| Common Name: | NITRIC ACID 67 - 70% OMNITRACE, NX0407 |
| Manufacturer: | EMD MILLIPORE |
| SDS Revision Date: | 2/20/2020 |
| SDS Format: | GHS-US |
| Item Number(s): | 20KN27, 20KN28 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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SUPELCO(R*)
WWW.SIGMAALDRICH.COM
SAFETY DATA SHEET
ACCORDING TO THE (US) HAZARD COMMUNICATION STANDARD (29 CFR 1910.1200)
REVISION DATE: 02/20/2020
VERSION: 3.0
| SECTION 1. IDENTIFICATION |  |
PRODUCT IDENTIFIER:
PRODUCT NUMBER: NX0407
PRODUCT NAME: NITRIC ACID 67 - 70% OMNITRACE(R*)
RELEVANT IDENTIFIED USES OF THE SUBSTANCE OR MIXTURE AND USES ADVISED
AGAINST:
IDENTIFIED USES: REAGENT FOR ANALYSIS
DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET:
COMPANY:
EMD MILLIPORE CORPORATION
400 SUMMIT DRIVE
BURLINGTON MASSACHUSETTS 01803
UNITED STATES OF AMERICA
GENERAL INQUIRIES:
+1 800-645-5476
MONDAY TO FRIDAY, 9:00 AM TO 4:00 PM EASTERN TIME (GMT-5)
MILLIPORE IS A BUSINESS OF MERCK KGAA, DARMSTADT, GERMANY.
EMERGENCY TELEPHONE:
800-424-9300 CHEMTREC (USA)
+1-703-527-3887 CHEMTREC (INTERNATIONAL)
24 HOURS/DAY; 7 DAYS/WEEK
| SECTION 2. HAZARDS IDENTIFICATION | |
GHS CLASSIFICATION:
OXIDIZING LIQUID, CATEGORY 3, H272
CORROSIVE TO METALS, CATEGORY 1, H290
ACUTE TOXICITY, CATEGORY 3, INHALATION, H331
SKIN CORROSION, CATEGORY 1A, H314
SERIOUS EYE DAMAGE, CATEGORY 1, H318
FOR THE FULL TEXT OF THE H-STATEMENTS MENTIONED IN THIS SECTION, SEE
SECTION 16.
GHS-LABELING:
HAZARD PICTOGRAMS:
FLAME OVER CIRCLE
SKULLS AND CROSSBONES
CORROSION
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H272: MAY INTENSIFY FIRE; OXIDIZER.
H290: MAY BE CORROSIVE TO METALS.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H331: TOXIC IF INHALED.
PRECAUTIONARY STATEMENTS:
P210: KEEP AWAY FROM HEAT.
P220: KEEP/STORE AWAY FROM CLOTHING/COMBUSTIBLE MATERIALS.
P221: TAKE ANY PRECAUTION TO AVOID MIXING WITH COMBUSTIBLES.
P234: KEEP ONLY IN ORIGINAL CONTAINER.
P261: AVOID BREATHING DUST/FUME/GAS/MIST/VAPORS/SPRAY.
P264: WASH SKIN THOROUGHLY AFTER HANDLING.
P271: USE ONLY OUTDOORS OR IN A WELL-VENTILATED AREA.
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
P301 + P330 + P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P303 + P361 + P353:
IF ON SKIN (OR HAIR):
TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING. RINSE SKIN WITH
WATER/SHOWER.
P304 + P340:
IF INHALED: REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P310: IMMEDIATELY CALL A POISON CENTER/DOCTOR.
P321:
SPECIFIC TREATMENT (SEE SUPPLEMENTAL FIRST AID INSTRUCTIONS ON THIS LABEL).
P363: WASH CONTAMINATED CLOTHING BEFORE REUSE.
P370 + P378:
IN CASE OF FIRE:
USE DRY SAND, DRY CHEMICAL OR ALCOHOL-RESISTANT FOAM TO EXTINGUISH.
P390: ABSORB SPILLAGE TO PREVENT MATERIAL DAMAGE.
P403 + P233:
STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY CLOSED.
P405: STORE LOCKED UP.
