| Common Name: | COMMERCIAL SOLUTIONS TILEX SOAP SCUM REMOVER & DISINFECTANT |
| Manufacturer: | CLOROX |
| SDS Revision Date: | 1/5/2015 |
| SDS Format: | GHS-US |
| Item Number(s): | 20K971 |
| Manufacturer Model Number(s): |
SDS Table of Contents
Click the desired link below to jump directly to that section in the SDS.
THE CLOROX COMPANY
SAFETY DATA SHEET
ISSUING DATE: JANUARY 5, 2015
REVISION DATE: NEW
REVISION NUMBER: 0
| 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION |  |
AND OF THE COMPANY/UNDERTAKING
PRODUCT IDENTIFIER:
PRODUCT NAME:
CLOROX COMMERCIAL SOLUTIONS(R*) TILEX(R*) SOAP SCUM REMOVER & DISINFECTANT
OTHER MEANS OF IDENTIFICATION:
EPA REGISTRATION NUMBER: 5813-40-67619
RECOMMENDED USE OF THE CHEMICAL AND RESTRICTIONS ON USE:
RECOMMENDED USE: DISINFECTING BATHROOM SPRAY CLEANER
USES ADVISED AGAINST: NO INFORMATION AVAILABLE
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
SUPPLIER ADDRESS:
THE CLOROX COMPANY
1221 BROADWAY
OAKLAND, CA 94612
USA
PHONE: 1-510-271-7000
EMERGENCY TELEPHONE NUMBER:
EMERGENCY PHONE NUMBERS:
FOR MEDICAL EMERGENCIES, CALL: 1-800-446-1014
FOR TRANSPORTATION EMERGENCIES, CALL CHEMTREC: 1-800-424-9300
| 2. HAZARDS IDENTIFICATION | |
CLASSIFICATION:
THIS CHEMICAL IS CONSIDERED HAZARDOUS BY THE 2012 OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200).
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
GHS LABEL ELEMENTS, INCLUDING PRECAUTIONARY STATEMENTS:
EMERGENCY OVERVIEW:
SIGNAL WORD: WARNING
HAZARD STATEMENTS: CAUSES SERIOUS EYE IRRITATION
EXCLAMATION MARK
APPEARANCE: CLEAR, COLORLESS
PHYSICAL STATE: LIQUID
ODOR: CITRUS, GREEN, SOLVENT
PRECAUTIONARY STATEMENTS - PREVENTION:
WASH HANDS AND ANY EXPOSED SKIN THOROUGHLY AFTER HANDLING.
WEAR EYE PROTECTION/FACE PROTECTION SUCH AS SAFETY GLASSES.
PRECAUTIONARY STATEMENTS - RESPONSE:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES,
IF PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ADVICE/ATTENTION.
PRECAUTIONARY STATEMENTS - STORAGE: NONE
PRECAUTIONARY STATEMENTS - DISPOSAL: NONE
HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NOT APPLICABLE
UNKNOWN TOXICITY:
2.155% OF THE MIXTURE CONSISTS OF INGREDIENT(S) OF UNKNOWN TOXICITY
OTHER INFORMATION: NO INFORMATION AVAILABLE.
INTERACTIONS WITH OTHER CHEMICALS:
DO NOT USE OR MIX WITH BLEACH-CONTAINING PRODUCTS. TO DO SO MAY RELEASE
SMALL AMOUNTS OF FORMALDEHYDE GAS.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NAME CAS-NO WEIGHT % TRADE SECRET
DIETHYLENE GLYCOL MONOBUTYL ETHER 112-34-5 1 - 5 *
TETRAPOTASSIUM ETHYLENEDIAMINE 5964-35-2 1 - 5 *
TETRAACETATE (EDTA)
N-ALKYL (68% C12, 32% C14) DIMETHYL 85409-23-0 0.1 - 0.2 *
ETHYLBENZYL AMMONIUM CHLORIDE
N-ALKYL (5% C12, 60% C14, 30% C16, 53516-76-0 0.1 - 0.2 *
5% C18) DIMETHYL BENZYL AMMONIUM
CHLORIDE
* THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS
A TRADE SECRET
| 4. FIRST AID MEASURES | |
FIRST AID MEASURES:
GENERAL ADVICE: SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN ATTENDANCE.
