| Common Name: | CAL-BLAST (4132-20) |
| Manufacturer: | NU-CALGON |
| SDS Revision Date: | 8/26/2019 |
| SDS Format: | GHS-CA |
| Item Number(s): | 20LP96 |
| Manufacturer Model Number(s): |
SDS Table of Contents
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NU-CALGON
SAFETY DATA SHEET
| 1. PRODUCT AND COMPANY IDENTIFICATION |  |
PRODUCT IDENTIFIER: CAL-BLAST(TM) (4132-20)
OTHER MEANS OF IDENTIFICATION: NOT AVAILABLE
RECOMMENDED USE: CLEANER.
RECOMMENDED RESTRICTIONS:
THIS CHEMICAL/PRODUCT IS NOT AND CANNOT BE DISTRIBUTED IN COMMERCE (AS
DEFINED IN TSCA SECTION 3(5)) OR PROCESSED (AS DEFINED IN TSCA SECTION
3(13)) FOR CONSUMER PAINT OR COATING REMOVAL.
MANUFACTURER INFORMATION:
NU-CALGON
2611 SCHUETZ ROAD
ST. LOUIS, MO 63043
US
PHONE: 314-469-7000 / 800-554-5499
EMERGENCY PHONE: 1-800-424-9300 (CHEMTREC)
SUPPLIER: SEE ABOVE.
| 2. HAZARDS IDENTIFICATION | |
PHYSICAL HAZARDS:
FLAMMABLE AEROSOLS: CATEGORY 1
GASES UNDER PRESSURE: LIQUEFIED GAS
HEALTH HAZARDS:
SKIN CORROSION/IRRITATION: CATEGORY 2
SERIOUS EYE DAMAGE/EYE IRRITATION: CATEGORY 2A
SENSITIZATION, SKIN: CATEGORY 1
CARCINOGENICITY: CATEGORY 1B
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE: CATEGORY 1
SPECIFIC TARGET ORGAN TOXICITY, SINGLE EXPOSURE:
CATEGORY 3 NARCOTIC EFFECTS
ENVIRONMENTAL HAZARDS: NOT CLASSIFIED.
WHMIS 2015 DEFINED HAZARDS: NOT CLASSIFIED
LABEL ELEMENTS:
FLAME
GAS CYLINDER
HEALTH HAZARD
EXCLAMATION MARK
SIGNAL WORD: DANGER
HAZARD STATEMENT:
EXTREMELY FLAMMABLE AEROSOL. CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF
HEATED. CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION. CAUSES
SERIOUS EYE IRRITATION. MAY CAUSE DROWSINESS OR DIZZINESS. MAY CAUSE
CANCER. CAUSES DAMAGE TO ORGANS.
PRECAUTIONARY STATEMENT:
PREVENTION:
KEEP AWAY FROM HEAT, HOT SURFACES, SPARKS, OPEN FLAMES AND OTHER IGNITION
SOURCES. NO SMOKING. DO NOT SPRAY ON AN OPEN FLAME OR OTHER IGNITION
SOURCE. DO NOT PIERCE OR BURN, EVEN AFTER USE. WASH THOROUGHLY AFTER
HANDLING. WEAR PROTECTIVE GLOVES, PROTECTIVE CLOTHING, EYE PROTECTION AND
FACE PROTECTION. DO NOT BREATHE GAS. CONTAMINATED WORK CLOTHING SHOULD NOT
BE ALLOWED OUT OF THE WORKPLACE. USE ONLY OUTDOORS OR IN A WELL-VENTILATED
AREA. OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL
SAFETY PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. DO NOT EAT, DRINK OR
SMOKE WHEN USING THIS PRODUCT.
RESPONSE:
IF ON SKIN: WASH WITH PLENTY OF WATER.
IF SKIN IRRITATION OR RASH OCCURS:
GET MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE
REUSE.
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING.
IF EYE IRRITATION PERSISTS: GET MEDICAL ATTENTION.
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
IF EXPOSED OR CONCERNED: GET MEDICAL ATTENTION.
STORAGE:
PROTECT FROM SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES EXCEEDING 50 DEG.
C/122 DEG. F. STORE IN A WELL-VENTILATED PLACE. KEEP CONTAINER TIGHTLY
CLOSED. STORE LOCKED UP.
DISPOSAL:
DISPOSE OF CONTAINER IN ACCORDANCE WITH LOCAL, REGIONAL, NATIONAL AND
INTERNATIONAL REGULATIONS.
WHMIS 2015:
HEALTH HAZARD(S) NOT OTHERWISE CLASSIFIED (HHNOC): NONE KNOWN
WHMIS 2015:
PHYSICAL HAZARD(S) NOT OTHERWISE CLASSIFIED (PHNOC): NONE KNOWN
HAZARD(S) NOT OTHERWISE CLASSIFIED (HNOC): NONE KNOWN.
SUPPLEMENTAL INFORMATION: NONE.
| 3. COMPOSITION/INFORMATION ON INGREDIENTS | |
MIXTURE:
CHEMICAL NAME COMMON NAME AND SYNONYMS CAS NUMBER %
D-LIMONENE 5989-27-5 1-5*
METHYLENE CHLORIDE 75-09-2 80-100*
ALL CONCENTRATIONS ARE IN PERCENT BY WEIGHT UNLESS INGREDIENT IS A GAS. GAS
CONCENTRATIONS ARE IN PERCENT BY VOLUME.