P406:
STORE IN CORROSIVE RESISTANT STAINLESS STEEL CONTAINER WITH A RESISTANT
INNER LINER.
P501: DISPOSE OF CONTENTS/CONTAINER TO AN APPROVED WASTE DISPOSAL PLANT.
OTHER HAZARDS: NONE KNOWN.
| SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
CHEMICAL NATURE: AQUEOUS SOLUTION
HAZARDOUS INGREDIENTS:
CHEMICAL NAME (CONCENTRATION) CAS-NO.
NITRIC ACID (>= 50% - <70%) 7697-37-2
EXACT PERCENTAGES ARE BEING WITHHELD AS A TRADE SECRET.
| SECTION 4. FIRST AID MEASURES | |
DESCRIPTION OF FIRST-AID MEASURES:
GENERAL ADVICE: FIRST AIDER NEEDS TO PROTECT HIMSELF.
INHALATION:
AFTER INHALATION: FRESH AIR. CALL IN PHYSICIAN.
| IF BREATHING STOPS:
| IMMEDIATELY APPLY ARTIFICIAL RESPIRATION, IF NECESSARY ALSO OXYGEN.
SKIN CONTACT:
IN CASE OF SKIN CONTACT: TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
RINSE SKIN WITH WATER/SHOWER. CALL A PHYSICIAN IMMEDIATELY.
EYE CONTACT:
AFTER EYE CONTACT: RINSE OUT WITH PLENTY OF WATER. IMMEDIATELY CALL IN
OPHTHALMOLOGIST. REMOVE CONTACT LENSES.
INGESTION:
AFTER SWALLOWING: MAKE VICTIM DRINK WATER (TWO GLASSES AT MOST), AVOID
VOMITING (RISK OF PERFORATION!). CALL A PHYSICIAN IMMEDIATELY. DO NOT
ATTEMPT TO NEUTRALIZE.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
MOST IMPORTANT SYMPTOMS AND EFFECTS, BOTH ACUTE AND DELAYED:
IRRITATION AND CORROSION, COUGH, SHORTNESS OF BREATH, BLOODY VOMITING,
DEATH, RISK OF BLINDNESS!
THE FOLLOWING APPLIES TO NITRITES/NITRATES IN GENERAL: METHEMOGLOBINEMIA
AFTER THE UPTAKE OF LARGE QUANTITIES.
INDICATION OF ANY IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
NO INFORMATION AVAILABLE.
| SECTION 5. FIRE-FIGHTING MEASURES | |
EXTINGUISHING MEDIA:
SUITABLE EXTINGUISHING MEDIA:
USE EXTINGUISHING MEASURES THAT ARE APPROPRIATE TO LOCAL CIRCUMSTANCES AND
THE SURROUNDING ENVIRONMENT.
UNSUITABLE EXTINGUISHING MEDIA:
FOR THIS SUBSTANCE/MIXTURE NO LIMITATIONS OF EXTINGUISHING AGENTS ARE
GIVEN.
SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE:
NOT COMBUSTIBLE.
HAS A FIRE-PROMOTING EFFECT DUE TO RELEASE OF OXYGEN.
AMBIENT FIRE MAY LIBERATE HAZARDOUS VAPORS.
FIRE MAY CAUSE EVOLUTION OF:
NITROUS GASES, NITROGEN OXIDES
ADVICE FOR FIREFIGHTERS:
SPECIAL PROTECTIVE EQUIPMENT FOR FIRE-FIGHTERS:
STAY IN DANGER AREA ONLY WITH SELF-CONTAINED BREATHING APPARATUS. PREVENT
SKIN CONTACT BY KEEPING A SAFE DISTANCE OR BY WEARING SUITABLE PROTECTIVE
CLOTHING.