EYE CONTACT:
RINSE IMMEDIATELY WITH PLENTY OF WATER, ALSO UNDER THE EYELIDS, FOR AT
LEAST 15 MINUTES. REMOVE CONTACT LENSES, IF PRESENT AND EASY TO DO.
CONTINUE RINSING. KEEP EYE WIDE OPEN WHILE RINSING. DO NOT RUB AFFECTED
AREA. GET MEDICAL ATTENTION IMMEDIATELY IF IRRITATION PERSISTS.
SKIN CONTACT:
TAKE OFF CONTAMINATED CLOTHING. RINSE SKIN IMMEDIATELY WITH PLENTY OF WATER
FOR 15-20 MINUTES. IF IRRITATION DEVELOPS, CALL A DOCTOR.
INHALATION: MOVE TO FRESH AIR. IF BREATHING IS AFFECTED, CALL A DOCTOR.
INGESTION:
CALL A POISON CONTROL CENTER OR DOCTOR IMMEDIATELY. HAVE PERSON SIP A
GLASSFUL OF WATER IF ABLE TO SWALLOW. DO NOT INDUCE VOMITING UNLESS TOLD
TO DO SO BY A POISON CONTROL CENTER OR DOCTOR.
PROTECTION OF FIRST-AIDERS:
AVOID CONTACT WITH SKIN, EYES OR CLOTHING. USE PERSONAL PROTECTIVE
EQUIPMENT AS REQUIRED. WEAR PERSONAL PROTECTIVE CLOTHING (SEE SECTION 8).
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
MOST IMPORTANT SYMPTOMS/EFFECTS: STINGING AND IRRITATION OF EYES.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY.
| 5. FIRE-FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA:
CAUTION: USE OF WATER SPRAY WHEN FIGHTING FIRE MAY BE INEFFICIENT.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: NO INFORMATION AVAILABLE
EXPLOSION DATA:
SENSITIVITY TO MECHANICAL IMPACT: NONE
SENSITIVITY TO STATIC DISCHARGE: NONE
PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
AS IN ANY FIRE, WEAR SELF-CONTAINED BREATHING APPARATUS PRESSURE-DEMAND,
MSHA/NIOSH (APPROVED OR EQUIVALENT) AND FULL PROTECTIVE GEAR.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
PERSONAL PRECAUTIONS:
AVOID CONTACT WITH EYES. USE PERSONAL PROTECTIVE EQUIPMENT AS REQUIRED.
OTHER INFORMATION: REFER TO PROTECTIVE MEASURES LISTED IN SECTIONS 7 AND 8.
ENVIRONMENTAL PRECAUTIONS:
ENVIRONMENTAL PRECAUTIONS:
SEE SECTION 12 FOR ADDITIONAL ECOLOGICAL INFORMATION.
METHODS AND MATERIAL FOR CONTAINMENT AND CLEANING UP:
METHODS FOR CONTAINMENT:
PREVENT FURTHER LEAKAGE OR SPILLAGE IF SAFE TO DO SO.
METHODS FOR CLEANING UP:
ABSORB AND CONTAINERIZE. WASH RESIDUAL DOWN TO SANITARY SEWER. CONTACT THE
SANITARY TREATMENT FACILITY IN ADVANCE TO ASSURE ABILITY TO PROCESS
WASHED-DOWN MATERIAL.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
HANDLING:
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
AVOID CONTACT WITH SKIN, EYES AND CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN
USING THIS PRODUCT.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORAGE:
KEEP CONTAINERS TIGHTLY CLOSED IN A DRY, COOL AND WELL-VENTILATED PLACE.
INCOMPATIBLE PRODUCTS: PRODUCTS CONTAINING BLEACH.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
CONTROL PARAMETERS:
EXPOSURE GUIDELINES:
CHEMICAL NAME ACGIH TLV OSHA PEL NIOSH IDLH
DIETHYLENE GLYCOL 10 PPM TWA
MONOBUTYL ETHER INHALABLE FRACTION
1310-73-2 AND VAPOR
ACGIH TLV:
AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS - THRESHOLD LIMIT
VALUE.
OSHA PEL:
OCCUPATIONAL SAFETY AND HEALTH ADMINISTRATION - PERMISSIBLE EXPOSURE
LIMITS.