COMPOSITION COMMENTS:
US GHS:
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET IN ACCORDANCE WITH PARAGRAPH (I) OF SUBSECTION 1910.1200.
*CANADA GHS:
THE EXACT PERCENTAGE (CONCENTRATION) OF COMPOSITION HAS BEEN WITHHELD AS A
TRADE SECRET.
| 4. FIRST AID MEASURES | |
INHALATION:
IF INHALED:
REMOVE PERSON TO FRESH AIR AND KEEP COMFORTABLE FOR BREATHING. CALL A
POISON CENTER OR DOCTOR IF YOU FEEL UNWELL.
SKIN CONTACT:
IF ON SKIN:
WASH WITH PLENTY OF SOAP AND WATER. IF SKIN IRRITATION OR RASH OCCURS: GET
MEDICAL ATTENTION. TAKE OFF CONTAMINATED CLOTHING AND WASH IT BEFORE REUSE.
EYE CONTACT:
IF IN EYES:
RINSE CAUTIOUSLY WITH WATER FOR SEVERAL MINUTES. REMOVE CONTACT LENSES, IF
PRESENT AND EASY TO DO. CONTINUE RINSING. IF EYE IRRITATION PERSISTS: GET
MEDICAL ATTENTION.
INGESTION:
NOT LIKELY, DUE TO THE FORM OF THE PRODUCT. IN THE UNLIKELY EVENT OF
SWALLOWING CONTACT A PHYSICIAN OR POISON CONTROL CENTER. RINSE MOUTH. DO
NOT INDUCE VOMITING. IF VOMITING OCCURS NATURALLY, HAVE VICTIM LEAN FORWARD
TO REDUCE RISK OF ASPIRATION. NEVER GIVE ANYTHING BY MOUTH IF VICTIM IS
UNCONSCIOUS OR IS CONVULSING. OBTAIN MEDICAL ATTENTION.
MOST IMPORTANT SYMPTOMS/EFFECTS, ACUTE AND DELAYED:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED:
PROVIDE GENERAL SUPPORTIVE MEASURES AND TREAT SYMPTOMATICALLY. SYMPTOMS MAY
BE DELAYED.
GENERAL INFORMATION:
IF EXPOSED OR CONCERNED: GET MEDICAL ADVICE/ATTENTION. IF YOU FEEL UNWELL,
SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE POSSIBLE). ENSURE THAT MEDICAL
PERSONNEL ARE AWARE OF THE MATERIAL(S) INVOLVED AND TAKE PRECAUTIONS TO
PROTECT THEMSELVES. SHOW THIS SAFETY DATA SHEET TO THE DOCTOR IN
ATTENDANCE. WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID CONTACT WITH
EYES AND SKIN. KEEP OUT OF REACH OF CHILDREN.
| 5. FIRE FIGHTING MEASURES | |
SUITABLE EXTINGUISHING MEDIA:
WATER FOG. FOAM. DRY CHEMICAL POWDER. CARBON DIOXIDE.
UNSUITABLE EXTINGUISHING MEDIA: NOT AVAILABLE.
SPECIFIC HAZARDS ARISING FROM THE CHEMICAL:
CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER MAY EXPLODE WHEN EXPOSED TO
HEAT OR FLAME. DURING FIRE, GASES HAZARDOUS TO HEALTH MAY BE FORMED.
SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS:
NOT AVAILABLE.
FIRE-FIGHTING EQUIPMENT/INSTRUCTIONS:
IN CASE OF FIRE:
STOP LEAK IF SAFE TO DO SO. DO NOT MOVE CARGO OR VEHICLE IF CARGO HAS BEEN
EXPOSED TO HEAT. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. CONTAINERS SHOULD BE COOLED WITH WATER TO PREVENT VAPOR PRESSURE
BUILD UP. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER OR
MONITOR NOZZLES, IF POSSIBLE. IF NOT, WITHDRAW AND LET FIRE BURN OUT.
SPECIFIC METHODS:
USE STANDARD FIREFIGHTING PROCEDURES AND CONSIDER THE HAZARDS OF OTHER
INVOLVED MATERIALS. MOVE CONTAINERS FROM FIRE AREA IF YOU CAN DO SO WITHOUT
RISK. COOL CONTAINERS EXPOSED TO FLAMES WITH WATER UNTIL WELL AFTER THE
FIRE IS OUT. IN THE EVENT OF FIRE AND/OR EXPLOSION DO NOT BREATHE FUMES.
GENERAL FIRE HAZARDS:
EXTREMELY FLAMMABLE AEROSOL. CONTENTS UNDER PRESSURE. PRESSURIZED CONTAINER
MAY EXPLODE WHEN EXPOSED TO HEAT OR FLAME.
HAZARDOUS COMBUSTION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: OXIDES OF CARBON. CHLORINE GAS.