FURTHER INFORMATION:
SUPPRESS (KNOCK DOWN) GASES/VAPORS/MISTS WITH A WATER SPRAY JET. COOL
CLOSED CONTAINERS EXPOSED TO FIRE WITH WATER SPRAY. PREVENT FIRE
EXTINGUISHING WATER FROM CONTAMINATING SURFACE WATER OR THE GROUND WATER
SYSTEM.
| SECTION 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
ADVICE FOR NON-EMERGENCY PERSONNEL: AVOID SUBSTANCE CONTACT. DO NOT BREATHE
VAPORS, AEROSOLS. ENSURE ADEQUATE VENTILATION. EVACUATE THE DANGER AREA,
OBSERVE EMERGENCY PROCEDURES, CONSULT AN EXPERT.
ADVICE FOR EMERGENCY RESPONDERS: PROTECTIVE EQUIPMENT SEE SECTION 8.
ENVIRONMENTAL PRECAUTIONS: DO NOT EMPTY INTO DRAINS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
COVER DRAINS. COLLECT, BIND, AND PUMP OFF SPILLS.
OBSERVE POSSIBLE MATERIAL RESTRICTIONS (SEE SECTIONS 7 AND 10).
TAKE UP WITH LIQUID-ABSORBENT AND NEUTRALIZING MATERIAL (E.G. CHEMIZORB(R*)
H+, ART. NO. 101595). DISPOSE OF PROPERLY. CLEAN UP AFFECTED AREA.
| SECTION 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING: OBSERVE LABEL PRECAUTIONS.
| WORK UNDER HOOD. DO NOT INHALE SUBSTANCE/MIXTURE. AVOID GENERATION OF
| VAPORS/AEROSOLS.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
REQUIREMENTS FOR STORAGE AREAS AND CONTAINERS:
NO METAL OR LIGHT-WEIGHT-METAL CONTAINERS.
| TIGHTLY CLOSED. DO NOT STORE NEAR COMBUSTIBLE MATERIALS. KEEP LOCKED UP
| OR IN AN AREA ACCESSIBLE ONLY TO QUALIFIED OR AUTHORIZED PERSONS.
STORE AT ROOM TEMPERATURE.
| SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
EXPOSURE LIMIT(S):
COMPONENTS:
BASIS VALUE THRESHOLD LIMITS REMARKS
NITRIC ACID 7697-37-2
ACGIH TIME WEIGHTED AVERAGE (TWA): 2 PPM
SHORT TERM EXPOSURE LIMIT (STEL): 4 PPM
NIOSH/GUIDE RECOMMENDED EXPOSURE LIMIT (REL): 2 PPM
5 MG/M3
SHORT TERM EXPOSURE LIMIT (STEL): 4 PPM
10 MG/M3
OSHA_TRANS PEL: 2 PPM
5 MG/M3
Z1A TIME WEIGHTED AVERAGE (TWA): 2 PPM
5 MG/M3
SHORT TERM EXPOSURE LIMIT (STEL): 4 PPM
10 MG/M3
ENGINEERING MEASURES:
TECHNICAL MEASURES AND APPROPRIATE WORKING OPERATIONS SHOULD BE GIVEN
PRIORITY OVER THE USE OF PERSONAL PROTECTIVE EQUIPMENT.
INDIVIDUAL PROTECTION MEASURES:
PROTECTIVE CLOTHING SHOULD BE SELECTED SPECIFICALLY FOR THE WORKPLACE,
DEPENDING ON CONCENTRATION AND QUANTITY OF THE HAZARDOUS SUBSTANCES
HANDLED. THE CHEMICAL RESISTANCE OF THE PROTECTIVE EQUIPMENT SHOULD BE
INQUIRED AT THE RESPECTIVE SUPPLIER.
HYGIENE MEASURES:
IMMEDIATELY CHANGE CONTAMINATED CLOTHING. APPLY SKIN- PROTECTIVE BARRIER
CREAM. WASH HANDS AND FACE AFTER WORKING WITH SUBSTANCE.
EYE/FACE PROTECTION: TIGHTLY FITTING SAFETY GOGGLES
HAND PROTECTION:
FULL CONTACT:
GLOVE MATERIAL: VITON (R)
GLOVE THICKNESS: 0.7 MM
BREAK THROUGH TIME: >480 MIN
SPLASH CONTACT:
GLOVE MATERIAL: NATURAL LATEX
GLOVE THICKNESS: 0.6 MM
BREAK THROUGH TIME: >120 MIN
THE PROTECTIVE GLOVES TO BE USED MUST COMPLY WITH THE SPECIFICATIONS OF EC
DIRECTIVE 89/686/EEC AND THE RELATED STANDARD EN374, FOR EXAMPLE KCL 890
VITOJECT(R*) (FULL CONTACT), KCL 706 LAPREN(R*) (SPLASH CONTACT).
