| Common Name: | COMBICOULOMAT FRITLESS KARL FISCHER REAGENT FOR COULOMETRIC WATER DETERM, 109257 |
| Manufacturer: | EMD MILLIPORE |
| SDS Revision Date: | 4/23/2014 |
| SDS Format: | No Format Specified |
| Item Number(s): | 20KM94 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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M
SAFETY DATA SHEET
ACCORDING TO THE (US) HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200)
REVISION DATE: 04/23/2014
VERSION: 1.3
| SECTION 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NUMBER: 109257
PRODUCT NAME:
COMBICOULOMAT FRITLESS KARL FISCHER REAGENT FOR COULOMETRIC WATER
DETERMINATION FOR CELLS WITH AND WITHOUT DIAPHRAGM APURA(R*)
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES:
USE RESTRICTED UNDER TSCA TO RESEARCH AND DEVELOPMENT OR AS ANALYTICAL
REAGENT. USES REGULATED UNDER FDA OR FIFRA ARE NOT AFFECTED.
REAGENT FOR ANALYSIS
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
EMD MILLIPORE CORPORATION
290 CONCORD ROAD
BILLERICA, MA 01821
UNITED STATES OF AMERICA
GENERAL INQUIRIES: +1-978-715-4321
MONDAY TO FRIDAY, 9:00 AM TO 4:00 PM EASTERN TIME (GMT-5)
EMERGENCY TELEPHONE:
800-424-9300 CHEMTREC (USA)
+1-703-527-3887 CHEMTREC (INTERNATIONAL) 24 HOURS/DAY; 7 DAYS/WEEK
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
FLAMMABLE LIQUID, CATEGORY 2, H225
ACUTE TOXICITY, CATEGORY 3, ORAL, H301
ACUTE TOXICITY, CATEGORY 3, INHALATION, H331
ACUTE TOXICITY, CATEGORY 3, DERMAL, H311
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - SINGLE EXPOSURE, CATEGORY 1,
EYES, H370
CHRONIC AQUATIC TOXICITY, CATEGORY 3, H412
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
GHS-LABELING:
HAZARD PICTOGRAMS:
FLAME
SKULLS AND CROSSBONES
HEALTH HAZARD
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H301 + H311 + H331: TOXIC IF SWALLOWED, IN CONTACT WITH SKIN OR IF INHALED.
H370: CAUSES DAMAGE TO ORGANS (EYES).
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
PRECAUTIONARY STATEMENTS:
P210: KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES/HOT SURFACES. - NO SMOKING.
P233: KEEP CONTAINER TIGHTLY CLOSED.
P240: GROUND/BOND CONTAINER AND RECEIVING EQUIPMENT.
P273: AVOID RELEASE TO THE ENVIRONMENT.
P280: WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING.
P302 + P352 - IF ON SKIN: WASH WITH PLENTY OF SOAP AND WATER.
P304 + P340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P308 + P310:
IF EXPOSED OR CONCERNED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
P403 + P235: STORE IN A WELL-VENTILATED PLACE. KEEP COOL.
OSHA HAZARDS:
THIS MATERIAL IS CONSIDERED HAZARDOUS BY THE OSHA HAZARD COMMUNICATION
STANDARD (29 CFR 1910.1200). THIS INFORMATION IS BASED ON 29 CFR 1910.1200
CRITERIA PRIOR TO ADOPTION OF THE GHS AND MAY DEVIATE FROM THE GHS
INFORMATION.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NATURE: MIXTURE OF INORGANIC AND ORGANIC COMPOUNDS
HAZARDOUS INGREDIENTS:
CHEMICAL NAME (CONCENTRATION) CAS-NO.
METHANOL (>/=70% - <90%) 67-56-1
EXACT PERCENTAGES ARE BEING WITHHELD AS A TRADE SECRET.
BROMOFORM (>/=1% - <5%) 75-25-2
EXACT PERCENTAGES ARE BEING WITHHELD AS A TRADE SECRET.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST-AID MEASURES:
GENERAL ADVICE: FIRST AIDER NEEDS TO PROTECT HIMSELF.
INHALATION:
AFTER INHALATION: FRESH AIR.