PHOSGENE.
| 6. ACCIDENTAL RELEASE MEASURES | |
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES:
KEEP UNNECESSARY PERSONNEL AWAY. KEEP PEOPLE AWAY FROM AND UPWIND OF
SPILL/LEAK. KEEP OUT OF LOW AREAS. MANY GASES ARE HEAVIER THAN AIR AND
WILL SPREAD ALONG GROUND AND COLLECT IN LOW OR CONFINED AREAS (SEWERS,
BASEMENTS, TANKS). WEAR APPROPRIATE PROTECTIVE EQUIPMENT AND CLOTHING
DURING CLEAN-UP. DO NOT BREATHE GAS. EMERGENCY PERSONNEL NEED
SELF-CONTAINED BREATHING EQUIPMENT. DO NOT TOUCH DAMAGED CONTAINERS OR
SPILLED MATERIAL UNLESS WEARING APPROPRIATE PROTECTIVE CLOTHING. VENTILATE
CLOSED SPACES BEFORE ENTERING THEM. LOCAL AUTHORITIES SHOULD BE ADVISED IF
SIGNIFICANT SPILLAGES CANNOT BE CONTAINED. FOR PERSONAL PROTECTION, SEE
SECTION 8 OF THE SDS.
METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP:
REFER TO ATTACHED SAFETY DATA SHEETS AND/OR INSTRUCTIONS FOR USE. STOP LEAK
IF YOU CAN DO SO WITHOUT RISK. MOVE THE CYLINDER TO A SAFE AND OPEN AREA IF
THE LEAK IS IRREPARABLE. ISOLATE AREA UNTIL GAS HAS DISPERSED. ELIMINATE
ALL IGNITION SOURCES (NO SMOKING, FLARES, SPARKS, OR FLAMES IN IMMEDIATE
AREA). KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED
MATERIAL. COVER WITH PLASTIC SHEET TO PREVENT SPREADING. ABSORB IN
VERMICULITE, DRY SAND OR EARTH AND PLACE INTO CONTAINERS. FOLLOWING PRODUCT
RECOVERY, FLUSH AREA WITH WATER.
SMALL SPILLS:
WIPE UP WITH ABSORBENT MATERIAL (E.G. CLOTH, FLEECE). CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. FOR WASTE DISPOSAL, SEE
SECTION 13 OF THE SDS.
ENVIRONMENTAL PRECAUTIONS:
AVOID DISCHARGE INTO DRAINS, WATER COURSES OR ONTO THE GROUND. DO NOT
DISCHARGE INTO LAKES, STREAMS, PONDS OR PUBLIC WATERS.
| 7. HANDLING AND STORAGE | |
PRECAUTIONS FOR SAFE HANDLING:
OBTAIN SPECIAL INSTRUCTIONS BEFORE USE. DO NOT HANDLE UNTIL ALL SAFETY
PRECAUTIONS HAVE BEEN READ AND UNDERSTOOD. KEEP AWAY FROM HEAT/SPARKS/OPEN
FLAMES/HOT SURFACES. - NO SMOKING. DO NOT SMOKE WHILE USING OR UNTIL
SPRAYED SURFACE IS THOROUGHLY DRY. PRESSURIZED CONTAINER: DO NOT PIERCE OR
BURN, EVEN AFTER USE. DO NOT USE IF SPRAY BUTTON IS MISSING OR DEFECTIVE.
DO NOT SPRAY ON A NAKED FLAME OR ANY OTHER INCANDESCENT MATERIAL. DO NOT
CUT, WELD, SOLDER, DRILL, GRIND, OR EXPOSE CONTAINERS TO HEAT, FLAME,
SPARKS, OR OTHER SOURCES OF IGNITION. ALL EQUIPMENT USED WHEN HANDLING THE
PRODUCT MUST BE GROUNDED. PROTECT CYLINDERS FROM PHYSICAL DAMAGE; DO NOT
DRAG, ROLL, SLIDE, OR DROP. USE ONLY PROPERLY SPECIFIED EQUIPMENT WHICH IS
SUITABLE FOR THIS PRODUCT, ITS SUPPLY PRESSURE AND TEMPERATURE. CONTACT
YOUR GAS SUPPLIER IF IN DOUBT. DO NOT RE-USE EMPTY CONTAINERS. DO NOT
BREATHE GAS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING. WHEN USING, DO
NOT EAT, DRINK OR SMOKE. USE ONLY IN WELL-VENTILATED AREAS. AVOID
PROLONGED EXPOSURE. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT. WASH
THOROUGHLY AFTER HANDLING. USE GOOD INDUSTRIAL HYGIENE PRACTICES IN
HANDLING THIS MATERIAL.
CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES:
STORE LOCKED UP. PRESSURIZED CONTAINER. PROTECT FROM SUNLIGHT AND DO NOT
EXPOSE TO TEMPERATURES EXCEEDING 50 DEG. C/122 DEG. F. DO NOT HANDLE OR
STORE NEAR AN OPEN FLAME, HEAT OR OTHER SOURCES OF IGNITION. DO NOT
PUNCTURE, INCINERATE OR CRUSH. STORE IN A WELL-VENTILATED PLACE. STORE AWAY
FROM INCOMPATIBLE MATERIALS (SEE SECTION 10 OF THE SDS). CYLINDERS SHOULD
BE STORED UPRIGHT, WITH VALVE PROTECTION CAP IN PLACE, AND FIRMLY SECURED
TO PREVENT FALLING OR BEING KNOCKED OVER. STORED CONTAINERS SHOULD BE
PERIODICALLY CHECKED FOR GENERAL CONDITION AND LEAKAGE. KEEP OUT OF REACH
OF CHILDREN.