THE BREAKTHROUGH TIMES STATED ABOVE WERE DETERMINED BY KCL IN LABORATORY
TESTS ACC. TO EN374 WITH SAMPLES OF THE RECOMMENDED GLOVE TYPES.
THIS RECOMMENDATION APPLIES ONLY TO THE PRODUCT STATED IN THE SAFETY DATA
SHEET AND SUPPLIED BY US AS WELL AS TO THE PURPOSE SPECIFIED BY US. WHEN
DISSOLVING IN OR MIXING WITH OTHER SUBSTANCES AND UNDER CONDITIONS
DEVIATING FROM THOSE STATED IN EN374 PLEASE CONTACT THE SUPPLIER OF
CE-APPROVED GLOVES (E.G. KCL GMBH, D-36124 EICHENZELL, INTERNET:
WWW.KCL.DE).
OTHER PROTECTIVE EQUIPMENT: ACID-RESISTANT PROTECTIVE CLOTHING.
RESPIRATORY PROTECTION:
| REQUIRED WHEN VAPORS/AEROSOLS ARE GENERATED.
| RECOMMENDED FILTER TYPE: FILTER E-(P3)
| THE ENTREPENEUR HAS TO ENSURE THAT MAINTENANCE, CLEANING AND TESTING OF
| RESPIRATORY PROTECTIVE DEVICES ARE PERFORMED ACCORDING TO THE
| INSTRUCTIONS OF THE PRODUCER. THESE MEASURES HAVE TO BE PROPERLY
| DOCUMENTED.
| SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES | |
PHYSICAL STATE: LIQUID
COLOR: COLORLESS
ODOR: STINGING
ODOR THRESHOLD: 0.27 PPM (ANHYDROUS SUBSTANCE)
PH: <1 AT 68 DEG. F (20 DEG. C)
MELTING POINT: CA. -26 DEG. F (-32 DEG. C)
BOILING POINT/BOILING RANGE: 250 DEG. F (121 DEG. C) AT 1,013 HPA
FLASH POINT: NOT APPLICABLE
EVAPORATION RATE: NO INFORMATION AVAILABLE.
FLAMMABILITY (SOLID, GAS): NO INFORMATION AVAILABLE.
LOWER EXPLOSION LIMIT: NO INFORMATION AVAILABLE.
UPPER EXPLOSION LIMIT: NO INFORMATION AVAILABLE.
VAPOR PRESSURE: CA.9.4 HPA AT 68 DEG. F (20 DEG. C)
RELATIVE VAPOR DENSITY: NO INFORMATION AVAILABLE.
DENSITY: 1.39 G/CM3 AT 68 DEG. F (20 DEG. C)
RELATIVE DENSITY: NO INFORMATION AVAILABLE.
WATER SOLUBILITY: AT 68 DEG. F (20 DEG. C) SOLUBLE
PARTITION COEFFICIENT N-OCTANOL/WATER: NO INFORMATION AVAILABLE.
AUTOIGNITION TEMPERATURE: NO INFORMATION AVAILABLE.
DECOMPOSITION TEMPERATURE:
DISTILLABLE IN AN UNDECOMPOSED STATE AT NORMAL PRESSURE.
VISCOSITY, DYNAMIC: NO INFORMATION AVAILABLE.
EXPLOSIVE PROPERTIES: NOT CLASSIFIED AS EXPLOSIVE.
OXIDIZING PROPERTIES:
THE SUBSTANCE OR MIXTURE IS CLASSIFIED AS OXIDIZING WITH THE CATEGORY 3.
IGNITION TEMPERATURE: NOT APPLICABLE
CORROSION: MAY BE CORROSIVE TO METALS.
| SECTION 10. STABILITY AND REACTIVITY | |
REACTIVITY: STRONG OXIDIZING AGENT
CHEMICAL STABILITY:
THE PRODUCT IS CHEMICALLY STABLE UNDER STANDARD AMBIENT CONDITIONS (ROOM
TEMPERATURE) .