IF BREATHING STOPS:
IMMEDIATELY APPLY ARTIFICIAL RESPIRATION, IF NECESSARY OXYGEN. IMMEDIATELY
CALL IN PHYSICIAN. FRESH AIR.
SKIN CONTACT:
AFTER SKIN CONTACT:
WASH OFF WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING. CALL A
PHYSICIAN IMMEDIATELY.
EYE CONTACT:
AFTER EYE CONTACT:
RINSE OUT WITH PLENTY OF WATER WITH THE EYELID HELD WIDE OPEN. CALL IN
OPHTHALMOLOGIST IF NECESSARY.
INGESTION:
AFTER SWALLOWING:
FRESH AIR. MAKE VICTIM DRINK ETHANOL (E.G. 1 DRINKING GLASS OF A 40%
ALCOHOLIC BEVERAGE). CALL A DOCTOR IMMEDIATELY (MENTION METHANOL
INGESTION). ONLY IN EXCEPTIONAL CASES, IF NO MEDICAL CARE IS AVAILABLE
WITHIN ONE HOUR, INDUCE VOMITING (ONLY IN FULLY CONSCIOUS PERSONS) AND MAKE
VICTIM DRINK ETHANOL AGAIN (APPROX. 0.3 ML OF A 40% ALCOHOLIC BEVERAGE/KG
BODY WEIGHT/HOUR).
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
IRRITANT EFFECTS, DIZZINESS, NARCOSIS, AGITATION, SPASMS, INEBRIATION,
NAUSEA, VOMITING, HEADACHE, BLINDNESS, IMPAIRMENT OF VISION, COMA
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NO INFORMATION AVAILABLE.
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA: CARBON DIOXIDE (CO2), FOAM, DRY POWDER
UNSUITABLE EXTINGUISHING MEDIA:
FOR THIS SUBSTANCE/MIXTURE NO LIMITATIONS OF EXTINGUISHING AGENTS ARE
GIVEN.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
COMBUSTIBLE MATERIAL, VAPORS ARE HEAVIER THAN AIR AND MAY SPREAD ALONG
FLOORS.
FORMS EXPLOSIVE MIXTURES WITH AIR AT AMBIENT TEMPERATURES.
PAY ATTENTION TO FLASHBACK.
DEVELOPMENT OF HAZARDOUS COMBUSTION GASES OR VAPORS POSSIBLE IN THE EVENT
OF FIRE.
FIRE MAY CAUSE EVOLUTION OF: HYDROGEN BROMIDE
ADVICE FOR FIREFIGHTERS:
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
STAY IN DANGER AREA ONLY WITH SELF-CONTAINED BREATHING APPARATUS. PREVENT
SKIN CONTACT BY KEEPING A SAFE DISTANCE OR BY WEARING SUITABLE PROTECTIVE
CLOTHING.
FURTHER INFORMATION:
COOL CLOSED CONTAINERS EXPOSED TO FIRE WITH WATER SPRAY. SUPPRESS (KNOCK
DOWN)
GASES/VAPORS/MISTS WITH A WATER SPRAY JET. PREVENT FIRE EXTINGUISHING WATER
FROM CONTAMINATING SURFACE WATER OR THE GROUND WATER SYSTEM.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ADVICE FOR NON-EMERGENCY PERSONNEL:
AVOID SUBSTANCE CONTACT. DO NOT BREATHE VAPORS, AEROSOLS. ENSURE ADEQUATE
VENTILATION. EVACUATE THE DANGER AREA, OBSERVE EMERGENCY PROCEDURES,
CONSULT AN EXPERT.
ADVICE FOR EMERGENCY RESPONDERS: PROTECTIVE EQUIPMENT SEE SECTION 8.
ENVIRONMENTAL PRECAUTIONS: DO NOT EMPTY INTO DRAINS. RISK OF EXPLOSION.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
COVER DRAINS. COLLECT, BIND, AND PUMP OFF SPILLS.
OBSERVE POSSIBLE MATERIAL RESTRICTIONS (SEE SECTIONS 7 AND 10).
TAKE UP WITH LIQUID-ABSORBENT MATERIAL (E.G. CHEMIZORB(R*)). DISPOSE OF
PROPERLY. CLEAN UP AFFECTED AREA.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
WORK UNDER HOOD. DO NOT INHALE SUBSTANCE/MIXTURE. AVOID GENERATION OF
VAPORS/AEROSOLS.