| 8. EXPOSURE CONTROLS/PERSONAL PROTECTION | |
OCCUPATIONAL EXPOSURE LIMITS:
CANADA. ALBERTA OELS (OCCUPATIONAL HEALTH & SAFETY CODE, SCHEDULE 1, TABLE
2):
COMPONENTS TYPE VALUE
METHYLENE CHLORIDE TWA 174 MG/M3
(CAS 75-09-2) 50 PPM
CANADA. BRITISH COLUMBIA OELS. (OCCUPATIONAL EXPOSURE LIMITS FOR CHEMICAL
SUBSTANCES, OCCUPATIONAL HEALTH AND SAFETY REGULATION 296/97, AS AMENDED):
COMPONENTS TYPE VALUE
METHYLENE CHLORIDE TWA 25 PPM
(CAS 75-09-2)
CANADA. MANITOBA OELS (REG. 217/2006, THE WORKPLACE SAFETY AND HEALTH ACT):
COMPONENTS TYPE VALUE
METHYLENE CHLORIDE TWA 50 PPM
(CAS 75-09-2)
CANADA. ONTARIO OELS. (CONTROL OF EXPOSURE TO BIOLOGICAL OR CHEMICAL
AGENTS):
COMPONENTS TYPE VALUE
METHYLENE CHLORIDE TWA 50 PPM
(CAS 75-09-2)
CANADA. QUEBEC OELS. (MINISTRY OF LABOR - REGULATION RESPECTING THE QUALITY
OF THE WORK ENVIRONMENT):
COMPONENTS TYPE VALUE
METHYLENE CHLORIDE TWA 174 MG/M3
(CAS 75-09-2) 50 PPM
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
COMPONENTS TYPE VALUE
METHYLENE CHLORIDE STEL 125 PPM
(CAS 75-09-2) TWA 25 PPM
US. ACGIH THRESHOLD LIMIT VALUES:
COMPONENTS TYPE VALUE
METHYLENE CHLORIDE TWA 50 PPM
(CAS 75-09-2)
US. AIHA WORKPLACE ENVIRONMENTAL EXPOSURE LEVEL (WEEL) GUIDES:
COMPONENTS TYPE VALUE
D-LIMONENE TWA 165.5 MG/M3
(CAS 5989-27-5) 30 PPM
BIOLOGICAL LIMIT VALUES:
ACGIH BIOLOGICAL EXPOSURE INDICES:
COMPONENTS VALUE DETERMINANT SPECIMEN SAMPLING TIME
METHYLENE CHLORIDE 0.3 MG/L DICHLOROMETHANE URINE *
(CAS 75-09-2)
* - FOR SAMPLING DETAILS, PLEASE SEE THE SOURCE DOCUMENT.
APPROPRIATE ENGINEERING CONTROLS:
GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES PER HOUR) SHOULD BE
USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS. IF APPLICABLE,
USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR OTHER ENGINEERING
CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW RECOMMENDED EXPOSURE LIMITS. IF
EXPOSURE LIMITS HAVE NOT BEEN ESTABLISHED, MAINTAIN AIRBORNE LEVELS TO AN
ACCEPTABLE LEVEL.
INDIVIDUAL PROTECTION MEASURES, SUCH AS PERSONAL PROTECTIVE EQUIPMENT:
EYE/FACE PROTECTION: WEAR SAFETY GLASSES WITH SIDE SHIELDS (OR GOGGLES).
SKIN PROTECTION:
HAND PROTECTION: IMPERVIOUS GLOVES. CONFIRM WITH REPUTABLE SUPPLIER FIRST.
OTHER:
WEAR APPROPRIATE CHEMICAL RESISTANT CLOTHING. USE OF AN IMPERVIOUS APRON IS
RECOMMENDED. AS REQUIRED BY EMPLOYER CODE.
RESPIRATORY PROTECTION:
WHERE EXPOSURE GUIDELINE LEVELS MAY BE EXCEEDED, USE AN APPROVED NIOSH
RESPIRATOR. RESPIRATOR SHOULD BE SELECTED BY AND USED UNDER THE DIRECTION
OF A TRAINED HEALTH AND SAFETY PROFESSIONAL FOLLOWING REQUIREMENTS FOUND
IN OSHA'S RESPIRATOR STANDARD (29 CFR 1910.134), CAN/CSA-Z94.4 AND ANSI'S
STANDARD FOR RESPIRATORY PROTECTION (Z88.2).
THERMAL HAZARDS: NOT APPLICABLE.
GENERAL HYGIENE CONSIDERATIONS:
WHEN USING DO NOT SMOKE. ALWAYS OBSERVE GOOD PERSONAL HYGIENE MEASURES,
SUCH AS WASHING AFTER HANDLING THE MATERIAL AND BEFORE EATING, DRINKING,
AND/OR SMOKING. ROUTINELY WASH WORK CLOTHING AND PROTECTIVE EQUIPMENT TO
REMOVE CONTAMINANTS. CONTAMINATED WORK CLOTHING SHOULD NOT BE ALLOWED OUT
OF THE WORKPLACE. WHEN USING DO NOT EAT OR DRINK.
| 9. PHYSICAL AND CHEMICAL PROPERTIES | |
APPEARANCE: CLEAR
PHYSICAL STATE: GAS.
FORM: AEROSOL.
COLOR: COLORLESS
ODOR: SOLVENT
ODOR THRESHOLD: NOT AVAILABLE.
PH: NOT AVAILABLE.
MELTING POINT/FREEZING POINT: NOT AVAILABLE.