POSSIBILITY OF HAZARDOUS REACTIONS:
RISK OF EXPLOSION WITH:
ACETONE, ACETONITRILE, ACETYLIDENE, ALCOHOLS, ANILINE, ANTIMONY HYDRIDE,
ARSENIC HYDRIDE, ORGANIC SUBSTANCES, BENZENE, PHOSPHIDES, ANILINES, AMINES,
HALOGENATED HYDROCARBON, DIETHYL ETHER, DIMETHYL ETHER, HYDRAZINES, NITRO
COMPOUNDS, SULFIDES, DIOXANE, ACETIC ACID, ACETIC ANHYDRIDE, ETHANOL,
ETHYLENE GLYCOL, FLUORINE, FORMALDEHYDE, RUBBER, OILS, HYDRAZINE HYDRATE,
HYDROCARBONS, COPPER, LITHIUM SILICIDE, ORGANIC SOLVENTS, MANGANESE,
CYANIDES, POWDERED METALS, METHANOL, PETROL, PHOSPHORUS TRICHLORIDE,
PHOSPHORUS HYDROGEN, ANHYDRIDES, REDUCING AGENTS, SULFUR DIOXIDE, BORANES,
THIOCYANATES, TITANIUM, TOLUENE, IMPURITIES, NITRIC ACID, HYDROGEN
PEROXIDE, TIN, SUGARS, XYLENE, DICHLOROMETHANE, CARBON/SOOT
POTASSIUM CHLORATE, WITH, ORGANIC SUBSTANCES
MERCURY(II) NITRATE, WITH, ETHANOL
ORGANIC SUBSTANCES, WITH, SULFURIC ACID
NITROBENZENE, WITH, SULFURIC ACID
POTASSIUM PERMANGANATE, WITH, ALCOHOLS
GLYCEROL, WITH, SULFURIC ACID
RISK OF IGNITION OR FORMATION OF INFLAMMABLE GASES OR VAPORS WITH:
AMINES, AMMONIA, COMBUSTIBLE SUBSTANCES, ALDEHYDES, FURFURYL ALCOHOL,
HYDROGEN IODIDE, POTASSIUM, LITHIUM, MAGNESIUM, PHOSPHIDES, SODIUM,
HYDRIDES, PHOSPHORUS, PYRIDINE, HYDROGEN SULFIDE, THIOPHENE
VIOLENT REACTIONS POSSIBLE WITH:
NITRILES, ANTIMONY, ARSENIC, BORON, FERRIC OXIDE, ALKALINES, SODIUM
HYPOCHLORITE, FORMIC ACID, HALOGEN-HALOGEN COMPOUNDS, GERMANIUM, GLYCEROL,
NITRIDES, SODIUM HYDROXIDE SOLUTION, SODIUM HYDROXIDE, SULFURIC ACID,
SELENIUM, BISMUTH, CHLORATES
CONDITIONS TO AVOID: NO INFORMATION AVAILABLE
INCOMPATIBLE MATERIALS:
CELLULOSE, METALS
CONTACT WITH METALS MAY LEAD TO THE FORMATION OF NITROUS GASES AND
HYDROGEN.
HAZARDOUS DECOMPOSITION PRODUCTS:
IN THE EVENT OF FIRE: SEE SECTION 5.
| SECTION 11. TOXICOLOGICAL INFORMATION | |
INFORMATION ON TOXICOLOGICAL EFFECTS:
LIKELY ROUTE OF EXPOSURE: INHALATION, EYE CONTACT, SKIN CONTACT
TARGET ORGANS:
EYES
SKIN
RESPIRATORY SYSTEM
TEETH
ACUTE ORAL TOXICITY:
SYMPTOMS:
IF INGESTED, SEVERE BURNS OF THE MOUTH AND THROAT, AS WELL AS A DANGER OF
PERFORATION OF THE ESOPHAGUS AND THE STOMACH.