OBSERVE LABEL PRECAUTIONS.
ADVICE ON PROTECTION AGAINST FIRE AND EXPLOSION:
KEEP AWAY FROM OPEN FLAMES, HOT SURFACES AND SOURCES OF IGNITION. TAKE
PRECAUTIONARY MEASURES AGAINST STATIC DISCHARGE.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
KEEP CONTAINER TIGHTLY CLOSED IN A DRY AND WELL-VENTILATED PLACE. KEEP AWAY
FROM HEAT AND SOURCES OF IGNITION. KEEP LOCKED UP OR IN AN AREA ACCESSIBLE
ONLY TO QUALIFIED OR AUTHORIZED PERSONS.
STORE AT +15 DEG. C TO +25 DEG. C (+59 DEG. F TO +77 DEG. F).
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE LIMIT(S):
INGREDIENTS
BASIS VALUE THRESHOLD LIMITS REMARKS
METHANOL 67-56-1:
ACGIH TIME WEIGHTED 200 PPM
AVERAGE (TWA)
SHORT TERM EXPOSURE 250 PPM
LIMIT (STEL)
SKIN DESIGNATION CAN BE ABSORBED
THROUGH THE SKIN.
NIOSH/GUIDE RECOMMENDED 200 PPM
EXPOSURE LIMIT (REL) 260 MG/M3
SKIN DESIGNATION CAN BE ABSORBED
THROUGH THE SKIN.
SHORT TERM EXPOSURE 250 PPM
LIMIT (STEL) 325 MG/M3
OSHA_TRANS PEL 200 PPM
260 MG/M3
Z1A TIME WEIGHTED 200 PPM
AVERAGE (TWA) 260 MG/M3
SKIN DESIGNATION CAN BE ABSORBED
(FINAL RULE LIMIT THROUGH THE SKIN.
APPLIES)
SHORT TERM EXPOSURE 250 PPM
LIMIT (STEL) 325 MG/M3
BROMOFORM 75-25-2:
ACGIH TIME WEIGHTED AVERAGE 0.5 PPM
(TWA)
NIOSH/GUIDE RECOMMENDED EXPOSURE 0.5 PPM
LIMIT (REL) 5 MG/M3
SKIN DESIGNATION CAN BE ABSORBED
THROUGH THE SKIN.
OSHA_TRANS PEL 0.5 PPM
5 MG/M3
SKIN DESIGNATION CAN BE ABSORBED
THROUGH THE SKIN.
Z1A TIME WEIGHTED 0.5 PPM
AVERAGE (TWA) 5 MG/M3
SKIN DESIGNATION CAN BE ABSORBED
(FINAL RULE LIMIT THROUGH THE SKIN.
APPLIES)
ENGINEERING MEASURES:
TECHNICAL MEASURES AND APPROPRIATE WORKING OPERATIONS SHOULD BE GIVEN
PRIORITY OVER THE USE OF PERSONAL PROTECTIVE EQUIPMENT.
INDIVIDUAL PROTECTION MEASURES:
PROTECTIVE CLOTHING SHOULD BE SELECTED SPECIFICALLY FOR THE WORKPLACE,
DEPENDING ON CONCENTRATION AND QUANTITY OF THE HAZARDOUS SUBSTANCES
HANDLED. THE CHEMICAL RESISTANCE OF THE PROTECTIVE EQUIPMENT SHOULD BE
INQUIRED AT THE RESPECTIVE SUPPLIER.
HYGIENE MEASURES:
IMMEDIATELY CHANGE CONTAMINATED CLOTHING. APPLY SKIN- PROTECTIVE BARRIER
CREAM. WASH HANDS AND FACE AFTER WORKING WITH SUBSTANCE.
EYE/FACE PROTECTION: SAFETY GLASSES
HAND PROTECTION:
CHEMICAL-RESISTANT, IMPERVIOUS GLOVES COMPLYING WITH AN APPROVED STANDARD
SHOULD BE WORN AT ALL TIMES WHEN HANDLING CHEMICAL PRODUCTS IF A RISK
ASSESSMENT INDICATES THIS IS NECESSARY.
