
(NICNAS). CERTAIN RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR
ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE NEW SUBSTANCE
NOTIFICATION REQUIREMENTS OF CEPA.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE CHINA "MEASURES
ON ENVIRONMENTAL MANAGEMENT OF NEW CHEMICAL SUBSTANCE". CERTAIN
RESTRICTIONS MAY APPLY. CONTACT THE SELLING DIVISION FOR ADDITIONAL
INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
THE KOREAN TOXIC CHEMICAL CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
JAPAN CHEMICAL SUBSTANCE CONTROL LAW. CERTAIN RESTRICTIONS MAY APPLY.
CONTACT THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS MATERIAL ARE IN COMPLIANCE WITH THE PROVISIONS OF
PHILIPPINES RA 6969 REQUIREMENTS. CERTAIN RESTRICTIONS MAY APPLY. CONTACT
THE SELLING DIVISION FOR ADDITIONAL INFORMATION.
THE COMPONENTS OF THIS PRODUCT ARE IN COMPLIANCE WITH THE CHEMICAL
NOTIFICATION REQUIREMENTS OF TSCA.
CONTACT 3M FOR MORE INFORMATION.
15.4. INTERNATIONAL REGULATIONS: CONTACT 3M FOR MORE INFORMATION.
THIS SDS HAS BEEN PREPARED TO MEET THE U.S. OSHA HAZARD COMMUNICATION
STANDARD, 29 CFR 1910.1200.
| SECTION 16: OTHER INFORMATION | |
NFPA HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
INSTABILITY 1
SPECIAL HAZARDS NONE
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA) HAZARD RATINGS ARE DESIGNED FOR
USE BY EMERGENCY RESPONSE PERSONNEL TO ADDRESS THE HAZARDS THAT ARE
PRESENTED BY SHORT-TERM, ACUTE EXPOSURE TO A MATERIAL UNDER CONDITIONS OF
FIRE, SPILL, OR SIMILAR EMERGENCIES. HAZARD RATINGS ARE PRIMARILY BASED ON
THE INHERENT PHYSICAL AND TOXIC PROPERTIES OF THE MATERIAL BUT ALSO INCLUDE
THE TOXIC PROPERTIES OF COMBUSTION OR DECOMPOSITION PRODUCTS THAT ARE KNOWN
TO BE GENERATED IN SIGNIFICANT QUANTITIES.
HMIS HAZARD CLASSIFICATION:
HEALTH 3
FLAMMABILITY 0
PHYSICAL HAZARD 1
PERSONAL PROTECTION X - SEE PPE SECTION.
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS(R*) IV) HAZARD RATINGS ARE
DESIGNED TO INFORM EMPLOYEES OF CHEMICAL HAZARDS IN THE WORKPLACE. THESE
RATINGS ARE BASED ON THE INHERENT PROPERTIES OF THE MATERIAL UNDER EXPECTED
CONDITIONS OF NORMAL USE AND ARE NOT INTENDED FOR USE IN EMERGENCY
SITUATIONS. HMIS(R*) IV RATINGS ARE TO BE USED WITH A FULLY IMPLEMENTED
HMIS(R*) IV PROGRAM. HMIS(R*) IS A REGISTERED MARK OF THE AMERICAN COATINGS
ASSOCIATION (ACA).
DOCUMENT GROUP: 31-9335-6
VERSION NUMBER: 4.00
ISSUE DATE: 07/13/17
SUPERCEDES DATE: 05/05/14
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AS OF THE DATE ISSUED. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED,
INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
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