ACUTE INHALATION TOXICITY:
SYMPTOMS:
BURNS OF MUCOUS MEMBRANES, COUGH, SHORTNESS OF BREATH, POSSIBLE DAMAGES:,
DAMAGE OF RESPIRATORY TRACT, AFTER A LATENCY PERIOD:, INHALATION MAY LEAD
TO THE FORMATION OF OEDEMAS IN THE RESPIRATORY TRACT.
ACUTE TOXICITY ESTIMATE:
4.62 MG/L; 4 H; VAPOR
CALCULATION METHOD
SKIN IRRITATION: MIXTURE CAUSES SEVERE BURNS.
EYE IRRITATION: MIXTURE CAUSES SERIOUS EYE DAMAGE. RISK OF BLINDNESS!
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - SINGLE EXPOSURE:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS SPECIFIC TARGET ORGAN
TOXICANT, SINGLE EXPOSURE.
SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY - REPEATED EXPOSURE:
THE SUBSTANCE OR MIXTURE IS NOT CLASSIFIED AS SPECIFIC TARGET ORGAN
TOXICANT, REPEATED EXPOSURE.
ASPIRATION HAZARD:
REGARDING THE AVAILABLE DATA THE CLASSIFICATION CRITERIA ARE NOT FULFILLED.
CARCINOGENICITY:
IARC:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS PROBABLE, POSSIBLE OR CONFIRMED HUMAN CARCINOGEN BY
IARC.
OSHA:
NO COMPONENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS ON OSHA'S LIST OF REGULATED CARCINOGENS.
NTP:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A KNOWN OR ANTICIPATED CARCINOGEN BY NTP.
ACGIH:
NO INGREDIENT OF THIS PRODUCT PRESENT AT LEVELS GREATER THAN OR EQUAL TO
0.1% IS IDENTIFIED AS A CARCINOGEN OR POTENTIAL CARCINOGEN BY ACGIH.
FURTHER INFORMATION:
AFTER UPTAKE:
BLOODY VOMITING, STRONG PAIN (RISK OF PERFORATION!), TISSUE DAMAGE, DEATH
THE FOLLOWING APPLIES TO NITRITES/NITRATES IN GENERAL: METHEMOGLOBINEMIA
AFTER THE UPTAKE OF LARGE QUANTITIES.
OTHER DANGEROUS PROPERTIES CAN NOT BE EXCLUDED.
THIS SUBSTANCE SHOULD BE HANDLED WITH PARTICULAR CARE.
COMPONENTS:
NITRIC ACID:
ACUTE INHALATION TOXICITY:
LC50 RAT: >2.65 MG/L; 4 H; VAPOR
OECD TEST GUIDELINE 403
GERM CELL MUTAGENICITY:
GENOTOXICITY IN VITRO
AMES TEST
SALMONELLA TYPHIMURIUM
RESULT: NEGATIVE
METHOD: OECD TEST GUIDELINE 471
| SECTION 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: NO INFORMATION AVAILABLE.
PERSISTENCE AND DEGRADABILITY: BIODEGRADABILITY
THE METHODS FOR DETERMINING THE BIOLOGICAL DEGRADABILITY ARE NOT APPLICABLE
TO INORGANIC SUBSTANCES.
BIOACCUMULATIVE POTENTIAL: NO INFORMATION AVAILABLE.
MOBILITY IN SOIL: NO INFORMATION AVAILABLE.
ADDITIONAL ECOLOGICAL INFORMATION:
BIOLOGICAL EFFECTS:
HARMFUL EFFECT DUE TO PH SHIFT. FORMS CORROSIVE MIXTURES WITH WATER EVEN IF
DILUTED. DOES NOT CAUSE BIOLOGICAL OXYGEN DEFICIT. HAZARD FOR DRINKING
WATER SUPPLIES.
DISCHARGE INTO THE ENVIRONMENT MUST BE AVOIDED.
COMPONENTS:
NITRIC ACID:
BIODEGRADABILITY:
THE METHODS FOR DETERMINING THE BIOLOGICAL DEGRADABILITY ARE NOT APPLICABLE
TO INORGANIC SUBSTANCES.