OTHER PROTECTIVE EQUIPMENT: FLAME RETARDANT ANTISTATIC PROTECTIVE CLOTHING
RESPIRATORY PROTECTION:
REQUIRED WHEN VAPORS/AEROSOLS ARE GENERATED.
USE A PROPERLY FITTED, AIR-PURIFYING OR AIR-FED RESPIRATOR COMPLYING WITH
AN APPROVED STANDARD IF A RISK ASSESSMENT INDICATES THIS IS NECESSARY.
RESPIRATOR SELECTION MUST BE BASED ON KNOWN OR ANTICIPATED EXPOSURE LEVELS,
THE HAZARDS OF THE PRODUCT AND THE SAFE WORKING LIMITS OF THE SELECTED
RESPIRATOR.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: YELLOW
ODOR: OF METHANOL
ODOR THRESHOLD: NO INFORMATION AVAILABLE.
PH: CA. 5.5 AT 68 DEG. F (20 DEG. C)
MELTING POINT: NO INFORMATION AVAILABLE.
BOILING POINT: NO INFORMATION AVAILABLE.
FLASH POINT: CA. 54 DEG. F (12 DEG. C)
EVAPORATION RATE: NO INFORMATION AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT APPLICABLE
LOWER EXPLOSION LIMIT: NO INFORMATION AVAILABLE.
UPPER EXPLOSION LIMIT: NO INFORMATION AVAILABLE.
VAPOR PRESSURE: NO INFORMATION AVAILABLE.
RELATIVE VAPOR DENSITY: NO INFORMATION AVAILABLE.
DENSITY: CA. 0.92 G/CM3 AT 68 DEG. F (20 DEG. C)
RELATIVE DENSITY: NO INFORMATION AVAILABLE.
WATER SOLUBILITY: AT 68 DEG. F (20 DEG. C) PARTLY SOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO INFORMATION AVAILABLE.
AUTOIGNITION TEMPERATURE: NO INFORMATION AVAILABLE.
DECOMPOSITION TEMPERATURE: NO INFORMATION AVAILABLE.
VISCOSITY, DYNAMIC: NO INFORMATION AVAILABLE.
EXPLOSIVE PROPERTIES: NOT CLASSIFIED AS EXPLOSIVE.
OXIDIZING PROPERTIES: NONE
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: VAPORS MAY FORM EXPLOSIVE MIXTURE WITH AIR.
CHEMICAL STABILITY:
THE PRODUCT IS CHEMICALLY STABLE UNDER STANDARD AMBIENT CONDITIONS (ROOM
TEMPERATURE) .
POSSIBILITY OF HAZARDOUS REACTIONS:
RISK OF EXPLOSION WITH:
OXIDIZING AGENTS, PERCHLORIC ACID, PERCHLORATES, SALTS OF OXYHALOGENIC
ACIDS, CHROMIUM(VI) OXIDE, HALOGEN OXIDES, NITROGEN OXIDES, NONMETALLIC
OXIDES, CHROMOSULFURIC ACID, CHLORATES, HYDRIDES, ZINC DIETHYL, HALOGENS,
MAGNESIUM, HYDROGEN PEROXIDE, NITRIC ACID
EXOTHERMIC REACTION WITH:
ACID HALIDES, ACID ANHYDRIDES, REDUCING AGENTS, ACIDS
GENERATES DANGEROUS GASES OR FUMES IN CONTACT WITH:
ALKALINE EARTH METALS, ALKALI METALS
CONDITIONS TO AVOID:
WARMING.
A RANGE FROM APPROX. 15 KELVIN BELOW THE FLASH POINT IS TO BE RATED AS
CRITICAL.