NIOSH IDLH: IMMEDIATELY DANGEROUS TO LIFE OR HEALTH.
APPROPRIATE ENGINEERING CONTROLS:
ENGINEERING MEASURES:
SHOWERS
EYEWASH STATIONS
VENTILATION SYSTEMS
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION:
IF SPLASHES ARE LIKELY TO OCCUR, WEAR SAFETY GLASSES WITH SIDE-SHIELDS.
NONE REQUIRED FOR CONSUMER USE.
SKIN AND BODY PROTECTION:
WEAR RUBBER OR NEOPRENE GLOVES IF THERE IS THE POTENTIAL FOR REPEATED OR
PROLONGED SKIN CONTACT.
RESPIRATORY PROTECTION:
IF EXPOSURE LIMITS ARE EXCEEDED OR IRRITATION IS EXPERIENCED, NIOSH/MSHA
APPROVED RESPIRATORY PROTECTION SHOULD BE WORN. POSITIVE-PRESSURE SUPPLIED
AIR RESPIRATORS MAY BE REQUIRED FOR HIGH AIRBORNE CONTAMINANT
CONCENTRATIONS. RESPIRATORY PROTECTION MUST BE PROVIDED IN ACCORDANCE WITH
CURRENT LOCAL REGULATIONS.
HYGIENE MEASURES:
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE RE-USE. AVOID CONTACT WITH
SKIN, EYES AND CLOTHING. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL AND CHEMICAL PROPERTIES:
PHYSICAL STATE: LIQUID
APPEARANCE: CLEAR
COLOR: COLORLESS
ODOR: CITRUS, GREEN, SOLVENT
ODOR THRESHOLD: NO INFORMATION AVAILABLE
PROPERTY VALUES REMARKS/METHOD
PH 11 - 12.5 NONE KNOWN
MELTING/FREEZING POINT NO DATA AVAILABLE NONE KNOWN
BOILING POINT / BOILING RANGE NO DATA AVAILABLE NONE KNOWN
FLASH POINT NOT FLAMMABLE NONE KNOWN
EVAPORATION RATE NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY (SOLID, GAS) NO DATA AVAILABLE NONE KNOWN
FLAMMABILITY LIMITS IN AIR:
UPPER FLAMMABILITY LIMIT NO DATA AVAILABLE NONE KNOWN
LOWER FLAMMABILITY LIMIT NO DATA AVAILABLE NONE KNOWN
VAPOR PRESSURE NO DATA AVAILABLE NONE KNOWN
VAPOR DENSITY NO DATA AVAILABLE NONE KNOWN
SPECIFIC GRAVITY APPROX. 1.0 NONE KNOWN
WATER SOLUBILITY SOLUBLE IN WATER NONE KNOWN
SOLUBILITY IN OTHER SOLVENTS NO DATA AVAILABLE NONE KNOWN
PARTITION COEFFICIENT N-OCTANOL/WATER NO DATA AVAILABLE NONE KNOWN
AUTOIGNITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
DECOMPOSITION TEMPERATURE NO DATA AVAILABLE NONE KNOWN
KINEMATIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
DYNAMIC VISCOSITY NO DATA AVAILABLE NONE KNOWN
EXPLOSIVE PROPERTIES NOT EXPLOSIVE
OXIDIZING PROPERTIES NO DATA AVAILABLE
OTHER INFORMATION:
SOFTENING POINT NO DATA AVAILABLE
VOC CONTENT (%) NO DATA AVAILABLE
PARTICLE SIZE NO DATA AVAILABLE
PARTICLE SIZE DISTRIBUTION NO DATA AVAILABLE
| 10. STABILITY AND REACTIVITY | |
REACTIVITY:
DO NOT USE OR MIX WITH BLEACH-CONTAINING PRODUCTS. TO DO SO MAY RELEASE
SMALL AMOUNTS OF FORMALDEHYDE GAS.
CHEMICAL STABILITY: STABLE UNDER RECOMMENDED STORAGE CONDITIONS.
POSSIBILITY OF HAZARDOUS REACTIONS: NONE UNDER NORMAL PROCESSING.
CONDITIONS TO AVOID: NONE KNOWN BASED ON INFORMATION SUPPLIED.
INCOMPATIBLE MATERIALS: PRODUCTS CONTAINING BLEACH.