PARTITION COEFFICIENT N-OCTANOL/WATER:
LOG POW: -2.3
OECD TEST GUIDELINE 107
BIOACCUMULATION IS NOT EXPECTED.
SUBSTANCE DOES NOT MEETS THE CRITERIA FOR PBT OR VPVB ACCORDING TO
REGULATION (EC) NO 1907/2006, ANNEX XIII.
HENRY CONSTANT
2482 PA*M3/MOL
METHOD: (CALCULATED)
(LIT.) DISTRIBUTION PREFERENTIALLY IN AIR.
| SECTION 13. DISPOSAL CONSIDERATIONS | |
THE INFORMATION PRESENTED ONLY APPLIES TO THE MATERIAL AS SUPPLIED. THE
IDENTIFICATION BASED ON CHARACTERISTIC(S) OR LISTING MAY NOT APPLY IF THE
MATERIAL HAS BEEN USED OR OTHERWISE CONTAMINATED. IT IS THE RESPONSIBILITY
OF THE WASTE GENERATOR TO DETERMINE THE TOXICITY AND PHYSICAL PROPERTIES OF
THE MATERIAL GENERATED TO DETERMINE THE PROPER WASTE IDENTIFICATION AND
DISPOSAL METHODS IN COMPLIANCE WITH APPLICABLE REGULATIONS. DISPOSAL SHOULD
BE IN ACCORDANCE WITH APPLICABLE REGIONAL, NATIONAL AND LOCAL LAWS AND
REGULATIONS.
| SECTION 14. TRANSPORT INFORMATION | |
LAND TRANSPORT (DOT):
UN NUMBER: UN 2031
PROPER SHIPPING NAME: NITRIC ACID
CLASS: 8 (5.1)
PACKING GROUP: II
ENVIRONMENTALLY HAZARDOUS:
AIR TRANSPORT (IATA):
UN NUMBER: UN 2031
PROPER SHIPPING NAME: NITRIC ACID
CLASS: 8 (5.1)
PACKING GROUP: II
ENVIRONMENTALLY HAZARDOUS:
SPECIAL PRECAUTIONS FOR USER:
YES
NOT PERMITTED FOR TRANSPORT
SEA TRANSPORT (IMDG):
UN NUMBER: UN 2031
PROPER SHIPPING NAME: NITRIC ACID WITH AT LEAST 65% BUT NOT MORE THAN 70%
CLASS: 8 (5.1)
PACKING GROUP: II
ENVIRONMENTALLY HAZARDOUS:-
SPECIAL PRECAUTIONS FOR USER: YES
EMS: F-A S-Q
| SECTION 15. REGULATORY INFORMATION | |
UNITED STATES OF AMERICA:
SARA 313:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 313:
COMPONENTS
NITRIC ACID 7697-37-2 65%
SARA 302:
THE FOLLOWING COMPONENTS ARE SUBJECT TO REPORTING LEVELS ESTABLISHED BY
SARA TITLE III, SECTION 302:
COMPONENTS
NITRIC ACID 7697-37-2
CLEAN WATER ACT:
THE FOLLOWING HAZARDOUS SUBSTANCES ARE LISTED UNDER THE U.S. CLEANWATER
ACT, SECTION 311, TABLE 116.4A:
COMPONENTS
NITRIC ACID
THE FOLLOWING HAZARDOUS CHEMICALS ARE LISTED UNDER THE U.S. CLEANWATER ACT,
SECTION 311, TABLE 117.3:
COMPONENTS
NITRIC ACID
THIS PRODUCT DOES NOT CONTAIN ANY TOXIC POLLUTANTS LISTED UNDER THE U.S.
CLEAN WATER ACT SECTION 307
DEA LIST I: NOT LISTED
DEA LIST II: NOT LISTED
US STATE REGULATIONS:
MASSACHUSETTS RIGHT TO KNOW:
COMPONENTS
NITRIC ACID
PENNSYLVANIA RIGHT TO KNOW:
COMPONENTS
NITRIC ACID
NEW JERSEY RIGHT TO KNOW:
COMPONENTS
NITRIC ACID
CALIFORNIA PROP 65 COMPONENTS:
THIS PRODUCT DOES NOT CONTAIN ANY CHEMICALS KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER, BIRTH, OR ANY OTHER REPRODUCTIVE DEFECTS.