INCOMPATIBLE MATERIALS:
VARIOUS PLASTICS, VARIOUS ALLOYS, ZINC ALLOYS, MAGNESIUM
HAZARDOUS DECOMPOSITION PRODUCTS:
IN THE EVENT OF FIRE: SEE SECTION 5.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTE OF EXPOSURE: EYE CONTACT, SKIN CONTACT
TARGET ORGANS:
EYES
SKIN
RESPIRATORY SYSTEM
CENTRAL NERVOUS SYSTEM
GASTROINTESTINAL TRACT
LIVER
KIDNEYS
ACUTE ORAL TOXICITY
ABSORPTION
ACUTE TOXICITY ESTIMATE: 135.2 MG/KG
CALCULATION METHOD
ACUTE INHALATION TOXICITY:
ABSORPTION
SYMPTOMS: MUCOSAL IRRITATIONS
ACUTE TOXICITY ESTIMATE: 3.92 MG/L; 4 H
CALCULATION METHOD
ACUTE DERMAL TOXICITY
ABSORPTION
ACUTE TOXICITY ESTIMATE: 407.33 MG/KG CALCULATION METHOD
EYE IRRITATION: SLIGHT IRRITATION MUCOSAL IRRITATIONS
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - SINGLE EXPOSURE:
MIXTURE CAUSES DAMAGE TO ORGANS.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - REPEATED EXPOSURE:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS SPECIFIC TARGET ORGAN
TOXICANT, REPEATED EXPOSURE.
ASPIRATION HAZARD:
REGARDING THE AVAILABLE DATA THE CLASSIFICATION CRITERIA ARE NOT FULFILLED.
CARCINOGENICITY:
IARC:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY OSHA.
NTP:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
ACGIH: CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS.
BROMOFORM 75-25-2
FURTHER INFORMATION:
SYSTEMIC EFFECTS:
ACIDOSIS, DROP IN BLOOD PRESSURE, AGITATION, SPASMS, INEBRIATION,
DIZZINESS, DROWSINESS, HEADACHE, IMPAIRMENT OF VISION, BLINDNESS,
IRREVERSIBLE DAMAGE OF THE OPTICAL NERVE. NARCOSIS, COMA
SYMPTOMS MAY BE DELAYED.
DAMAGE TO: LIVER, KIDNEY, CARDIAC
FURTHER DATA:
OTHER DANGEROUS PROPERTIES CAN NOT BE EXCLUDED.
HANDLE IN ACCORDANCE WITH GOOD INDUSTRIAL HYGIENE AND SAFETY PRACTICE.
INGREDIENTS:
METHANOL:
ACUTE ORAL TOXICITY:
LDLO HUMAN: 143 MG/KG (RTECS)
LD50 RAT: 5,628 MG/KG (IUCLID)
ACUTE INHALATION TOXICITY:
LC50 RAT: 85.26 MG/L; 4 H (IUCLID)
ACUTE DERMAL TOXICITY:
LD50 RABBIT: CA. 17,100 MG/KG (EXTERNAL MSDS)
SENSITIZATION:
SENSITIZATION TEST: GUINEA PIG
RESULT: NEGATIVE
(IUCLID)
GERM CELL MUTAGENICITY:
GENOTOXICITY IN VIVO:
MUTAGENICITY (MAMMAL CELL TEST): MICRONUCLEUS.
RESULT: NEGATIVE
(IUCLID)
GENOTOXICITY IN VITRO:
AMES TEST
RESULT: NEGATIVE
(IUCLID)
BROMOFORM:
ACUTE ORAL TOXICITY:
LD50 RAT: 933 MG/KG (RTECS)
LDLO HUMAN: 143 MG/KG (LIT.)
ACUTE INHALATION TOXICITY:
LC50 RAT:
31.7 MG/L; 2 H (EXTERNAL MSDS) (REGULATION (EC) NO 1272/2008, ANNEX VI)
SKIN IRRITATION:
RABBIT
RESULT: IRRITATIONS
(EXTERNAL MSDS)
EYE IRRITATION:
RABBIT
RESULT: EYE IRRITATION
(EXTERNAL MSDS)
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: NO INFORMATION AVAILABLE.
PERSISTENCE AND DEGRADABILITY: NO INFORMATION AVAILABLE.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
INGREDIENTS:
METHANOL:
TOXICITY TO FISH:
LC50 LEPOMIS MACROCHIRUS (BLUEGILL SUNFISH):
15,400 MG/L; 96 H (IN SOFT WATER) (ECOTOX DATABASE)
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC5 E.SULCATUM: >10,000 MG/L; 72 H (LIT.)