HAZARDOUS DECOMPOSITION PRODUCTS: NONE KNOWN BASED ON INFORMATION SUPPLIED.
| 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
PRODUCT INFORMATION:
INHALATION: EXPOSURE TO VAPOR OR MIST MAY IRRITATE RESPIRATORY TRACT.
EYE CONTACT: MAY CAUSE EYE IRRITATION.
SKIN CONTACT: PROLONGED CONTACT MAY CAUSE IRRITATION.
INGESTION:
INGESTION MAY CAUSE IRRITATION TO MUCOUS MEMBRANES AND GASTROINTESTINAL
IRRITATION, NAUSEA, VOMITING, AND DIARRHEA.
COMPONENT INFORMATION:
CHEMICAL NAME LD50 ORAL LD50 DERMAL LC50 INHALATION
DIETHYLENE GLYCOL 3384 MG/KG 2700 MG/KG
MONOBUTYL ETHER (RAT) (RABBIT)
112-34-5
INFORMATION ON TOXICOLOGICAL EFFECTS:
SYMPTOMS: MAY CAUSE REDNESS AND TEARING OF THE EYES.
DELAYED AND IMMEDIATE EFFECTS AS WELL AS CHRONIC EFFECTS FROM SHORT AND
LONG-TERM EXPOSURE:
SENSITIZATION: NO INFORMATION AVAILABLE.
MUTAGENIC EFFECTS: NO INFORMATION AVAILABLE.
CARCINOGENICITY: CONTAINS NO INGREDIENT LISTED AS A CARCINOGEN.
REPRODUCTIVE TOXICITY: NO INFORMATION AVAILABLE
STOT - SINGLE EXPOSURE: NO INFORMATION AVAILABLE.
STOT - REPEATED EXPOSURE: NO INFORMATION AVAILABLE.
CHRONIC TOXICITY: CARCINOGENIC POTENTIAL IS UNKNOWN
TARGET ORGAN EFFECTS:
RESPIRATORY SYSTEM, EYES, SKIN, GASTROINTESTINAL TRACT (GI).
ASPIRATION HAZARD: NO INFORMATION AVAILABLE.
NUMERICAL MEASURES OF TOXICITY PRODUCT INFORMATION:
THE FOLLOWING VALUES ARE CALCULATED BASED ON CHAPTER 3.1 OF THE GHS
DOCUMENT: NOT APPLICABLE
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: HARMFUL TO AQUATIC LIFE
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATION: NO INFORMATION AVAILABLE.
OTHER ADVERSE EFFECTS: NO INFORMATION AVAILABLE.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL METHODS:
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE, AND LOCAL
REGULATIONS.
CONTAMINATED PACKAGING:
DO NOT REUSE EMPTY CONTAINERS. DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE, AND LOCAL REGULATIONS.
| 14. TRANSPORT INFORMATION | |
DOT: NOT REGULATED
TDG: NOT REGULATED
ICAO: NOT REGULATED
IATA: NOT REGULATED
IMDG/IMO: NOT REGULATED
| 15. REGULATORY INFORMATION | |
CHEMICAL INVENTORIES:
TSCA:
ALL COMPONENTS OF THIS PRODUCT ARE EITHER ON THE TSCA 8(B) INVENTORY OR
OTHERWISE EXEMPT FROM LISTING.
DSL/NDSL: ALL COMPONENTS ARE ON THE DSL OR NDSL.
TSCA - UNITED STATES TOXIC SUBSTANCES CONTROL ACT SECTION 8(B) INVENTORY
DSL/NDSL - CANADIAN DOMESTIC SUBSTANCES LIST/NON-DOMESTIC SUBSTANCES LIST
U.S. FEDERAL REGULATIONS:
SARA 313:
SECTION 313 OF TITLE III OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION
ACT OF 1986 (SARA). THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL WHICH IS
SUBJECT TO THE REPORTING REQUIREMENTS OF THE ACT AND TITLE 40 OF THE CODE
OF FEDERAL REGULATIONS, PART 372.