NOTIFICATION STATUS:
TSCA: ALL COMPONENTS OF THE PRODUCT ARE LISTED IN THE TSCA-INVENTORY.
DSL: ALL COMPONENTS OF THIS PRODUCT ARE ON THE CANADIAN DSL
| SECTION 16. OTHER INFORMATION | |
TRAINING ADVICE:
PROVIDE ADEQUATE INFORMATION, INSTRUCTION AND TRAINING FOR OPERATORS.
LABELING:
HAZARD PICTOGRAMS:
FLAME OVER CIRCLE
SKULLS AND CROSSBONES
CORROSION
SIGNAL WORD: DANGER
HAZARD STATEMENTS:
H272: MAY INTENSIFY FIRE; OXIDIZER.
H290: MAY BE CORROSIVE TO METALS.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H331: TOXIC IF INHALED.
EUH071: CORROSIVE TO THE RESPIRATORY TRACT.
PRECAUTIONARY STATEMENTS:
PREVENTION:
P280:
WEAR PROTECTIVE GLOVES/PROTECTIVE CLOTHING/EYE PROTECTION/FACE PROTECTION.
RESPONSE:
P301 + P330 + P331:
IF SWALLOWED: RINSE MOUTH. DO NOT INDUCE VOMITING.
P304 + P340:
IF INHALED:
REMOVE VICTIM TO FRESH AIR AND KEEP AT REST IN A POSITION COMFORTABLE FOR
BREATHING.
P305 + P351 + P338:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
P308 + P310:
IF EXPOSED OR CONCERNED:
IMMEDIATELY CALL A POISON CENTER OR DOCTOR/PHYSICIAN.
FULL TEXT OF H-STATEMENTS REFERRED TO UNDER SECTIONS 2 AND 3.:
H272: MAY INTENSIFY FIRE; OXIDIZER.
H290: MAY BE CORROSIVE TO METALS.
H314: CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.
H318: CAUSES SERIOUS EYE DAMAGE.
H331: TOXIC IF INHALED.
KEY OR LEGEND TO ABBREVIATIONS AND ACRONYMS USED IN THE SAFETY DATA SHEET:
USED ABBREVIATIONS AND ACRONYMS CAN BE LOOKED UP AT WWW.WIKIPEDIA.ORG.
REVISION DATE: 02/20/2020
THE BRANDING ON THE HEADER AND/OR FOOTER OF THIS DOCUMENT MAY TEMPORARILY
NOT VISUALLY MATCH THE PRODUCT PURCHASED AS WE TRANSITION OUR BRANDING.
HOWEVER, ALL OF THE INFORMATION IN THE DOCUMENT REGARDING THE PRODUCT
REMAINS UNCHANGED AND MATCHES THE PRODUCT ORDERED. FOR FURTHER INFORMATION
PLEASE CONTACT MLSBRANDING@SIAL.COM.
THE INFORMATION CONTAINED HEREIN IS BASED ON THE PRESENT STATE OF OUR
KNOWLEDGE. IT CHARACTERIZES THE PRODUCT WITH REGARD TO APPROPRIATE SAFETY
PRECAUTIONS. IT DOES NOT REPRESENT A WARRANTY OF ANY PRODUCT PROPERTIES AND
WE ASSUME NO LIABILITY FOR ANY LOSS OR INJURY WHICH MAY RESULT FROM THE USE
OF THIS INFORMATION. USERS SHOULD CONDUCT THEIR OWN INVESTIGATIONS TO
DETERMINE THE SUITABILITY OF THE INFORMATION.
ALL RIGHTS RESERVED. MILLIPORE AND THE "M" MARK ARE REGISTERED TRADEMARKS
OF MERCK KGAA, DARMSTADT, GERMANY.
THE LIFE SCIENCE BUSINESS OF MERCK KGAA, DARMSTADT, GERMANY OPERATES AS
MILLIPORE SIGMA IN THE US AND CANADA
MILLIPORE SIGMA