EC50 DAPHNIA MAGNA (WATER FLEA): >10,000 MG/L; 48 H (IUCLID)
TOXICITY TO ALGAE:
EC50 PSEUDOKIRCHNERIELLA SUBCAPITATA (GREEN ALGAE):
CA. 22,000 MG/L; 96 H (EXTERNAL MSDS)
IC5 SCENEDESMUS QUADRICAUDA (GREEN ALGAE): 8,000 MG/L; 8 D (IUCLID)
TOXICITY TO BACTERIA:
EC5 PSEUDOMONAS FLUORESCENS: 6,600 MG/L; 16 H (IUCLID)
TOXICITY TO FISH (CHRONIC TOXICITY):
NOEC ORYZIAS LATIPES (ORANGE-RED KILLIFISH):
7,900 MG/L; 200 H (EXTERNAL MSDS)
BIODEGRADABILITY:
99%; 30 D
OECD TEST GUIDELINE 301D
READILY BIODEGRADABLE.
BIOCHEMICAL OXYGEN DEMAND (BOD): 600 - 1,120 MG/G (5 D) (IUCLID)
CHEMICAL OXYGEN DEMAND (COD): 1,420 MG/G (IUCLID)
THEORETICAL OXYGEN DEMAND (THOD): 1,500 MG/G (LIT.)
RATIO BOD/THBOD:
BOD5: 76%
CLOSED BOTTLE TEST
SUBSTANCE DOES NOT MEETS THE CRITERIA FOR PBT OR VPVB ACCORDING TO
REGULATION (EC) NO 1907/2006, ANNEX XIII.
STABILITY IN WATER:
2.2 YR
REACTION WITH HYDROXYL RADICALS (IUCLID)
BROMOFORM:
TOXICITY TO FISH:
LC50 LEPOMIS MACROCHIRUS (BLUEGILL SUNFISH): 29 MG/L; 96 H (LIT.)
TOXICITY TO DAPHNIA AND OTHER AQUATIC INVERTEBRATES:
EC50 DAPHNIA MAGNA (WATER FLEA): 46 MG/L; 48 H (LIT.)
DISTRIBUTION AMONG ENVIRONMENTAL COMPARTMENTS:
ADSORPTION/SOIL
LOG KOC: 2.10
(EXPERIMENTAL)
MODERATELY MOBILE IN SOILS
| SECTION 13. DISPOSAL CONSIDERATIONS | |
THE INFORMATION PRESENTED ONLY APPLIES TO THE MATERIAL AS SUPPLIED. THE
IDENTIFICATION BASED ON CHARACTERISTIC(S) OR LISTING MAY NOT APPLY IF THE
MATERIAL HAS BEEN USED OR OTHERWISE CONTAMINATED. IT IS THE RESPONSIBILITY
OF THE WASTE GENERATOR TO DETERMINE THE TOXICITY AND PHYSICAL PROPERTIES OF
THE MATERIAL GENERATED TO DETERMINE THE PROPER WASTE IDENTIFICATION AND
DISPOSAL METHODS IN COMPLIANCE WITH APPLICABLE REGULATIONS. DISPOSAL SHOULD
BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND LOCAL LAWS AND
REGULATIONS.
| SECTION 14. TRANSPORT INFORMATION | |
LAND TRANSPORT (DOT):
UN NUMBER: UN 1230
PROPER SHIPPING NAME: METHANOL SOLUTION
CLASS: 3
PACKING GROUP: II
ENVIRONMENTALLY HAZARDOUS:
AIR TRANSPORT (IATA):
UN NUMBER: UN 1230
PROPER SHIPPING NAME: METHANOL SOLUTION
CLASS: 3 (6.1)
PACKING GROUP: II
ENVIRONMENTALLY HAZARDOUS:
SPECIAL PRECAUTIONS FOR USER: NO
SEA TRANSPORT (IMDG):
UN NUMBER: UN 1230
PROPER SHIPPING NAME: METHANOL SOLUTION
CLASS: 3 (6.1)
PACKING GROUP: II
ENVIRONMENTALLY HAZARDOUS:
SPECIAL PRECAUTIONS FOR USER: YES
EMS: F-E S-D
| SECTION 15. REGULATORY INFORMATION | |
UNITED STATES OF AMERICA:
OSHA HAZARDS:
FLAMMABLE LIQUID
TARGET ORGAN EFFECTS
TOXIC BY INHALATION.