INITIAL BOILING POINT AND BOILING RANGE: NOT AVAILABLE.
POUR POINT: NOT AVAILABLE.
SPECIFIC GRAVITY: NOT AVAILABLE.
PARTITION COEFFICIENT (N-OCTANOL/WATER): NOT AVAILABLE.
FLASH POINT: NOT AVAILABLE.
EVAPORATION RATE: NOT AVAILABLE.
FLAMMABILITY (SOLID, GAS): NOT AVAILABLE.
UPPER/LOWER FLAMMABILITY OR EXPLOSIVE LIMITS:
FLAMMABILITY LIMIT - LOWER (%): NOT AVAILABLE.
FLAMMABILITY LIMIT - UPPER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - LOWER (%): NOT AVAILABLE.
EXPLOSIVE LIMIT - UPPER (%): NOT AVAILABLE.
VAPOR PRESSURE: NOT AVAILABLE.
VAPOR DENSITY: NOT AVAILABLE.
RELATIVE DENSITY: 1.30 - 1.34
SOLUBILITY(IES): NOT AVAILABLE.
AUTO-IGNITION TEMPERATURE: NOT AVAILABLE.
DECOMPOSITION TEMPERATURE: NOT AVAILABLE.
VISCOSITY: NOT AVAILABLE.
OTHER INFORMATION:
EXPLOSIVE PROPERTIES: NOT EXPLOSIVE.
FLAME EXTENSION: 0
FLAMMABILITY (FLASH BACK): NO
HEAT OF COMBUSTION: LEVEL 1
OXIDIZING PROPERTIES: NOT OXIDIZING.
| 10. STABILITY AND REACTIVITY | |
REACTIVITY: THIS PRODUCT MAY REACT WITH STRONG OXIDIZING AGENTS.
POSSIBILITY OF HAZARDOUS REACTIONS:
NO DANGEROUS REACTION KNOWN UNDER CONDITIONS OF NORMAL USE.
CHEMICAL STABILITY: MATERIAL IS STABLE UNDER NORMAL CONDITIONS.
CONDITIONS TO AVOID: HEAT. DO NOT MIX WITH OTHER CHEMICALS.
INCOMPATIBLE MATERIALS: STRONG OXIDIZING AGENTS.
HAZARDOUS DECOMPOSITION PRODUCTS:
MAY INCLUDE AND ARE NOT LIMITED TO: CHLORINE GAS. PHOSGENE. OXIDES OF
CARBON.
| 11. TOXICOLOGICAL INFORMATION | |
ROUTES OF EXPOSURE: EYE, SKIN CONTACT, INHALATION, INGESTION.
INFORMATION ON LIKELY ROUTES OF EXPOSURE:
INGESTION: MAY CAUSE STOMACH DISTRESS, NAUSEA OR VOMITING.
INHALATION:
MAY CAUSE DAMAGE TO ORGANS BY INHALATION. MAY CAUSE DROWSINESS AND
DIZZINESS. HEADACHE. NAUSEA, VOMITING. PROLONGED INHALATION MAY BE
HARMFUL.
SKIN CONTACT: CAUSES SKIN IRRITATION. MAY CAUSE AN ALLERGIC SKIN REACTION.
EYE CONTACT: CAUSES SERIOUS EYE IRRITATION.
SYMPTOMS RELATED TO THE PHYSICAL, CHEMICAL AND TOXICOLOGICAL
CHARACTERISTICS:
MAY CAUSE DROWSINESS AND DIZZINESS. HEADACHE. NAUSEA, VOMITING. SEVERE EYE
IRRITATION. SYMPTOMS MAY INCLUDE STINGING, TEARING, REDNESS, SWELLING, AND
BLURRED VISION. SKIN IRRITATION. MAY CAUSE REDNESS AND PAIN. MAY CAUSE AN
ALLERGIC SKIN REACTION. DERMATITIS. RASH.
INFORMATION ON TOXICOLOGICAL EFFECTS:
ACUTE TOXICITY: NARCOTIC EFFECTS. MAY CAUSE AN ALLERGIC SKIN REACTION.
COMPONENTS SPECIES TEST RESULTS
D-LIMONENE (CAS 5989-27-5)
ACUTE:
DERMAL:
LD50 RABBIT 5 G/KG, HSDB
INHALATION:
LC50 NOT AVAILABLE
ORAL:
LD50 MOUSE 5600 - 6600 MG/KG, HSDB
RAT >2000 MG/KG, ECHA
4400 MG/KG, FISHER SCIENTIFIC
METHYLENE CHLORIDE (CAS 75-09-2):
ACUTE:
DERMAL:
LD50 RAT >2000 MG/KG, ECHA
INHALATION:
LC50 MOUSE 49000 MG/M3, 7 HOURS, ECHA
ORAL:
LD50 RAT >2000 MG/KG, ECHA
SKIN CORROSION/IRRITATION: CAUSES SKIN IRRITATION.
EXPOSURE MINUTES: NOT AVAILABLE.
ERYTHEMA VALUE: NOT AVAILABLE.
OEDEMA VALUE: NOT AVAILABLE.
SERIOUS EYE DAMAGE/EYE IRRITATION: CAUSES SERIOUS EYE IRRITATION.
CORNEAL OPACITY VALUE: NOT AVAILABLE.
IRIS LESION VALUE: NOT AVAILABLE.
CONJUNCTIVAL REDDENING VALUE: NOT AVAILABLE.