CHEMICAL NAME CAS-NO WEIGHT % SARA 313 - THRESHOLD
VALUES %
DIETHYLENE GLYCOL MONOBUTYL 112-34-5 1 - 5 1.0
ETHER (GLYCOL ETHERS CATEGORY)
SARA 311/312 HAZARD CATEGORIES:
ACUTE HEALTH HAZARD: YES
CHRONIC HEALTH HAZARD: NO
FIRE HAZARD: NO
SUDDEN RELEASE OF PRESSURE HAZARD: NO
REACTIVE HAZARD: NO
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS POLLUTANTS
PURSUANT TO THE CLEAN WATER ACT (40 CFR 122.21 AND 40 CFR 122.42).
CERCLA:
THIS MATERIAL, AS SUPPLIED, DOES NOT CONTAIN ANY SUBSTANCES REGULATED AS
HAZARDOUS SUBSTANCES UNDER THE COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA) (40 CFR 302) OR THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) (40 CFR 355). THERE MAY BE
SPECIFIC REPORTING REQUIREMENTS AT THE LOCAL, REGIONAL, OR STATE LEVEL
PERTAINING TO RELEASES OF THIS MATERIAL.
EPA STATEMENT:
THIS CHEMICAL IS A PESTICIDE PRODUCT REGISTERED BY THE ENVIRONMENTAL
PROTECTION AGENCY AND IS SUBJECT TO CERTAIN LABELING REQUIREMENTS UNDER
FEDERAL PESTICIDE LAW. THESE REQUIREMENTS DIFFER FROM THE CLASSIFICATION
CRITERIA AND HAZARD INFORMATION REQUIRED FOR SAFETY DATA SHEETS AND FOR
WORKPLACE LABELS OF NON-PESTICIDE CHEMICALS. FOLLOWING IS THE HAZARD
INFORMATION AS REQUIRED ON THE PESTICIDE LABEL:
WARNING:
CAUSES SUBSTANTIAL BUT TEMPORARY EYE INJURY. HARMFUL IF ABSORBED THROUGH
SKIN. AVOID BREATHING SPRAY MIST. DO NOT GET IN EYES, ON SKIN OR ON
CLOTHING. WEAR SAFETY GLASSES OR GOGGLES. WASH THOROUGHLY WITH SOAP AND
WATER AFTER HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
U.S. STATE REGULATIONS:
CALIFORNIA PROPOSITION 65:
THIS PRODUCT DOES NOT CONTAIN ANY PROPOSITION 65 CHEMICALS.
U.S. STATE RIGHT-TO-KNOW REGULATIONS:
CHEMICAL NAME NEW MASSACHUSETTS PENNSYLVANIA RHODE ILLINOIS
JERSEY ISLAND
DIETHYLENE GLYCOL X X
MONOBUTYL ETHER
(GLYCOL ETHERS
CATEGORY)
112-34-5
INTERNATIONAL REGULATIONS:
CANADA:
WHMIS HAZARD CLASS:
D2B: TOXIC MATERIALS
| 16. OTHER INFORMATION | |
NFPA:
HEALTH HAZARD 2
FLAMMABILITY 0
INSTABILITY 0
PHYSICAL AND CHEMICAL HAZARDS
HMIS:
HEALTH HAZARD 2
FLAMMABILITY 0
PHYSICAL HAZARD 0
PERSONAL PROTECTION B
PREPARED BY:
PRODUCT STEWARDSHIP
23 BRITISH AMERICAN BLVD.
LATHAM, NY 12110
1-800-572-6501
REVISION DATE: NEW
REVISION NOTE: NEW
REFERENCE: 1067476-B/51589001.003/1103604
GENERAL DISCLAIMER:
THE INFORMATION PROVIDED IN THIS SAFETY DATA SHEET IS CORRECT TO THE BEST
OF OUR KNOWLEDGE, INFORMATION AND BELIEF AT THE DATE OF ITS PUBLICATION.
THE INFORMATION GIVEN IS DESIGNED ONLY AS A GUIDANCE FOR SAFE HANDLING,
USE, PROCESSING, STORAGE, TRANSPORTATION, DISPOSAL AND RELEASE AND IS NOT
TO BE CONSIDERED A WARRANTY OR QUALITY SPECIFICATION. THE INFORMATION
RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED AND MAY NOT BE VALID FOR
SUCH MATERIAL USED IN COMBINATION WITH ANY OTHER MATERIALS OR IN ANY
PROCESS, UNLESS SPECIFIED IN THE TEXT.