TOXIC BY INGESTION
TOXIC BY SKIN ABSORPTION
SKIN IRRITANT
EYE IRRITANT
THIS INFORMATION IS BASED ON 29 CFR 1910.1200 CRITERIA PRIOR TO ADOPTION OF
THE GHS, AND MAY DEVIATE FROM THE GHS INFORMATION ON THE LABEL AND IN
SECTION 2.
SARA 311/312 HAZARDS:
FIRE HAZARD
ACUTE HEALTH HAZARD
CHRONIC HEALTH HAZARD
SARA 313:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 313:
INGREDIENTS:
BROMOFORM 75-25-2 2.95%
METHANOL 67-56-1 73.65%
SARA 302:
SARA 302:
NO CHEMICALS IN THIS MATERIAL ARE SUBJECT TO THE REPORTING REQUIREMENTS OF
SARA TITLE III, SECTION 302.
CLEAN WATER ACT:
THIS PRODUCT DOES NOT CONTAIN ANY HAZARDOUS SUBSTANCES LISTED UNDER THE
U.S. CLEANWATER ACT, SECTION 311, TABLE 116.4A.
THIS PRODUCT DOES NOT CONTAIN ANY HAZARDOUS CHEMICALS LISTED UNDER THE U.S.
CLEANWATER ACT, SECTION 311, TABLE 117.3.
DEA LIST I: LISTED
INGREDIENTS:
IODINE 7553-56-2
DEA LIST II: NOT LISTED
US STATE REGULATIONS:
MASSACHUSETTS RIGHT TO KNOW:
INGREDIENTS:
METHANOL
BROMOFORM
PENNSYLVANIA RIGHT TO KNOW:
INGREDIENTS:
METHANOL
BROMOFORM
NEW JERSEY RIGHT TO KNOW:
INGREDIENTS:
METHANOL
BROMOFORM
GUANIDINIUM IODIDE
CALIFORNIA PROP 65 COMPONENTS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
INGREDIENTS: METHANOL
CALIFORNIA PROP 65 COMPONENTS:
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL KNOWN IN THE STATE OF CALIFORNIA TO CAUSE
CANCER.
INGREDIENTS: BROMOFORM
NOTIFICATION STATUS:
TSCA:
NOT LISTED ON TSCA INVENTORY. FOR RESEARCH AND DEVELOPMENT USE ONLY. NOT
FOR MANUFACTURING OR COMMERCIAL PURPOSES.
DSL:
THIS PRODUCT CONTAINS ONE OR SEVERAL COMPONENTS THAT ARE NOT ON THE
CANADIAN DSL NOR NDSL.
| SECTION 16. OTHER INFORMATION | |
TRAINING ADVICE:
PROVIDE ADEQUATE INFORMATION, INSTRUCTION AND TRAINING FOR OPERATORS.
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.
H225: HIGHLY FLAMMABLE LIQUID AND VAPOR.
H301: TOXIC IF SWALLOWED.
H311: TOXIC IN CONTACT WITH SKIN.
H331: TOXIC IF INHALED.
H370: CAUSES DAMAGE TO ORGANS.
H412: HARMFUL TO AQUATIC LIFE WITH LONG LASTING EFFECTS.
KEY OR LEGEND TO ABBREVIATIONS AND ACRONYMS USED IN THE SAFETY DATA SHEET
USED ABBREVIATIONS AND ACRONYMS CAN BE LOOKED UP AT WWW.WIKIPEDIA.ORG.
REVISION DATE: 04/23/2014
THE INFORMATION CONTAINED HEREIN IS BASED ON THE PRESENT STATE OF OUR
KNOWLEDGE. IT CHARACTERIZES THE PRODUCT WITH REGARD TO APPROPRIATE SAFETY
PRECAUTIONS. IT DOES NOT REPRESENT A WARRANTY OF ANY PRODUCT PROPERTIES AND
WE ASSUME NO LIABILITY FOR ANY LOSS OR INJURY WHICH MAY RESULT FROM THE USE
OF THIS INFORMATION. USERS SHOULD CONDUCT THEIR OWN INVESTIGATIONS TO
DETERMINE THE SUITABILITY OF THE INFORMATION.
ALL RIGHTS RESERVED. MILLIPORE AND THE "M" MARK ARE REGISTERED TRADEMARKS
OF MERCK KGAA, DARMSTADT, GERMANY.