CONJUNCTIVAL OEDEMA VALUE: NOT AVAILABLE.
RECOVER DAYS: NOT AVAILABLE.
RESPIRATORY OR SKIN SENSITIZATION:
RESPIRATORY SENSITIZATION: NOT A RESPIRATORY SENSITIZER.
SKIN SENSITIZATION: MAY CAUSE AN ALLERGIC SKIN REACTION.
MUTAGENICITY: NOT CLASSIFIED.
CARCINOGENICITY: MAY CAUSE CANCER. SEE BELOW.
ACGIH CARCINOGENS:
METHYLENE CHLORIDE (CAS 75-09-2):
A3 CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS.
CANADA - MANITOBA OELS: CARCINOGENICITY
DICHLOROMETHANE (CAS 75-09-2):
CONFIRMED ANIMAL CARCINOGEN WITH UNKNOWN RELEVANCE TO HUMANS.
CANADA - QUEBEC OELS: CARCINOGEN CATEGORY
METHYLENE CHLORIDE (CAS 75-09-2): SUSPECTED CARCINOGENIC EFFECT IN HUMANS.
IARC MONOGRAPHS. OVERALL EVALUATION OF CARCINOGENICITY:
D-LIMONENE (CAS 5989-27-5):
VOLUME 73 - 3 NOT CLASSIFIABLE AS TO CARCINOGENICITY TO HUMANS.
METHYLENE CHLORIDE (CAS 75-09-2):
VOLUME 71, VOLUME 110 - 2A PROBABLY CARCINOGENIC TO HUMANS.
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2)
US NTP REPORT ON CARCINOGENS: ANTICIPATED CARCINOGEN
METHYLENE CHLORIDE (CAS 75-09-2) REASONABLY ANTICIPATED TO BE A HUMAN
CARCINOGEN.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
METHYLENE CHLORIDE (CAS 75-09-2): CANCER
REPRODUCTIVE TOXICITY:
THIS PRODUCT IS NOT EXPECTED TO CAUSE REPRODUCTIVE OR DEVELOPMENTAL
EFFECTS.
TERATOGENICITY: NOT AVAILABLE.
SPECIFIC TARGET ORGAN TOXICITY - SINGLE EXPOSURE:
CAUSES DAMAGE TO ORGANS. MAY CAUSE DROWSINESS AND DIZZINESS.
SPECIFIC TARGET ORGAN TOXICITY - REPEATED EXPOSURE: NOT CLASSIFIED.
ASPIRATION HAZARD: NOT LIKELY, DUE TO THE FORM OF THE PRODUCT.
CHRONIC EFFECTS:
PROLONGED INHALATION MAY BE HARMFUL. PROLONGED EXPOSURE MAY CAUSE CHRONIC
EFFECTS.
| 12. ECOLOGICAL INFORMATION | |
ECOTOXICITY: SEE BELOW
ECOTOXICOLOGICAL DATA:
COMPONENTS SPECIES TEST RESULTS
D-LIMONENE (CAS 5989-27-5):
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA PULEX) 69.6 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES 0.619 - 0.796 MG/L, 96 HOURS
PROMELAS)
METHYLENE CHLORIDE (CAS 75-09-2):
ALGAE IC50 ALGAE 500 MG/L, 72 HOURS
CRUSTACEA EC50 DAPHNIA 1689.5 MG/L, 48 HOURS
AQUATIC:
CRUSTACEA EC50 WATER FLEA (DAPHNIA MAGNA) 1250 MG/L, 48 HOURS
FISH LC50 FATHEAD MINNOW (PIMEPHALES 140.8 - 277.8 MG/L, 96 HOURS
PROMELAS)
PERSISTENCE AND DEGRADABILITY:
NO DATA IS AVAILABLE ON THE DEGRADABILITY OF THIS PRODUCT.
BIOACCUMULATIVE POTENTIAL:
MOBILITY IN SOIL: NO DATA AVAILABLE.
MOBILITY IN GENERAL: NOT AVAILABLE.
OTHER ADVERSE EFFECTS:
NO OTHER ADVERSE ENVIRONMENTAL EFFECTS (E.G. OZONE DEPLETION, PHOTOCHEMICAL
OZONE CREATION POTENTIAL, ENDOCRINE DISRUPTION, GLOBAL WARMING POTENTIAL)
ARE EXPECTED FROM THIS COMPONENT.
| 13. DISPOSAL CONSIDERATIONS | |
DISPOSAL INSTRUCTIONS:
COLLECT AND RECLAIM OR DISPOSE IN SEALED CONTAINERS AT LICENSED WASTE
DISPOSAL SITE. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE OR
CRUSH. DISPOSE OF CONTENTS/CONTAINER IN ACCORDANCE WITH
LOCAL/REGIONAL/NATIONAL/INTERNATIONAL REGULATIONS.
LOCAL DISPOSAL REGULATIONS:
DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
HAZARDOUS WASTE CODE:
THE WASTE CODE SHOULD BE ASSIGNED IN DISCUSSION BETWEEN THE USER, THE
PRODUCER AND THE WASTE DISPOSAL COMPANY.
WASTE FROM RESIDUES / UNUSED PRODUCTS:
DISPOSE OF IN ACCORDANCE WITH LOCAL REGULATIONS. EMPTY CONTAINERS OR LINERS
MAY RETAIN SOME PRODUCT RESIDUES. THIS MATERIAL AND ITS CONTAINER MUST BE
DISPOSED OF IN A SAFE MANNER (SEE: DISPOSAL INSTRUCTIONS).
CONTAMINATED PACKAGING:
SINCE EMPTIED CONTAINERS MAY RETAIN PRODUCT RESIDUE, FOLLOW LABEL WARNINGS
EVEN AFTER CONTAINER IS EMPTIED. EMPTY CONTAINERS SHOULD BE TAKEN TO AN
APPROVED WASTE HANDLING SITE FOR RECYCLING OR DISPOSAL. DO NOT RE-USE EMPTY
CONTAINERS.
| 14. TRANSPORT INFORMATION | |
TRANSPORT OF DANGEROUS GOODS (TDG) PROOF OF CLASSIFICATION:
CLASSIFICATION METHOD:
CLASSIFIED AS PER PART 2, SECTIONS 2.1 - 2.8 OF THE TRANSPORTATION OF
DANGEROUS GOODS REGULATIONS. IF APPLICABLE, THE TECHNICAL NAME AND THE
CLASSIFICATION OF THE PRODUCT WILL APPEAR BELOW.
U.S. DEPARTMENT OF TRANSPORTATION (DOT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, (EACH NOT EXCEEDING 1 L CAPACITY)
HAZARD CLASS: LIMITED QUANTITY - US
SPECIAL PROVISIONS: N82
PACKAGING EXCEPTIONS: 306
PACKAGING NON BULK: NONE
PACKAGING BULK: NONE
TRANSPORTATION OF DANGEROUS GOODS (TDG - CANADA):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, CONTAINING SUBSTANCES IN CLASS 6.1, PACKING GROUP III
HAZARD CLASS: LIMITED QUANTITY - CANADA
IATA/ICAO (AIR):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME:
AEROSOLS, FLAMMABLE, CONTAINING SUBSTANCES IN DIVISION 6.1, PACKING GROUP
III
HAZARD CLASS: LIMITED QUANTITY - IATA
IMDG (MARINE TRANSPORT):
BASIC SHIPPING REQUIREMENTS:
UN NUMBER: UN1950
PROPER SHIPPING NAME: AEROSOLS
HAZARD CLASS: LIMITED QUANTITY - IMDG
DOT; IMDG; TDG:
LIMITED QUANTITTY FOR PACKAGES NOT PREPARED FOR AIR TRANSPORT
IATA: LIMITED QUANTITY MARKING FOR PACKAGES PREPARED FOR AIR TRANSPORT
| 15. REGULATORY INFORMATION | |
CANADIAN FEDERAL REGULATIONS:
THIS PRODUCT HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE HPR AND THE SDS CONTAINS ALL THE INFORMATION REQUIRED BY THE HPR.
CANADA CEPA SCHEDULE I: LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
CANADA NPRI VOCS WITH ADDITIONAL REPORTING REQUIREMENTS:
MASS REPORTING THRESHOLD/IDENTIFICATION NUMBER:
D-LIMONENE (CAS 5989-27-5): 1 TONNES
EXPORT CONTROL LIST (CEPA 1999, SCHEDULE 3): NOT LISTED.
GREENHOUSE GASES: NOT LISTED.
PRECURSOR CONTROL REGULATIONS: NOT REGULATED.
WHMIS 2015 EXEMPTIONS: NOT APPLICABLE
US FEDERAL REGULATIONS:
THIS PRODUCT IS A "HAZARDOUS CHEMICAL" AS DEFINED BY THE OSHA HAZARD
COMMUNICATION STANDARD, 29 CFR 1910.1200.
ALL CHEMICALS USED ARE ON THE TSCA INVENTORY. THIS CHEMICAL/PRODUCT IS NOT
AND CANNOT BE DISTRIBUTED IN COMMERCE (AS DEFINED IN TSCA SECTION 3(5)) OR
PROCESSED (AS DEFINED IN TSCA SECTION 3(13)) FOR CONSUMER PAINT OR COATING
REMOVAL.
TSCA SECTION 12(B) EXPORT NOTIFICATION (40 CFR 707, SUBPT. D):
METHYLENE CHLORIDE (CAS 75-09-2): 0.1% ANNUAL EXPORT NOTIFICATION REQUIRED.
CERCLA HAZARDOUS SUBSTANCE LIST (40 CFR 302.4):
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
US. OSHA SPECIFICALLY REGULATED SUBSTANCES (29 CFR 1910.1001-1050):
METHYLENE CHLORIDE (CAS 75-09-2):
CANCER
HEART
CENTRAL NERVOUS SYSTEM
LIVER
SKIN IRRITATION
EYE IRRITATION
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 (SARA):
HAZARD CATEGORIES:
IMMEDIATE HAZARD: YES
DELAYED HAZARD: YES
FIRE HAZARD: NO
REACTIVITY HAZARD: NO
PRESSURE HAZARD: YES
SARA 302 EXTREMELY HAZARDOUS SUBSTANCE: NO
SARA 311/312 HAZARDOUS CHEMICAL: NO
SARA 313 (TRI REPORTING):
CHEMICAL NAME CAS NUMBER % BY WT.
METHYLENE CHLORIDE 75-09-2 80-100*
OTHER FEDERAL REGULATIONS:
CLEAN AIR ACT (CAA) SECTION 112 HAZARDOUS AIR POLLUTANTS (HAPS) LIST:
METHYLENE CHLORIDE (CAS 75-09-2)
CLEAN AIR ACT (CAA) SECTION 112(R) ACCIDENTAL RELEASE PREVENTION (40 CFR
68.130): NOT REGULATED.
US STATE REGULATIONS: SEE BELOW
US - CALIFORNIA HAZARDOUS SUBSTANCES (DIRECTOR'S): LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
US - ILLINOIS CHEMICAL SAFETY ACT: LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2)
US - LOUISIANA SPILL REPORTING: LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
US - MICHIGAN CRITICAL MATERIALS REGISTER: PARAMETER NUMBER
METHYLENE CHLORIDE (CAS 75-09-2)
US - MINNESOTA HAZ SUBS: LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
US - NEW JERSEY RTK - SUBSTANCES: LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2)
US - NORTH CAROLINA TOXIC AIR POLLUTANTS: LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2)
US - PENNSYLVANIA RTK - HAZARDOUS SUBSTANCES: SPECIAL HAZARD
METHYLENE CHLORIDE (CAS 75-09-2)
US - TEXAS EFFECTS SCREENING LEVELS: LISTED SUBSTANCE
D-LIMONENE (CAS 5989-27-5): LISTED.
METHYLENE CHLORIDE (CAS 75-09-2): LISTED.
US - WASHINGTON CHEMICAL OF HIGH CONCERN TO CHILDREN: LISTED SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2)
US. MASSACHUSETTS RTK - SUBSTANCE LIST:
METHYLENE CHLORIDE (CAS 75-09-2)
US. NEW JERSEY WORKER AND COMMUNITY RIGHT-TO-KNOW ACT:
METHYLENE CHLORIDE (CAS 75-09-2)
US. PENNSYLVANIA WORKER AND COMMUNITY RIGHT-TO-KNOW LAW:
METHYLENE CHLORIDE (CAS 75-09-2)
US. RHODE ISLAND RTK: METHYLENE CHLORIDE (CAS 75-09-2)
US. CALIFORNIA PROPOSITION 65:
WARNING:
THIS PRODUCT CAN EXPOSE YOU TO METHYLENE CHLORIDE, WHICH IS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE CANCER. FOR MORE INFORMATION GO TO
WWW.P65WARNINGS.CA.GOV.
US - CALIFORNIA PROPOSITION 65 - CRT: LISTED DATE/CARCINOGENIC SUBSTANCE
METHYLENE CHLORIDE (CAS 75-09-2):
LISTED: APRIL 1, 1988
INVENTORY STATUS:
COUNTRY(S) OR INVENTORY NAME ON INVENTORY
REGION (YES/NO)*
CANADA DOMESTIC SUBSTANCES LIST (DSL) YES
CANADA NON-DOMESTIC SUBSTANCES LIST (NDSL) NO
UNITED STATES TOXIC SUBSTANCES CONTROL ACT (TSCA) YES
& PUERTO RICO INVENTORY
*A "YES" INDICATES THAT ALL COMPONENTS OF THIS PRODUCT COMPLY WITH THE
INVENTORY REQUIREMENTS ADMINISTERED BY THE GOVERNING COUNTRY(S)
| 16. OTHER INFORMATION | |
HEALTH 2*
FLAMMABILITY 1
PHYSICAL HAZARD 0
PERSONAL PROTECTION X
NFPA:
2
1
0
LEGEND:
SEVERE 4
SERIOUS 3
MODERATE 2
SLIGHT 1
MINIMAL 0
DISCLAIMER:
THE INFORMATION IN THE SHEET WAS WRITTEN BASED ON THE BEST KNOWLEDGE AND
EXPERIENCE CURRENTLY AVAILABLE. INFORMATION CONTAINED HEREIN WAS OBTAINED
FROM SOURCES CONSIDERED TECHNICALLY ACCURATE AND RELIABLE. WHILE EVERY
EFFORT HAS BEEN MADE TO ENSURE FULL DISCLOSURE OF PRODUCT HAZARDS, IN SOME
CASES DATA IS NOT AVAILABLE AND IS SO STATED. SINCE CONDITIONS OF ACTUAL
PRODUCT USE ARE BEYOND CONTROL OF THE SUPPLIER, IT IS ASSUMED THAT USERS OF
THIS MATERIAL HAVE BEEN FULLY TRAINED ACCORDING TO THE REQUIREMENTS OF ALL
APPLICABLE LEGISLATION AND REGULATORY INSTRUMENTS. NO WARRANTY, EXPRESSED
OR IMPLIED, IS MADE AND SUPPLIER WILL NOT BE LIABLE FOR ANY LOSSES,
INJURIES OR CONSEQUENTIAL DAMAGES WHICH MAY RESULT FROM THE USE OF OR
RELIANCE ON ANY INFORMATION CONTAINED IN THIS DOCUMENT.
ISSUE DATE: 26-AUGUST-2019
VERSION #: 1.1
EFFECTIVE DATE: 26-AUGUST-2019
PREPARED BY: NU-CALGON
TECHNICAL SERVICE PHONE: (314) 469-7000
OTHER INFORMATION:
FOR AN UPDATED SDS, PLEASE CONTACT THE SUPPLIER/MANUFACTURER LISTED AT THE
BEGINNING OF THIS DOCUMENT.
#21713
4132-20 (CANADA/US GHS)